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. 2023 May 26;23(11):5076–5082. doi: 10.1021/acs.nanolett.3c00996

High-Q Trampoline Resonators from Strained Crystalline InGaP for Integrated Free-Space Optomechanics

Sushanth Kini Manjeshwar , Anastasiia Ciers , Fia Hellman , Jürgen Bläsing , André Strittmatter , Witlef Wieczorek †,*
PMCID: PMC10273471  PMID: 37234019

Abstract

graphic file with name nl3c00996_0006.jpg

Nanomechanical resonators realized from tensile-strained materials reach ultralow mechanical dissipation in the kHz to MHz frequency range. Tensile-strained crystalline materials that are compatible with epitaxial growth of heterostructures would thereby at the same time allow realizing monolithic free-space optomechanical devices, which benefit from stability, ultrasmall mode volumes, and scalability. In our work, we demonstrate nanomechanical string and trampoline resonators made from tensile-strained InGaP, which is a crystalline material that is epitaxially grown on an AlGaAs heterostructure. We characterize the mechanical properties of suspended InGaP nanostrings, such as anisotropic stress, yield strength, and intrinsic quality factor. We find that the latter degrades over time. We reach mechanical quality factors surpassing 107 at room temperature with a Q·f product as high as 7 × 1011Hz with trampoline-shaped resonators. The trampoline is patterned with a photonic crystal to engineer its out-of-plane reflectivity, desired for efficient signal transduction of mechanical motion to light.

Keywords: nanomechanics, optomechanics, photonic crystal, radiation loss, high stress, InGaP


Mechanical dissipation in nano- and micromechanical resonators has been drastically reduced in recent years by the use of dissipation dilution, soft clamping, and strain-engineering techniques.16 Most of these methods require the use of tensile-strained materials, such as the widely employed amorphous SiN4,5,712 and, more recently, crystalline materials such as SiC,13,14 Si,15 GaNAs,16 and InGaP.1719 Ultrahigh-quality-factor mechanical resonators fabricated from these materials open up exciting prospects for nanomechanical sensing by reaching unprecedented force sensitivities15,20,21 and, when the resonators are coupled to light, pave the way for generating optomechanical quantum states at room temperature.8,22,23 Strained crystalline materials compatible with epitaxial layer growth can realize integrated cavity optomechanical devices through bottom-up growth and top-down microfabrication. At the same time, this integrated approach would enable on-chip stability and scalability. Current optomechanical devices incorporating chip-based mechanical resonators that are coupled to out-of-plane light resort to stacking of multiple chips24 or to assembling independent components.25,26 Integrating the free-space optical cavity and the mechanical resonator on a single chip would provide alignment-free devices with ultrasmall mode volumes to drastically increase the interaction strength between out-of-plane light and mechanical motion.

InGaP is a crystalline material that can be epitaxially grown on (Al,Ga)As and, therefore, would enable realization of integrated free-space cavity optomechanics on a chip. Further, InGaP can be grown with tensile strain on (Al,Ga)As determined by the Ga content of the InGaP layer and thus has the potential to lead to ultralow dissipation mechanical resonators. Tensile-strained nanomechanical resonators fabricated from InGaP have been recently demonstrated in membrane17 and string-type geometries.18,19 Membrane-type resonators have thereby reached quality factors of up to 106 at room temperature.17 Further, it was experimentally confirmed that stress is anisotropic in InGaP,18 which opens up new avenues for strain engineering the geometry of nanomechanical resonators.

In our work, we demonstrate trampoline-shaped nanomechanical InGaP resonators that combine low mechanical dissipation with engineered optical reflectivity, a crucial step toward free-space cavity optomechanics on a chip. We achieve mechanical quality factors surpassing 107 at room temperature with trampoline-shaped nanomechanical resonators, which employ a simple geometry to dilute the material’s intrinsic dissipation.8,9,14,27 For transduction of mechanical displacement to the light field we engineer the out-of-plane reflectivity of the resonator at telecom wavelengths by patterning the central area of the 73 nm thick InGaP trampoline with a photonic crystal.8,26,2831 We first study the mechanical material properties of the strained InGaP layer1719 by fabricating and characterizing string resonators to determine the intrinsic stress, yield strength, and the intrinsic quality factor. We then demonstrate high-Q trampoline-shaped InGaP nanomechanical resonators with engineered optical reflectivity.

We fabricate InGaP string- and trampoline-shaped mechanical resonators from a III–V material heterostructure grown via metal–organic chemical vapor deposition (MOCVD). A 400 nm thick GaAs buffer layer is grown on a GaAs substrate along the [0 0 1] crystal direction followed by a 73 nm thick In1–xGaxP layer, a sacrificial layer of Al0.68Ga0.32As with a thickness of 785 nm, and another In1–xGaxP layer of 75 nm thickness. Note that the as-grown structure would allow for implementing sub-μm-spaced two-element optomechanics on a chip.26

The devices in this work were fabricated after stripping the top In1–xGaxP and Al0.68Ga0.32As layers. From X-ray diffraction analysis we find that the gallium content in the as-grown InGaP layer is 0.53 ≤ x ≤ 0.59, with a value of x = 0.5658 matching our inference of released stress from InGaP string resonators. Hence, we will assume throughout the rest of this work x = 0.5658 (abbreviated as 0.57). We use electron-beam lithography to expose the resonator patterns to a resist stack containing an adhesion promoter and an electron beam resist. Chlorine-based RIE-ICP etching is then used to transfer the pattern onto the InGaP device layer followed by releasing the devices with a selective anisotropic wet etch using a mixture of citric acid and hydrogen peroxide.32 Finally, we perform critical point drying to prevent the devices from collapsing due to capillary forces. Figure 1 shows fabricated trampoline resonators.

