The first publication, analyzing the prospects for the use of laser radiation, was published under the authorship of the American physicist Arthur Shawlow in November 1960 (Schawlow, A. L. Bell Lab. Rec., November, 403 (1960)) immediately after the creation of the first laser by Theodor Meiman on 16 May 1960. Later, Arthur Shawlow received the Nobel Prize. Subsequently, many brilliant scientists (A. Zeveil, V.S. Letokhov, N.V. Karlov, and many others) joined the topic of laser-induced processes, which ensured rapid progress in this area [1,2,3,4,5,6,7]. As a result, new directions in chemistry and physics have been formed—laser chemistry and laser physics, which continue to be a dynamically developing science. These laser-related directions consider the fundamental issues of the synthesis/transformation of substances and the problems of high precision and highly controlled laser technologies. Insightful publications of the late 20th century reporting on original ideas of laser irradiation use for various processes of materials transformation and fabrication [8,9,10] turned into extensive areas related to laser technologies since the beginning of the 21st century.
This Special Issue aims to bring the fields of laser technologies and metal nanostructures together for both benefits. We consider different aspects of laser technologies for fabrication of metal-based functional nanomaterials here, as numerous modern instruments and devices are based on processes related to metal nanostructures. It should be noted that the laser effect on a material can initiate physical phenomena (heating, phase transitions, etc.) and/or chemical phenomena (oxidation, reduction, chemical transformations). Thus, the articles of the current Special issue harmoniously combine physical and chemical phenomena and offer advanced laser technologies to modern society.
Regarding publications in laser-induced physical processes, one can find the article by A. V. Agapovichev et al. on selective laser melting to produce Ni-Cr-Al-Ti-Based Superalloy [11]. The authors of the article present sintering processes by pulsed nanosecond laser for obtaining aerosol agglomerates of Pt, Au, and Ag NPs [12]. The interesting combination of processes of laser-induced surface texturing simultaneously with laser-induced anchoring of silver NPs from colloidal solution is discussed by Jakub Siegel et al. in [13]. Such textured polymer surfaces decorated with Ag NPs can be prospective antimicrobial coatings. Another example of laser-induced physical phenomena is laser shock peening, demonstrating significantly improving the fretting fatigue life of TC11 titanium alloy [14]. In the article by Piotr Kupracz et al. [15] laser re-solidification was demonstrated as an approach for the modulation of morphology and structure of metal-decorated TiO2 nanotubes to obtain visible light harvesting.
Interesting advanced approaches for creating nanostructured metal materials with various functionality were presented in laser-induced chemical processes. Thus, laser ablation of monocrystalline silicon in isopropanol containing AgNO3 allowed the single-step formation of Ag-decorated Si microspheres with SERS performance [16]. Here, the physical process of laser ablation is accompanied by the chemical process of Ag NPs formation onto ablated Si species. Femtosecond laser reductive sintering allowed for obtaining high-purity Cu patterns from CuO NPs inks [17]. At the same time, a variant of selective laser reductive sintering created copper and nickel microsensors for non-enzymatic glucose detection [18]. Highly controllable decoration of substrates by plasmonic Ag, Pt NPs with uniform or periodic NPs distribution was demonstrated due to laser-induced deposition [19]. This laser-induced process is based on the photodecomposition of metal-containing precursors and following redox processes onto the substrate surface. Interestingly, a similar process can be realized as a laser-induced thermal process resulting in composite materials based on iridium, gold, and platinum [20].
Conflicts of Interest
The authors declare no conflict of interest.
Footnotes
Disclaimer/Publisher’s Note: The statements, opinions and data contained in all publications are solely those of the individual author(s) and contributor(s) and not of MDPI and/or the editor(s). MDPI and/or the editor(s) disclaim responsibility for any injury to people or property resulting from any ideas, methods, instructions or products referred to in the content.
