Supplementary Materials

The PDF file includes:

  • Scheme S1. Synthetic procedure of 3-TCPP.
  • Fig. S1. Characterization of BPY as a pillar in UPF-1.
  • Fig. S2. Coordination environment of Zn2+ ion of new SBU, (Zn(COO)3(μ2−O)Zn(COO)3.
  • Fig. S3. Packing of rhombicuboctahedron and cuboid of UPF-1.
  • Fig. S4. Thermogravimetric analysis data for UPF-1.
  • Fig. S5. 1H NMR data for trace of solvent content in the UPF-1.
  • Fig. S6. Simulated and experimental PXRD patterns of UPF-1 from 100 to 313 K.
  • Fig. S7. Perspective view of the (002) and (220) planes in UPF-1.
  • Fig. S8. Thermal expansion coefficients of UPF-1.
  • Fig. S9. Transformation of a cuboid in UPF-1.
  • Fig. S10. Schematic representation in a corotating model.
  • Fig. S11. Calculated θ values from temperature-dependent PXRD data of UPF-1.
  • Fig. S12. Schematic illustration of the corotating model.
  • Fig. S13. Calculated (x, y) coordinates from 0° to 90°, derived from equation.
  • Fig. S14. Energy as a function of deformations Di’s.
  • Table S1. Temperature-dependent cell parameters (Å) and unit cell volume (Å3) data from synchrotron PXRD.
  • Table S2. Temperature-dependent SCXRD of UPF-1.
  • Table S3. Thermal expansion coefficients from the a and c parameters and cell volume of SCXRD.
  • Table S4. Thermal expansion coefficients from the a and c parameters and cell volume of PXRD.
  • Table S5. Thermal expansion coefficient of reported solid-state structures.
  • Table S6. The values of d1, d2 and volume of cuboid depending on temperature.
  • Table S7. Optimized lattice parameters Ly ( Ly*) and bond angles Zn─O─Zn projected on the xy plane with respect to strained Lx’s.
  • Table S8. Stiffness tensor components (Cij’s) of UPF-1 in GPa.
  • Table S9. Elastic constants of UPF-1.
  • Table S10. Poisson’s ratio of a variety of materials.
  • Reference (53–76)

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Other Supplementary Material for this manuscript includes the following:

  • Data file S1 (.cif format). Crystallographic data for UPF-1_193K.
  • Data file S2 (.cif format). Crystallographic data for UPF-1_213K.
  • Data file S3 (.cif format). Crystallographic data for UPF-1_233K.
  • Data file S4 (.cif format). Crystallographic data for UPF-1_253K.
  • Data file S5 (.cif format). Crystallographic data for UPF-1_273K.
  • Data file S6 (.cif format). Crystallographic data for UPF-1_293K.
  • Data file S7 (.cif format). Crystallographic data for UPF-1_313K.
  • Data file S8 (.pdf format). checkCIF for crystal structures of UPF-1_193K.
  • Data file S9 (.pdf format). checkCIF for crystal structures of UPF-1_213K.
  • Data file S10 (.pdf format). checkCIF for crystal structures of UPF-1_233K.
  • Data file S11 (.pdf format). checkCIF for crystal structures of UPF-1_253K.
  • Data file S12 (.pdf format). checkCIF for crystal structures of UPF-1_273K.
  • Data file S13 (.pdf format). checkCIF for crystal structures of UPF-1_293K.
  • Data file S14 (.pdf format). checkCIF for crystal structures of UPF-1_313K.
  • Movie S1 (.avi format). Animation of hinged cube tessellation.
  • Movie S2 (.mp4 format). Rotating movement of UPF-1 structure depending on temperature.

Files in this Data Supplement: