data_I _shelx_title ' x730out_a.res in C2/c' _shelx_refln_list_code 4 _shelx_F_calc_maximum 498.59 _exptl_crystal_F_000 1872.00 _reflns_d_resolution_high 0.7703 loop_ _space_group_symop_operation_xyz 'x, y, z' '-x, y, -z+1/2' 'x+1/2, y+1/2, z' '-x+1/2, y+1/2, -z+1/2' '-x, -y, -z' 'x, -y, z-1/2' '-x+1/2, -y+1/2, -z' 'x+1/2, -y+1/2, z-1/2' _cell_length_a 19.9356 _cell_length_b 10.6032 _cell_length_c 18.6922 _cell_angle_alpha 90.000 _cell_angle_beta 105.925 _cell_angle_gamma 90.000 _shelx_F_squared_multiplier 1.000 loop_ _refln_index_h _refln_index_k _refln_index_l _refln_F_squared_calc _refln_F_squared_meas _refln_F_squared_sigma _refln_observed_status 2 0 0 85512.83 61598.11 841.21 o 4 0 0 228.41 366.72 20.20 o 6 0 0 2934.36 2944.50 49.79 o 8 0 0 19877.96 20500.88 250.13 o 10 0 0 3065.68 2849.83 173.04 o 12 0 0 2687.90 2643.35 144.33 o 14 0 0 9644.10 8846.57 258.57 o 16 0 0 36545.60 38120.49 1345.21 o 18 0 0 912.00 1027.86 124.42 o 20 0 0 4855.76 4744.17 486.69 o 22 0 0 573.43 668.51 76.99 o 24 0 0 26.84 0.53 28.71 o 3 1 0 732.71 559.89 21.89 o 5 1 0 10108.09 10065.67 136.07 o 7 1 0 44605.22 46710.22 566.61 o 9 1 0 6283.38 6141.03 114.37 o 11 1 0 24371.86 23638.60 319.63 o 13 1 0 3487.05 3324.49 175.52 o 15 1 0 12.43 15.45 34.86 o 17 1 0 12788.72 13192.61 471.35 o 19 1 0 179.59 204.58 33.85 o 21 1 0 1629.49 1737.75 154.64 o 23 1 0 1556.77 1453.50 172.48 o 0 2 0 36543.64 36829.50 533.49 o 2 2 0 2157.58 2452.94 41.37 o 4 2 0 1539.40 1472.69 40.17 o 6 2 0 33299.46 31519.84 288.18 o 8 2 0 7790.25 8305.62 152.36 o 10 2 0 70778.62 72267.37 867.63 o 12 2 0 4.92 31.21 27.90 o 14 2 0 4771.28 4748.38 155.64 o 16 2 0 2236.60 2296.31 119.59 o 18 2 0 2425.55 2431.22 157.80 o 20 2 0 329.76 382.19 72.49 o 22 2 0 2569.85 2786.90 183.86 o 24 2 0 210.92 185.22 50.81 o 1 3 0 6016.47 5454.88 71.61 o 3 3 0 5092.20 5212.93 124.38 o 5 3 0 5129.39 4791.31 105.77 o 7 3 0 2288.19 2994.43 68.28 o 9 3 0 73.72 103.99 12.41 o 11 3 0 34556.85 36278.09 437.10 o 13 3 0 6837.53 6611.91 228.15 o 15 3 0 14.78 34.55 18.49 o 17 3 0 11765.49 12088.07 328.89 o 19 3 0 248.71 349.63 51.01 o 21 3 0 1454.93 1637.33 115.49 o 23 3 0 160.23 82.97 46.76 o 0 4 0 49041.02 46158.33 1173.17 o 2 4 0 2299.96 2122.36 72.10 o 4 4 0 299.00 267.29 21.21 o 6 4 0 2844.95 2851.86 68.14 o 8 4 0 1132.32 1134.55 61.59 o 10 4 0 13038.33 12847.65 260.20 o 12 4 0 9939.26 10502.23 244.39 o 14 4 0 3006.26 3153.49 130.54 o 16 4 0 13200.41 13214.26 354.20 o 18 4 0 352.46 397.77 44.98 o 20 4 0 1082.18 1072.43 102.05 o 22 4 0 234.84 