References
- 1.Zewail A.H. Laser selective chemistry—Is it possible? Phys. Today. 1980;33:27. doi: 10.1063/1.2913821. [DOI] [Google Scholar]
- 2.Letokhov V.S. Laser-induced chemistry. Nature. 1983;305:103. doi: 10.1038/305103a0. [DOI] [Google Scholar]
- 3.Karlov N.V. Laser-induced chemical reactions. Appl. Opt. 1974;13:301. doi: 10.1364/AO.13.000301. [DOI] [PubMed] [Google Scholar]
- 4.Geohegan D.B., Puretzky A.A., Duscher G., Pennycook S.J. Time-resolved imaging of gas phase nanoparticle synthesis by laser ablation. Appl. Phys. Lett. 1998;72:2987. doi: 10.1063/1.121516. [DOI] [Google Scholar]
- 5.Semaltianos N.G. Nanoparticles by Laser Ablation. Crit. Rev. Solid State Mater. Sci. 2010;35:105. doi: 10.1080/10408431003788233. [DOI] [Google Scholar]
- 6.Kim D., Jang D. Synthesis of nanoparticles and suspensions by pulsed laser ablation of microparticles in liquid. Appl. Surf. Sci. 2007;253:8045. doi: 10.1016/j.apsusc.2007.02.153. [DOI] [Google Scholar]
- 7.Zeng H., Du X.W., Singh S.C., Kulinich S.A., Yang S., He J., Cai W. Nanomaterials via laser ablation/irradiation in liquid: A review. Adv. Funct. Mater. 2012;22:1333. doi: 10.1002/adfm.201102295. [DOI] [Google Scholar]
- 8.Roberts M.A., Rossier J.S., Bercier P., Girault H. UV Laser Machined Polymer Substrates for the Development of Microdiagnostic Systems. Anal. Chem. 1997;69:2035. doi: 10.1021/ac961038q. [DOI] [PubMed] [Google Scholar]
- 9.Nakano S., Matsuoka T., Kiyama S., Kawata H., Nakamura N., Nakashima Y., Tsuda S., Nishiwaki H., Ohnishi M., Nagaoka I. Laser Patterning Method for Integrated Type a-Si Solar Cell Submodules. Jpn. J. Appl. Phys. 1986;25:1936. doi: 10.1143/JJAP.25.1936. [DOI] [Google Scholar]
- 10.Keicher D.M., Smugeresky J.E. The laser forming of metallic components using particulate materials. JOM. 1997;49:51. doi: 10.1007/BF02914686. [DOI] [Google Scholar]
- 11.Agapovichev A.V., Khaimovich A.I., Smelov V.G., Kokareva V.V., Zemlyakov E.V., Babkin K.D., Kovchik A.Y. Multiresponse Optimization of Selective Laser Melting Parameters for the Ni-Cr-Al-Ti-Based Superalloy Using Gray Relational Analysis. Materials. 2023;16:2088. doi: 10.3390/ma16052088. [DOI] [PMC free article] [PubMed] [Google Scholar]
- 12.Khabarov K., Nouraldeen M., Tikhonov S., Lizunova A., Seraya O., Filalova E., Ivanov V. Comparison of Aerosol Pt, Au and Ag Nanoparticles Agglomerates Laser Sintering. Materials. 2022;15:227. doi: 10.3390/ma15010227. [DOI] [PMC free article] [PubMed] [Google Scholar]
- 13.Siegel J., Savenkova T., Pryjmaková J., Slepička P., Šlouf M., Švorčík V. Surface Texturing of Polyethylene Terephthalate Induced by Excimer Laser in Silver Nanoparticle Colloids. Materials. 2021;14:3263. doi: 10.3390/ma14123263. [DOI] [PMC free article] [PubMed] [Google Scholar]
- 14.Yang X., Zhang H., Cui H., Wen C. Effect of Laser Shock Peening on Fretting Fatigue Life of TC11 Titanium Alloy. Materials. 2020;13:4711. doi: 10.3390/ma13214711. [DOI] [PMC free article] [PubMed] [Google Scholar]
- 15.Kupracz P., Grochowska K., Karczewski J., Wawrzyniak J., Siuzdak K. The Effect of Laser Re-Solidification on Microstructure and Photo-Electrochemical Properties of Fe-Decorated TiO2 Nanotubes. Materials. 2020;13:4019. doi: 10.3390/ma13184019. [DOI] [PMC free article] [PubMed] [Google Scholar]
- 16.Gurbatov S., Puzikov V., Modin E., Shevlyagin A., Gerasimenko A., Mitsai E., Kulinich S.A., Kuchmizhak A. Ag-Decorated Si Microspheres Produced by Laser Ablation in Liquid: All-in-One Temperature-Feedback SERS-Based Platform for Nanosensing. Materials. 2022;15:8091. doi: 10.3390/ma15228091. [DOI] [PMC free article] [PubMed] [Google Scholar]
- 17.Mizoshiri M., Yoshidomi K. Cu Patterning Using Femtosecond Laser Reductive Sintering of CuO Nanoparticles under Inert Gas Injection. Materials. 2021;14:3285. doi: 10.3390/ma14123285. [DOI] [PMC free article] [PubMed] [Google Scholar]
- 18.Tumkin I.I., Khairullina E.M., Panov M.S., Yoshidomi K., Mizoshiri M. Copper and Nickel Microsensors Produced by Selective Laser Reductive Sintering for Non-Enzymatic Glucose Detection. Materials. 2021;14:2493. doi: 10.3390/ma14102493. [DOI] [PMC free article] [PubMed] [Google Scholar]
- 19.Mamonova D.V., Vasileva A.A., Petrov Y.V., Danilov D.V., Kolesnikov I.E., Kalinichev A.A., Bachmann J., Manshina A.A. Laser-Induced Deposition of Plasmonic Ag and Pt Nanoparticles, and Periodic Arrays. Materials. 2021;14:10. doi: 10.3390/ma14010010. [DOI] [PMC free article] [PubMed] [Google Scholar]
- 20.Panov S.M., Khairullina M.E., Vshivtcev S.F., Ryazantsev N.M., Tumkin I.I. Laser-Induced Synthesis of Composite Materials Based on Iridium, Gold and Platinum for Non-Enzymatic Glucose Sensing. Materials. 2020;13:3359. doi: 10.3390/ma13153359. [DOI] [PMC free article] [PubMed] [Google Scholar]