Abstract
Alloys based on NiAl-Cr-Co (base) with complex dopants (base+2.5Mo-0.5Re-0.5Ta, base+2.5Mo-1.5Re-1.5Ta, base+2.5Mo-1.5Ta-1.5La-0.5Ru, base+2.5Mo-1.5Re-1.5Ta-0.2Ti, base+2.5Mo-1.5Re-1.5Ta-0.2Zr) were fabricated by centrifugal SHS metallurgy. The phase and impurity compositions, structure, mechanical properties, and the mechanism of high-temperature oxidation at T = 1150 °C were studied; the kinetic oxidation curves, fitting equations and parabolic rate constant were plotted. Al2O3 and Co2CrO4 were the major phases of the oxidized layer. Three layers were formed: I—the continuous Al2O3 layer with Co2CrO4 inclusions; II—the transitional MeN-Me layer with AlN inclusions; and III—the metal layer with AlN inclusions. The positive effect of thermo-vacuum treatment (TVT) on high-temperature oxidation resistance of the alloy was observed. The total weight gain by the samples after oxidative annealing decreased threefold (from 120 ± 5 g/m2 to 40 ± 5 g/m2). The phases containing Ru and Ti microdopants, which reduced the content of dissolved nitrogen and oxygen in the intermetallic phase to the values ∑O, N = 0.0145 wt.% for the base+2.5Mo-1.5Ta-1.5La-0.5Ru alloy and ∑O,N = 0.0223 wt.% for the base+2.5Mo-1.5Re-1.5Ta-0.2Ti alloy, were identified by transmission electron microscopy (TEM). In addition, with the significant high-temperature oxidation resistance, the latter alloy with Ti had the optimal combination of mechanical properties (σucs = 1644 ± 30 MPa; σys = 1518 ± 25 MPa).
Keywords: centrifugal SHS metallurgy, heat-resistant alloys, high-temperature oxidation resistance, kinetics and mechanism of oxidation
1. Introduction
NiAl is widely used to produce heat-resistant alloys for the components of gas-turbine engines. The drawbacks of these alloys include low mechanical strength and ductility at room temperature, resulting in insufficient manufacturability and risk of failure [1,2,3,4,5,6,7,8]. Various plasticizers are added to alloys for increasing fracture toughness [3,4,5,6,7,8,9,10]. An essential requirement on hot gas path materials is the oxidation resistance of the surface at high temperatures and under thermocyclic loading [11,12,13,14,15,16,17,18,19].
One of the known methods for producing cast and powder intermetallic-based materials is the self-propagating high-temperature synthesis (SHS) and its technological types: elemental synthesis [20,21,22,23,24,25] and centrifugal SHS casting [25,26,27,28,29]. For both of them, research aiming to optimize the composition and modes for synthesizing CompoNiAl series alloys based on NiAl-Cr-Co (base) is currently underway [27,28,29,30].
Microdoping with molybdenum and niobium (the base+MoNb alloy) obtained by elemental synthesis enhances resistance to viscoplastic deformation at temperatures above 800 °C due to the formation of the Cr0.5Mo0.5 and Cr0.7Mo0.3 phases [31,32]. High-level mechanical properties were attained at 900 °C for the studied samples after HIP: σucs = 615 ± 9 MPa; σys = 488 ± 7 MPa; and εpd = 62.2 ± 1.4 %.
It was found for the cast SHS alloys base+X (where X = La, Mo, Ta, Re, Zr) [32,33] Reference addedthat doping the alloy with Mo and Re resulted in the formation of a cellular eutectic structure [32]. Doping with up to 15% Mo and 1.5% Re improved mechanical properties up to the following values σucs = 1604 ± 80 MPa, σys = 1520 ± 80 MPa, and εpd = 0.79%; additional annealing at T = 1250 °C for 180 min enhanced the properties to σucs = 1800 ± 80 MPa, σys = 1670 ± 80 MPa, and εpd = 1.58%. In turn, rhenium modified the structure of the base+15Mo1.5Re alloy, thus enhancing mechanical properties up to the values σucs = 1682 ± 60 MPa, σys = 1538 ± 60 MPa, and εpd = 0.87%; additional annealing further improved them to the values σucs = 2019 ± 60 MPa, σys = 1622 ± 60 MPa, and εpd = 5.88%. The hierarchical three-level structure of the base+15%Mo alloy was identified: the first level was formed by dendritic β-NiAl grains with interlayers of molybdenum-containing (Ni,Co,Cr)3Mo3C and (Mo0.8Cr0.2)xBy phases having a cell size up to 50 µm; the second level consisted of strengthening submicron-sized Cr(Mo) particles distributed along grain boundaries; and the third level comprised coherent Cr(Mo) nanoprecipitates (sized 10–40 nm) within the bulk of β-NiAl dendrites. Doping with interstitial elements enhanced the oxidation resistance of the β-alloy due to the formation of additional phases [33]. Volatile oxides MoO3, Mo3O4 and CoMoO4 disrupting the integrity of the protective layer were formed upon oxidation of alloys doped with molybdenum. Oxygen and nitrogen penetration depth increased with molybdenum concentration. In the tantalum-containing alloy, the Ta2O5 phase was formed in the intergrain space; this phase reduced the rate and depth of oxygen diffusion. The alloy doped with zirconium was characterized by the best high-temperature oxidation resistance; the extent of oxidation after 30 h was 21 g/m2. The zirconium-containing continuous upper layer Al2O3 + Zr5Al3O0.5 blocked the external diffusion of oxygen and nitrogen, thus increasing high-temperature oxidation resistance [33]. Aheiev et al. [33] also studied the effect of nitrogen dissolved in the alloy on the mechanism of high-temperature oxidation. Nitrogen reacts with aluminum to form aluminum nitride AlN, thus altering the oxidation mechanism. The vacuum induction melting (VIM) technique was used for degassing the alloy. The extent of oxidation after 30 h was 50 g/m2 for the base alloy and 22 g/m2 for the base+VIM alloy. However, the technological process of VIM is extensive; therefore, microdoping of alloys with metals (Ti, Zr, Hf, Re, etc.) exhibiting high chemical affinity for oxygen and nitrogen is performed to reduce the content of gas impurities. Thus, doping with titanium allowed one to bind gas impurities and noticeably reduce their content in the nickel aluminide-based solid solution, which had a positive effect on properties of the alloy [1,2]. Density increased [32] and the end products became heavier with the rising content of rhenium dopant in β-NiAl. Ruthenium is an expensive interstitial element but has an advantage over rhenium in terms of its density: ρRe = 21.02 g/cm3 and ρRu = 12.41 g/cm3. Re and Ru exhibit similar effects: they stabilize the phase composition and ensure comminution of structural components, showing tendency toward low liquation during crystallization [1]. Furthermore, ruthenium is an active getter of dissolved gases. The effect of Ru on the base composition of the base alloy [27,28] has not been studied earlier.