Figure 1.

Figure 1

Tensile-strained trampoline resonators made from a 73 nm thick crystalline InGaP layer. Scanning electron microscope (SEM) images of (a) trampoline resonators oriented along different crystal directions and varied tether length (tether width 1 μm, central pad area 100 × 100 μm2). The angles 0°, 45°, and 90° denote the crystal directions [1 1 0], [1 0 0], and Inline graphic respectively. (b) Close-up of a trampoline resonator with a tether length of 750 μm. Enlarged views of the resonator in (b) showing (c) the photonic crystal (PhC) pattern on the central area with PhC hole radius rPhC = 544 nm and period aPhC = 1304 nm, (d) the tether connection to the central pad, and (e) the tether clamping to the substrate.

Material properties of the InGaP layer, in particular its tensile stress, yield strength, and intrinsic mechanical quality factor, are key factors to engineer high-quality mechanical resonators at desired eigenfrequencies. We determine these material properties experimentally by fabricating nanostring resonators, following methods introduced in refs (18), (19), (33), and (34).

The intrinsic stress in the In0.43Ga0.57P layer originates from its lattice mismatch with the GaAs buffer layer. The in-plane as-grown strain of the thin In1–xGaxP layer is

graphic file with name nl3c00996_m001.jpg 1

where aGaAs and Inline graphic are the lattice constants of GaAs and In1–xGaxP, respectively. One can tune the as-grown stress in the In1–xGaxP device layer by varying x to obtain compressive stress for x < 0.515 and tensile stress for x > 0.515 (see Supporting Information). The InGaP layer can be grown without defects until a certain critical thickness governed by x, which is 1132 nm for x = 0.5658.35 In our case, the InGaP device layer has an as-grown thickness of 73 nm, which is well below this limit (see Supporting Information).

The crystalline structure of In1–xGaxP results in an orientation-dependent released axial stress σ(x, θ)18 (for details see Supporting Information)

graphic file with name nl3c00996_m003.jpg 2

where the angle θ is defined with respect to the crystal directions as shown in the inset of Figure 2. Importantly, σ(x, θ) is the released stress as Young’s modulus E(x, θ) accounts for an anisotropic Poisson ratio (see Supporting Information). We determine the anisotropic stress in In0.43Ga0.57P from measurements of string resonators of different lengths oriented along different directions. The eigenmode frequencies of tensile-strained string resonators are given by36

graphic file with name nl3c00996_m004.jpg 3

where n is the mode number, ρ(x) is the density of the material, and L is the length of the resonator.

Figure 2.

Figure 2

Tensile stress of the 73 nm thick In0.43Ga0.57P string resonators. (a) Mechanical frequencies of the fundamental mode of string resonators of different lengths (with a width of 200 nm) along the three crystal directions [1 1 0], [1 0 0], and Inline graphic denoted as 0°, 45°, and 90°, respectively. The lines are a fit to the expected frequencies of tensile-strained string resonators (eq 3). The inset shows an optical microscope image of string resonators of different lengths oriented along 0°. (b) The extracted tensile stress along different crystal directions is shown as points. The dashed line shows the tensile stress σ(x, θ) predicted from in-plane strain ϵ(x) and Young’s modulus E(x, θ); see eq 2. The solid line shows the tensile stress that takes into account an additional angle-dependent contribution to Young’s modulus (see eq 4).

We fabricated string resonators with lengths between 20 and 160 μm and a width of 200 nm along the crystal directions [1 1 0], [1 0 0], and Inline graphic We measured their thermally driven displacement noise power spectrum (NPS) in a high vacuum environment with an optical homodyne detection setup; for details see ref (31). The same setup was used for characterizing the mechanical properties of the InGaP trampoline resonators. Figure 2a shows the measured fundamental eigenmode frequencies of the 200 nm wide string resonators. We use the measured eigenfrequencies of all identified eigenmodes to determine the stress along the different crystal directions using eq 3 and ρ(0.57). We obtain a released stress in the string resonators of σ(0°) = 467.7(71) MPa, σ(45°) = 313.3(54) MPa, and σ(90°) = 374.9(164) MPa.

We can estimate the Ga content of the In1–xGaxP layer based on the experimentally determined stress values by using eq 2. Note that this equation accounts for stress relaxation by incorporating Poisson’s ratio in E(x, θ) (see Supporting Information). We estimate a Ga content of 0.5667, 0.5649, and 0.5566 from the stress along 0°, 45°, and 90°, respectively. As the Ga contents along 0° and 45° are similar, we use the average value of x = 0.5658 to estimate the expected crystal-direction-dependent released stress, seen as the dashed-line in Figure 2b. This prediction captures the released stress along 0° and 45°, as expected, but not along 90°. However, from the crystal structure, we would expect the stress to be identical along the 0° and 90° directions. This unexpected deviation has also been observed in ref (18), which attributed it to a defect density that varies along different crystal directions. Alternatively, spontaneous ordering in MOCVD growth may also be a possible reason.37 This modification of Young’s modulus, ΔE(x, θ), can be modeled with a cos(2θ) function as

graphic file with name nl3c00996_m006.jpg 4

We obtain α = −5.9 GPa and β = 11.3 GPa (in ref (18) α = −5.5 GPa, β = 5.1 GPa). The stress including the deviation ΔE(x, θ) is shown as the solid line in Figure 2b and captures the data well. We attribute the remarkably small difference between our determined values for α and β and the ones from ref (18) to the difference in growth method (MOCVD vs MBE), the gallium content (0.5658 vs 0.59), and the resonator’s support geometry. Experimental determination of Young’s modulus along the crystal directions of InGaP38 together with detailed material studies is required to explore the microscopic origin for this additional anisotropy.

It is desirable to maximize the strain (respective stress) in the mechanical device layer to increase the effect of dissipation dilution. Since InGaP is a brittle material, a limit is set by the maximal applicable stress, i.e., σyield(θ), after which the material breaks. We determine the yield strength of the InGaP layer experimentally following the method from ref (34). In our case, the yield stress depends on the orientation of the string resonators with respect to the crystal directions. We obtain yield stresses σyield of 5.5(8) GPa, 3.3(5) GPa, and 3.7(5) GPa along 0°, 45°, and 90°, respectively (see Supporting Information). The corresponding yield strain of ϵyield(θ) = σyield(θ)/[E(θ) + ΔE(θ)] is 0.043(8), 0.041(8), and 0.034(5), along 0°, 45°, and 90°, respectively. The obtained yield strength is comparable to Si3N4 (6 GPa) but lower than the one of SiC (21 GPa) or diamond (35 GPa).6

The quality factor Q of a mechanical resonator is generally given by39

graphic file with name nl3c00996_m007.jpg 5

where Qint and Qext are the quality factors limited by intrinsic and extrinsic loss mechanisms, respectively. In the following, we determine Qint, which captures material-related loss processes of the 73 nm thick InGaP layer. To this end, we use string resonators and we confirmed that they are not limited by clamping loss or gas damping (Supporting Information), which determine Qext in our case.

We determine Qint of the 73 nm InGaP layer from measurements of the quality factor of strained InGaP string resonators. Importantly, the stress in the string resonators dilutes Qint by a factor D(6,33,36)

graphic file with name nl3c00996_m008.jpg 6

The dilution factor D depends on the stress, resonator geometry and displacement mode profile. For a uniform string resonator, one obtains33,40

graphic file with name nl3c00996_m009.jpg 7

where n is the mode number and λ is a stress parameter given as

graphic file with name nl3c00996_m010.jpg 8

with length L and thickness h of the string resonator.

We fabricated strings of different lengths with a width of 2 μm oriented along different crystal directions to infer Qint. Figure 3a shows the measured quality factors for the fundamental mode extracted from ringdown measurements. Using D1, we obtain Qint of 7550 ± 140 and 8150 ± 320 along 0° and 90°, respectively. Our determined average Qint of about 7.9 × 103 for the 73 nm thick InGaP layer is comparable to LPCVD-grown Si3N4 (66 nm thick, Qint =3.75 × 103;41 with Qint = 6.9 × 103 × h[100 nm] 33,41 for 73 nm SiN, Qint = 5 × 103) and 14 nm thick s-Si (8 × 10315) and larger than for 75 nm thick SiC (1.5 × 10214).

Figure 3.

Figure 3

Determination of the intrinsic mechanical quality factor using InGaP string resonators. (a) Measured Q factors (squares) for the fundamental mode of string resonators with varying lengths oriented along 0° and 90°. The dashed (solid) lines are fits to extract Qint at day 1 (day 60). The dots (crosses) show QDFEM obtained from FEM, when using Qint from day 1 (day 60) as input. (b) We observe that Qint degrades over time, shown for two samples (squares and circles). The solid (dashed) line indicates when the sample was stored in vacuum (ambient condition). (c) The relative change of the resonance frequency of the string resonators, i.e., Δf = (fday xfday 1)/fday 1, is shown over the same time period.

The dilution factor can be numerically computed using FEM simulations (see Supporting Information).27,33,42 This approach is required when analyzing dissipation dilution of more complex mechanical resonator geometries, as in our case, trampoline mechanical resonators including a PhC pattern. We verify the FEM approach by simulating the dilution factor DFEM for string resonators. Using the experimentally determined intrinsic quality factor, Qint, we calculate QDFEM = DFEMQint, which is shown in Figure 3a. We find that QD is slightly larger than the measured Q factors, similar to other works.14,27,43

We observe that the mechanical quality factor of the string resonators decreases with time. Figure 3b shows this change of Qint for two different samples. The samples were measured in high vacuum, but they were stored in between measurements either in vacuum or under ambient conditions; see Figure 3b. Qint decreases over two months by up to a factor of 4. During the same time period the resonance frequency changes by less than 2%; see Figure 3c. We hypothesize that the degradation of the quality factor is not due to a gradual relaxation of the tensile stress of the InGaP layer. At the moment, we can only speculate that the InGaP layer undergoes some modification, for example, moisture-induced degradation44 or other processes45 that may lead to an increase of mechanical dissipation. Future work is required to determine the cause of the InGaP degradation. To this end, the InGaP layer can be examined periodically with X-ray diffraction (to obtain information about the formation of an oxide surface layer) and photoemission spectroscopy (to obtain data on the elements present on the surface and their chemical state). Scanning near-field optical microscopy, micro-Raman, or tip-enhanced Raman spectroscopy can be used on the InGaP nanomechanical resonators to obtain, e.g., spatial information about potential strain changes. Mitigation strategies include surface passivation46 or capping of the InGaP layer with thin GaAs layers.

