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. Author manuscript; available in PMC: 2017 May 27.
Published in final edited form as: Chem Asian J. 2017 Apr 20;12(10):1048–1051. doi: 10.1002/asia.201700354

Table 2.

Application scope.

graphic file with name emss-72601-i002.jpg
Entry[a] R T [°C] t [h] Conv.[b] [%] Yield[c] [%] TON[d] TOF[d] [h−1]
1 Ph 60 8 > 95 94 1880 235
2 Ph 25 8    25 24   480   60
3 4-Cl-C6H4 60 8 > 98 96 1920 240
4 4-F-C6H4 60 8 > 98 98 1960 245
5 PhOCH2 60 8 > 95 94 1880 235
6 Ph2CHOCH2 60 8    71 70 1400 175
7 ClCH2 60 8    89 88 1760 220
8 vinyl 60 8 > 98 93 1860 232
9 but-3-enyl 60 8 > 98 98 1960 245
10 but-3-enyl 25 20 > 98 98 1960   98
11 Me 25 8    57 55 1100 137
12 Me 25 20 > 95 88 1760   88
[a]

4 mmol scale (neat)

[b]

judged by 1H NMR of the reaction mixture

[c]

isolated yield after filtration over a short plug of silica

[d]

based on 1a. TON= turnover number; TOF= turnover frequency.