Therefore, research into the effect of chemical composition on oxidation resistance, mechanical properties, and searching for the optimal compositions of the β-NiAl-based alloy is rather relevant today. This study aimed to produce cast NiAl-Cr-Co (base) alloys doped with complex additives by centrifugal SHS metallurgy and investigate the features of their microstructure, mechanical properties, kinetics and the mechanism of oxidation.
2. Materials and Methods
The calculated compositions of the alloys in the base+X system are listed in Table 1.
Table 1.
No. | Composition of the Base | Composition of the Dopant (X), wt.% |
---|---|---|
1 | NiAl-12Cr-6Co (base) |
+2.5Mo-0.5Re-0.5Ta |
2 | +2.5Mo-1.5Re-1.5Ta | |
3 | +2.5Mo-1.5Ta-1.5La-0.5Ru | |
4 | +2.5Mo-1.5Re-1.5Ta-0.2Ti | |
5 | +2.5Mo-1.5Re-1.5Ta-0.2Zr |
Synthesis was carried out using a radial-type centrifugal setup under high gravity conditions (up to 150 g). The general scheme of the employed centrifugal setup was provided in refs. [23,24,25,26].
The design of the setup allows one to specify the number of revolutions of the centrifuge rotor in a controlled manner to ensure the desired acceleration level. A distinctive feature of this technology is that the relatively available oxide feedstock is used and high combustion temperature (2100–3500 °C) is attained, so the phase of the target product can be separated from the cinder phase. The chemical scheme of the process can be represented as:
NiO + Cr2O3 + Co3O4 + MoO3 + Al + (X) + (FA) –> [NiAl-Cr-Co-Mo-(X)] + Al2O3 | (1) |
where: FA (functional additive) is CaF2, Na3[AlF6], etc; X is Me (Zr, Ta, Re, Ru, Ti, La).
Table 2 lists grades and properties of the initial powders. Dopants were added to the reaction mixture so as to obtain the desired composition of the alloy.
Table 2.
Compound | CAS No or Grade | Standard: GOST/TU/ISO/ASTM | Particle Size, µm | Chemical Composition, % |
---|---|---|---|---|
Major components | ||||
NiO | 1313-99-1 | GOST 17607-72/ISO 12169 | <40 | 99.00 |
Cr2O3 | 1308-38-9 | TU 6-09-4272-84/ISO 4621 | <20 | 99.00 |
Co3O4 | 1307-96-6 | GOST 18671-73 | <30 | 99.00 |
Al | P3 | GOST 6058-73/ASTM B221-21 & B595-2 | <140 | 98.00 |
Al | Al300 | TU 48-5-226-87/ASTM B221-21 | <50 | 99.70 |
Modifying additives (MA) | ||||
MoO3 | 1313-27-5 | TU 6-09-4471-77/ASTM A146-04 | <50 | 99.00 |
Zr | 702 (shaving) | TU 95.166-83/ASTM B551 | ≤600 | 99.80 |
Ta | EB | TU 48-19-72-92/ASTM B708-12 | <20 | 98.00 |
Re | 7440-15-5 | TU 48-4-195-87/ASTM E696-07 | <150 | 99.99 |
Ru | 7440-18-8 | GOST 12343-79/ASTM-B717 | ≤100 | 99.95 |
Ti | TF-0 | TU 14-22-57-92/ASTM B367-00 | ≤30 | 99.80 |
La | F01 | TU 1-92-200-2000 | ≤100 | 99.97 |
The scheme for preparing exothermic mixtures included drying the components in SNOL-type drying ovens at 90 °C during 1 h, dosing reagents, mixing and casting the mixture in graphite molds. Mixing was carried out in an MP4/0.5 planetary mill with a 1 L drum during 15–20 min at the ball-to-powder ratio of 1:5. The combustion temperature of the mixtures was higher than the melting point of the end products of synthesis, enabling complete phase segregation due to gravity separation of the metallic melt and cinder (Figure 1). The Zr, Ta, Re, Ru and La components were added to the reaction mixture as pure elements, while Mo was added as MoO3 oxide. Aluminum was used to reduce the oxide charge. Different grades of aluminum are used to control SHS processes [25].
Thermodynamic calculations of the adiabatic combustion temperature (Tf) were preliminarily performed using the THERMO software ver.3 package. Tf was 2300–2400 °C for all the compositions under study, being noticeably higher than the melting points of the synthesis products. The optimal acceleration values for these systems were identified earlier and were equal to 140–150 g [32]. The highest yield of the end product into a metal ingot was attained at this acceleration value. At least three ingots 80 mm in diameter and 25–30 mm high were synthesized for each composition (Table 1), making it possible to study homogeneity and reproducibility of the results. According to the recommendations [32], thermo-vacuum treatment (TVT) of the ingots was carried out at 1250 °C for 2 h to enhance ductility and residual strain. TVT led to strain relaxation, and the recrystallization of grains of the major β-NiAl phase and excess phases. Furthermore, TVT contributed to the degassing of dissolved or adsorbed impurities (nitrogen and oxygen) [33].
A Thermo Fisher Scientific Finnigan Element glow discharge mass spectrometer and a double-focusing spectrum analyzer (in the Nier–Johnson geometry) were employed for quantitative analysis of major components and impurities. This instrument was used to identify the chemical composition of both the base and impurity elements.
The phase composition was determined by X-ray phase analysis (XRD) on a D2 PHASER diffractometer (Bruker AXS GmbH, Mannheim, Germany) using Cu-Kα radiation in the 2θ range = 10–140°.
The microstructural studies were carried out on an S-3400N scanning electron microscope (Hitachi, Tokyo, Japan) coupled to a NORAN System 7 X-ray microanalysis system (Thermo Scientific, Waltham, MA, USA), as well as a JEM-2100 transmission electron microscope (TEM) (Jeol, Tokyo, Japan) using a Gatan 650 Single Tilt Rotation Analytical Specimen Holder (Gatan, Inc., Pleasanton, CA, USA). The samples (lamellae) were fabricated from the preliminarily prepared foil using the focused ion beam technique on a Quanta 200 3D FIB instrument (FEI Company, Hillsboro, OR, USA). TEM foils were prepared by ion etching on PIPS II system (Gatan, Inc., Pleasanton, CA, USA).
Compression tests were carried out on an LF-100KN universal testing machine (Walter+Bai AG, Löhningen, Switzerland) at room temperature in compliance with the State Standard GOST 25.503-97.
Oxidative annealing was carried out in air at 1150 °C during 30 h in an SShOL 1.1.6/12-M3 laboratory pit-type electric furnace; the samples were weighed periodically. Changes in sample weight normalized to the unit surface area over a certain time period were determined. The experimental data were used to plot the oxidation curves and fitting equations. Samples 8 mm in diameter and 4 mm high were cut on an EDM machine GX-320L (CHMER EDM, Taichung, Taiwan) and ground to a roughness of Rz = 5.
3. Results and Discussion
The low ductility of intermetallic alloys at room temperature impedes their practical application for fabricating geometrically complex items. The presence of detrimental impurities is an additional factor deteriorating properties of the alloys. Therefore, an important problem is controlling the chemical composition and impurity content in alloys. Chemical analysis of the synthesized ingots showed that they corresponded to the calculated compositions for the major components of the alloy. Table 3 lists the impurity composition of base-X alloys. The total contents of Mg, Na, Si, Ca, K, Fe Mn, Cu, W, S and C impurities are provided.
Table 3.
Element | Concentration, wt.% | ||||
---|---|---|---|---|---|
*+2.5Mo-0.5Re-0.5Ta | *+2.5Mo-1.5Re-1.5Ta | *+2.5Mo-1.5Ta-1.5La-0.5Ru | *+2.5Mo-1.5Re-1.5Ta-0.2Ti | *+2.5Mo-1.5Re-1.5Ta-0.2Zr | |
O | 0.0261 | 0.0281 | 0.0136 | 0.0212 | 0.0321 |
N | 0.0023 | 0.0029 | 0.0009 | 0.0013 | 0.0026 |
∑gas impurities | 0.0283 | 0.0310 | 0.0145 | 0.0223 | 0.0346 |
∑impurity elements ** | 0.1449 | 0.1135 | 0.1395 | 0.1478 | 0.1613 |
* NiAl-12Cr-6Co (base-X); ** ∑Mg,Na,Si,Ca,K,FeMn Cu,W,S,C.
Impurity elements Mg, Na, Si, Ca, K, Mn and Cu are the accompanying ones and are transferred to the synthesis products from the starting reagents. The total impurity content is 0.15 ± 0.02 wt.%, which lies within the acceptance region for heat-resistant nickel alloys. Meanwhile, technical solutions that would reduce their concentration need to be found. The excessive content of carbon (up to 0.017 wt.%) in all the samples is due to the fact that SHS was performed in graphite molds. Most of La participates in the reaction of oxide reduction, being regarded as a competitor of the major reducing agent (Al). Therefore, La content in the ingot of alloy 3 (base+2.5Mo-1.5Ta-1.5La-0.5Ru) was decreased (0.86 wt.%) compared to the calculated value. Importantly, the contents of oxygen and nitrogen impurities decline to the value ∑O,N = 0.0145 wt.% for the base+2.5Mo-1.5Ta-1.5La-0.5Ru alloy and ∑O,N = 0.0223 wt.% for the base+2.5Mo-1.5Re-1.5Ta-0.2Ti alloy. Ruthenium and titanium act as getters of oxygen and nitrogen, thus exhibiting a positive effect on strength properties and high-temperature oxidation resistance of the alloy.
Figure 2 and Table 4 show the phase composition of the synthesized alloys. β-NiAl was the major phase. The Ni(Al,Ta) phase was present in alloys 2 and 3 with Ta content up to 1.5%, while alloy 3 contained the MoNi phase. The Ni(Al,Ti) phase was identified in alloy 4 doped with 0.2% Ti, while doping with 0.2% Zr (alloy 5) gave rise to the Ni2(Zr,Al) phase.
Table 4.
No. | Modifying Additive X | Phase | Mass Fraction, % | Lattice Parameters, Å | ||
---|---|---|---|---|---|---|
a | b | c | ||||
1 | 2.5%Mo-0.5%Re-0.5%Ta | NiAl | 100 | 2.867 | - | - |
2 | 2.5%Mo-1.5%Re-1.5%Ta | NiAl | 80 | 2.879 | - | - |
Ni(Al,X) * | 14 | 2.931 | - | - | ||
Ni(Al,Ta) | 6 | 2.997 | - | - | ||
3 | 2.5%Mo-1.5%Ta-1.5%La-0.5%Ru | NiAl | 74 | 2.882 | - | - |
MoNi | 18 | 9.089 | 9.084 | 8.834 | ||
Ni(Al,Ta) | 8 | 2.918 | - | - | ||
4 | 2.5%Mo-1.5%Re-1.5%Ta-0.2%Ti | NiAl | 54 | 2.884 | - | - |
Ni(Al,Ti) | 46 | 2.927 | - | - | ||
5 | 2.5%Mo-1.5%Re-1.5%Ta-0.2%Zr | NiAl | 86 | 2.896 | - | - |
Ni2(Zr,Al) | 14 | 2.983 | - | - |
* In addition to the major phase with the B2-type structure, there are phases with the same structure or bcc solutions; however, the phase composition cannot be determined by this method.
Figure 3 shows that in the case of complex doping of an alloy with Mo, Re and Ta metals, inclusions based on solid solution of chromium of different compositions were formed in the β-NiAl matrix. For the base+2.5Mo-0.5Re-0.5Ta composition, globular micron- and submicron-sized inclusions based on solid solution of chromium reside inside β-NiAl grains. Inclusions 2–8 µm thick with compositions (Cr)Ni,Al,Mo,Re, (Cr)Mo,Ta and (Cr)Mo were formed in the intergrain space.
As Ta and Re concentrations were increased to 1.5%, the (base+2.5%Mo-1.5%Re-1.5%Ta) alloy acquired a well-defined mesh structure (Figure 4). Cr- and Re-based solid solutions were contained within intergrain interlayers. The Ni(Al,Ta) phase was located at grain boundaries between the solid solution and the NiAl matrix. Submicron-sized NiAl precipitates were detected inside the interdendritic layers. As demonstrated by Aheiev et al. [31], tantalum localization along the boundaries of the major phase grains had a positive effect on strength properties and increased plastic strain at room temperature. Stringed precipitates of α-Cr were also revealed in the NiAl matrix.
In the base+2.5%Mo-1.5%Ta-1.5%La-0.5%Ru alloy (Figure 5), a multicomponent eutectic system was formed between dendrite branches. MoNi precipitates resided in the center of the intergrain space. The (Cr)Ni,Co,Mo solid solution was formed around the MoNi phase. Furthermore, the intergrain space hosted a chromium-based solid solution with dissolved Mo, Ta, Ru and La. Identically to the alloy described previously, the Ni(Al,Ta) intermetallic phase was formed at grain boundaries, and stringed inclusions of α-Cr were observed inside the grain.
Additional doping of the alloy with titanium (base+2.5%Mo-1.5%Re-1.5%Ta-0.2%Ti) did not qualitatively alter the structure (Figure 6). The Ni(Al,Ti) was formed at grain boundaries, which increased plastic strain resistance and strength of the alloy as it can be seen in Table 5. The interdendritic layer hosted the chromium-based solid solution, while the matrix contained stringed inclusions of α-Cr.
Table 5.
No. | base+X Alloy | Hardness, HV |
σucs, MPa |
σys, MPa | εpd, % |
---|---|---|---|---|---|
1 | +2.5Mo-0.5%Re-0.5%Ta | 5.15 | 1266 | 1117 | <1 |
2 | +2.5Mo-1.5%Re-1.5%Ta | 4.94 | 924 | - | <1 * |
3 | +2.5Mo-1.5%Ta-1.5%La-0.5%Ru | 5.51 | 1241 | - | <1 * |
4 | +2.5Mo-1.5%Re-1.5%Ta-0.2%Ti | 5.56 | 1644 | 1518 | <1 |
5 | +2.5Mo-1.5%Re-1.5%Ta-0.2%Zr | 5.12 | 1304 | - | <1 * |
* The samples have undergone brittle failure.
