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. 2023 Jun 16;9(6):e17350. doi: 10.1016/j.heliyon.2023.e17350

A bibliometric survey of research trends in vitrimer

Harsh Sharma a, Balaji Krishnakumar b, Tarik J Dickens b, Gun Jin Yun c, Ajay Kumar a,∗∗, Sravendra Rana a,
PMCID: PMC10333614  PMID: 37441386

Abstract

The recent trends of vitrimer studies enhance the thermoset material with superior properties, therefore, it is particularly important to address the critical scientific inquiries in this area using their research metrics. The reported vitrimer systems have been highly required for future real-time applications; however, the inquisitiveness of material exchange mechanisms extends the research studies further. Significantly, more scientific information's are required to achieve the evident prospective outcomes via these materials. This article highlights the trends and developments of the most relevant publications, authors, articles, countries, and keywords in the vitrimer research field over the past 10 years. The represented bibliometric survey would elevate the basic understanding of the current vitrimer research stats and also help follow the particular research community to learn and develop insight. To generate bibliometric networks, bibliometric data has obtained from Scopus and visualised in VOS-viewer; as an overview of that, the highest number of publications were from China, United States, France, United Kingdom, and Spain.

Keywords: Vitrimers, Self-healing, Recycling, Stress relaxation, Bibliometric analysis

1. Introduction

To achieve sustainable development goals, there is a high demand for designing structural materials with recyclable, healable and reprocessable features [[1], [2], [3], [4], [5]]. Several attempts have made in the past to address the issues associated with traditional cross-linked materials [[6], [7], [8], [9]]. Importantly, emphasis has been placed on employing supramolecular interactions at the cross-link sites of polymeric materials, where the materials can exhibit recyclability and healability when subjected to appropriate external stimuli [[10], [11], [12], [13], [14], [15]]. Non-covalent bonds such as hydrogen bonds [16,17], π-π stacking [18], and metal-ligand bonds [19] were added to the thermosetting matrix to achieve recyclability and self-healing in thermosetting materials. However, because non-covalent adaptive bond interactions have weaker bonding energies (usually 1–5 kcal/mol) [20] than covalent bond interactions (50–150 kcal/mol) [21]; they may result in inferior mechanical characteristics.

Dynamic covalent bonds based approaches can be a potential platform to design recyclable and self-healable polymer networks [[22], [23], [24], [25], [26], [27]]. Regardless of the bond exchange mechanism, such systems are known as covalent adaptable networks (CANs), and the subclass of CANs comprising associative dynamic covalent bonds are known as “vitrimer” as reported by Leibler and co-workers [1]. Vitrimers, a new type of polymeric material, are known to have distinct properties that combine the advantages of thermosets and thermoplastics. Vitrimers offer several advantages over traditional polymers. First, they possess excellent mechanical properties, combining high strength and stiffness with the ability to be reconfigured. This unique combination allows vitrimers to be self-healing, meaning they can repair themselves when damaged or fractured. Additionally, vitrimers can be recycled and reprocessed multiple times without significant loss of material properties, reducing waste and promoting sustainability [28]. At low temperatures, vitrimers behave as a cross-linked thermoset; however, at high temperatures the covalent bonds in the polymer network would exchange the bonds with adjacent free molecules and detach with the old bonds, which can follow the Arrhenius [29,30] and William-Landel-Ferry equation (WLF) [31,32] at their exchanging time. This behaviour allows them to maintain permanent crosslink density, and the same time behaving them as viscoelastic liquids [2,3,[33], [34], [35], [36], [37], [38], [39], [40]]. To effectuate this, various chemical processes, such as transesterification [41], transamination [4,42], alkoxyamine exchange [43,44], olefin metathesis [45], and thiol-disulfide exchange [46,47], have been deployed in the production of vitrimers for various applications in the past decade. In the field of materials science, they can be used in coatings, adhesives, composites, and 3D printing materials. Their reconfigurability and self-healing properties makes them promise for applications in automotive parts, aerospace components, and consumer goods. Furthermore, vitrimers hold potential in biomedical applications, such as drug delivery systems, tissue engineering, and shape-memory devices [[48], [49], [50]]. Thus, it is critical that polymer researchers are made aware of current research trends and directions in vitrimer processing.

Expert evaluation and research metrics have gradually been used to address critical scientific inquiry in a specific field. To overcome manual review deficiencies in engineering studies [51] and other fields, bibliometric analysis has given a profound, quantitative, and less skewed linkages to the network between many features of massive bibliometric datasets. Bibliometric analysis is a popular and reliable method for discovering and interpreting vast amounts of scientific data [52].

Intriguingly, bibliometric analysis of the published literature in vitrimer studies is required to keep readers and policymakers up to date on present and emerging research topics. Significantly, prior studies on vitrimer materials reviews/mini-review have qualitatively discussed the material chemistries and properties, however, this is the first report about the quantitative analysis of vitrimers. Hence, the purpose of this research is to highlight the trends and advancement of the most prominent publication sources, keywords, authors, papers, and the nation of origination in vitrimer research over the last 10 years. The bibliometric analysis gives valuable and statistical insight into vitrimer current and future research trends. It also provides a better perspective about the theoretical structure and cluster themes of vitrimer, as well as highlights the major issues and significant contributions of top publications and researchers in the evolving field. Perhaps, in the future vitrimer investigation databases will be abundant; however, it could be a burden to attain the exact vitrimer synthesis and research practice, in that case, this paper needs to be detailed on this occasion. Exploring thriving research trends and, making this milestone data article would effectively promote this field, and benchmark to fascinate the vitrimers system further. In addition, the networks visualisation of bibliometric co-occurrences and co-citations is a critical tool for understanding the relationships and connections between scientific publications. It plays a crucial role in identifying research trends by highlighting clusters of related publications and revealing emerging areas of study. These visualizations allow researchers to explore the overall research landscape, identifying influential works and important research communities. Additionally, they help trace the diffusion of knowledge within the scientific community by visualizing the connections between highly cited publications. It serves as a roadmap for academics and research organisations to share their advanced technologies, collaborate on new research, and launch creative joint ventures. A bibliometric network is created and utilized to show the annual distribution and top growth trends across publication sources, articles, authors, and countries in vitrimer research.

2. Methodology

The bibliometric analysis technique was used in the current study to quantitatively visualise scientific data and generate bibliometric maps [53]. The method could be suited for this evaluation since it uses extensive bibliographic data to highlight and assess the development of vitrimer over a period. While the most popular databases for citation indexing and gathering academic literature are Google Scholar, Scopus, and Web of Science. Although, more excellent bibliometric data coverage, a wider selection of journals, and a quicker indexing procedure have made Scopus is the preferred alternative for researchers over to Web of Science [[54], [55], [56]]. Based on citation data, VOS Viewer produces maps of authors, articles, and journals and provides a map of keywords based on co-occurrence data [57]. The researchers also use a number of other bibliometric mapping tools, including Bibliometrix [58], CitiNetExplorer [59], and Pajek [60]. However, the alternative software offers small bibliometric maps and easy graphical representations, which are inadequately represented in comparison to VOSviewer. Therefore, the current study used Scopus as a data retriever tool and VOSviewer as a network mapping technique. An inclusion criterion was applied to filter relevant publications for this analysis (Table 1).