314.38 55.08 o 1 5 0 29211.22 29384.74 511.77 o 3 5 0 1230.41 1511.24 60.86 o 5 5 0 766.04 795.45 75.86 o 7 5 0 4834.90 5022.83 126.67 o 9 5 0 27606.15 30472.79 581.54 o 11 5 0 3405.52 3262.81 132.39 o 13 5 0 2201.02 2193.36 75.62 o 15 5 0 724.24 639.69 50.11 o 17 5 0 4783.55 4872.41 310.68 o 19 5 0 44.48 81.06 27.91 o 21 5 0 1133.97 1131.28 137.03 o 23 5 0 147.15 211.47 56.38 o 0 6 0 24542.41 25870.50 756.89 o 2 6 0 19637.26 18613.91 335.07 o 4 6 0 13441.60 13901.10 328.54 o 6 6 0 22446.10 24098.99 296.38 o 8 6 0 206.87 228.85 29.26 o 10 6 0 27419.26 27678.07 495.74 o 12 6 0 273.75 233.12 30.63 o 14 6 0 7042.17 6995.67 168.13 o 16 6 0 0.22 42.11 16.54 o 18 6 0 4185.64 4091.57 264.30 o 20 6 0 78.60 44.17 19.93 o 22 6 0 2230.30 1934.32 174.58 o 1 7 0 1645.45 1919.21 169.59 o 3 7 0 504.49 695.79 78.07 o 5 7 0 147.66 125.78 15.24 o 7 7 0 7805.34 7737.90 253.00 o 9 7 0 4683.90 4762.21 199.56 o 11 7 0 1532.96 1403.08 114.00 o 13 7 0 6089.62 5991.87 224.06 o 15 7 0 17.64 47.30 18.12 o 17 7 0 877.04 702.11 80.09 o 19 7 0 456.68 410.63 74.07 o 21 7 0 547.21 502.22 77.70 o 0 8 0 414.05 468.26 76.59 o 2 8 0 20.21 34.52 14.68 o 4 8 0 5749.71 5408.28 251.51 o 6 8 0 96.88 112.36 24.31 o 8 8 0 2177.95 2119.36 112.08 o 10 8 0 279.28 366.22 37.43 o 12 8 0 1611.53 1607.59 83.80 o 14 8 0 249.94 265.37 35.10 o 16 8 0 208.42 214.91 35.37 o 18 8 0 0.28 45.08 36.58 o 20 8 0 5700.53 5595.66 360.13 o 1 9 0 2.27 -9.49 16.51 o 3 9 0 18264.39 18895.19 434.66 o 5 9 0 1673.17 1697.34 108.75 o 7 9 0 2616.15 2610.99 111.20 o 9 9 0 16.59 55.65 29.15 o 11 9 0 114.82 98.65 33.03 o 13 9 0 3320.87 3233.78 150.67 o 15 9 0 3.10 51.90 18.65 o 17 9 0 2.18 7.59 21.95 o 0 10 0 637.84 560.61 66.05 o 2 10 0 8187.12 8781.64 343.74 o 4 10 0 2175.33 2488.69 344.22 o 6 10 0 32.41 77.06 40.70 o 8 10 0 425.31 433.99 45.71 o 10 10 0 4674.67 4413.65 264.12 o 12 10 0 306.25 335.90 47.33 o 14 10 0 3672.77 3494.16 238.77 o 16 10 0 630.58 677.90 81.79 o 1 11 0 750.09 667.51 71.20 o 3 11 0 9208.07 9382.62 377.36 o 5 11 0 582.07 615.77 71.86 o 7 11 0 2340.68 2626.55 182.15 o 9 11 0 5708.66 5897.23 257.34 o 11 11 0 320.02 327.78 49.74 o 13 11 0 1963.94 1554.41 135.31 o 0 12 0 1254.99 1407.76 171.74 o 2 12 0 1152.27 1041.36 84.75 o 4 12 0 4333.58 4325.41 293.34 o 6 12 0 3980.22 4353.53 251.59 o 8 12 0 12179.65 13458.98 880.79 o 10 12 0 437.53 474.75 65.90 o 12 12 0 511.74 575.98 74.65 o 1 13 0 224.61 357.31 74.34 o 3 13 0 2998.73 3028.73 230.77 o 5 13 0 1429.68 1263.47 122.22 o 7 13 0 1581.49 1468.82 100.99 o -25 1 1 