For efficient transduction of mechanical motion to out-of-plane light, the reflectivity of the mechanical resonator is desired to be close to unity. At the same time, the thickness of the device layer should be sufficiently thin to keep mechanical damping small. These requirements can be fulfilled by patterning thin mechanical resonators with a PhC.8,26,2831 We, therefore, choose a trampoline-shaped geometry, which allows patterning its central area with a PhC to achieve the desired reflectivity and at the same time allows decreasing mechanical dissipation by use of dissipation dilution;8,9 see Figure 4b.

Figure 4.

Figure 4

Mechanical properties of InGaP trampoline resonators. (a) Noise power spectrum (NPS) of a trampoline resonator of 750 μm tether length, 1 μm tether width, and central PhC pad size of 100 × 100 μm2. The insets show FEM simulated mode shapes depicting the out-of-plane displacement w. (b) FEM simulations of the first principal stress in the released device at the tether connection to the pad and the clamping region. (c) Ringdown measurement on day 5 of the fundamental mode of the trampoline from (a), which was placed in vacuum directly after fabrication on day one. We obtain a Q of 1.8 × 107 from a fit (solid line) to the decay. (d) Dependence of Q on pressure for the fundamental mode of trampolines of different lengths with tethers oriented along different crystal directions (0°/90° marked by a circle, 45°/135° by a cross). The solid lines show the quality factor limited by gas damping for trampolines of tether lengths 250 μm, 500 μm, and 750 μm.

References (8) and (9) demonstrated that high-Q trampolines can be realized with thin and long tethers that connect the central pad to the support. In our work, we can reliably fabricate InGaP trampolines with a tether width of 1 μm and tether length of up to 750 μm (Figure 1b) and with a radius of 10 μm at the tether clamp to the support (Figure 1e) and of 200 μm at the tether clamp to the pad (Figure 1d).

Figure 4a shows a thermally driven displacement noise power spectrum of an InGaP trampoline resonator. The tethers of this device are 750 μm long and oriented along 45°/135°. We observe the fundamental mode at 38.5 kHz and several higher-order modes, which we identify by comparing measured eigenfrequencies to the ones simulated via FEM. Table 1 shows measured fundamental mode eigenfrequencies for trampolines with various tether lengths. As expected, we find that trampolines with shorter tether lengths exhibit higher resonance frequencies. We observe that trampolines whose tethers are oriented along 0°/90° have larger frequencies than the ones oriented along 45°/135°. We can understand this behavior as the stress along 0°/90° is larger than the one along 45°/135° (see Figure 2b) resulting in a higher resonance frequency. We find a good agreement with the eigenfrequencies calculated with FEM. In the FEM simulations, we take into account the anisotropy of Young’s modulus (eq 2) but do not account for its deviation (eq 4), which is a possible reason for the small discrepancy between the FEM and measurement results.

Table 1. Measured and FEM-Simulated Eigenfrequencies of the Fundamental Mode of Trampolines with Varied Tether Length and Orientation.

tether
frequency (kHz)
length (μm) orientation measured simulated
250 0°/90° 90.9 106.9
  45°/135° 80 90.5
500 0°/90° 54.2 62.3
  45°/135° 43.7 52.4
750 0°/90° 40.1 47.8
  45°/135° 38.5 40.1

The highest mechanical Q factor that we measure is 1.8 × 107 for the fundamental mode of the InGaP trampoline with 750 μm tether length (see Figure 4c), resulting in a Q·f product of 7 × 1011 Hz. We measured this value at room temperature at a pressure of 8 × 10–6 mbar, which is close to the minimal achievable pressure that we can reach in our setup. With the current devices, we reach a calculated thermal noise limited force sensitivity of 50 aN/Inline graphic When compared to SiN-based membrane-type devices at room temperature, our value lies in the same order of magnitude as reached with phononic band gap SiN membranes (37 aN/Inline graphic21) and SiN trampolines (19.5 aN/Inline graphic8,9).

We already noticed that the mechanical Q of the InGaP string resonators decreases with time. We observe the same trend for the InGaP trampoline resonators. This behavior complicates a definite identification of the loss mechanism that limits the Q of InGaP trampolines. Nevertheless, we look at different mechanical damping mechanisms in the following to analyze limits in achieving even higher Q. We consider gas damping first. To this end, we performed pressure-dependent measurements of various trampolines; the results are shown in Figure 4d. We observe a linear increase of Q with a decrease in pressure, as expected from gas damping36 (Supporting Information). The Q-factor of the 750 μm long trampoline (dark blue crosses) that was fabricated and immediately measured follows this gas-damping prediction. However, for samples that were measured with a delay after fabrication (other colors in Figure 4d), we observe a deviation from the gas damping limit at lower pressures, which indicates that the Q factor of these trampolines reaches another limiting mechanism. As reaching low pressures requires some days of pumping, this deviation may originate from the degradation of Qint over time. The amount of dissipation dilution achieved with the trampoline geometry may also limit the maximally achievable Q. To evaluate this, we computed DQ via FEM and obtain a value of DQ = 1750 for the 750 μm tethered trampoline. With Qint = 7.9 × 103 we obtain QD ∼ 1.38 × 107. This Q factor is close to the experimentally obtained result. Hence, the trampoline resonators may currently be limited by the achievable gas pressure or by the amount of dissipation dilution. Stabilization of Qint is required to identify with certainty the limiting damping mechanism and apply strategies to further reduce it.

In the following, we characterize the optical reflectance of the trampoline resonators patterned with a PhC. For details of the measurement setup, we refer the reader to ref (31). Figure 5a shows reflectance spectra of three trampolines with square PhC patterns of lattice constant aPhC = 1309 nm and PhC radii rPhC of 480 nm, 553 nm, and 605 nm. We evaluated the PhC parameters via image recognition applied to high-magnification SEM images of the respective PhC pattern after fabrication. We observe that the PhC trampolines demonstrate an engineered reflectance in the wavelength range of 1510–1620 nm with a pronounced modulation. The latter can be understood by noting that the trampoline is separated from the GaAs substrate by a vacuum gap of about 15 μm, originating from the release of the trampoline in the wet etch fabrication step. This gap forms a low-quality optical cavity between the trampoline and the GaAs substrate.

Figure 5.

Figure 5

Reflectance spectra of InGaP trampoline resonators patterned with a PhC. (a) Measurements for rPhC of 480 nm, 553 nm, and 605 nm (dots) and RCWA simulation for rPhC = 605 nm (solid line). (b) Simulation of a reflectance map when varying the PhC radius. Other parameters are aPhC = 1309 nm, dPhC = 73 nm, vacuum gap 14.8 μm, and the GaAs substrate is a semi-infinite layer.

This interpretation is supported by rigorous coupled wave analysis (RCWA) simulations of our system31,47 (for parameters see Supporting Information). Figure 5b shows a simulated reflectance map when varying the PhC radius. We observe pronounced dips in reflectivity when hitting the cavity resonance condition. The simulated free spectral range is about 75 nm, which is close to the expected value given by the gap and noting that the PhC additionally modifies the effective cavity length.48 When decreasing rPhC, the cavity dip shifts to longer wavelengths implying an increased cavity length. This effect is also seen in the measurements, Figure 5a. Another dip occurs in the reflectance map, which originates from the coupling of focused light into a guided resonance of the PhC.31,49

To conclude, we have demonstrated that trampoline-shaped resonators in tensile-strained 73 nm thick InGaP exhibit mechanical quality factors surpassing 107 at room temperature at pressures of 8 × 10–6 mbar, resulting in a Q·f product of 7 × 1011 Hz. An enhancement by a factor of 10 would place the presented InGaP trampoline mechanical resonators in the regime of quantum optomechanics at room temperature.8 The trampoline resonator was patterned with a PhC to engineer its out-of-plane reflectivity. We observed that the intrinsic mechanical quality factor of the InGaP mechanical resonators decreased over time. This undesired effect should receive future attention and may require surface passivation techniques.46 Once this issue is solved, mechanical dissipation in InGaP resonators can be further reduced by a simple increase of the tether length of the trampoline8,9 or by applying more sophisticated methods such as hierarchical clamping structures,27 machine-learning supported engineering of mechanical dissipation,11,12 quasi-phononic band gaps,4 or density phononic crystal engineering.50 Notably, the InGaP mechanical device layers can be incorporated in (Al,Ga)As heterostructures via epitaxial layer growth. This approach would allow the realization of integrated free-space cavity optomechanical systems in a crystalline material platform (see Supporting Information). Such compact optomechanical systems could implement bound-states in the continuum-based optomechanics,51 multielement,52 or hybrid optomechanical systems53 on a chip.

The data used in this work can be found in the open-access Zenodo database: 10.5281/zenodo.7441332.54

Acknowledgments

We gratefully acknowledge Eva Weig, Nils Johan Engelsen, and Claus Gärtner for insightful discussions, Max Trippel and Tommy Müller for support in sample growth, and Joachim Ciers for ellipsometer measurements. This work was supported in part by the QuantERA project C’MON-QSENS!, the Knut and Alice Wallenberg Foundation through a Wallenberg Academy Fellowship (W.W.), by the Wallenberg Center for Quantum Technology (WACQT, A.C.), by Chalmers Excellence Initiative Nano, and by the Swedish Research Council (Grant 2019-04946). Sample fabrication was performed in the Myfab Nanofabrication Laboratory at Chalmers. Simulations were performed on resources provided by the Swedish National Infrastructure for Computing (SNIC) at Tetralith, Linköping University, partially funded by the Swedish Research Council (Grant 2018-05973).

Supporting Information Available

The Supporting Information is available free of charge at https://pubs.acs.org/doi/10.1021/acs.nanolett.3c00996.

  • Details on fabrication, material properties, mechanical damping, parameters, and applications of the demonstrated nanomechanical resonators (PDF)

The authors declare no competing financial interest.

Supplementary Material

nl3c00996_si_001.pdf (2.6MB, pdf)

References

  1. González G. I.; Saulson P. R. Brownian motion of a mass suspended by an anelastic wire. J. Acoust. Soc. Am. 1994, 96, 207–212. 10.1121/1.410467. [DOI] [Google Scholar]
  2. Unterreithmeier Q. P.; Faust T.; Kotthaus J. P. Damping of Nanomechanical Resonators. Phys. Rev. Lett. 2010, 105, 027205. 10.1103/PhysRevLett.105.027205. [DOI] [PubMed] [Google Scholar]
  3. Schmid S.; Jensen K. D.; Nielsen K. H.; Boisen A. Damping Mechanisms in High-Q Micro and Nanomechanical String Resonators. Phys. Rev. B 2011, 84, 165307. 10.1103/PhysRevB.84.165307. [DOI] [Google Scholar]
  4. Tsaturyan Y.; Barg A.; Polzik E. S.; Schliesser A. Ultracoherent nanomechanical resonators via soft clamping and dissipation dilution. Nature Nanotechnol. 2017, 12, 776–783. 10.1038/nnano.2017.101. [DOI] [PMC free article] [PubMed] [Google Scholar]
  5. Ghadimi A. H.; Fedorov S. A.; Engelsen N. J.; Bereyhi M. J.; Schilling R.; Wilson D. J.; Kippenberg T. J. Elastic strain engineering for ultralow mechanical dissipation. Science 2018, 360, 764–768. 10.1126/science.aar6939. [DOI] [PubMed] [Google Scholar]
  6. Sementilli L.; Romero E.; Bowen W. P. Nanomechanical Dissipation and Strain Engineering. Adv. Funct. Mater. 2022, 32, 2105247. 10.1002/adfm.202105247. [DOI] [Google Scholar]
  7. Verbridge S. S.; Parpia J. M.; Reichenbach R. B.; Bellan L. M.; Craighead H. G. High Quality Factor Resonance at Room Temperature with Nanostrings under High Tensile Stress. J. Appl. Phys. 2006, 99, 124304. 10.1063/1.2204829. [DOI] [Google Scholar]
  8. Norte R. A.; Moura J. P.; Gröblacher S. Mechanical resonators for quantum optomechanics experiments at room temperature. Phys. Rev. Lett. 2016, 116, 147202. 10.1103/PhysRevLett.116.147202. [DOI] [PubMed] [Google Scholar]
  9. Reinhardt C.; Müller T.; Bourassa A.; Sankey J. C. Ultralow-Noise SiN Trampoline Resonators for Sensing and Optomechanics. Phys. Rev. X 2016, 6, 021001. 10.1103/PhysRevX.6.021001. [DOI] [Google Scholar]
  10. Reetz C.; Fischer R.; Assumpção G.; McNally D.; Burns P.; Sankey J.; Regal C. Analysis of Membrane Phononic Crystals with Wide Band Gaps and Low-Mass Defects. Phys. Rev. Applied 2019, 12, 044027. 10.1103/PhysRevApplied.12.044027. [DOI] [Google Scholar]
  11. Høj D.; Wang F.; Gao W.; Hoff U. B.; Sigmund O.; Andersen U. L. Ultra-Coherent Nanomechanical Resonators Based on Inverse Design. Nat. Commun. 2021, 12, 5766. 10.1038/s41467-021-26102-4. [DOI] [PMC free article] [PubMed] [Google Scholar]
  12. Shin D.; Cupertino A.; de Jong M. H.; Steeneken P. G.; Bessa M. A.; Norte R. A. Spiderweb nanomechanical resonators via bayesian optimization: inspired by nature and guided by machine learning. Adv. Mater. 2022, 34, 2106248. 10.1002/adma.202106248. [DOI] [PubMed] [Google Scholar]
  13. Kermany A. R.; Brawley G.; Mishra N.; Sheridan E.; Bowen W. P.; Iacopi F. Microresonators with Q-factors over a million from highly stressed epitaxial silicon carbide on silicon. Appl. Phys. Lett. 2014, 104, 081901. 10.1063/1.4866268. [DOI] [Google Scholar]
  14. Romero E.; Valenzuela V. M.; Kermany A. R.; Sementilli L.; Iacopi F.; Bowen W. P. Engineering the dissipation of crystalline micromechanical resonators. Phys. Rev. Applied 2020, 13, 044007. 10.1103/PhysRevApplied.13.044007. [DOI] [Google Scholar]
  15. Beccari A.; Visani D. A.; Fedorov S. A.; Bereyhi M. J.; Boureau V.; Engelsen N. J.; Kippenberg T. J. Strained crystalline nanomechanical resonators with quality factors above 10 billion. Nat. Phys. 2022, 18, 436–441. 10.1038/s41567-021-01498-4. [DOI] [Google Scholar]
  16. Onomitsu K.; Mitsuhara M.; Yamamoto H.; Yamaguchi H. Ultrahigh-Q Micromechanical Resonators by Using Epitaxially Induced Tensile Strain in GaNAs. Appl. Phys. Express 2013, 6, 111201. 10.7567/APEX.6.111201. [DOI] [Google Scholar]
  17. Cole G. D.; Yu P.-L.; Gärtner C.; Siquans K.; Moghadas Nia R.; Schmöle J.; Hoelscher-Obermaier J.; Purdy T. P.; Wieczorek W.; Regal C. A.; Aspelmeyer M. Tensile-strained InxGa1–xP membranes for cavity optomechanics. Appl. Phys. Lett. 2014, 104, 201908. 10.1063/1.4879755. [DOI] [Google Scholar]
  18. Bückle M.; Hauber V. C.; Cole G. D.; Gärtner C.; Zeimer U.; Grenzer J.; Weig E. M. Stress control of tensile-strained InxGa1–xP nanomechanical string resonators. Appl. Phys. Lett. 2018, 113, 201903. 10.1063/1.5054076. [DOI] [Google Scholar]
  19. Bückle M.; Klaß Y. S.; Nägele F. B.; Braive R.; Weig E. M. Universal Length Dependence of Tensile Stress in Nanomechanical String Resonators. Phys. Rev. Applied 2021, 15, 034063. 10.1103/PhysRevApplied.15.034063. [DOI] [Google Scholar]
  20. Mason D.; Chen J.; Rossi M.; Tsaturyan Y.; Schliesser A. Continuous Force and Displacement Measurement below the Standard Quantum Limit. Nat. Phys. 2019, 15, 745–749. 10.1038/s41567-019-0533-5. [DOI] [Google Scholar]
  21. Hälg D.; Gisler T.; Tsaturyan Y.; Catalini L.; Grob U.; Krass M.-D.; Héritier M.; Mattiat H.; Thamm A.-K.; Schirhagl R.; Langman E. C.; Schliesser A.; Degen C. L.; Eichler A. Membrane-Based Scanning Force Microscopy. Phys. Rev. Appl. 2021, 15, L021001. 10.1103/PhysRevApplied.15.L021001. [DOI] [Google Scholar]
  22. MacCabe G. S.; Ren H.; Luo J.; Cohen J. D.; Zhou H.; Sipahigil A.; Mirhosseini M.; Painter O. Nano-acoustic resonator with ultralong phonon lifetime. Science 2020, 370, 840–843. 10.1126/science.abc7312. [DOI] [PubMed] [Google Scholar]
  23. Barzanjeh S.; Xuereb A.; Gröblacher S.; Paternostro M.; Regal C. A.; Weig E. M. Optomechanics for Quantum Technologies. Nat. Phys. 2022, 18, 15–24. 10.1038/s41567-021-01402-0. [DOI] [Google Scholar]
  24. Nair B.; Naesby A.; Dantan A. Optomechanical characterization of silicon nitride membrane arrays. Optics Letters 2017, 42, 1341–1344. 10.1364/OL.42.001341. [DOI] [PubMed] [Google Scholar]
  25. Piergentili P.; Catalini L.; Bawaj M.; Zippilli S.; Malossi N.; Natali R.; Vitali D.; Giuseppe G. D. Two-Membrane Cavity Optomechanics. New J. Phys. 2018, 20, 083024. 10.1088/1367-2630/aad85f. [DOI] [Google Scholar]
  26. Gärtner C.; Moura J. P.; Haaxman W.; Norte R. A.; Gröblacher S. Integrated optomechanical arrays of two high reflectivity SiN membranes. Nano Lett. 2018, 18, 7171–7175. 10.1021/acs.nanolett.8b03240. [DOI] [PMC free article] [PubMed] [Google Scholar]
  27. Bereyhi M. J.; Beccari A.; Groth R.; Fedorov S. A.; Arabmoheghi A.; Kippenberg T. J.; Engelsen N. J. Hierarchical tensile structures with ultralow mechanical dissipation. Nat. Commun. 2022, 13, 3097. 10.1038/s41467-022-30586-z. [DOI] [PMC free article] [PubMed] [Google Scholar]
  28. Bui C. H.; Zheng J.; Hoch S. W.; Lee L. Y. T.; Harris J. G. E.; Wei Wong C. High-Reflectivity, High-Q Micromechanical Membranes via Guided Resonances for Enhanced Optomechanical Coupling. Appl. Phys. Lett. 2012, 100, 021110. 10.1063/1.3658731. [DOI] [Google Scholar]
  29. Makles K.; Antoni T.; Kuhn A. G.; Deléglise S.; Briant T.; Cohadon P.-F.; Braive R.; Beaudoin G.; Pinard L.; Michel C.; Dolique V.; Flaminio R.; Cagnoli G.; Robert-Philip I.; Heidmann A. 2D Photonic-Crystal Optomechanical Nanoresonator. Opt. Lett. 2015, 40, 174–177. 10.1364/OL.40.000174. [DOI] [PubMed] [Google Scholar]
  30. Bernard S.; Reinhardt C.; Dumont V.; Peter Y.-A.; Sankey J. C. Precision Resonance Tuning and Design of SiN Photonic Crystal Reflectors. Opt. Lett. 2016, 41, 5624–5627. 10.1364/OL.41.005624. [DOI] [PubMed] [Google Scholar]
  31. Kini Manjeshwar S.; Elkhouly K.; Fitzgerald J. M.; Ekman M.; Zhang Y.; Zhang F.; Wang S. M.; Tassin P.; Wieczorek W. Suspended photonic crystal membranes in AlGaAs heterostructures for integrated multi-element optomechanics. Appl. Phys. Lett. 2020, 116, 264001. 10.1063/5.0012667. [DOI] [Google Scholar]
  32. Arslan D.; Dehé A.; Hartnagel H. L. New concept of lateral GaAs field emitter for sensor applications. Journal of Vacuum Science & Technology B: Microelectronics and Nanometer Structures Processing, Measurement, and Phenomena 1999, 17, 784–787. 10.1116/1.590640. [DOI] [Google Scholar]
  33. Fedorov S. A.; Engelsen N. J.; Ghadimi A. H.; Bereyhi M. J.; Schilling R.; Wilson D. J.; Kippenberg T. J. Generalized dissipation dilution in strained mechanical resonators. Phys. Rev. B 2019, 99, 054107. 10.1103/PhysRevB.99.054107. [DOI] [Google Scholar]
  34. Bereyhi M. J.; Beccari A.; Fedorov S. A.; Ghadimi A. H.; Schilling R.; Wilson D. J.; Engelsen N. J.; Kippenberg T. J. Clamp-Tapering Increases the Quality Factor of Stressed Nanobeams. Nano Lett. 2019, 19, 2329–2333. 10.1021/acs.nanolett.8b04942. [DOI] [PubMed] [Google Scholar]
  35. People R.; Bean J. C. Calculation of critical layer thickness versus lattice mismatch for GexSi1-x/Si strained-layer heterostructures. Appl. Phys. Lett. 1985, 47, 322–324. 10.1063/1.96206. [DOI] [Google Scholar]
  36. Schmid S.; Villanueva L. G.; Roukes M. L.. Fundamentals of Nanomechanical Resonators; Springer, 2016; Vol. 49. [Google Scholar]
  37. Zakaria A.; Fetzer C. M.; Goorsky M. S. Influence of the Degree of Order of InGaP on Its Hardness Determined Using Nanoindentation. J. Appl. Phys. 2010, 108, 074908. 10.1063/1.3477322. [DOI] [Google Scholar]
  38. Klaß Y. S.; Doster J.; Bückle M.; Braive R.; Weig E. M. Determining Young’s Modulus via the Eigenmode Spectrum of a Nanomechanical String Resonator. Appl. Phys. Lett. 2022, 121, 083501. 10.1063/5.0100405. [DOI] [Google Scholar]
  39. Imboden M.; Mohanty P. Dissipation in Nanoelectromechanical Systems. Phys. Rep. 2014, 534, 89–146. 10.1016/j.physrep.2013.09.003. [DOI] [Google Scholar]
  40. Yu P.-L.; Purdy T. P.; Regal C. A. Control of Material Damping in High-Q Membrane Microresonators. Phys. Rev. Lett. 2012, 108, 083603. 10.1103/PhysRevLett.108.083603. [DOI] [PubMed] [Google Scholar]
  41. Villanueva L. G.; Schmid S. Evidence of surface loss as ubiquitous limiting damping mechanism in SiN micro-and nanomechanical resonators. Phys. Rev. Lett. 2014, 113, 227201. 10.1103/PhysRevLett.113.227201. [DOI] [PubMed] [Google Scholar]
  42. Fedorov S.Mechanical resonators with high dissipation dilution in precision and quantum measurements. Ph.D. thesis, EPFL, Lausanne, 2020. [Google Scholar]
  43. Bereyhi M. J.; Arabmoheghi A.; Beccari A.; Fedorov S. A.; Huang G.; Kippenberg T. J.; Engelsen N. J. Perimeter Modes of Nanomechanical Resonators Exhibit Quality Factors Exceeding 109 at Room Temperature. Phys. Rev. X 2022, 12, 021036. 10.1103/PhysRevX.12.021036. [DOI] [Google Scholar]
  44. Kim T. S.; Kim H. J.; Geum D.-M.; Han J.-H.; Kim I. S.; Hong N.; Ryu G. H.; Kang J.; Choi W. J.; Yu K. J. Ultra-Lightweight, Flexible InGaP/GaAs Tandem Solar Cells with a Dual-Function Encapsulation Layer. ACS Appl. Mater. Interfaces 2021, 13, 13248–13253. 10.1021/acsami.1c00006. [DOI] [PubMed] [Google Scholar]
  45. Bahl S.; Camnitz L.; Houng D.; Mierzwinski M.; Turner J.; Lefforge G.. Reliability Investigation of InGaP/GaAs Heterojunction Bipolar Transistors. Proceedings of International Electron Devices Meeting; IEEE, 1995; pp 815–818. [Google Scholar]
  46. Gorbylev V. A.; Chelniy A. A.; Polyakov A. Y.; Pearton S. J.; Smirnov N. B.; Wilson R. G.; Milnes A. G.; Cnekalin A. A.; Govorkov A. V.; Leiferov B. M.; Borodina O. M.; Balmashnov A. A. Hydrogen Passivation Effects in InGaAlP and InGaP. J. Appl. Phys. 1994, 76, 7390–7398. 10.1063/1.357964. [DOI] [Google Scholar]
  47. Liu V.; Fan S. S4: A free electromagnetic solver for layered periodic structures. Comput. Phys. Commun. 2012, 183, 2233–2244. 10.1016/j.cpc.2012.04.026. [DOI] [Google Scholar]
  48. Pottier P.; Shi L.; Peter Y.-A. Evolution of modes of Fabry-Perot cavity based on photonic crystal guided-mode resonance mirrors. JOSA B 2012, 29, 2698–2703. 10.1364/JOSAB.29.002698. [DOI] [Google Scholar]
  49. Moura J. P.; Norte R. A.; Guo J.; Schäfermeier C.; Gröblacher S. Centimeter-Scale Suspended Photonic Crystal Mirrors. Opt. Express 2018, 26, 1895–1909. 10.1364/OE.26.001895. [DOI] [PubMed] [Google Scholar]
  50. Høj D.; Hoff U. B.; Andersen U. L. Ultra-Coherent Nanomechanical Resonators Based on Density Phononic Crystal Engineering. arXiv 2022, 2207.06703. [Google Scholar]
  51. Fitzgerald J. M.; Manjeshwar S. K.; Wieczorek W.; Tassin P. Cavity Optomechanics with Photonic Bound States in the Continuum. Phys. Rev. Research 2021, 3, 013131. 10.1103/PhysRevResearch.3.013131. [DOI] [Google Scholar]
  52. Xuereb A.; Genes C.; Dantan A. Strong Coupling and Long-Range Collective Interactions in Optomechanical Arrays. Phys. Rev. Lett. 2012, 109, 223601. 10.1103/PhysRevLett.109.223601. [DOI] [PubMed] [Google Scholar]
  53. Midolo L.; Schliesser A.; Fiore A. Nano-Opto-Electro-Mechanical Systems. Nat. Nanotechnol. 2018, 13, 11. 10.1038/s41565-017-0039-1. [DOI] [PubMed] [Google Scholar]
  54. Kini Manjeshwar S.; Ciers A.; Hellman F.; Bläsing J.; Strittmater A.; Wieczorek W.. Micromechanical high-Q trampoline resonators from strained crystalline InGaP for integrated free-space optomechanics; 2022; Data at 10.5281/zenodo.7441332. [DOI] [PMC free article] [PubMed] [Google Scholar]

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