Table 1.

Inclusion criteria were used for gathering data from Scopus as of 23 Jan 2023.

S. No. Option Criteria Applied
1. Language English
2. Publication date Jan. 2014–2023

The authors, abstract, keywords search strings defined to conduct the research were “vitrimer”. The applied search string suggests 490 research articles, 37 reviews, 21 conference papers and 24 other publications in preliminary results (2014–2023). The next search was then limited to only English-language publications that resulted in 561 English publications. In January 2023, the data were retrieved as Comma Separated Values (CSV) files, which were then imported and examined by VOS viewer software (version 1.6.19). The annual distribution and growth trend, keyword co-occurrence, top publication sources, authors, articles, and countries in vitrimer research were examined using a bibliometric network; and each of them provides specific importance and estimation like an emergent and exploration, common presence and close proximity, credible and valuable reproduction, communicate and collaborate, insights and evaluation, cognizant and contribution, respectively.

3. Results and discussion

3.1. Annual distribution and growth trends

For the “vitrimer” search string, the first article was published in 2012, and up to 2013 only 1 article was published. From 2014 to 2023, there was a rise in vitrimer articles to 561, indicating an increase of more than 98%. The rising interest of vitrimer research has occurred due to its sustainable properties, which has resulted in a significant number of publications. Fig. 1 shows the annual distribution and growing trend in vitrimer research.

Fig. 1.

Fig. 1

Number of Publications on topic “vitrimer”. Source: http://www.scopus.com (accessed on 25 Jan. 2023).

3.2. Contribution of publication sources

Mapping publication sources is critical for assessing growth in research output. Table 2 shows the top publication sources/journals with at least 10 documents from January 2014 to January 2023. American Chemical Society (ACS) Macromolecules, Elsevier Polymer, ACS Applied Polymer Materials and Multidisciplinary Digital Publishing Institute (MDPI) Polymers are the top four most recommended sources for vitrimer publication having 51, 30, 27 and 23 documents, respectively. These documents were able to receive 2426, 556, 291 and 302 citations, respectively. As indicated in Table 2, the journal impact factor (JIF) was employed to assess the value of journals to the scientific community. Ahmad and co-workers [61,62] adopted a similar approach, stating that the JIF shows a journal's authority and influence. As a result, the top three journals in terms of relevance for vitrimer articles were the Chemical Engineering Journal (JIF = 16.744), the Journal of Materials Chemistry A (JIF = 14.511), and Composites Part B: Engineering (JIF = 11.322). The network representation of the top recommended publication sources for vitrimer is shown in Fig. 2. The size of the circle shows the journal's publishing count, i.e., the larger the circle size, the more papers published, but it does not imply the journal's authority or prestige.

Table 2.

Publication sources with a minimum of 10 documents from Jan. 2014 to Jan. 2023.

S.No. Sources Publications Citations JIF
1. ACS Macromolecules 51 2426 6.057
2. Polymer 30 556 4.432
3. ACS Applied Polymer Materials 27 291 4.855
4. Polymers 23 302 4.967
5. Polymer Chemistry 20 735 5.367
6. ACS Applied Materials and Interfaces 20 700 10.383
7. European polymer Journal 18 602 5.546
8. ACS Sustainable Chemistry and Engineering 18 642 9.224
9. Chemical Engineering Journal 17 511 16.744
10. Composites Science and Technology 14 390 9.878
11. Journal of Applied Polymer Science 14 118 3.057
12. ACS Macro letters 12 795 7.015
13. composites Part B: Engineering 10 199 11.322
14. Journal of Materials Chemistry A 10 404 14.511
15. Industrial Crops and Products 10 138 6.449

Fig. 2.

Fig. 2

Visualisation of publication sources with a minimum of 10 documents.

Furthermore, circles of the same colour indicate the association and interconnectedness of the publication sources. By grouping the circles by colour, it is possible to see which publications are most closely related to one another based on their frequency. This information can be useful for understanding the relationships between different research areas and for identifying key publications in a particular field. The two dissimilar shades observed represent two related groups, with 13 and 2 items in red (Group 1) and green (Group 2), respectively. Publication sources of a similar colour that are close together show a stronger relationship than those that are far apart. The majority of the sources cite articles from ACS Macromolecules, ACS Macro Letters, and ACS Applied Materials and Interfaces. Closely connected publication sources form a comparable cluster, and the network edges show citation links.

Co-Occurrence of Keywords; Keywords assists the researcher in interpreting the main information of a document and subject categories and determining the development and trend of study in the field [63]. Table 3 lists the most frequently used keywords in vitrimer publications. The top three terms are vitrimer, crosslinking, and stress relaxation, with 206, 150, and 114 occurrences, respectively.

Table 3.

Top occurring keywords in “vitrimer” publications.

S.No. Keywords Occurrences S.No. Keywords Occurrences
1. Vitrimer 206 16. Curing 61
2. Crosslinking 150 17. Glass Transition 60
3. Stress Relaxation 114 18. Recyclability 60
4. Recycling 105 19. Activation Energy 59
5. Vitrimers 89 20. Dynamics 58
6. Esters 87 21. Reprocessability 52
7. Self-healing Materials 81 22. Sulfur Compounds 50
8. Thermosets 79 23. Mechanical Properties 48
9. Tensile Strength 77 24. Recyclables 46
10. Self-healing 77 25. Bio-based 41
11. Epoxy 75 26. Polymers 39
12. Catalysts 71 27. Property 37
13. Transesterification 68 28. Rubber 36
14. Exchange Reaction 68 29. Amines 35
15. Epoxy Resins 63 30. Transesterification Reaction 35

Fig. 3, Fig. 4 exhibit a keyword co-occurrence network and overlay visualisation, in which the size of the circle represents the frequency of keyword usage, and its position indicates a correlation in publications. VOSviewer identified four groupings, with red (Group 1) having 15, green (Group 2) having 11, and blue (Group 3) having 4. Keywords like “vitrimer”, “crosslinking”, “stress relaxation”, “recycling”, and “vitrimers” had more occurrences and larger circle sizes than the other keywords.

Fig. 3.

Fig. 3

Keyword co-occurrence network visualisation.

Fig. 4.

Fig. 4

Keyword co-occurrence overlay visualisation.

