data_rovis41_0m _audit_creation_method SHELXL-97 _chemical_name_systematic ; ? ; _chemical_name_common ? _chemical_melting_point ? _chemical_formula_moiety ? _chemical_formula_sum 'C34 H50 Cl N O2 P Rh' _chemical_formula_weight 674.08 loop_ _atom_type_symbol _atom_type_description _atom_type_scat_dispersion_real _atom_type_scat_dispersion_imag _atom_type_scat_source 'C' 'C' 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' 'H' 'H' 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' 'N' 'N' 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' 'O' 'O' 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' 'Cl' 'Cl' 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' 'Rh' 'Rh' -1.1178 0.9187 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' 'P' 'P' 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4' _symmetry_cell_setting Triclinic _symmetry_space_group_name_H-M P-1 loop_ _symmetry_equiv_pos_as_xyz 'x, y, z' '-x, -y, -z' _cell_length_a 10.4105(5) _cell_length_b 10.8685(6) _cell_length_c 16.5368(10) _cell_angle_alpha 77.003(3) _cell_angle_beta 76.360(2) _cell_angle_gamma 64.354(2) _cell_volume 1622.99(15) _cell_formula_units_Z 2 _cell_measurement_temperature 296(2) _cell_measurement_reflns_used 9703 _cell_measurement_theta_min 2.30 _cell_measurement_theta_max 33.29 _exptl_crystal_description Trapazoidal _exptl_crystal_colour yellow _exptl_crystal_size_max 0.70 _exptl_crystal_size_mid 0.37 _exptl_crystal_size_min 0.17 _exptl_crystal_density_meas 'not determined' _exptl_crystal_density_diffrn 1.379 _exptl_crystal_density_method 'not measured' _exptl_crystal_F_000 708 _exptl_absorpt_coefficient_mu 0.688 _exptl_absorpt_correction_type multi-scan _exptl_absorpt_correction_T_min 0.6455 _exptl_absorpt_correction_T_max 0.8890 _exptl_absorpt_process_details 'Sheldrick, G. M. (2008) SADABS. University of G\"ottingen, Germany.' _exptl_special_details ; ? ; _diffrn_ambient_temperature 296(2) _diffrn_radiation_wavelength 0.71073 _diffrn_radiation_type MoK\a _diffrn_radiation_source 'fine-focus sealed tube' _diffrn_radiation_monochromator graphite _diffrn_measurement_device_type 'CCD area detector' _diffrn_measurement_method 'phi and omega scans' _diffrn_detector_area_resol_mean ? _diffrn_standards_number ? _diffrn_standards_interval_count ? _diffrn_standards_interval_time ? _diffrn_standards_decay_% ? _diffrn_reflns_number 19235 _diffrn_reflns_av_R_equivalents 0.0176 _diffrn_reflns_av_sigmaI/netI 0.0358 _diffrn_reflns_limit_h_min -16 _diffrn_reflns_limit_h_max 13 _diffrn_reflns_limit_k_min -16 _diffrn_reflns_limit_k_max 15 _diffrn_reflns_limit_l_min -25 _diffrn_reflns_limit_l_max 25 _diffrn_reflns_theta_min 2.10 _diffrn_reflns_theta_max 33.37 _reflns_number_total 12140 _reflns_number_gt 10644 _reflns_threshold_expression >2sigma(I) _computing_data_collection 'APEX2 (Bruker, 2009)' _computing_cell_refinement 'APEX2 (Bruker, 2009)' _computing_data_reduction 'APEX2 (Bruker, 2009)' _computing_structure_solution 'XS (Sheldrick, 2008)' _computing_structure_refinement 'XL (Sheldrick, 2008)' _computing_molecular_graphics 'APEX2 (Bruker, 2009)' _computing_publication_material 'APEX2 (Bruker, 2009)' _refine_special_details ; Refinement of F^2^ against ALL reflections. The weighted R-factor wR and goodness of fit S are based on F^2^, conventional R-factors R are based on F, with F set to zero for negative F^2^. The threshold expression of F^2^ > 2sigma(F^2^) is used only for calculating R-factors(gt) etc. and is not relevant to the choice of reflections for refinement. R-factors based on F^2^ are statistically about twice as large as those based on F, and R- factors based on ALL data will be even larger. ; _refine_ls_structure_factor_coef Fsqd _refine_ls_matrix_type full _refine_ls_weighting_scheme calc _refine_ls_weighting_details 'calc w=1/[\s^2^(Fo^2^)+(0.0228P)^2^+1.6833P] where P=(Fo^2^+2Fc^2^)/3' _atom_sites_solution_primary direct _atom_sites_solution_secondary difmap _atom_sites_solution_hydrogens geom _refine_ls_hydrogen_treatment mixed _refine_ls_extinction_method none _refine_ls_extinction_coef ? _refine_ls_number_reflns 12140 _refine_ls_number_parameters 389 _refine_ls_number_restraints 0 _refine_ls_R_factor_all 0.0410 _refine_ls_R_factor_gt 0.0336 _refine_ls_wR_factor_ref 0.0792 _refine_ls_wR_factor_gt 0.0761 _refine_ls_goodness_of_fit_ref 1.104 _refine_ls_restrained_S_all 1.104 _refine_ls_shift/su_max 0.001 _refine_ls_shift/su_mean 0.000 loop_ _atom_site_label _atom_site_type_symbol _atom_site_fract_x _atom_site_fract_y _atom_site_fract_z _atom_site_U_iso_or_equiv _atom_site_adp_type _atom_site_occupancy _atom_site_symmetry_multiplicity _atom_site_calc_flag _atom_site_refinement_flags _atom_site_disorder_assembly _atom_site_disorder_group C1 C 0.26789(18) 0.64116(18) 0.41771(11) 0.0175(3) Uani 1 1 d . . . H1 H 0.2976 0.6842 0.4478 0.021 Uiso 1 1 calc R . . C2 C 0.37110(17) 0.56003(16) 0.35856(10) 0.0133(3) Uani 1 1 d . . . C3 