373.86 367.09 76.54 o -23 1 1 2086.65 2155.26 175.14 o -21 1 1 992.99 1180.08 73.77 o -19 1 1 5786.01 5952.47 219.60 o -17 1 1 440.41 560.71 48.75 o -15 1 1 2313.58 2362.04 124.56 o -13 1 1 1621.89 2083.29 130.93 o -11 1 1 2281.04 2547.38 97.62 o -9 1 1 369.18 313.80 26.07 o -7 1 1 32872.84 32326.22 354.51 o -5 1 1 14568.16 15213.35 118.41 o -3 1 1 1891.78 1933.56 41.44 o -1 1 1 1909.94 1896.29 42.57 o 1 1 1 27401.10 27080.44 289.04 o 3 1 1 5899.27 6753.46 87.97 o 5 1 1 2103.94 2370.87 53.58 o 7 1 1 2673.35 2518.70 53.86 o 9 1 1 3067.41 3037.31 85.11 o 11 1 1 13407.97 13601.40 175.86 o 13 1 1 6.74 14.42 10.49 o 15 1 1 1292.53 1488.65 105.99 o 17 1 1 222.52 329.55 52.54 o 19 1 1 4866.80 4893.81 298.97 o 21 1 1 650.76 593.12 69.52 o 23 1 1 1208.80 1587.53 108.72 o -24 2 1 148.82 142.30 35.92 o -22 2 1 3.87 58.08 26.00 o -20 2 1 12.80 20.27 17.06 o -18 2 1 4428.65 4553.94 191.49 o -16 2 1 1463.32 1363.64 99.97 o -14 2 1 539.06 509.73 47.02 o -12 2 1 5080.00 5145.39 128.38 o -10 2 1 825.79 599.23 102.61 o -8 2 1 2.75 50.46 5.89 o -6 2 1 16413.24 15879.56 183.74 o -4 2 1 57544.41 60640.01 485.97 o -2 2 1 782.91 812.84 33.90 o 0 2 1 11589.37 11025.34 124.79 o 2 2 1 8047.18 8254.18 95.74 o 4 2 1 4298.36 3989.37 57.68 o 6 2 1 11942.46 12539.30 266.38 o 8 2 1 34383.40 37294.40 346.55 o 10 2 1 6.44 43.71 15.01 o 12 2 1 6438.23 6734.58 201.73 o 14 2 1 1856.75 1637.65 89.92 o 16 2 1 1555.25 1594.63 100.63 o 18 2 1 5343.39 5574.44 188.58 o 20 2 1 149.15 71.65 58.52 o 22 2 1 575.67 761.23 77.46 o 24 2 1 32.30 13.53 26.89 o -23 3 1 366.80 419.04 83.34 o -21 3 1 476.51 517.89 62.05 o -19 3 1 700.39 634.43 62.99 o -17 3 1 8518.84 9110.78 261.36 o -15 3 1 6264.25 6029.26 164.62 o -13 3 1 6454.74 6840.05 249.75 o -11 3 1 2413.59 2568.15 98.12 o -9 3 1 166.88 162.98 24.90 o -7 3 1 1072.64 1342.12 62.71 o -5 3 1 1156.91 1173.81 59.12 o -3 3 1 14174.11 14319.87 212.46 o -1 3 1 8335.30 8239.21 134.02 o 1 3 1 21352.71 20454.56 321.83 o 3 3 1 12346.19 11826.48 148.92 o 5 3 1 355.61 341.50 24.98 o 7 3 1 150.00 120.20 15.36 o 9 3 1 605.58 679.40 40.27 o 11 3 1 14459.05 15531.09 183.27 o 13 3 1 16668.57 16062.30 306.88 o 15 3 1 7594.19 7263.21 146.13 o 17 3 1 2843.29 3071.58 192.27 o 19 3 1 577.09 579.47 61.76 o 21 3 1 17.21 2.47 31.37 o 23 3 1 264.68 358.43 58.92 o -24 4 1 887.77 855.52 96.93 o -22 4 1 143.47 122.58 32.69 o -20 4 1 2246.73 2221.89 191.09 o -18 4 1 321.98 315.72 65.00 o -16 4 1 352.57 444.85 40.39 o -14 4 1 648.29 781.37 50.16 o -12 4 1 9052.62 8631.68 202.09 o -10 4 1 