4. Contribution of authors

The relationship between authors and co-authors gives important information about the primary research groups working on a specific topic; also, each researcher's individual number of articles and citations help measure their influence in a particular field. As a result, the number of publications and citations indicated in Table 4 evaluates a researcher's contribution and influence. The average citation is calculated by dividing the total number of citations by the number of documents per author. Yang Y., Zhang J., and Zhang S. have 30, 26, and 25 published articles, respectively., J.M. Winne, F.E. Du Prez and L. Leibler have the most overall citations, with 2479, 2442 and 1982, respectively. The leading authors in terms of average citations are Leibler L., Nicolay R., and Winne J.M., with approximately 247, 224, and 206 average citations, respectively. The data reveals that citations in the field of vitrimer connect researchers from various geographical regions.

Table 4.

Authors with a minimum of 5 publications and 200 citations in “vitrimer” research.

S.No. Authors Publications Citations Average Citation Total Link Strength
1. Yang Y. 30 1400 46.67 62
2. Zhang J. 26 1304 50.15 75
3. Zhang S. 25 1019 40.76 77
4. Wei Y. 23 1392 60.53 64
5. Liu T. 22 1245 56.59 71
6. Ji Y. 19 1176 61.90 59
7. Liu Y. 17 513 30.18 60
8. Wang S. 17 584 34.36 53
9. Wang Y. 17 603 35.48 18
10. Hao C. 16 1019 63.69 65
11. Zhang L. 16 664 41.5 19
12. Zhang X. 15 566 37.73 29
13. Li Y. 14 698 49.86 30
14. Wang D. 14 247 17.65 11
15. Zhao W. 14 365 26.07 7
16. Hayashi M. 14 200 14.28 2
17. Du Prez F.E. 13 2442 187.84 23
18. Guo B. 12 718 59.83 43
19. Zhang Y. 12 356 29.67 38
20. Winne J.M. 12 2479 206.58 24
21. Zhang H. 12 360 30 24
22. Wang H. 12 215 17.92 21
23. Zhang B. 12 269 22.42 18
24. Zhu J. 11 578 52.54 40
25. Chen Y. 11 332 30.18 22
26. Qi H. J. 11 608 55.27 22
27. Li G. 11 225 57.5 5
28. Wu Y. 10 285 69.5 39
29. Xu X. 10 564 56.4 38
30. Tang Z. 10 499 49.9 35
31. Liu W. 10 575 57.5 32
32. Liu H. 10 695 69.5 24
33. Xu Y. 10 298 29.8 21
34. Wang B. 9 365 40.55 35
35. Chen Q. 9 383 42.55 21
36. Zeng J.-B. 9 328 36.44 12
37. Terentjev E.M. 9 314 34.89 3
38. Tournilhac F. 9 487 54.11 3
39. Wang L. 8 769 96.13 29
40. Chen M. 8 283 35.37 27
41. Wu S. 8 366 45.75 23
42. Leibler L. 8 1982 247.75 13
43. Guerre M. 8 557 69.63 12
44. Li Y.-D. 8 323 40.37 12
45. Rana S. 8 238 29.75 11
46. Zhou Y. 8 272 34 4
47. Zhao X. 7 280 40 20
48. Kuang X. 7 513 73.29 12
49. Nicolay R. 7 1571 224.42 11
50. Wang T. 7 728 104 11
51. Li Q. 6 357 59.5 34
52. Ma S. 6 357 59.5 34
53. Han J. 6 522 87 28
54. Zhou L. 6 299 49.83 21
55. Shi Q. 6 565 94.17 16
56. Yu K. 6 587 97.83 14
57. Krishnakumar B. 6 238 39.67 9
58. Yang X. 5 432 86.4 12
59. Zhao X.-L. 5 203 40.6 12
60. Binder W·H. 5 219 43.8 8
61. Wang W. 5 220 44 8

Fig. 5, Fig. 6 depict eight significant groups (at least three authors in each group) working in the field of vitrimer. Zhang J., Wang Y., Du Prez F.E., and Liu Y. are authors from notable research groups in the vitrimer study field.

Fig. 5.

Fig. 5

Author contribution visualisation based on citations and co-authorship.

Fig. 6.

Fig. 6

Author contribution density visualisation based on citations and co-authorship.

4.1. Contribution of publications

The article-citation relationship informs researchers about the familiarity of the published work. A higher citation metric indicates that the article's quality is likely exceptional, and many authors in the research field will cite it. The current analysis chose papers with at least 120 citations, reducing the number of documents to 35 (Table 5). This aided in the study of the most referenced publications and the publications with the greatest impact on vitrimer research.

Table 5.

Publications with a minimum of 120 citations in “vitrimer” research.

S.No. Publications Citations Ref. S.No. Publications Citations Ref.
1. Denissen W. (2016) 814 [3] 19. Liu T. (2018) 161 [64]
2. Röttger M. (2017) 651 [65] 20. Chen Q. (2016) 158 [66]
3. Denissen W. (2015) 572 [4] 21. Zhang S. (2018) 155 [67]
4. Fortman D. J. (2015) 472 [68] 22. Yang X. (2020) 152 [69]
5. Yang Y. (2016) 283 [70] 23. Imbernon L. (2016) 150 [71]
6. Denissen W. (2017) 272 [72] 24. Krishnakumar B. (2020) 149 [25]
7. Yu K. (2016) 260 [73] 25. Chen M. (2019) 146 [74]
8. Fortman D. J. (2018) 255 [75] 26. Li L. (2018) 138 [76]
9. Shi Q. (2017) 254 [77] 27. Ma Z. (2017) 136 [78]
10. Liu T. (2017) 243 [79] 28. Legrand A. (2016) 135 [80]
11. Yang Y. (2014) 223 [81] 29. Zhang L. (2017) 134 [82]
12. Wang S. (2019) 214 [83] 30. Guerre M. (2018) 133 [84]
13. Deng J. (2018) 191 [85] 31. Dhers S. (2019) 128 [86]
14. Azcune I. (2016) 181 [87] 32. Liu Y. (2018) 127 [88]
15. Yang Z. (2016) 168 [89] 33. Imbernon L. (2016) 123 [90]
16. Guerre M. (2020) 167 [5] 34. Liu Y. (2019) 122 [91]
17. Hendriks B. (2017) 167 [92] 35. Meng F. (2016) 122 [93]
18. Han J. (2018) 165 [94]

According to Table 5, the top four most cited publications were “Vitrimers: Permanent Organic Networks with Glass-like Fluidity” by Wim Denissen, “High-performance vitrimers from commodity thermoplastics through dioxaborolane metathesis” by Max Röttger, “Vinylogous Urethane Vitrimers” by Wim Denissen, and “Mechanically Activated, Catalyst-Free Polyhydroxyurethane Vitrimers” by David J Fortman. The increase in citations demonstrates the importance of the papers in advancing vitrimer research. Fig. 7 depicts the articles with at least 120 citations and identified three groups, with red (group 1), green (group 2), and blue (group 3) having 15, 11, and 9 publications, respectively. The data reveals that citations in the field of vitrimer connect experts from various geographical places.

Fig. 7.

