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. Author manuscript; available in PMC: 2023 Apr 14.
Published in final edited form as: Environ Sci Technol. 2023 Mar 27;57(14):5592–5602. doi: 10.1021/acs.est.2c07178

Table 1.

Modeled kinetics of precursor biosorption and PFHxS formation in a water-sediment slurry.a

PFHxSAmS PFHxSAm FHxSA

kbio

Rate constant
[day−1]
19°C
29°C
−2.7 (−1.2 – −4.2)
−5.0 (−3.7 – −6.4)
−4.9 (−3.4 – −6.4)
−3.7 (−2.4 – −5.0)
−0.2 (−0.04 – −0.4)
−0.7 (−0.2 – −1.4)

Half-life
[day]
19°C
29°C
0.3 (0.2 – 0.6)
0.1 (0.1 – 0.2)
0.1 (0.1 – 0.2)
0.2 (0.1 – 0.3)
3.5 (1.7 – 17)
1.0 (0.5 – 3.5)

kcontrol

Rate constant
[day−1]
19°C
29°C
−0.4 (−0.3 – −0.4)
−1.6 (−1.2 – −2.0)
−1.3 (−0.7 – −2.0)
−1.4 (−0.8 – −2.0)
−0.1 (−0.1 – −0.2)
−0.3 (−0.1 – −0.6)

Half-life
[day]
19°C
29°C
1.7 (1.7 – 2.3)
0.4 (0.3 – 0.6)
0.5 (0.3 – 1.0)
0.5 (0.3 – 0.9)
6.9 (3.5 – 6.9)
2.3 (1.2 – 6.9)

kPFHxS

Rate Constant
[nM day−1]
19°C
29°C
6 (1 – 12) 10−3
9 (3 – 14) 10−3
6 (1 – 11) 10−3
9 (4 – 16) 10−3
3 (2 – 4) 10−2
8 (6 – 9) 10−2

Activation energy
[kJ mol−1]
24 (−63 – 120) 31 (−51 – 120) 73 (49 – 98)
a

Results show the expected mean and the 90th confidence interval in parentheses.