C 0.31914(16) 0.49670(16) 0.31672(10) 0.0119(3) Uani 1 1 d . . . C4 C 0.17252(16) 0.52665(16) 0.32396(10) 0.0133(3) Uani 1 1 d . . . C5 C 0.12308(18) 0.66111(18) 0.43398(11) 0.0185(3) Uani 1 1 d . . . C6 C 0.07283(17) 0.60611(17) 0.38547(11) 0.0159(3) Uani 1 1 d . . . C7 C 0.0212(2) 0.7467(2) 0.50142(14) 0.0293(4) Uani 1 1 d . . . H7A H 0.0739 0.7761 0.5279 0.044 Uiso 1 1 calc R . . H7B H -0.0220 0.6923 0.5427 0.044 Uiso 1 1 calc R . . H7C H -0.0528 0.8260 0.4765 0.044 Uiso 1 1 calc R . . C8 C -0.08416(18) 0.6305(2) 0.40041(12) 0.0222(3) Uani 1 1 d . . . H8A H -0.0977 0.5748 0.3683 0.033 Uiso 1 1 calc R . . H8B H -0.1408 0.7260 0.3834 0.033 Uiso 1 1 calc R . . H8C H -0.1141 0.6061 0.4591 0.033 Uiso 1 1 calc R . . C9 C 0.52511(17) 0.55515(18) 0.33543(11) 0.0167(3) Uani 1 1 d . . . C10 C 0.5482(2) 0.6415(2) 0.38790(12) 0.0234(4) Uani 1 1 d . . . H10A H 0.5377 0.6035 0.4462 0.035 Uiso 1 1 calc R . . H10B H 0.4779 0.7347 0.3804 0.035 Uiso 1 1 calc R . . H10C H 0.6433 0.6403 0.3700 0.035 Uiso 1 1 calc R . . C11 C 0.5462(2) 0.6175(2) 0.24274(12) 0.0238(4) Uani 1 1 d . . . H11A H 0.6423 0.6144 0.2266 0.036 Uiso 1 1 calc R . . H11B H 0.4777 0.7115 0.2353 0.036 Uiso 1 1 calc R . . H11C H 0.5319 0.5656 0.2083 0.036 Uiso 1 1 calc R . . C12 C 0.64162(19) 0.4076(2) 0.34846(13) 0.0233(4) Uani 1 1 d . . . H12A H 0.6231 0.3656 0.4051 0.035 Uiso 1 1 calc R . . H12B H 0.7348 0.4109 0.3385 0.035 Uiso 1 1 calc R . . H12C H 0.6396 0.3545 0.3099 0.035 Uiso 1 1 calc R . . C13 C 0.65769(19) 0.0718(2) 0.36058(12) 0.0222(3) Uani 1 1 d . . . H13A H 0.7027 0.0984 0.3940 0.033 Uiso 1 1 calc R . . H13B H 0.7074 0.0721 0.3038 0.033 Uiso 1 1 calc R . . H13C H 0.6619 -0.0191 0.3831 0.033 Uiso 1 1 calc R . . C14 C 0.4216(2) 0.1871(2) 0.44532(11) 0.0251(4) Uani 1 1 d . . . H14A H 0.3942 0.1106 0.4667 0.038 Uiso 1 1 calc R . . H14B H 0.3365 0.2711 0.4419 0.038 Uiso 1 1 calc R . . H14C H 0.4777 0.1913 0.4823 0.038 Uiso 1 1 calc R . . C15 C 0.12405(16) 0.47963(17) 0.26300(10) 0.0139(3) Uani 1 1 d . . . C16 C 0.16842(16) 0.33843(17) 0.26275(10) 0.0143(3) Uani 1 1 d . . . C17 C 0.10713(17) 0.28631(19) 0.21943(11) 0.0176(3) Uani 1 1 d . . . C18 C 0.01642(19) 0.3863(2) 0.16458(12) 0.0217(3) Uani 1 1 d . . . H18 H -0.0247 0.3567 0.1328 0.026 Uiso 1 1 calc R . . C19 C -0.01612(18) 0.5260(2) 0.15451(11) 0.0207(3) Uani 1 1 d . . . C20 C 0.03418(17) 0.57599(18) 0.20651(11) 0.0169(3) Uani 1 1 d . . . C21 C -0.0045(2) 0.72790(19) 0.19868(12) 0.0223(3) Uani 1 1 d . . . H21A H 0.0527 0.7429 0.2302 0.034 Uiso 1 1 calc R . . H21B H -0.1049 0.7738 0.2203 0.034 Uiso 1 1 calc R . . H21C H 0.0140 0.7640 0.1406 0.034 Uiso 1 1 calc R . . C22 C -0.1070(2) 0.6240(2) 0.08930(13) 0.0284(4) Uani 1 1 d . . . H22A H -0.1369 0.5738 0.0620 0.043 Uiso 1 1 calc R . . H22B H -0.0513 0.6671 0.0483 0.043 Uiso 1 1 calc R . . H22C H -0.1905 0.6933 0.1161 0.043 Uiso 1 1 calc R . . C23 C 0.12644(19) 0.1357(2) 0.22766(13) 0.0224(4) Uani 1 1 d . . . C24 C 0.1991(2) 0.0396(2) 0.30204(14) 0.0271(4) Uani 1 1 d . . . H24A H 0.1942 -0.0481 0.3073 0.041 Uiso 1 1 calc R . . H24B H 0.1504 0.0796 0.3527 0.041 Uiso 1 1 calc R . . H24C H 0.2983 0.0272 0.2926 0.041 Uiso 1 1 calc R . . C25 C 0.2139(2) 0.0773(2) 0.14603(15) 0.0326(5) Uani 1 1 d . . . H25A H 0.1661 0.1339 0.0995 0.049 Uiso 1 1 calc R . . H25B H 0.2216 -0.0150 0.1498 0.049 Uiso 1 1 calc R . . H25C H 0.3086 0.0765 0.1378 0.049 Uiso 1 1 calc R . . C26 C -0.0240(2) 0.1330(2) 0.24115(18) 0.0360(5) Uani 1 1 d . . . H26A H -0.0726 0.1885 0.1947 0.054 Uiso 1 1 calc R . . H26B H -0.0793 0.1690 0.2922 0.054 Uiso 1 1 calc R . . H26C H -0.0138 0.0398 0.2450 0.054 Uiso 1 1 calc R . . C27 C 0.6145(2) 0.08153(18) 0.02889(11) 0.0194(3) Uani 1 1 d . . . C28 C 0.74039(19) 0.05500(18) 0.05517(11) 0.0193(3) Uani 1 1 d . . . C29 C 0.8267(2) 0.14181(19) 0.02744(13) 0.0237(4) Uani 1 1 d . . . H29A H 0.8802 0.1246 -0.0283 0.028 Uiso 1 1 calc R . . H29B H 0.8961 0.1138 0.0652 0.028 Uiso 1 1 calc R . . C30 C 0.73457(19) 0.29710(19) 0.02550(12) 0.0217(3) Uani 1 1 d . . . H30A H 0.7932 0.3417 0.0329 0.026 Uiso 1 1 calc R . . H30B H 0.7044 0.3349 -0.0292 0.026 Uiso 1 1 calc R . . C31 C 0.60103(18) 0.33007(17) 0.09321(11) 0.0162(3) Uani 1 1 d . . . C32 C 0.46412(18) 0.34642(17) 0.08227(11) 0.0162(3) Uani 1 1 d . . . C33 C 0.4271(2) 0.32340(19) 0.00565(11) 0.0214(3) Uani 1 1 d . . . H33A H 0.4094 0.4061 -0.0352 0.026 Uiso 1 1 calc R . . H33B H 0.3384 0.3087 0.0216 0.026 Uiso 1 1 calc R . . C34 C 0.5448(2) 0.2006(2) -0.03588(12) 0.0231(4) Uani 1 1 d . . . H34A H 0.5027 0.1709 -0.0702 0.028 Uiso 1 1 calc R . . H34B H 0.6177 0.2291 -0.0724 0.028 Uiso 1 1 calc R . . Cl3 Cl 0.58955(5) -0.06873(4) 0.22467(3) 0.02093(8) Uani 1 1 d . . . N1 N 0.50699(15) 0.16908(15) 0.36196(9) 0.0158(3) Uani 1 1 d . . . O1 O 0.27737(12) 0.25079(12) 0.31051(7) 0.0142(2) Uani 1 1 d . . . O2 O 0.41352(12) 0.40650(12) 0.25989(7) 0.0124(2) Uani 1 1 d . . . P1 P 0.44035(4) 0.24374(4) 0.27493(3) 0.01183(7) Uani 1 1 d . . . Rh1 Rh 0.560215(13) 0.153633(13) 0.155917(8) 0.01234(3) Uani 1 1 d . . . H5 H 0.381(2) 0.401(2) 0.1165(14) 0.017(5) Uiso 1 1 d . . . H3 H 0.784(2) -0.030(2) 0.0836(13) 0.014(5) Uiso 1 1 d . . . H2 H 0.604(2) 0.377(2) 0.1363(14) 0.019(5) Uiso 1 1 d . . . H4 H 0.575(3) 0.018(3) 0.0435(16) 0.029(6) Uiso 1 1 d . . . loop_ _atom_site_aniso_label _atom_site_aniso_U_11 _atom_site_aniso_U_22 _atom_site_aniso_U_33 _atom_site_aniso_U_23 _atom_site_aniso_U_13 _atom_site_aniso_U_12 C1 0.0190(7) 0.0184(8) 0.0168(7) -0.0073(6) -0.0027(6) -0.0069(6) C2 0.0141(6) 0.0126(7) 0.0136(7) -0.0021(5) -0.0032(5) -0.0050(5) C3 0.0123(6) 0.0112(6) 0.0112(6) -0.0032(5) -0.0002(5) -0.0039(5) C4 0.0122(6) 0.0131(7) 0.0145(7) -0.0033(5) -0.0016(5) -0.0045(5) C5 0.0171(7) 0.0184(8) 0.0182(8) -0.0091(6) 0.0016(6) -0.0047(6) C6 0.0119(6) 0.0158(7) 0.0181(7) -0.0048(6) -0.0002(5) -0.0036(5) C7 0.0231(9) 0.0350(11) 0.0299(10) -0.0220(9) 0.0046(7) -0.0077(8) C8 0.0123(7) 0.0251(9) 0.0270(9) -0.0099(7) 0.0020(6) -0.0050(6) C9 0.0145(7) 0.0204(8) 0.0179(7) -0.0060(6) -0.0013(5) -0.0085(6) C10 0.0221(8) 0.0305(10) 0.0248(9) -0.0096(7) -0.0038(7) -0.0143(7) C11 0.0302(9) 0.0293(10) 0.0197(8) -0.0057(7) 0.0022(7) -0.0212(8) C12 0.0153(7) 0.0220(9) 0.0333(10) -0.0075(7) -0.0061(7) -0.0052(6) C13 0.0164(7) 0.0230(9) 0.0211(8) 0.0004(7) -0.0043(6) -0.0035(6) C14 0.0259(9) 0.0280(10) 0.0138(8) -0.0016(7) -0.0005(6) -0.0058(7) C15 0.0111(6) 0.0165(7) 0.0144(7) -0.0039(6) -0.0014(5) -0.0053(5) C16 0.0102(6) 0.0173(7) 0.0151(7) -0.0048(6) 0.0000(5) -0.0050(5) C17 0.0137(7) 0.0220(8) 0.0199(8) -0.0105(6) 0.0017(6) -0.0081(6) C18 0.0176(7) 0.0314(10) 0.0209(8) -0.0119(7) -0.0032(6) -0.0101(7) C19 0.0127(7) 0.0309(9) 0.0170(8) -0.0050(7) -0.0029(6) -0.0064(7) C20 0.0112(6) 0.0195(8) 0.0175(7) -0.0028(6) -0.0017(5) -0.0042(6) C21 0.0192(8) 0.0184(8) 0.0248(9) 0.0011(7) -0.0066(6) -0.0038(6) C22 0.0207(8) 0.0400(12) 0.0222(9) -0.0040(8) -0.0087(7) -0.0077(8) C23 0.0161(7) 0.0225(9) 0.0327(10) -0.0164(7) 0.0037(7) -0.0092(6) C24 0.0268(9) 0.0198(9) 0.0371(11) -0.0081(8) 0.0025(8) -0.0132(7) C25 0.0294(10) 0.0331(11) 0.0366(12) -0.0234(9) 0.0046(8) -0.0098(9) C26 0.0203(9) 0.0307(11) 0.0650(16) -0.0217(11) 0.0011(9) -0.0142(8) C27 0.0272(8) 0.0149(7) 0.0149(7) -0.0066(6) -0.0005(6) -0.0065(6) C28 0.0204(8) 0.0135(7) 0.0179(8) -0.0054(6) 0.0033(6) -0.0029(6) C29 0.0179(8) 0.0195(8) 0.0265(9) -0.0044(7) 0.0059(6) -0.0052(6) C30 0.0204(8) 0.0199(8) 0.0226(9) -0.0043(7) 