Fig. 7

Visualisation of publications with a minimum of 120 citations.

Contribution of Countries

Table 6 reveals that 675 documents from 18 countries were published. The country China had the most publications (286), followed by the United States with 120. France came in third with 57 publications, while the United Kingdom came in fourth with 24. Following that, eleven countries published documents ranging from 10 to 23, while three countries published documents ranging from 1 to 9. China has received the most citations (7950), followed by the United States (4838), and France (3685). Furthermore, when compared to the other countries, Belgium and France have the highest average number of citations per document (147.36) and (64.65), respectively. These countries exhibit a higher level of research due to key contributing factors such as robust funding and research infrastructure, effective collaboration between academia and industry, and the implementation of supportive policy initiatives. The network and density visualisation of countries with minimum 5 publications are shown in Fig. 8, Fig. 9.

Table 6.

Countries with a minimum of 5 publications in “vitrimer” research.

S.No. Country Publications Citations Average Citation per Document
1. China 286 7950 27.80
2. United States 120 4838 40.32
3. France 57 3685 64.65
4. United Kingdom 24 532 22.17
5. Spain 23 468 20.35
6. Germany 21 508 24.20
7. Belgium 17 2505 147.35
8. Japan 16 288 18
9. Netherlands 14 464 33.14
10. Singapore 14 690 49.29
11. South Korea 14 115 8.21
12. India 13 272 20.92
13. Austria 13 187 14.39
14. Italy 12 186 15.5
15. Canada 12 324 27
16. Taiwan 8 163 20.38
17. Australia 6 84 14
18. Luxembourg 5 91 18.2

Fig. 8.

Fig. 8

Visualisation of countries with a minimum of 5 publications.

Fig. 9.

Fig. 9

Density visualisation of countries with a minimum of 5 publications.

5. Existing polymers vs vitrimer materials

Conventional polymers have been extensively studied for decades, and they form a mature field of research with a substantial body of literature. This extensive research has led to a significant number of publications and citations. Polymer research has a broad scope, covering a wide range of topics such as polymer synthesis, characterization, processing, and applications [95]. It encompasses various polymer types, including thermoplastics, thermosets, elastomers, and composites [96]. The impact of conventional polymer research is evident in many industries, with numerous practical applications and commercial products derived from polymer science [97]. This impact is reflected in the number of citations and the wide dissemination of polymer research findings. However, as a mature field, the rate of growth in conventional polymer research may have slowed down in recent years compared to emerging areas like vitrimer research [98].

Vitrimer research is a relatively newer and rapidly growing field within polymer science. While it has gained significant attention in recent years, it may not have reached the same level of bibliometric trends and impact as conventional polymers due to its nascent stage. The number of vitrimer-related publications and citations has been increasing, reflecting a growing interest in this area. Researchers are exploring new synthesis methods, understanding the properties of vitrimers, and investigating their applications [51]. Vitrimer materials offer unique properties and capabilities, such as self-healing, reprocessing, and shape memory behavior, which have attracted considerable attention from the scientific community [[99], [100], [101]]. These unique features may contribute to the growing trend of vitrimer research. As the field continues to advance and more researchers contribute to vitrimer studies, it is expected that bibliometric trends and impact will continue to rise, albeit at a different pace compared to conventional polymers. Therefore, the vitrimer bibliometric growing trends are far better than contemporary polymer. However, it requires a detailed analysis of recent data, including the number of publications, citations, and their impact within their respective fields. As bibliometric trends can fluctuate over time, it's essential to consult up-to-date bibliometric databases or conduct a comprehensive analysis to draw specific conclusions on the growth of vitrimer research compared to conventional polymer research.

6. Summary and outlook

This survey performed a bibliometric analysis of vitrimer publications retrieved from the Scopus database between January 2014 and January 2023; and the bibliometric findings from this study would be helpful for academicians and policymakers to exchange research skills and to work together on cutting-edge vitrimeric research including the formation of collaborative ventures. Furthermore, it can assist researchers, governments, and businesses in anticipating future inventive areas, prioritising funding areas, and evaluating the impact of previous collaborations. However, it is important to consider certain limitations when conducting bibliometric analysis for more robust and transparent analysis, including the limited availability of data, inconsistent indexing, language bias, and the time lag in data availability.

The current study discovered that research on vitrimer is quickly advancing, and additional research is required to design advanced materials. Likewise, the studies on exploring new combinations of monomers for vitrimer synthesis, understanding the curing kinetics and healing mechanism of vitrimers, and adopting eco-friendly synthesis routes for long-term durability, stability, and sustainable recycling can be the potential research directions for further investigation in the field of vitrimers.

Following are the key findings from the bibliometric analysis:

  • 1.

    The top four most popular journals for vitrimer publications in terms of publishing sources are ACS Macromolecules, Polymer, ACS Applied Polymer Materials, and Polymers. ACS Macromolecules, ACS Macro Letters, Polymer Chemistry, and ACS Applied Materials and Interfaces were the publications that the majority of the sources were citing.

  • 2.

    The most often used keywords in terms of keyword co-occurrence are vitrimer, crosslinking, and stress relaxation. The results may help future researchers to select keywords for a specific research field.

  • 3.

    Yang Y., Zhang J., and Zhang S. have the most documents in terms of author contribution, whereas F.E. Du Prez has the most citations overall. The analysis demonstrates how citations in the field of vitrimer connect researchers from various geographical locations.

  • 4.

    Denissen W. (2016), Röttger M. (2017), and Denissen W. (2015) were the top three most cited publications in terms of publication contribution. These documents' bigger network circle diameters than the others suggest that they have an impact on vitrimer research in various geographical areas.

  • 5.

    The largest number of publications came from the countries like China, the United States, France, and the United Kingdom. According to the country dependent cooperation network, most countries actively collaborate on research with China, France, and the United States.

Author contribution statement

All authors listed have significantly contributed to the development and the writing of this article.

Data availability statement

All publication data on which these studies are based have been drawn from public source, Scopus (http://www.scopus.com/). The search string used for finding vitrimer related documents and the retrieved. CSV file are uploaded in repository (https://github.com/HarshSh22/ResearchTrendsinVitrimer.git). The annual distribution and growth trends plot have been drawn from public source (https://www.meta-chart.com/). The co-citation, co-occurrence and all the bibliometric networks have been created through open-source software: VOSviewer version 1.6.19 (https://www.vosviewer.com), to run VOSviewer java version 1.8.0_361 (Oracle Corporation) have been used.

Declaration of competing interest

The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper.

Acknowledgements

We gratefully acknowledge the financial support from the Science and Engineering Research Board (SERB-DST), Government of India (Grant No. CRG/2021/006957). Harsh Sharma would like to acknowledge UPES for JRF fellowship. Authors are grateful to the BK21 Program funded by the Ministry of Education (MOE, Korea), the National Research Foundation of Korea (NRF-4199990513944), and The Institute of Engineering Research at Seoul National University for their support.

