This PDF file includes:

• Fig. S1. Hydrogel performances and characterizations of N-pepABS.
• Fig. S2. CA IX–related cell behaviors in MDA-MB-231 and HeLa cells.
• Fig. S3. CA IX–related endocytosis performances in MDA-MB-231.
• Fig. S4. CA IX down-regulation inhibits nanofiber endocytosis under hypoxia.
• Fig. S5. Acid vesicle injuries blocked protective autophagy in MDA-MB-231 cells.
• Fig. S6. The antihypoxic cancer cells effects of N-pepABS treatment in vivo.
• Fig. S7. Inhibition of tumor growth and metastasis on 4T1 tumor model.
• Fig. S8. In vivo toxicity evaluation after different treatments.
• Fig. S9. The synthesis and characterization of samples.

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