0.0045(6) -0.0093(7) C31 0.0194(7) 0.0117(7) 0.0163(7) -0.0033(6) 0.0009(6) -0.0065(6) C32 0.0176(7) 0.0126(7) 0.0147(7) -0.0020(6) -0.0018(5) -0.0031(6) C33 0.0244(8) 0.0186(8) 0.0183(8) -0.0016(6) -0.0074(6) -0.0043(7) C34 0.0323(9) 0.0202(8) 0.0168(8) -0.0053(6) -0.0051(7) -0.0084(7) Cl3 0.02174(18) 0.01195(17) 0.0247(2) -0.00146(14) 0.00193(15) -0.00604(14) N1 0.0144(6) 0.0163(6) 0.0131(6) -0.0007(5) -0.0018(5) -0.0038(5) O1 0.0113(5) 0.0139(5) 0.0163(5) -0.0023(4) -0.0004(4) -0.0049(4) O2 0.0119(5) 0.0116(5) 0.0132(5) -0.0044(4) 0.0006(4) -0.0044(4) P1 0.01081(16) 0.01128(17) 0.01233(17) -0.00256(13) -0.00035(13) -0.00375(13) Rh1 0.01215(5) 0.00985(5) 0.01325(6) -0.00308(4) 0.00022(4) -0.00321(4) _geom_special_details ; All esds (except the esd in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell esds are taken into account individually in the estimation of esds in distances, angles and torsion angles; correlations between esds in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell esds is used for estimating esds involving l.s. planes. ; loop_ _geom_bond_atom_site_label_1 _geom_bond_atom_site_label_2 _geom_bond_distance _geom_bond_site_symmetry_2 _geom_bond_publ_flag C1 C5 1.394(2) . ? C1 C2 1.400(2) . ? C2 C3 1.399(2) . ? C2 C9 1.538(2) . ? C3 C4 1.397(2) . ? C3 O2 1.3982(18) . ? C4 C6 1.407(2) . ? C4 C15 1.492(2) . ? C5 C6 1.400(2) . ? C5 C7 1.513(2) . ? C6 C8 1.505(2) . ? C9 C10 1.533(2) . ? C9 C11 1.536(3) . ? C9 C12 1.540(3) . ? C13 N1 1.462(2) . ? C14 N1 1.457(2) . ? C15 C16 1.399(2) . ? C15 C20 1.403(2) . ? C16 C17 1.397(2) . ? C16 O1 1.402(2) . ? C17 C18 1.403(3) . ? C17 C23 1.538(3) . ? C18 C19 1.383(3) . ? C19 C20 1.407(2) . ? C19 C22 1.512(3) . ? C20 C21 1.503(3) . ? C23 C24 1.534(3) . ? C23 C25 1.536(3) . ? C23 C26 1.541(3) . ? C27 C28 1.369(3) . ? C27 C34 1.510(3) . ? C27 Rh1 2.2678(17) . ? C28 C29 1.501(3) . ? C28 Rh1 2.2432(17) . ? C29 C30 1.536(3) . ? C30 C31 1.526(2) . ? C31 C32 1.409(2) . ? C31 Rh1 2.1299(17) . ? C32 C33 1.508(2) . ? C32 Rh1 2.1182(17) . ? C33 C34 1.534(3) . ? Cl3 Rh1 2.3485(4) . ? N1 P1 1.6337(15) . ? O1 P1 1.6333(12) . ? O2 P1 1.6359(12) . ? P1 Rh1 2.2451(4) . ? loop_ _geom_angle_atom_site_label_1 _geom_angle_atom_site_label_2 _geom_angle_atom_site_label_3 _geom_angle _geom_angle_site_symmetry_1 _geom_angle_site_symmetry_3 _geom_angle_publ_flag C5 C1 C2 123.69(15) . . ? C3 C2 C1 114.97(14) . . ? C3 C2 C9 123.15(14) . . ? C1 C2 C9 121.57(14) . . ? C4 C3 O2 