Contributor Information

Ajay Kumar, Email: akumar@ddn.upes.ac.in.

Sravendra Rana, Email: srana@ddn.upes.ac.in.

References

  • 1.Montarnal D., Capelot M., Tournilhac F., Leibler L. Silica-like malleable materials from permanent organic networks. Science. 2011;334:965–968. doi: 10.1126/science.1212648. [DOI] [PubMed] [Google Scholar]
  • 2.Smallenburg F., Leibler L., Sciortino F. Patchy particle model for vitrimers. Phys. Rev. Lett. 2013;111 doi: 10.1103/PhysRevLett.111.188002. [DOI] [PubMed] [Google Scholar]
  • 3.Denissen W., Winne J.M., Du Prez F.E. Vitrimers: permanent organic networks with glass-like fluidity. Chem. Sci. 2016;7:30–38. doi: 10.1039/c5sc02223a. [DOI] [PMC free article] [PubMed] [Google Scholar]
  • 4.Denissen W., Rivero G., Nicolaÿ R., Leibler L., Winne J.M., Du Prez F.E. Vinylogous urethane vitrimers. Adv. Funct. Mater. 2015;25:2451–2457. [Google Scholar]
  • 5.Guerre M., Taplan C., Winne J.M., Du Prez F.E. Vitrimers: directing chemical reactivity to control material properties. Chem. Sci. 2020;11:4855–4870. doi: 10.1039/d0sc01069c. [DOI] [PMC free article] [PubMed] [Google Scholar]
  • 6.Sahayaraj A.F. Revolutionizing energy storage: the rise of silicon-based solutions. Silicon. 2023 doi: 10.1007/s12633-023-02417-3. In Press. [DOI] [Google Scholar]
  • 7.Manickam T., Iyyadurai J., Jaganathan M., Babuchellam A., Mayakrishnan M., Arockiasamy F.S. Effect of stacking sequence on mechanical, water absorption, and biodegradable properties of novel hybrid composites for structural applications. Int. Polym. Process. 2023;38:88–96. [Google Scholar]
  • 8.Arockiasamy F.S., Muthukrishnan M. Experimental investigation on the effect of fiber volume fraction of sponge gourd outer skin fiber reinforced epoxy composites. Polym. Compos. 2022;43:6932–6942. [Google Scholar]
  • 9.Felix Sahayaraj A., Jenish I., Tamilselvan M., Muthukrishnan M., Kumar B.A. Mechanical and morphological characterization of sisal/kenaf/pineapple mat reinforced hybrid composites. Int. Polym. Process. 2022;37:581–588. [Google Scholar]
  • 10.Bosman A.W., Brunsveld L., Folmer B.J.B., Sijbesma R.P., Meijer E.W. Supramolecular polymers: from scientific curiosity to technological reality. Macromol. Symp. 2003;201:143–154. [Google Scholar]
  • 11.Vahid Ezzatizadeh M.A.P., Pinto R.M., Sandi C., Sandi M., Al-Mahdawi S., te Riele H. 基因的改变NIH public access. NIH Public Acess. 2012;23:1–7. [Google Scholar]
  • 12.Cordier P., Tournilhac F., Soulié-Ziakovic C., Leibler L. Self-healing and thermoreversible rubber from supramolecular assembly. Nature. 2008;451:977–980. doi: 10.1038/nature06669. [DOI] [PubMed] [Google Scholar]
  • 13.Harada A., Takashima Y., Nakahata M. Supramolecular polymeric materials via cyclodextrin-guest interactions. Acc. Chem. Res. 2014;47:2128–2140. doi: 10.1021/ar500109h. [DOI] [PubMed] [Google Scholar]
  • 14.Hayashi M., Matsushima S., Noro A., Matsushita Y. Mechanical property enhancement of ABA block copolymer-based elastomers by incorporating transient cross-links into soft middle block. Macromolecules. 2015;48:421–431. [Google Scholar]
  • 15.Kawana S., Nakagawa S., Nakai S., Sakamoto M., Ishii Y., Yoshie N. Interphase synergistic effects of dynamic bonds in multiphase thermoplastic elastomers. J. Mater. Chem. A. 2019;7:21195–21206. [Google Scholar]
  • 16.Bowman C.N., Kloxin C.J. Covalent adaptable networks: reversible bond structures incorporated in polymer networks. Angew. Chem., Int. Ed. 2012;51:4272–4274. doi: 10.1002/anie.201200708. [DOI] [PubMed] [Google Scholar]
  • 17.Campanella A., Döhler D., Binder W.H. Self-healing in supramolecular polymers, macromol. Rapid Commun. 2018;39 doi: 10.1002/marc.201700739. [DOI] [PubMed] [Google Scholar]
  • 18.Thakur V.K., Kessler M.R. Self-healing polymer nanocomposite materials: a review. Polymer. 2015;69:369–383. [Google Scholar]
  • 19.Fischer H. Self-repairing material systems - a dream or a reality. Nat. Sci. 2010;2:873–901. [Google Scholar]
  • 20.Biology M.C., Darnell J., Lodish H., Baltimore D. In: Scientific American Books. Darnell J., Lodish H., Baltimore D., editors. W. H. Freeman & Co.; New York, NY: 1986. Molecular cell biology; p. 1186. $42.95, Gamete Res. 17 (1987) 95–95. [Google Scholar]
  • 21.Smith T. Fundam. Anaesth. Cambridge University Press; 2016. Physical chemistry; pp. 537–549. [Google Scholar]
  • 22.Alabiso W., Schlögl S. The impact of vitrimers on the industry of the future: chemistry, properties and sustainable forward-looking applications. Polymers. 2020;12 doi: 10.3390/polym12081660. [DOI] [PMC free article] [PubMed] [Google Scholar]
  • 23.Krishnan B.P., Saalwaechter K., Adjedje V.K.B., Binder W.H. Design, synthesis and characterization of vitrimers with low topology freezing transition temperature. Polymers. 2022;14 doi: 10.3390/polym14122456. [DOI] [PMC free article] [PubMed] [Google Scholar]
  • 24.Kaiser S., Wurzer S., Pilz G., Kern W., Schlögl S. Stress relaxation and thermally adaptable properties in vitrimer-like elastomers from HXNBR rubber with covalent bonds. Soft Matter. 2019;15:6062–6072. doi: 10.1039/c9sm00856j. [DOI] [PubMed] [Google Scholar]
  • 25.Krishnakumar B., Sanka R.V.S.P., Binder W.H., Parthasarthy V., Rana S., Karak N. Vitrimers: associative dynamic covalent adaptive networks in thermoset polymers. Chem. Eng. J. 2020;385 [Google Scholar]
  • 26.Krishnakumar B., Prasanna Sanka R.V.S., Binder W.H., Park C., Jung J., Parthasarthy V., Rana S., Yun G.J. Catalyst free self-healable vitrimer/graphene oxide nanocomposites. Compos. B Eng. 2020;184 [Google Scholar]
  • 27.Krishnakumar B., Pucci A., Wadgaonkar P.P., Kumar I., Binder W.H., Rana S. Vitrimers based on bio-derived chemicals: overview and future prospects. Chem. Eng. J. 2021 [Google Scholar]
  • 28.Capelot M., Montarnal D., Tournilhac F., Leibler L. Metal-catalyzed transesterification for healing and assembling of thermosets. J. Am. Chem. Soc. 2012;134:7664–7667. doi: 10.1021/ja302894k. [DOI] [PubMed] [Google Scholar]
  • 29.McMullin P.W. Mechanics of materials. Introd. to Struct. 2016:96–125. [Google Scholar]
  • 30.McKeen L.W. Permeability Prop. Plast. Elastomers. Elsevier; 2012. Introduction to permeation of plastics and elastomers; pp. 1–20. [Google Scholar]
  • 31.Saalwächter K., Spiess H.W. Polymer Science: A Comprehensive Reference. Elsevier; 2012. Solid-state NMR of polymers; pp. 185–219. [Google Scholar]
  • 32.Tcharkhtchi A., Nony F., Khelladi S., Fitoussi J., Farzaneh S. Adv. Compos. Manuf. Process Des. Elsevier; 2015. Epoxy/amine reactive systems for composites materials and their thermomechanical properties; pp. 269–296. [Google Scholar]
  • 33.Ciarella S., Sciortino F., Ellenbroek W.G. Dynamics of vitrimers: defects as a highway to stress relaxation. Phys. Rev. Lett. 2018;121 doi: 10.1103/PhysRevLett.121.058003. [DOI] [PubMed] [Google Scholar]
  • 34.Ciarella S., Biezemans R.A., Janssen L.M.C. Understanding, predicting, and tuning the fragility of vitrimeric polymers. Proc. Natl. Acad. Sci. USA. 2019;116:25013–25022. doi: 10.1073/pnas.1912571116. [DOI] [PMC free article] [PubMed] [Google Scholar]
  • 35.Meng F., Saed M.O., Terentjev E.M. Elasticity and relaxation in full and partial vitrimer networks. Macromolecules. 2019;52:7423–7429. [Google Scholar]
  • 36.Tito N.B., Creton C., Storm C., Ellenbroek W.G. Harnessing entropy to enhance toughness in reversibly crosslinked polymer networks. Soft Matter. 2019;15:2190–2203. doi: 10.1039/c8sm02577k. [DOI] [PubMed] [Google Scholar]
  • 37.Wu J., Li S., Liu H., Qian H.-J., Lu Z.-Y. Dynamics and reaction kinetics of coarse-grained bulk vitrimers: a molecular dynamics study. Phys. Chem. Chem. Phys. 2019;21:13258–13267. doi: 10.1039/c9cp01766f. [DOI] [PubMed] [Google Scholar]
  • 38.Winne J.M., Leibler L., Du Prez F.E. Dynamic covalent chemistry in polymer networks: a mechanistic perspective. Polym. Chem. 2019;10:6091–6108. [Google Scholar]
  • 39.Van Zee N.J., Nicolaÿ R. Vitrimers: permanently crosslinked polymers with dynamic network topology. Prog. Polym. Sci. 2020;104 [Google Scholar]
  • 40.Zhang Z.P., Rong M.Z., Zhang M.Q. Polymer engineering based on reversible covalent chemistry: a promising innovative pathway towards new materials and new functionalities. Prog. Polym. Sci. 2018;80:39–93. [Google Scholar]
  • 41.Brutman J.P., Delgado P.A., Hillmyer M.A., Vitrimers Polylactide. ACS Macro Lett. 2014;3:607–610. doi: 10.1021/mz500269w. [DOI] [PubMed] [Google Scholar]
  • 42.Taynton P., Yu K., Shoemaker R.K., Jin Y., Qi H.J., Zhang W. Heat- or water-driven malleability in a highly recyclable covalent network polymer. Adv. Mater. 2014;26:3938–3942. doi: 10.1002/adma.201400317. [DOI] [PubMed] [Google Scholar]
  • 43.Wojtecki R.J., Meador M.A., Rowan S.J. Using the dynamic bond to access macroscopically responsive structurally dynamic polymers. Nat. Mater. 2011;10:14–27. doi: 10.1038/nmat2891. [DOI] [PubMed] [Google Scholar]
  • 44.Yuan C., Zhang M.Q., Rong M.Z. Application of alkoxyamine in self-healing of epoxy. J. Mater. Chem. A. 2014;2:6558–6566. [Google Scholar]
  • 45.Lu Y., Tournilhac F., Leibler L., Guan Z. Making insoluble polymer networks malleable via olefin metathesis. J. Am. Chem. Soc. 2012;134:8424–8427. doi: 10.1021/ja303356z. [DOI] [PubMed] [Google Scholar]
  • 46.Pepels M., Filot I., Klumperman B., Goossens H. Self-healing systems based on disulfide–thiol exchange reactions. Polym. Chem. 2013;4:4955. [Google Scholar]
  • 47.Martinez-Diaz D., Cortés A., Jiménez-Suárez A., Prolongo S.G. Hardener isomerism and content of dynamic disulfide bond effect on chemical recycling of epoxy networks. ACS Appl. Polym. Mater. 2022;4:5068–5076. [Google Scholar]
  • 48.Guadagno L., Vertuccio L., Naddeo C., Calabrese E., Barra G., Raimondo M., Sorrentino A., Binder W.H., Michael P., Rana S. Reversible self-healing carbon-based nanocomposites for structural applications. Polymers. 2019;11:903. doi: 10.3390/polym11050903. [DOI] [PMC free article] [PubMed] [Google Scholar]
  • 49.Rossegger E., Höller R., Reisinger D., Strasser J., Fleisch M., Griesser T., Schlögl S. Digital light processing 3D printing with thiol-Acrylate vitrimers. Polym. Chem. 2021;12:638–644. [Google Scholar]
  • 50.Shaukat U., Sölle B., Rossegger E., Rana S., Schlögl S. Vat photopolymerization 3D-printing of dynamic thiol-acrylate photopolymers using bio-derived building blocks. Polymers. 2022;14 doi: 10.3390/polym14245377. [DOI] [PMC free article] [PubMed] [Google Scholar]
  • 51.Memon H., Wei Y., Zhu C. Recyclable and reformable epoxy resins based on dynamic covalent bonds – present, past, and future. Polym. Test. 2022;105 [Google Scholar]
  • 52.Donthu N., Kumar S., Mukherjee D., Pandey N., Marc W. How to conduct a bibliometric analysis : an overview and guidelines. J. Bus. Res. 2021;133:285–296. [Google Scholar]
  • 53.Price D.D.S. A general theory of bibliometric and other cumulative advantage processes. J. Am. Soc. Inf. Sci. 1976;27:292–306. [Google Scholar]
  • 54.Aghaei Chadegani A., Salehi H., Md Yunus M.M., Farhadi H., Fooladi M., Farhadi M., Ale Ebrahim N. A comparison between two main academic literature collections: Web of science and scopus databases. Asian Soc. Sci. 2013;9:18–26. [Google Scholar]