In a similar manner, doping the alloy with 0.2% Zr (base+2.5%Mo-1.5%Re-1.5%Ta-0.2%Zr) resulted in the precipitation of the Ni2(Zr,Al) phase (Figure 7). The intergrain layers were formed by solid solution based on chromium and rhenium with NiAl precipitates. Microprobe analysis showed that tantalum was a component of the (Re)Cr,Mo,Ta solid solution.
Table 5 lists the results of measuring the mechanical properties of cast SHS alloys. One can see that the base+2.5%Mo-1.5%Re-1.5%Ta-0.2%Ti alloy had the best combination of properties (hardness, strength, the yield point and residual strain): σucs = 1644 ± 30 MPa, σys = 1518 ± 25 MPa (Figure 8).
In order to study the effect of complex doping on the high-temperature oxidation resistance of the alloys, air annealing at 1150 °C was performed during 30 h; the samples were periodically weighed. When investigating the oxidative resistance for the previous series of alloys, Aheiev et al. [31] demonstrated that a multilayer oxide film was formed in the alloys characterized by the greatest weight gain. The transitional MeN-Me layer mainly consisted of nitrides due to the high content of dissolved nitrogen, which diffused from the alloy along grain boundaries to interact with aluminum, thus disrupting alloy integrity. Therefore, additional vacuum annealing (TVT at 700 °C during 2 h) was carried out in this study for the base+2.5Mo-1.5%Re-1.5%Ta alloy as an example.
Table 6 lists the weight gain values after oxidative annealing at 1150 °C during 30 h, as well as the kinetic regression equations corresponding to the oxidation curves shown in Figure 9. Figure 9b,d shows the parabolic rate constant determined for each composition. The parabolic rate constant kp was measured by the method as follows (2). Line 2.2 corresponds to the sample subjected to additional vacuum annealing. The parabolic rate constant of oxidation is shown in Figure 9b,d. The parabolic rate constant was measured as follows:
(2) |
where: ∆m is the mass change; S is the surface area; t is time.
Table 6.
No. | base+X alloy | Fitting Equation | Weight Gain, g/m2 |
---|---|---|---|
1 | +2.5Mo-0.5%Re-0.5%Ta | y = 0.0002x3 − 0.0076x2 + 0.231x + 2.2869 | 7.282 |
2.1 | +2.5Mo-1.5%Re-1.5%Ta | y = 23.084ln(x) + 45.958 | 133.624 |
2.2 | +2.5Mo-1.5%Re-1.5%Ta (TVT *) | y = − 0.0295x2 + 2.3405x + 3.6274 | 48.372 |
3 | +2.5Mo-1.5%Ta-1.5%La-0.5%Ru | y = 0.0002x3 − 0.0094x2 + 0.165x + 1.096 | 2.772 |
4 | +2.5Mo-1.5%Re-1.5%Ta-0.2%Ti | y = −0.044x2 + 3.1537x + 0.3412 | 55.886 |
5 | +2.5Mo-1.5%Re-1.5%Ta-0.2%Zr | y = −0.0295x2 + 2.593x + 5.6503 | 57.546 |
*—TVT—thermo-vacuum treatment.
For samples 1, 2.2, 3, 4 and 5, the shape of the curves corresponds to the parabolic law of oxidation: a continuous barrier oxide layer was formed within the first few hours of oxidation, inhibiting oxygen diffusion into the sample. The oxidation curve of sample 2.1 is fitted by logarithmic law (local phase segregation takes place due to the internal stress emerging during thermal cycling).
Figure 10 shows the appearance of the oxidized samples. Each alloy had its own hue and certain topology. Signs of physical degradation were observed for none of the samples.
Table 7 summarizes the results of XRD analysis of the oxidized layer of the samples; the XRD spectra are shown in Figure 11. Al2O3 was the main oxidation product. Co2CrO4 was the next phase (according to its weight fraction). Lines belonging to NiAl were also present in the XRD spectra along with those corresponding to oxides. Traces of the Ni3AlN phase were detected among the oxidation products with composition 1.
Table 7.
No. | Base+X Alloy | Phase | wt.% | Lattice Parameters, Å | |
---|---|---|---|---|---|
a | c | ||||
1 | +2.5%Mo-0.5%Re-0.5%Ta | Al2O3 | 84 | 4.772 | 13.044 |
NiAl | 11 | 2.878 | - | ||
MoNi | 4 | 3.644 | - | ||
Ni3AlN | 1 | 3.808 | - | ||
2 | +2.5%Mo-1.5%Re-1.5%Ta | Al2O3 | 42 | 4.770 | 13.054 |
Co2CrO4 | 40 | 8.168 | - | ||
MoNi | 13 | 3.598 | - | ||
NiAl | 5 | 2.887 | - | ||
3 | +2.5%Mo-1.5%Ta-1.5%La-0.5%Ru | Al2O3 | 66 | 4.767 | - |
Co2CrO4 | 13 | 8.135 | - | ||
NiAl | 13 | 2.868 | - | ||
TaCo2 | 8 | 4.765 | 15.287 | ||
4 | +2.5%Mo-1.5%Re-1.5%Ta-0.2%Ti | Al2O3 | 69 | 4.792 | 13.094 |
Co2CrO4 | 20 | 8.163 | - | ||
NiAl | 6 | 2.884 | - | ||
Ni(1−x)Al(x) | 5 | 3.605 | - | ||
5 | +2.5%Mo-1.5%Re-1.5%Ta-0.2%Zr | Al2O3 | 63 | 4.781 | 13.066 |
Co2CrO4 | 30 | 8.163 | - | ||
MoNi | 7 | 3.605 | - |
Figure 12 shows the microstructures of the samples after high-temperature oxidation resistance tests, the size of oxide and transitional layers being specified. One can see that in all the cases, a continuous oxide film impeding diffusion-controlled penetration of oxygen and nitrogen to the alloy was formed at the initial oxidation stage. A transitional MeN-Me layer was formed in the alloys with increased Re content (1.5%), being indicative of nitrogen diffusion in the alloy.
A thorough analysis of the oxidation mechanism is provided in Figure 13, Figure 14, Figure 15, Figure 16, Figure 17, Figure 18, Figure 19, Figure 20, Figure 21, Figure 22 and Figure 23. Alloy 2.2 containing Mo, Re and Ta microdopants was chosen as an example of the positive effect of thermo-vacuum treatment of cast SHS alloys on the microstructure after high-temperature oxidation resistance testing; its analysis is provided in Figure 15.