19481.26 19393.19 243.01 o -8 4 1 1778.89 1988.58 53.34 o -6 4 1 1846.94 2294.29 69.70 o -4 4 1 10859.99 10552.87 169.25 o -2 4 1 1755.01 2086.38 73.52 o 0 4 1 864.24 978.83 49.52 o 2 4 1 6510.23 5696.23 101.51 o 4 4 1 41923.36 44301.70 485.49 o 6 4 1 9013.25 9273.64 174.00 o 8 4 1 706.66 677.77 38.31 o 10 4 1 15549.27 15992.82 296.60 o 12 4 1 2717.70 2820.95 117.28 o 14 4 1 207.79 181.39 34.09 o 16 4 1 945.90 981.90 70.73 o 18 4 1 15.15 7.64 38.81 o 20 4 1 3813.90 4144.34 265.87 o 22 4 1 353.48 306.02 56.74 o -23 5 1 1981.40 1817.20 146.28 o -21 5 1 2383.95 2382.62 193.44 o -19 5 1 23.45 31.64 17.26 o -17 5 1 829.66 856.29 72.37 o -15 5 1 217.13 319.39 34.41 o -13 5 1 713.56 619.05 45.05 o -11 5 1 19.18 30.63 12.89 o -9 5 1 17115.21 17310.75 230.06 o -7 5 1 25108.29 24957.63 335.71 o -5 5 1 27994.70 28524.15 352.31 o -3 5 1 64.54 52.91 13.07 o -1 5 1 8746.10 8961.77 163.42 o 1 5 1 13768.96 13948.41 275.20 o 3 5 1 66.57 73.30 34.33 o 5 5 1 11339.32 11294.39 186.03 o 7 5 1 30556.55 31521.22 383.16 o 9 5 1 20591.46 21525.74 242.50 o 11 5 1 220.10 246.03 31.79 o 13 5 1 8.77 11.26 12.40 o 15 5 1 5.78 21.25 12.44 o 17 5 1 522.74 480.01 49.34 o 19 5 1 42.65 41.46 16.72 o 21 5 1 692.94 635.67 91.64 o -22 6 1 61.35 63.73 30.45 o -20 6 1 526.93 542.19 68.85 o -18 6 1 4101.86 4220.19 216.40 o -16 6 1 330.47 354.46 32.40 o -14 6 1 328.64 401.22 34.88 o -12 6 1 1829.32 1735.16 99.08 o -10 6 1 9635.53 9947.25 242.56 o -8 6 1 3973.51 4222.49 120.91 o -6 6 1 10322.53 10570.55 256.19 o -4 6 1 11282.97 10916.40 262.23 o -2 6 1 15886.21 15340.81 329.33 o 0 6 1 4716.98 4927.76 129.76 o 2 6 1 5763.39 5257.60 125.47 o 4 6 1 203.48 162.40 19.54 o 6 6 1 3883.00 3946.94 162.86 o 8 6 1 1722.27 1726.14 74.22 o 10 6 1 2759.26 2984.29 112.68 o 12 6 1 4797.02 4904.17 163.70 o 14 6 1 791.42 829.18 59.35 o 16 6 1 1430.62 1458.29 106.17 o 18 6 1 2719.96 2962.65 144.70 o 20 6 1 630.83 608.08 87.87 o 22 6 1 450.58 540.29 62.29 o -21 7 1 178.28 159.13 45.11 o -19 7 1 447.98 386.29 49.98 o -17 7 1 4745.57 4095.49 232.27 o -15 7 1 7573.48 7702.06 301.41 o -13 7 1 4246.46 4391.61 137.22 o -11 7 1 199.27 277.71 23.00 o -9 7 1 2934.80 2992.18 92.99 o -7 7 1 4164.64 4344.21 150.98 o -5 7 1 609.56 577.93 58.52 o -3 7 1 20431.92 21253.57 376.70 o -1 7 1 56033.68 55165.84 1012.66 o 1 7 1 40560.10 40375.65 773.52 o 3 7 1 19947.62 19849.66 407.28 o 5 7 1 952.89 1287.91 68.03 o 7 7 1 454.55 426.62 41.02 o 9 7 1 64.36 66.09 17.49 o 11 7 1 566.92 589.90 47.85 o 13 7 1 14469.38 14455.35 399.65 o 15 7 1 10089.04 