  • 55.Lasda Bergman E.M. Finding citations to social work literature: the relative benefits of using Web of science, scopus, or Google scholar. J. Acad. Librarian. 2012;38:370–379. [Google Scholar]
  • 56.Meho L.I. Using Scopus's CiteScore for assessing the quality of computer science conferences. J. Informetr. 2019;13:419–433. [Google Scholar]
  • 57.van Eck N.J., Waltman L. Software survey: VOSviewer, a computer program for bibliometric mapping. Scientometrics. 2010;84:523–538. doi: 10.1007/s11192-009-0146-3. [DOI] [PMC free article] [PubMed] [Google Scholar]
  • 58.Alzard M.H., El-Hassan H., El-Maaddawy T., Alsalami M., Abdulrahman F., Hassan A.A. A bibliometric analysis of the studies on self-healing concrete published between 1974 and 2021. Sustain. Times. 2022;14:1–22. [Google Scholar]
  • 59.van Eck N.J., Waltman L. Citation-based clustering of publications using CitNetExplorer and VOSviewer. Scientometrics. 2017;111:1053–1070. doi: 10.1007/s11192-017-2300-7. [DOI] [PMC free article] [PubMed] [Google Scholar]
  • 60.Mrvar A., Batagelj V. Analysis and visualization of large networks with program package Pajek. Complex Adapt. Syst. Model. 2016;4 [Google Scholar]
  • 61.Ahmad S., Sohail M., Waris A., Elginaid A., Abdel-Magid I.M. SCImago, eigenfactor score, and H5 index journal rank indicator: a study of journals in the area of construction and building technologies. DESIDOC J. Libr. Inf. Technol. 2018;38:278–285. [Google Scholar]
  • 62.Ahmad S.A.J., Abdel-Magid I.M., Hussain A. Comparison among journal impact factor, SCimago journal rank indicator, eigenfactor score and h5-index of environmental engineering journals. COLLNET J. Sci. Inf. Manag. 2017;11:133–151. [Google Scholar]
  • 63.Li W., Zhao Y. Bibliometric analysis of global environmental assessment research in a 20-year period. Environ. Impact Assess. Rev. 2015;50:158–166. [Google Scholar]
  • 64.Liu T., Hao C., Zhang S., Yang X., Wang L., Han J., Li Y., Xin J., Zhang J. A self-healable high glass transition temperature bioepoxy material based on vitrimer chemistry. Macromolecules. 2018;51:5577–5585. [Google Scholar]
  • 65.Röttger M., Domenech T., Van Der Weegen R., Breuillac A., Nicolaÿ R., Leibler L. High-performance vitrimers from commodity thermoplastics through dioxaborolane metathesis. Science. 2017;356:62–65. doi: 10.1126/science.aah5281. [DOI] [PubMed] [Google Scholar]
  • 66.Chen Q., Yu X., Pei Z., Yang Y., Wei Y., Ji Y. Multi-stimuli responsive and multi-functional oligoaniline-modified vitrimers. Chem. Sci. 2016;8:724–733. doi: 10.1039/c6sc02855a. [DOI] [PMC free article] [PubMed] [Google Scholar]
  • 67.Zhang S., Liu T., Hao C., Wang L., Han J., Liu H., Zhang J. Preparation of a lignin-based vitrimer material and its potential use for recoverable adhesives. Green Chem. 2018;20:2995–3000. [Google Scholar]
  • 68.Fortman D.J., Brutman J.P., Cramer C.J., Hillmyer M.A., Dichtel W.R. Mechanically activated, catalyst-free Polyhydroxyurethane vitrimers. J. Am. Chem. Soc. 2015;137:14019–14022. doi: 10.1021/jacs.5b08084. [DOI] [PubMed] [Google Scholar]
  • 69.Yang X., Guo L., Xu X., Shang S., Liu H. A fully bio-based epoxy vitrimer: self-healing, triple-shape memory and reprocessing triggered by dynamic covalent bond exchange. Mater. Des. 2020;186 [Google Scholar]
  • 70.Yang Y., Pei Z., Li Z., Wei Y., Ji Y. Making and remaking dynamic 3D structures by shining light on flat liquid crystalline vitrimer films without a mold. J. Am. Chem. Soc. 2016;138:2118–2121. doi: 10.1021/jacs.5b12531. [DOI] [PubMed] [Google Scholar]
  • 71.Imbernon L., Norvez S. From landfilling to vitrimer chemistry in rubber life cycle. Eur. Polym. J. 2016;82:347–376. [Google Scholar]
  • 72.Denissen W., Droesbeke M., Nicola R., Leibler L., Winne J.M., Du Prez F.E. Chemical control of the viscoelastic properties of vinylogous urethane vitrimers. Nat. Commun. 2017;8 doi: 10.1038/ncomms14857. [DOI] [PMC free article] [PubMed] [Google Scholar]
  • 73.Shi Q., Yu K., Dunn M.L., Wang T., Qi H.J. Solvent assisted pressure-free surface welding and reprocessing of malleable epoxy polymers. Macromolecules. 2016;49:5527–5537. [Google Scholar]
  • 74.Chen M., Zhou L., Wu Y., Zhao X., Zhang Y. Rapid stress relaxation and moderate temperature of malleability enabled by the synergy of disulfide metathesis and carboxylate transesterification in epoxy vitrimers. ACS Macro Lett. 2019;8:255–260. doi: 10.1021/acsmacrolett.9b00015. [DOI] [PubMed] [Google Scholar]
  • 75.Fortman D.J., Brutman J.P., De Hoe G.X., Snyder R.L., Dichtel W.R., Hillmyer M.A. Approaches to sustainable and continually recyclable cross-linked polymers. ACS Sustain. Chem. Eng. 2018;6:11145–11159. [Google Scholar]
  • 76.Li L., Chen X., Jin K., Torkelson J.M. Vitrimers designed both to strongly suppress creep and to recover original cross-link density after reprocessing: quantitative theory and experiments. Macromolecules. 2018;51:5537–5546. [Google Scholar]
  • 77.Shi Q., Yu K., Kuang X., Mu X., Dunn C.K., Dunn M.L., Wang T., Jerry Qi H. Recyclable 3D printing of vitrimer epoxy. Mater. Horiz. 2017;4:598–607. [Google Scholar]
  • 78.Ma Z., Wang Y., Zhu J., Yu J., Hu Z. Bio-based epoxy vitrimers: reprocessibility, controllable shape memory, and degradability. J. Polym. Sci. Part A Polym. Chem. 2017;55:1790–1799. [Google Scholar]
  • 79.Liu T., Hao C., Wang L., Li Y., Liu W., Xin J., Zhang J. Eugenol-derived biobased epoxy: shape memory, repairing, and recyclability. Macromolecules. 2017;50:8588–8597. [Google Scholar]
