This PDF file includes:

• fig. S1. FTIR spectrum of HB-Pd/C and HB.
  
• fig. S2. TEM image of large particle formation after homogeneous Pd(TFA)2-catalyzed reaction.
  
• fig. S3. Hot filtration test of HB-Pd/C–catalyzed aerobic oxidation reaction.
  
• fig. S4. XPS spectra of CB-Pd/C before and after reaction in Pd 3d region.
  
• fig. S5. TEM morphology and size distribution of BB-Pd/C and catalytic behavior.

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