The top dense oxidized layer on the base+2.5%Mo-0.5%Re-0.5%Ta sample with composition 1 consisted of Al2O3, which was a distinctive feature of this alloy compared to other ones. The Al2O3 alloy was formed during the initial oxidation period and impeded oxygen diffusion into the sample. The MoNi phase and the chromium-based solid solution resided in the oxidized layer as globular inclusions and around non-oxidized NiAl regions (Figure 13). Because of the small dopant concentration in the alloy with composition 1, the sample had a structure with a low content of solid-solution inclusions in the intergrain space. This factor could restrain oxygen and nitrogen diffusion at grain boundaries during the initial oxidation period, contributing to the formation of solid Al2O3 film, as well as preventing nitrogen diffusion and the formation of aluminum nitride. Meanwhile, nitrogen dissolved in the alloy entered the reaction yielding Ni3AlN nitride perovskite.
After oxidative annealing, the base+2.5%Mo-1.5%Re-1.5%Ta alloy with composition 2 (characterized by increased Re and Ta contents) had a multilayer surface structure. According to the pattern of oxygen and nitrogen distribution, the oxide layer could be subdivided into three sublayers: I—the continuous Al2O3 oxide film with a non-uniform distribution of Co2CrO4 spinel inclusions; II—the transitional MeN-Me layer containing AlN inclusions; and III—the metal layer with sparse inclusions of AlN (Figure 14). The oxide layer was formed at the initial stage during the formation of chromium, cobalt and aluminum oxides and Co2CrO4 spinel. The Co2CrO4 phase resulted from interaction between chromium and cobalt oxides. Spinel was composed of coarse grains with defects through which surface diffusion of oxygen and nitrogen into the sample could occur. In turn, the formation of Al2O3 reduced the partial pressure of oxygen and impeded spinel formation [34]. A continuous Al2O3 layer was located at the boundary between sublayers I and II, being responsible for the enhancement of oxidation resistance. Sublayer I contained, along with oxides, a small amount of the Ni3Al phase that had been formed during the oxidation of aluminum. In the transitional MeN-Me layer, nitrogen reacted with aluminum to yield AlN nitrides, which also depleted NiAl to Ni3Al. Along with Ni3Al, the interaction between nitrogen and aluminum contributed to the formation of the MoNi intermetallic phase [34].
In order to assess the effect of thermo-vacuum treatment on high-temperature oxidation resistance, we analyzed the microstructure of the oxidized alloy with composition 2 that had undergone vacuum annealing (Figure 15). Figure 12 (No. 2.2: base+2.5%Mo-1.5%Re-1.5%Ta+TVT) showed that the maximum thickness of the alloy after vacuum annealing was lower (135 µm) than that for the sample not subjected to TVT (160 µm). The average thickness of the oxidized layer for the sample after TVT was 50 µm. Weight gain was also approximately threefold lower (Table 6), thus proving the positive effect of vacuum annealing. Not only did nitride formation during the initial oxidation stage disrupt the integrity of ingots, but it also impeded the formation of the Al2O3 barrier oxide layer [35,36]. The lower content of nitrogen impurity inhibited the formation of nitrides in the alloy, thus increasing its oxidation resistance. An analysis of the alloy microstructure after TVT showed that the structure and the mechanism of formation of the oxidized layer were similar to those for the alloy not subjected to TVT: three sublayers were formed, NiAl became Al-depleted, and the Ni3Al and MoNi phases were precipitated [36].
Figure 16 shows the structure of the oxidized surface of the sample with composition 3 (base+2.5%Mo-1.5%Ta-1.5%La-0.5%Ru). The content of Co2CrO4 spinel in this sample was significantly lower (13.4 wt.%) (Table 6). The oxidized layer contained Al2O3 with chaotic inclusions of the Co2CrO4 phase. A distinctive feature of this alloy is that the Co2CrO4 phase was located under the Al2O3 layer [37,38]. Globular inclusions of chromium and unreacted regions of the TaCo2 phase and (Cr)Ni,Mo solid solution were detected in the oxidized layer. This sample did not contain the Ni3Al phase; AlN inclusions resided at the NiAl/(Cr)Ni,Mo interface.
A detailed analysis of the oxidized layer of the base+2.5%Mo-1.5%Ta-1.5%La-0.5%Ru sample was carried out by transmission electron microscopy (TEM). A lamella cut from a cross-section of the metal/oxidized layer interface by FIB was used as a study object (the lamella cutting site is indicated in Figure 16). Figure 17, Figure 18 and Figure 19 and Table 8 show the images of the lamella and the EDS maps of distribution of the respective elements. The near-surface layer consisted of Al2O3 (Figure 17, spectra 2 and 6), which was an efficient barrier blocking oxygen and nitrogen diffusion deep inside the sample. Nanosized inclusions of Co2CrO4 spinel with fcc crystal lattice (space group Fd3m) and lattice parameter a = 8.131 Å were arranged along the boundaries of Al2O3 grains (Figure 18). As found earlier, this phase present as coarse grains negatively affected the high-temperature oxidation resistance of alloys, since they caused the formation of cracks acting as oxygen diffusion channels. However, in the base+2.5%Mo-1.5%Ta-1.5%La-0.5%Ru alloy, the Co2CrO4 phase consisted of uniformly distributed particles sized up to 100 nm and did not cause cracking of the oxide layer. The electron diffraction data recorded for the surface region of the oxidized layer proved that nanosized Co2CrO4 spinel crystals were present (Figure 18). Under the layer based on Al2O3 and Co2CrO4, there was an interlayer consisting of coarse grains of chromium-based solid solution. It was shown by EDS that Co, Ni and Mo (15–20 wt.%) were dissolved in this phase. The substrate region immediately adjacent to the oxidized layer consisted of the Ni3Al phase formed via Ni depletion in NiAl (Figure 17 and Figure 18, spectrum 8). Lamellar AlN inclusions sized <1 µm (Figure 17 and Figure 18, spectra 3 and 4) were detected at the Ni3Al/MoNi interface (Figure 17 and Figure 18, spectra 3 and 4). They were formed via the diffusion of nitrogen dissolved in the alloy along grain boundaries towards the sample surface and interaction with aluminum.
Table 8.
Spectra | O | N | Al | Cr | Co | Ni | Mo | Ru |
---|---|---|---|---|---|---|---|---|
1 | 6.32 | - | 8.18 | 41.52 | 11.91 | 16.07 | 14.16 | 1.83 |
2 | 49.55 | - | 49.06 | 1.39 | - | - | - | - |
3 | 14.36 | 7.54 | 50.32 | 1.37 | 2.06 | 24.34 | - | - |
4 | - | 32.57 | 67.43 | - | - | - | - | - |
5 | - | - | 0.64 | 50.95 | 14.52 | 19.46 | 14.42 | - |
6 | 50.65 | - | 49.35 | - | - | - | - | - |
7 | 20.58 | - | 22.52 | 19.71 | 10.36 | 10.80 | 16.04 | - |
8 | - | - | 15.67 | 12.89 | 7.24 | 64.19 | - | - |
Ru is an efficient getter of oxygen and nitrogen [2]. Doping the alloy with this element significantly reduced the weight gain by the samples in oxidative testing. It is most likely that as oxygen diffused deep into the sample, Ru dissolved in the (Cr) phase formed stable complex oxide. The examination of the lamella revealed inclusions of this oxide. The small size of inclusions did not allow us to accurately identify the phase according to the electron diffraction data (Figure 18). However, relying on the chemical composition of this region, a hypothesis can be put forward that this oxide was chromium–ruthenium double oxide (CrxRuy)O2.
