Skip to main content
Science Progress logoLink to Science Progress
. 2008 Sep 1;91(3):219–240. doi: 10.3184/003685008X360632

The Myth of the Boiling Point

Hasok Chang 1,
PMCID: PMC10361150  PMID: 18853575

Abstract

Around 1800, many reputable scientists reported significant variations in the temperature of pure water boiling under normal atmospheric pressure. The reported variations included a difference of over 1°C between boiling in metallic and glass vessels (Gay-Lussac), and “superheating” up to 112°C on extracting dissolved air out of water (De Luc). I have confirmed most of these observations in my own experiments, many of which are described in this paper. Water boils at the “boiling point” only under very particular circumstances. Our common-sense intuition about the fixedness of the boiling point is only sustained by our limited experience.

Keywords: boiling point, replications of historical experiments, superheating, water, De Luc, Gay-Lussac

Full Text

The Full Text of this article is available as a PDF (1.6 MB).

References

  • 1.Chang H. (2004) Inventing temperature: measurement and scientific progress. Oxford University Press, New York. [Google Scholar]
  • 2.Newton I. (1701) Scala Graduum Caloris. Calorum Descriptiones et Signa. Phil. Trans. Roy. Soc. Lond., 22, 824–829. [Google Scholar]
  • 3.Cavendish H., Heberden W., Aubert A., De Luc J.-A., Maskelyne N., Horsley S., and Planta J. (1777) The Report of the Committee appointed by the Royal Society to consider of the best method of adjusting the fixed points of thermometers; and of the precautions necessary to be used in making experiments with those instruments. Phil. Trans. Roy. Soc. