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. 2023 Mar 31;145(14):8271. doi: 10.1021/jacs.3c02230

Correction to “Photogeneration of Spin Quintet Triplet–Triplet Excitations in DNA-Assembled Pentacene Stacks”

Sarah R E Orsborne, Jeffrey Gorman, Leah R Weiss, Akshay Sridhar, Naitik A Panjwani, Giorgio Divitini, Peter Budden, David Palecek, Seán T J Ryan, Akshay Rao, Rosana Collepardo-Guevara, Afaf H El-Sagheer, Tom Brown, Jan Behrends, Richard H Friend , Florian Auras
PMCID: PMC10103125  PMID: 37000182

Pages 5436. In the analysis and discussion of the ESR experiments, the definition of the quintet zero-field-splitting Hamiltonian was mistakenly typed as

graphic file with name ja3c02230_m001.jpg

The equation and definition of its terms should read as follows:

graphic file with name ja3c02230_m002.jpg

where S is the vector of quintet spin operators, Î is the 5×5 identity matrix, and Ŝi is the spin operator defined along the principal axis i ∈ (,ŷ,) of the ZFS tensor Dq, determined by the symmetry of the underlying spin–spin interactions.

This is also updated in Section K (“Theoretical quintet (S=2) zero-field splitting parameters”, page S22) of the Supporting Information.

These corrections do not affect the conclusions presented in the published article.

Supporting Information Available

The Supporting Information is available free of charge at https://pubs.acs.org/doi/10.1021/jacs.3c02230.

  • Experimental methods, synthetic procedures, and additional spectroscopic data (updated) (PDF)

Supplementary Material

ja3c02230_si_001.pdf (41.1MB, pdf)

Associated Data

This section collects any data citations, data availability statements, or supplementary materials included in this article.

Supplementary Materials

ja3c02230_si_001.pdf (41.1MB, pdf)

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