116.60(13) . . ? C4 C3 C2 122.91(14) . . ? O2 C3 C2 120.33(13) . . ? C3 C4 C6 119.67(14) . . ? C3 C4 C15 119.01(14) . . ? C6 C4 C15 121.25(14) . . ? C1 C5 C6 119.50(15) . . ? C1 C5 C7 119.57(16) . . ? C6 C5 C7 120.88(16) . . ? C5 C6 C4 118.45(15) . . ? C5 C6 C8 120.17(15) . . ? C4 C6 C8 121.37(15) . . ? C10 C9 C11 107.65(15) . . ? C10 C9 C2 111.50(14) . . ? C11 C9 C2 107.96(14) . . ? C10 C9 C12 107.42(15) . . ? C11 C9 C12 109.48(15) . . ? C2 C9 C12 112.70(14) . . ? C16 C15 C20 120.09(15) . . ? C16 C15 C4 119.49(14) . . ? C20 C15 C4 120.42(15) . . ? C17 C16 C15 122.79(15) . . ? C17 C16 O1 121.46(15) . . ? C15 C16 O1 115.74(14) . . ? C16 C17 C18 114.22(16) . . ? C16 C17 C23 127.09(17) . . ? C18 C17 C23 118.68(16) . . ? C19 C18 C17 124.55(16) . . ? C18 C19 C20 119.32(16) . . ? C18 C19 C22 120.29(17) . . ? C20 C19 C22 120.39(18) . . ? C15 C20 C19 117.89(16) . . ? C15 C20 C21 121.95(16) . . ? C19 C20 C21 120.13(16) . . ? C24 C23 C25 108.90(17) . . ? C24 C23 C17 115.06(15) . . ? C25 C23 C17 109.30(17) . . ? C24 C23 C26 106.14(18) . . ? C25 C23 C26 108.87(17) . . ? C17 C23 C26 108.39(15) . . ? C28 C27 C34 124.64(17) . . ? C28 C27 Rh1 71.35(10) . . ? C34 C27 Rh1 110.21(11) . . ? C27 C28 C29 125.78(17) . . ? C27 C28 Rh1 73.31(10) . . ? C29 C28 Rh1 107.07(11) . . ? C28 C29 C30 113.71(15) . . ? C31 C30 C29 113.04(15) . . ? C32 C31 C30 124.82(16) . . ? C32 C31 Rh1 70.19(10) . . ? C30 C31 Rh1 113.59(11) . . ? C31 C32 C33 126.44(15) . . ? C31 C32 Rh1 71.09(10) . . ? C33 C32 Rh1 109.09(11) . . ? C32 C33 C34 113.89(15) . . ? C27 C34 C33 111.41(15) . . ? C14 N1 C13 115.22(14) . . ? C14 N1 P1 123.53(12) . . ? C13 N1 P1 121.16(12) . . ? C16 O1 P1 117.76(10) . . ? C3 O2 P1 122.20(10) . . ? O1 P1 N1 97.23(7) . . ? O1 P1 O2 101.98(6) . . ? N1 P1 O2 109.12(7) . . ? O1 P1 Rh1 119.26(5) . . ? N1 P1 Rh1 118.68(5) . . ? O2 P1 Rh1 108.89(4) . . ? C32 Rh1 C31 38.73(7) . . ? C32 Rh1 C28 96.83(7) . . ? C31 Rh1 C28 81.16(7) . . ? C32 Rh1 P1 91.19(5) . . ? C31 Rh1 P1 95.11(5) . . ? C28 Rh1 P1 161.50(5) . . ? C32 Rh1 C27 80.89(7) . . ? C31 Rh1 C27 88.00(7) . . ? C28 Rh1 C27 35.34(7) . . ? P1 Rh1 C27 163.15(5) . . ? C32 Rh1 Cl3 157.29(5) . . ? C31 Rh1 Cl3 162.92(5) . . ? C28 Rh1 Cl3 88.04(5) . . ? P1 Rh1 Cl3 90.953(16) . . ? C27 Rh1 Cl3 90.81(5) . . ? _diffrn_measured_fraction_theta_max 0.963 _diffrn_reflns_theta_full 33.37 _diffrn_measured_fraction_theta_full 0.963 _refine_diff_density_max 1.056 _refine_diff_density_min -0.844 _refine_diff_density_rms 0.093