This PDF file includes:

• Fig. S1. Local and global evaluation of the extracellular bath temperature.
• Fig. S2. TRPV1 is endogenously expressed in ECFCs, and it is efficiently activated by polymer photostimulation.
• Fig. S3. Current clamp measurements in HEK-293 cells.
• Fig. S4. Pharmacological study on ECFCs seeded on polymer substrates in the dark—Evaluation of effect on tubulogenesis.
• Fig. S5. Polymer photostability.
• Fig. S6. p65 NF-κB nuclear translocation is unaltered in ECFCs seeded on glass subjected to light-induced photostimulation.
• Fig. S7. mRNA levels of proangiogenic genes downstream of NF-κB signaling.
• Table S1. List of oligonucleotide primers used for real-time PCR.

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