Similar to alloy 2, the oxidized surface of the alloy with composition 4 (base+2.5%Mo-1.5%Re-1.5%Ta-0.2%Ti) (Figure 20) consisted of three layers. The top 40-µm-thick oxide layer composed of Al2O3 and Co2CrO4 spinel was characterized by low density and high pore content. Below, there was a thin continuous sublayer (5 µm) composed of Al2O3, which impeded oxygen penetration inside the material. A thick layer (up to 100 µm) based on AlN with inclusions of chromium-containing phases (Cr,Co)Ni, (Cr)MoRe and (Cr)Mo lay at the boundary with the substrate.
A lamella cut from the transverse section of the transitional MeN-Me layer in which nitrides are formed was studied by TEM (the lamella cutting site is shown in Figure 20). The structure of the lamella is presented in Figure 21 and Figure 22 and Table 9. Figure 21 also shows the EDS element distribution maps, where Ti inclusions were detected (spectra 1, 2 and 9). Aluminum nitride AlN, having the hexagonal crystal lattice (space group P63mc) and lattice parameters a = 3.083 Å, c = 5.001 Å, was the major phase of the transitional layer (Figure 21, spectra 3, 7 and 8). Nitrogen diffusing along boundaries of the grains of the loose Al2O3 + Co2CrO4 oxide layer into the metal, as well as nitrogen impurity dissolved in the alloy, reacted with aluminum contained in the matrix to give rise to AlN. Local Al depletion in the alloy yielded chromium (Cr)-based solid solution containing Ti, Co, Ni, Mo and Re at concentrations ranging from 7 to 25 wt.% (Figure 21, spectra 1, 2, 4, 5 and 6).
Table 9.
Spectra | N | Al | Ti | Cr | Co | Ni | Mo | Re |
---|---|---|---|---|---|---|---|---|
1 | - | - | 18.93 | 45.84 | 6.16 | 19.54 | 9.55 | - |
2 | 1.91 | 0.34 | 4.42 | 39.57 | 9.56 | 16.15 | 13.57 | 14.48 |
3 | 24.58 | 78.06 | - | 0.36 | - | - | - | - |
4 | - | - | - | 37.41 | 10.60 | 17.47 | 15.16 | 19.36 |
5 | 1.87 | - | - | 51.61 | 7.96 | 25.89 | 12.68 | - |
6 | - | - | - | 35.57 | 10.44 | 17.34 | 14.69 | 21.97 |
7 | 23.39 | 76.61 | - | - | - | - | - | - |
8 | 23.16 | 79.84 | - | - | - | - | - | - |
9 | 24.37 | - | 63.48 | 9.64 | 0.73 | 1.80 | - |
Submicron-sized inclusions of the fcc phase TiN with lattice parameter a = 4.205 Å were detected at the boundaries of the grains of chromium (Cr)-based solid solution and the Cr/aluminum nitride (AlN) interface (Figure 22). Not only did the resulting TiN bind nitrogen dissolve in the alloy, thus reducing its concentration (Table 3), but it also enhanced the activity of aluminum diffusing towards the surface, which contributed to the formation of a dense oxide layer [33,39].
The oxidized layer on the surface of the base+2.5%Mo-1.5%Re-1.5%Ta-0.2%Zr alloy had a structure identical to those of alloys 2 and 4. Its average thickness was 95 µm. A loose layer composed of a mixture of the Al2O3 + Co2CrO4 phases and a dense interlayer consisting of Al2O3 were formed on the surface (Figure 23). The significant high-temperature oxidation resistance was presumably ensured by nanosized inclusions of the Zr5Al3O0.5 phase as demonstrated earlier [32] for nickel monoaluminide doped with 0.5% Zr. The MoNi phase and (Cr)Re,Zr, (Cr)Re and (Cr)Co,Ni solid solutions were observed in the transitional layer. The metal layer of the NiAl matrix also contained AlN inclusions, being indicative of nitrogen diffusion along grain boundaries.
4. Conclusions
Cast alloys based on NiAl-Cr-Co (base+) with complex dopants added (base+2.5Mo-0.5Re-0.5Ta, base+2.5Mo-1.5Re-1.5Ta, base+2.5Mo-1.5Ta-1.5La-0.5Ru, base+2.5Mo-1.5Re-1.5Ta-0.2Ti, and base+2.5Mo-1.5Re-1.5Ta-0.2Zr) were fabricated by centrifugal SHS metallurgy.
The chemical composition was found to be consistent with the calculated one. The total content of impurity elements was 0.15 ± 0.02 wt.% and lay within the acceptance region. Due to binding of dissolved oxygen and nitrogen to form oxides and nitrides, doping with Ti and Ru reduced the negative role of gas impurities and enhanced high-temperature oxidation resistance of the alloy.
The kinetics and the mechanism of oxidation of alloys at T = 1150 °C were studied; the kinetic regression equations describing the oxidation law were plotted. Al2O3 and Co2CrO4 are the major phases in the oxidized layer. Three layers were found to be formed: I—the continuous Al2O3 layer with Co2CrO4 inclusions; II—the transitional MeN-Me layer with AlN inclusions; and III—the metallic layer with local AlN inclusions.
The positive effect of vacuum pre-annealing of ingots on their high-temperature oxidation resistance was observed for the base+2.5Mo-1.5Re-1.5Ta+(TVT) alloy as an example. The total weight gain of the annealed samples after the tests decreased threefold: from 120 ± 5 g/m2 to 40 ± 5 g/m2.
Phases containing ruthenium and titanium, which reduce the content of gas impurities in the base+ 2.5Mo-1.5Ta-1.5La-0.5Ru alloy to the value ∑O,N = 0.0145 wt.% and the base+2.5Mo-1.5Re-1.5Ta-0.2Ti alloy to the value ∑O,N = 0.0223 wt.%, were identified by TEM.
The NiAl-12Cr-6Co-2.5Mo-1.5Re-1.5Ta-0.2Ti alloy was found to have the optimal composition in this experimental series; it was characterized by strength properties σucs = 1644 ± 30 MPa, σys = 1518 ± 25 MPa and the total weight gain after oxidation of 52 g/m2.
Acknowledgments
The authors are grateful to N.V. Shvindina for performing SEM-EDS and S.I. Rupasov for conducting the strength tests.
Author Contributions
Conceptualization, E.A.L., V.V.S. and M.I.A.; methodology, E.A.L. and V.V.S.; investigation V.V.S., M.I.A., Y.Y.K. and P.A.L.; writing—original draft preparation, V.V.S., M.I.A., M.Y.B. and E.A.L.; writing—review and editing, E.A.L., V.V.S., M.I.A. and P.A.L.; visualization, M.I.A. and M.Y.B.; supervision, E.A.L. All authors have read and agreed to the published version of the manuscript.
