Table 4. Other σ2 values of Rhodamine 6G at selected wavelengths.
Wavelength (nm) | Solvent | Conc. (M) | Pulse | Original σ2 (GM) | Correction 1 σ2 (GM) | Correction 2 (final) σ2 (GM) | Ref. |
---|---|---|---|---|---|---|---|
694 | C2H5OH | n/a | ns | 355 ± 170 | 710 ± 355a | 277 ± 138b | Hermann and Ducuing, 1972 |
694 | CH3OH | 0.04 | 30 ps | 180 ± 20 | - | 180 ± 20 | Sperber and Penzkofer, 1986 |
690 | CH3OH | 1.1 10−4 | 100 fs | 136 | - | 156e | Albota et al., 1999 |
700 | 176 | ||||||
694 | CH3OH | 8 10−6 | 100 fs | 112 ± 22 | - | 112 ± 22 | Makarov et al., 2008 |
692 | CH3OH | n/a | 100 fs | 202 ± 16 | - | 202 ± 16 | de Reguardati et al., 2016 |
Suggested conditions and cross section value | |||||||
694 | CH3OH | 10−5 | 100 fs | 180 ± 23 | |||
730 | CH3OH | 8 10−6 | 100 fs | 50 ± 10 | - | 50 ± 10 | Makarov et al., 2008 |
730 | CH3OH | n/a | 100 fs | 50 ± 4 | - | 50 ± 4 | de Reguardati et al., 2016 |
Suggested conditions and cross section value | |||||||
730 | CH3OH | 10−5 | 100 fs | 50 | |||
812 | CH3OH | 8 10−6 | 100 fs | 71 ± 14 | - | 71 ± 14 | Makarov et al., 2008 |
812 | CH3OH | n/a | 100 fs | 79 ± 6 | - | 79 ± 6 | de Reguardati et al., 2016 |
Suggested conditions and cross section value | |||||||
812 | CH3OH | 10−5 | 100 fs | 75 | |||
940 | CH3OH | 1.1 10−4 | 100 fs | 7.7 | - | 7.7 | Albota et al., 1999 |
940 | CH3OH | 8 10−6 | 100 fs | 8.3 ± 1.7 | - | 8.3 ± 1.7 | Makarov et al., 2008 |
940 | CH3OH | n/a | 100 fs | 11.1 ± 0.9 | - | 11.1 ± 0.9 | de Reguardati et al., 2016 |
Suggested conditions and cross section value | |||||||
940 | CH3OH | 10−5 | 100 fs | 9.0 ± 1.0 | |||
960 | CH3OH | 1.1 10−4 | 100 fs | 12.7 | - | 12.7 | Albota et al., 1999 |
960 | CH3OH | 8 10−6 | 100 fs | 10.9 ± 2.2 | - | 10.9 ± 2.2 | Makarov et al., 2008 |
960 | CH3OH | n/a | 100 fs | 17 ± 1.4 | - | 17.0 ± 1.4 | de Reguardati et al., 2016 |
Suggested conditions and cross section value | |||||||
960 | CH3OH | 10−5 | 100 fs | 13 ± 2 |
Multiplied by factor 2 to conform with the more recent definition of σ2 (two photons are needed to excite one molecule), cf. Xu and Webb (1996); Kaatz and Shelton (1999); Makarov et al. (2008).
Multiplied by factor 0.39 to conform with the current reference value of quartz, d11 = 0.30 pm/V (versus 0.48 pm/V), see Kaatz and Shelton (1999).
Re-evaluated using the laser coherence function value g(2) = 2, see Weber (1971); Bradley et al. (1972); Kaatz and Shelton (1999). That factor was not included in original analysis.
Multiplied by factor 4 to conform with the more recent definition of σ2 (two photons are needed to excite one molecule), cf. Xu and Webb (1996); Kaatz and Shelton (1999); Makarov et al. (2008).
Interpolated between 690 and 700 nm measurements.