  • 80.Legrand A., Soulié-Ziakovic C. Silica-Epoxy vitrimer nanocomposites. Macromolecules. 2016;49:5893–5902. [Google Scholar]
  • 81.Yang Y., Pei Z., Zhang X., Tao L., Wei Y., Ji Y. Carbon nanotube-vitrimer composite for facile and efficient photo-welding of epoxy. Chem. Sci. 2014;5:3486–3492. doi: 10.1039/c6sc90083f. [DOI] [PMC free article] [PubMed] [Google Scholar]
  • 82.Tang Z., Liu Y., Guo B., Zhang L. Malleable, mechanically strong, and adaptive elastomers enabled by interfacial exchangeable bonds. Macromolecules. 2017;50:7584–7592. [Google Scholar]
  • 83.Wang S., Ma S., Li Q., Xu X., Wang B., Yuan W., Zhou S., You S., Zhu J. Facile: in situ preparation of high-performance epoxy vitrimer from renewable resources and its application in nondestructive recyclable carbon fiber composite. Green Chem. 2019;21:1484–1497. [Google Scholar]
  • 84.Guerre M., Taplan C., Nicolaÿ R., Winne J.M., Du Prez F.E. Fluorinated vitrimer elastomers with a dual temperature response. J. Am. Chem. Soc. 2018;140:13272–13284. doi: 10.1021/jacs.8b07094. [DOI] [PubMed] [Google Scholar]
  • 85.Deng J., Kuang X., Liu R., Ding W., Wang A.C., Lai Y.C., Dong K., Wen Z., Wang Y., Wang L., Qi H.J., Zhang T., Wang Z.L. Vitrimer elastomer-based jigsaw puzzle-like healable triboelectric nanogenerator for self-powered wearable electronics. Adv. Mater. 2018;30:1–10. doi: 10.1002/adma.201705918. [DOI] [PubMed] [Google Scholar]
  • 86.Dhers S., Vantomme G., Avérous L. A fully bio-based polyimine vitrimer derived from fructose. Green Chem. 2019;21:1596–1601. [Google Scholar]
  • 87.Azcune I., Odriozola I. Aromatic disulfide crosslinks in polymer systems: self-healing, reprocessability, recyclability and more. Eur. Polym. J. 2016;84:147–160. [Google Scholar]
  • 88.Liu Y., Tang Z., Chen Y., Zhang C., Guo B. Engineering of β-hydroxyl esters into elastomer-nanoparticle interface toward malleable, robust, and reprocessable vitrimer composites. ACS Appl. Mater. Interfaces. 2018;10:2992–3001. doi: 10.1021/acsami.7b17465. [DOI] [PubMed] [Google Scholar]
  • 89.Yang Z., Wang Q., Wang T. Dual-Triggered and thermally reconfigurable shape memory graphene-vitrimer composites. ACS Appl. Mater. Interfaces. 2016;8:21691–21699. doi: 10.1021/acsami.6b07403. [DOI] [PubMed] [Google Scholar]
  • 90.Imbernon L., Norvez S., Leibler L. Stress relaxation and self-adhesion of rubbers with exchangeable links. Macromolecules. 2016;49:2172–2178. [Google Scholar]
  • 91.Liu Y., Tang Z., Wu S., Guo B. Integrating sacrificial bonds into dynamic covalent networks toward mechanically robust and malleable elastomers. ACS Macro Lett. 2019;8:193–199. doi: 10.1021/acsmacrolett.9b00012. [DOI] [PubMed] [Google Scholar]
  • 92.Hendriks B., Waelkens J., Winne J.M., Du Prez F.E. Poly(thioether) vitrimers via transalkylation of trialkylsulfonium salts. ACS Macro Lett. 2017;6:930–934. doi: 10.1021/acsmacrolett.7b00494. [DOI] [PubMed] [Google Scholar]
  • 93.Meng F., Pritchard R.H., Terentjev E.M. Stress relaxation, dynamics, and plasticity of transient polymer networks. Macromolecules. 2016;49:2843–2852. [Google Scholar]
  • 94.Han J., Liu T., Hao C., Zhang S., Guo B., Zhang J. A catalyst-free epoxy vitrimer system based on multifunctional hyperbranched polymer. Macromolecules. 2018;51:6789–6799. [Google Scholar]
  • 95.Qureshi J. A review of fibre reinforced polymer structures. Fibers. 2022;10:27. [Google Scholar]
  • 96.Begum S., Fawzia S., Hashmi M.S.J. Polymer matrix composite with natural and synthetic fibres. Adv. Mater. Process. Technol. 2020;6:547–564. [Google Scholar]
  • 97.Alberto M. Fiber Reinf. Polym. - Technol. Appl. Concr. Repair. InTech; 2013. Introduction of fibre-reinforced polymers − polymers and composites: concepts, properties and processes; pp. 3–40. [Google Scholar]
  • 98.De Luzuriaga A.R., Rekondo A., Martín R., Markaide N. Reworkable , recyclable and repairable thermoset epoxy composites in transportation applications. FORMForum. 2016:1–9. [Google Scholar]
  • 99.Yu K., Shi Q., Dunn M.L., Wang T., Qi H.J. Carbon fiber reinforced thermoset composite with near 100% recyclability. Adv. Funct. Mater. 2016;26:6098–6106. [Google Scholar]
  • 100.Denissen W., De Baere I., Van Paepegem W., Leibler L., Winne J., Du Prez F.E. Vinylogous urea vitrimers and their application in fiber reinforced composites. Macromolecules. 2018;51:2054–2064. [Google Scholar]
  • 101.Si H., Zhou L., Wu Y., Song L., Kang M., Zhao X., Chen M. Rapidly reprocessable, degradable epoxy vitrimer and recyclable carbon fiber reinforced thermoset composites relied on high contents of exchangeable aromatic disulfide crosslinks. Compos. B Eng. 2020;199 [Google Scholar]

Associated Data

This section collects any data citations, data availability statements, or supplementary materials included in this article.

Data Availability Statement

All publication data on which these studies are based have been drawn from public source, Scopus (http://www.scopus.com/). The search string used for finding vitrimer related documents and the retrieved. CSV file are uploaded in repository (https://github.com/HarshSh22/ResearchTrendsinVitrimer.git). The annual distribution and growth trends plot have been drawn from public source (https://www.meta-chart.com/). The co-citation, co-occurrence and all the bibliometric networks have been created through open-source software: VOSviewer version 1.6.19 (https://www.vosviewer.com), to run VOSviewer java version 1.8.0_361 (Oracle Corporation) have been used.


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