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. Author manuscript; available in PMC: 2016 Aug 1.
Published in final edited form as: Chem Sci. 2015 Jun 12;6(8):4479–4483. doi: 10.1039/c5sc01553g

Table 2.

Desymmetrization of α-Quaternary Aldehyde 1 by Isomerization-Hydroacylationa

graphic file with name nihms697860f5.jpg
a

Reaction conditions: 0.1 mmol 1, x = 2.5 mol%, DCE (0.2 M), 40 °C, 4 h,

b

1 mmol 1c used,

c

x = 5, DCE (0.33 M), 30 °C, 2 h,

d

x = 6, DCE (0.33 M), 30 °C, 2 h.