This PDF file includes:

• Section S1. EINS measurement and data analysis
• Section S2. PNIPAM model development
• Section S3. MD simulations procedure
• Section S4. Reproducibility of numerical results
• Section S5. Calculation of I(Q) from numerical simulations
• Fig. S1. EINS data for PNIPAM 43 wt % sample.
• Fig. S2. EINS data for PNIPAM 60 wt % sample.
• Fig. S3. D₂O contribution to EINS spectra.
• Fig. S4. Schematic representation of the microgel network model.
• Fig. S5. Aging effect on water dynamics.
• Fig. S6. Aging effect on PNIPAM dynamics.
• Fig. S7. I(Q,0) from numerical simulations.
• Table S1. Thermal protocol followed during the EINS measurements.
• References (38–45)

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