Institutional Review Board Statement
Not applicable.
Informed Consent Statement
Not applicable.
Data Availability Statement
Data is contained within the article.
Conflicts of Interest
The authors declare no conflict of interest.
Funding Statement
This work was carried out with financial support from the Russian Science Foundation (project no. 19-79-10226 https://rscf.ru/project/19-79-10226).
Footnotes
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References
- 1.Logunov A.V. Heat-Resistant Nickel-Based Alloys for Blades and Discs of Gas Turbines. Gas Turbine Technologies; Rybinsk, Russia: 2017. p. 854. [Google Scholar]
- 2.Wang Y., Guo H.B., Peng H., Peng L.Q., Gong S.K. Diffusion barrier behaviors of (Ru,Ni)Al/NiAl coatings on Ni-based superalloy substrate. Intermetallics. 2011;19:191–195. doi: 10.1016/j.intermet.2010.08.016. [DOI] [Google Scholar]
- 3.Wang D., Liang Y., Ning H., Wang B. Effects of Zr and Co on the microstructure and mechanical properties of NiAl-based alloys. J. Alloys Compd. 2021;883:160815. doi: 10.1016/j.jallcom.2021.160815. [DOI] [Google Scholar]
- 4.Sui X., Lu J., Wei D., Zhang L., Wang R., Zhao W., Zhang W. Unveiling the influence of TiN on the microstructure and high-temperature oxidation behavior of Ti-Al-Cr composite coating. Corros. Sci. 2022;206:110539. doi: 10.1016/j.corsci.2022.110539. [DOI] [Google Scholar]
- 5.Hu L., Zhang G., Hu W., Gottstein G., Bogner S., Bührig-Polaczek A. Tensile creep of directionally solidified NiAl–9Mo in situ composites. Acta Mater. 2013;61:7155–7165. doi: 10.1016/j.actamat.2013.08.017. [DOI] [Google Scholar]
- 6.Seemüller C., Heilmaier M., Haenschke T., Bei H., Dlouhy A., George E.P. Influence of fiber alignment on creep in directionally solidified NiAl–10Mo in-situ composites. Intermetallics. 2013;35:110–115. doi: 10.1016/j.intermet.2012.12.007. [DOI] [Google Scholar]
- 7.Bei H., George E.P. Microstructures and mechanical properties of a directionally solidified NiAl–Mo eutectic alloy. Acta Mater. 2005;53:69–77. doi: 10.1016/j.actamat.2004.09.003. [DOI] [Google Scholar]
- 8.Shang Z., Shen J., Wang L., Du Y., Xiong Y., Fu H. Investigations on the microstructure and room temperature fracture toughness of directionally solidified NiAl-Cr(Mo) eutectic alloy. Intermetallics. 2015;57:25–33. doi: 10.1016/j.intermet.2014.09.012. [DOI] [Google Scholar]
- 9.Walter J.L., Cline H.E. The effect of solidification rate on structure and high-temperature strength of the eutectic NiAl-Cr Metall. Mater. Tran. B. 1970;1:1221–1229. doi: 10.1007/BF02900234. [DOI] [Google Scholar]
- 10.Cui C.Y., Chen Y.X., Guo J.T., Li D.X., Ye H.Q. Preliminary investigation of directionally solidified NiAl–28Cr–5.5Mo–0.5Hf composite. Mater. Lett. 2000;43:303–308. doi: 10.1016/S0167-577X(99)00278-5. [DOI] [Google Scholar]
- 11.Voitovich R.F., Golovko E.I. High-Temperature Oxidation of Metals and Alloys. Naukova Dumka; Kyiv, Ukraine: 1980. p. 296. [Google Scholar]
- 12.Klumpes R., Maree C.H.M., Schramm E., de Wit J.H.W. The influence of chromium on the oxidation of ß-NiAl at 1000 °C. Mater. Corros. 1996;47:619–624. doi: 10.1002/maco.19960471105. [DOI] [Google Scholar]
- 13.Johnson D.R., Chen X.F., Oliver B.F. Processing and mechanical properties of in-situ composites from the NiAlCr and the NiAl(Cr,Mo) eutectic systems. Intermetallics. 1995;3:99–113. doi: 10.1016/0966-9795(95)92674-O. [DOI] [Google Scholar]
- 14.Yang J.C., Schumann E., Levin I., Rühle M. Transient oxidation of NiAl. Acta Mater. 1998;46:2195–2201. doi: 10.1016/S1359-6454(97)00378-9. [DOI] [Google Scholar]
- 15.Grabke H. Oxidation of NiAl and FeAl. Intermetallics. 1999;7:1153–1158. doi: 10.1016/S0966-9795(99)00037-0. [DOI] [Google Scholar]
- 16.Gao W., Li Z., Wu Z., Li S., He Y. Oxidation behavior of Ni3Al and FeAl intermetallics under low oxygen partial pressures. Intermetallics. 2002;10:263–270. doi: 10.1016/S0966-9795(01)00132-7. [DOI] [Google Scholar]
- 17.Bo L., Fei L., Cong L., Yimin G., Congmin F., Xiaohu H. Effect of Cr element on the microstructure and oxidation resistance of novel NiAl-based high temperature lubricating composites. Corros. Sci. 2021;188:109554. doi: 10.1016/j.corsci.2021.109554. [DOI] [Google Scholar]
- 18.Ghoussoub J.N., Utada S., Pedraza F., Dick-Cleland W.J.B., Tang Y.T., Reed R.C. Alloy Design for Additive Manufacturing: Early-Stage Oxidation of Nickel-Based Superalloys. Met. Mater. Trans. A. 2023;54:1721–1729. doi: 10.1007/s11661-022-06860-6. [DOI] [Google Scholar]
- 19.Taylor C.D., Tossey B.M. High temperature oxidation of corrosion resistant alloys from machine learning. NPJ Mater. Degrad. 2021;5:38. doi: 10.1038/s41529-021-00184-3. [DOI] [Google Scholar]
- 20.Kurbatkina V.V. Self-Propagating High-Temperature Synthesis. Elsevier; Amsterdam, The Netherlands: 2017. Nickel Aluminides, in: Concise Encycl; pp. 212–213. [DOI] [Google Scholar]
- 21.Kurbatkina V.V., Patsera E.I., Levashov E.A., Kaplanskii Y.Y., Samokhin A.V. Fabrication of Narrow-Fraction Micropowders of NiAl-Based Refractory Alloy CompoNiAl-M5-3. Int. J. Self-Propagating High-Temp. Synth. 2018;27:236–244. doi: 10.3103/S1061386218040027. [DOI] [Google Scholar]
