Skip to main content
. Author manuscript; available in PMC: 2020 Aug 6.
Published in final edited form as: Bio Protoc. 2020 Jan 20;10(2):e3498. doi: 10.21769/BioProtoc.3498

Table 4. Other σ2 values of Rhodamine 6G at selected wavelengths.

The σ2 values showing satisfactory matching between two or more measurements are italicized in column 7. Recommended values of σ2 are calculated as average of these numbers for each wavelength.

Wavelength (nm) Solvent Conc. (M) Pulse Original σ2 (GM) Correction 1 σ2 (GM) Correction 2 (final) σ2 (GM) Ref.

694 C2H5OH n/a ns 355 ± 170 710 ± 355a 277 ± 138b Hermann and Ducuing, 1972
694 CH3OH 0.04 30 ps 180 ± 20 - 180 ± 20 Sperber and Penzkofer, 1986
690 CH3OH 1.1 10−4 100 fs 136 - 156e Albota et al., 1999
700 176
694 CH3OH 8 10−6 100 fs 112 ± 22 - 112 ± 22 Makarov et al., 2008
692 CH3OH n/a 100 fs 202 ± 16 - 202 ± 16 de Reguardati et al., 2016
Suggested conditions and cross section value
694 CH3OH 10−5 100 fs 180 ± 23
730 CH3OH 8 10−6 100 fs 50 ± 10 - 50 ± 10 Makarov et al., 2008
730 CH3OH n/a 100 fs 50 ± 4 - 50 ± 4 de Reguardati et al., 2016
Suggested conditions and cross section value
730 CH3OH 10−5 100 fs 50
812 CH3OH 8 10−6 100 fs 71 ± 14 - 71 ± 14 Makarov et al., 2008
812 CH3OH n/a 100 fs 79 ± 6 - 79 ± 6 de Reguardati et al., 2016
Suggested conditions and cross section value
812 CH3OH 10−5 100 fs 75
940 CH3OH 1.1 10−4 100 fs 7.7 - 7.7 Albota et al., 1999
940 CH3OH 8 10−6 100 fs 8.3 ± 1.7 - 8.3 ± 1.7 Makarov et al., 2008
940 CH3OH n/a 100 fs 11.1 ± 0.9 - 11.1 ± 0.9 de Reguardati et al., 2016
Suggested conditions and cross section value
940 CH3OH 10−5 100 fs 9.0 ± 1.0
960 CH3OH 1.1 10−4 100 fs 12.7 - 12.7 Albota et al., 1999
960 CH3OH 8 10−6 100 fs 10.9 ± 2.2 - 10.9 ± 2.2 Makarov et al., 2008
960 CH3OH n/a 100 fs 17 ± 1.4 - 17.0 ± 1.4 de Reguardati et al., 2016
Suggested conditions and cross section value
960 CH3OH 10−5 100 fs 13 ± 2
a

Multiplied by factor 2 to conform with the more recent definition of σ2 (two photons are needed to excite one molecule), cf. Xu and Webb (1996); Kaatz and Shelton (1999); Makarov et al. (2008).

b

Multiplied by factor 0.39 to conform with the current reference value of quartz, d11 = 0.30 pm/V (versus 0.48 pm/V), see Kaatz and Shelton (1999).

c

Re-evaluated using the laser coherence function value g(2) = 2, see Weber (1971); Bradley et al. (1972); Kaatz and Shelton (1999). That factor was not included in original analysis.

d

Multiplied by factor 4 to conform with the more recent definition of σ2 (two photons are needed to excite one molecule), cf. Xu and Webb (1996); Kaatz and Shelton (1999); Makarov et al. (2008).

e

Interpolated between 690 and 700 nm measurements.