10243.35 387.97 o 17 7 1 3289.77 2969.96 194.13 o 19 7 1 288.62 269.71 59.61 o 21 7 1 3.37 -1.36 30.50 o -20 8 1 1719.71 1649.82 143.69 o -18 8 1 2236.45 1921.47 200.11 o -16 8 1 684.48 598.46 67.03 o -14 8 1 765.62 620.13 48.36 o -12 8 1 6038.06 6224.53 167.45 o -10 8 1 1994.61 1974.77 66.31 o -8 8 1 2094.54 2063.98 80.25 o -6 8 1 3125.72 3165.70 89.06 o -4 8 1 9339.58 9056.18 247.33 o -2 8 1 5421.37 5226.74 165.53 o 0 8 1 1930.28 1613.12 105.75 o 2 8 1 180.58 187.44 24.13 o 4 8 1 1361.86 1493.90 71.86 o 6 8 1 1871.06 1965.04 104.48 o 8 8 1 467.92 424.41 31.45 o 10 8 1 769.28 743.16 51.50 o 12 8 1 10379.78 10145.92 360.83 o 14 8 1 700.27 697.82 62.37 o 16 8 1 489.25 322.79 46.75 o 18 8 1 1363.91 1355.20 143.30 o -19 9 1 329.92 147.92 154.27 o -17 9 1 6.83 15.38 18.22 o -15 9 1 698.82 593.42 59.39 o -13 9 1 110.28 98.76 30.26 o -11 9 1 80.25 105.91 23.44 o -9 9 1 8312.52 8244.64 219.04 o -7 9 1 5459.08 5415.24 160.05 o -5 9 1 338.02 365.14 33.30 o -3 9 1 1459.68 1562.26 94.05 o -1 9 1 640.23 683.72 50.50 o 1 9 1 202.45 163.21 43.06 o 3 9 1 4178.21 3727.92 182.91 o 5 9 1 5059.46 5393.61 295.24 o 7 9 1 22046.47 23868.00 584.56 o 9 9 1 8382.29 8509.80 207.72 o 11 9 1 1368.68 1258.15 99.64 o 13 9 1 28.96 14.09 23.62 o 15 9 1 1417.81 1360.17 115.88 o 17 9 1 23.94 74.00 27.46 o -16 10 1 533.74 530.03 68.30 o -14 10 1 380.85 400.42 51.52 o -12 10 1 2268.05 2118.62 137.32 o -10 10 1 5350.30 5042.16 184.02 o -8 10 1 4.68 26.63 15.55 o -6 10 1 1234.19 1197.46 121.37 o -4 10 1 1364.19 1612.80 169.38 o -2 10 1 3122.22 3247.89 174.44 o 0 10 1 457.45 455.04 47.51 o 2 10 1 794.62 804.59 78.08 o 4 10 1 1422.10 1357.47 105.20 o 6 10 1 2163.45 1956.03 128.19 o 8 10 1 0.17 34.57 15.31 o 10 10 1 638.83 590.59 78.04 o 12 10 1 596.23 550.17 71.72 o 14 10 1 576.17 270.76 94.47 o 16 10 1 12.08 -4.74 19.02 o -15 11 1 229.14 224.61 61.29 o -13 11 1 1530.54 1256.62 112.96 o -11 11 1 255.12 230.96 45.44 o -9 11 1 40.41 48.78 31.63 o -7 11 1 94.81 118.75 28.84 o -5 11 1 1.33 -17.26 17.26 o -3 11 1 143.29 120.92 27.33 o -1 11 1 897.53 1107.18 105.84 o 1 11 1 3011.51 2913.57 283.57 o 3 11 1 161.15 185.69 47.56 o 5 11 1 805.81 722.75 83.36 o 7 11 1 206.35 201.75 51.87 o 9 11 1 19.74 90.31 35.35 o 11 11 1 472.32 407.18 51.73 o 13 11 1 751.81 728.42 65.63 o -12 12 1 50.53 6.36 29.21 o -10 12 1 12.86 22.59 33.89 o -8 12 1 22.40 57.27 29.66 o -6 12 1 63.59 92.86 33.24 o -4 12 1 371.11 371.88 63.74 o -2 12 1 1823.87 1874.02 136.07 o 0 12 1 289.22 250.95 45.96 o 2 12 1 619.26 618.69 67.32 o 4 12 1 964.94 1046.53 76.12 o 6 12 1 8.38 5.10 17.74 o 8 12 1 19.47 88.16 38.32 o 10 12 1 471.54 464.31 62.18 o -7 13 1 1721.91 1569.41 119.04 o -5 13 1 1465.45 1401.31 99.47 o -3 13 1 360.82 366.05 69.62 o -1 13 1 867.70 940.16 75.65 o 1 13 1 476.40 534.93 74.62 o 3 13 1 1249.03 1199.83 106.42 o 5 13 1 2919.93 3001.09 206.03 o 7 13 1 153.91 93.37 30.03 o -24 0 2 3.55 89.43 50.23 o -22 0 2 1312.31 1409.32 215.28 o -20 0 2 3258.99 3286.05 365.42 o -18 0 2 376.66 427.18 60.09 o -16 0 2 21604.93 21855.00 725.98 o -14 0 2 6896.05 7356.24 328.54 o -12 0 2 45811.34 48045.63 998.59 o -10 0 2 4217.45 4443.91 153.66 o -8 0 2 5809.70 5292.87 132.79 o -6 0 2 26224.41 25772.11 680.75 o -4 0 2 30913.20 30485.70 904.89 o -2 0 2 5817.51 6152.49 225.96 o 2 0 2 4841.57 4712.10 95.89 o 4 0 2 248592.86 271030.94 13876.44 o 6 0 2 38562.02 37280.80 959.02 o 8 0 2 12528.64 13066.64 430.18 o 10 0 2 230.35 370.22 38.20 o 12 0 2 18964.85 18568.89 766.75 o 14 0 2 6789.54 6629.12 430.25 o 16 0 2 22147.04 22959.23 1508.35 o 18 0 2 297.76 410.23 52.04 o 20 0 2 2532.55 2757.33 312.42 o 22 0 2 257.71 225.57 70.28 o 24 0 2 174.76 239.60 59.78 o -25 1 2 750.94 652.50 76.76 o -23 1 2 2694.56 3007.15 191.69 o -21 1 2 2848.91 3254.96 209.51 o -19 1 2 245.06 245.55 54.40 o -17 1 2 4735.52 4690.45 132.59 o -15 1 2 211.45 244.36 38.28 o -13 1 2 66.99 273.39 42.55 o -11 1 2 57905.48 58537.09 668.90 o -9 1 2 9248.26 10739.20 352.45 o -7 1 2 800.83 906.92 52.92 o -5 1 2 94035.20 99620.22 851.86 o -3 1 2 245.83 390.27 21.07 o -1 1 2 65189.10 69789.70 949.03 o 1 1 2 7375.20 8038.21 84.74 o 3 1 2 1476.56 1431.29 48.03 o 5 1 2 54487.47 55648.54 448.85 o 7 1 2 17389.71 17924.23 236.12 o 9 1 2 115.79 181.40 18.65 o 11 1 2 18576.84 18883.28 273.07 o 13 1 2 1042.00 1104.12 63.16 o 15 1 2 4916.40 5089.52 138.78 o 17 1 2 5849.42 5981.63 198.86 o 19 1 2 1687.16 1826.61 162.31 o 21 1 2 2292.51 2414.84 139.21 o 23 1 2 606.11 706.19 69.82 o -24 2 2 1089.18 1067.14 102.99 o -22 2 2 13456.21 13804.97 231.32 o -20 2 2 432.30 417.80 42.41 o -18 2 2 739.38 764.41 63.26 o -16 2 2 1863.88 1968.46 115.09 o -14 2 2 221.51 283.78 75.17 o -12 2 2 8414.75 8043.68 183.04 o -10 2 2 10277.79 9588.42 228.81 o -8 2 2 15196.56 14789.11 135.80 o -6 2 2 51941.72 49723.78 417.05 o -4 2 2 5400.41 5435.18 75.94 o -2 2 2 27213.45 26751.91 219.92 o 0 2 2 10676.67 10380.32 152.05 o 2 2 2 40733.09 40259.06 323.89 o 4 2 2 5653.31 5883.25 100.41 o 6 2 2 107795.00 111898.03 1506.61 o 8 2 2 8533.92 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