- 22.Tsvetkov Y.V., Samokhin A.V., Alekseev N.V., Fadeev A.A., Sinaiskii M.A., Levashov E.A., Kaplanskii Y.Y. Plasma Spheroidization of Micropowders of a Heat-Resistant Alloy Based on Nickel Monoaluminide. Dokl. Chem. 2018;483:312–317. doi: 10.1134/S0012500818120030. [DOI] [Google Scholar]
- 23.Kaplanscky Y.Y., Levashov E.A., Korotitskiy A.V., Loginov P.A., Sentyurina Z.A., Mazalov A.B. Influence of aging and HIP treatment on the structure and properties of NiAl-based turbine blades manufactured by laser powder bed fusion. Addit. Manuf. 2020;31:100999. doi: 10.1016/j.addma.2019.100999. [DOI] [Google Scholar]
- 24.Sanin V., Andreev D., Ikornikov D., Yukhvid V. Cast Intermetallic Alloys and Composites Based on Them by Combined Centrifugal Casting—SHS Process. Open J. Metal. 2013;3:12–24. doi: 10.4236/ojmetal.2013.32A2003. [DOI] [Google Scholar]
- 25.Sanin V.V., Filonov M.R., Yukhvid V.I., Anikin Y.A., Mikhailov A.M. Investigation into the influence of the remelting temperature on the structural heredity of alloys fabricated by centrifugal SHS metallurgy. Russ. J. Non-Ferr. Met. 2016;57:124–130. doi: 10.3103/S1067821216020097. [DOI] [Google Scholar]
- 26.Zaitsev A.A., Sentyurina Z.A., Levashov E.A., Pogozhev Y.S., Sanin V.N., Loginov P.A., Petrzhik M.I. Structure and properties of NiAl-Cr(Co,Hf) alloys prepared by centrifugal SHS casting. Part 1—Room temperature investigations. Mater. Sci. Eng. A. 2017;690:463–472. doi: 10.1016/j.msea.2016.09.075. [DOI] [Google Scholar]
- 27.Zaitsev A.A., Sentyurina Z.A., Levashov E.A., Pogozhev Y.S., Sanin V.N., Sidorenko D.A. Structure and properties of NiAl-Cr(Co,Hf) alloys prepared by centrifugal SHS casting followed by vacuum induction remelting. Part 2—Evolution of the structure and mechanical behavior at high temperature. Mater. Sci. Eng. A. 2017;690:473–481. doi: 10.1016/j.msea.2017.02.089. [DOI] [Google Scholar]
- 28.Kaplanskii Y.Y., Zaitsev A.A., Sentyurina Z.A., Levashov E.A., Pogozhev Y.S., Loginov P.A., Logacheva A.I. The Structure and Properties of Pre-Alloyed NiAl-Cr(Co,Hf) Spherical Powders Produced by Plasma Rotating Electrode Processing for Additive Manufacturing. J. Mater. Res. Technol. 2018;7:461–468. doi: 10.1016/j.jmrt.2018.01.003. [DOI] [Google Scholar]
- 29.Kaplanskii Y.Y., Zaitsev A.A., Levashov E.A., Loginov P.A., Sentyurina Z.A. NiAl based alloy produced by HIP and SLM of pre-alloyed spherical powders. Evolution of the structure and mechanical behavior at high temperatures. Mater. Sci. Eng. A. 2018;717:48–59. doi: 10.1016/j.msea.2018.01.057. [DOI] [Google Scholar]
- 30.Kaplanskii Y.Y., Levashov E.A., Bashkirov E.A., Korotitskiy A.V. Effect of molybdenum on structural evolution and thermomechanical behavior of a heat-resistant nickel aluminide-based alloy. J. Alloys Compd. 2021;892:162247. doi: 10.1016/j.jallcom.2021.162247. [DOI] [Google Scholar]
- 31.Sanin V.V., Kaplansky Y.Y., Aheiev M.I., Levashov E.A., Petrzhik M.I., Bychkova M.Y., Samokhin A.V., Fadeev A.A., Sanin V.N. Structure and Properties of Heat-Resistant Alloys NiAl–Cr–Co–X (X = La, Mo, Zr, Ta, Re) and Fabrication of Powders for Additive Manufacturing. Materials. 2021;14:3144. doi: 10.3390/ma14123144. [DOI] [PMC free article] [PubMed] [Google Scholar]
- 32.Aheiev M.I., Sanin V.V., Shvindina N.V., Kaplanskii Y.Y., Levashov E.A. Oxidation kinetics and mechanism of nickel alloys. Izv. Vuzov. Poroshkovaya Metall. I Funktsional’nye Pokrytiya (Powder Metall. Funct. Coat.) 2022;16:4–23. doi: 10.17073/1997-308X-2022-3-4-23. (In Russian) [DOI] [Google Scholar]
- 33.Peng X., Li W., Fu L.B., Li Y.T., Jiang S.M., Gong J., Sun C. Role of Re in NiAl bond coating on isothermal oxidation behavior of a thermal barrier coating system at 1100 °C. Corros. Sci. 2023;218:111151. doi: 10.1016/j.corsci.2023.111151. [DOI] [Google Scholar]
- 34.Zhu D., Wang X., Jia P., Cai C., Huang J., Zhou G. One-dimensional γ-Al2O3 growth from the oxidation of NiAl. Corros. Sci. 2023;216:11109. doi: 10.1016/j.corsci.2023.111069. [DOI] [Google Scholar]
- 35.Zhang W.L., Li S.M., Fu L.B., Li W., Sun J., Wang T.G., Jiang S.M., Gong J., Sun C. Preparation and cyclic oxidation resistance of Hf-doped NiAl coating. Corros. Sci. 2022;195:110014. doi: 10.1016/j.corsci.2021.110014. [DOI] [Google Scholar]
- 36.Kovalev A.I., Wainstein D.L., Rashkovskiy A.Y. Influence of Al grain boundaries segregations and La-doping on embrittlement of intermetallic NiAl. Appl. Surf. Sci. 2015;254:323–327. doi: 10.1016/j.apsusc.2015.06.110. [DOI] [Google Scholar]
- 37.Zhao C., Zhou Y., Zou Z., Luo L., Zhao X., Guo F., Xiao P. Effect of alloyed Lu, Hf and Cr on the oxidation and spallation behavior of NiAl. Corros. Sci. 2017;126:334–343. doi: 10.1016/j.corsci.2017.07.016. [DOI] [Google Scholar]
- 38.Han Y., Zhu Z., Li X., Shen S., Ye F. Effects of vacuum pre-oxidation process on thermally-grown oxides layer of CoCrAlY high temperature corrosion resistance coating. Trans. Nonferrous Met. Soc. China. 2015;25:3305–3314. doi: 10.1016/S1003-6326(15)63991-7. [DOI] [Google Scholar]
- 39.Levashov E.A., Mukasyan A.S., Rogachev A.S., Shtansky D.V. Self-Propagating High-Temperature Synthesis of Advanced Materials and Coatings. Int. Mater. Rev. 2017;62:203–239. doi: 10.1080/09506608.2016.1243291. [DOI] [Google Scholar]
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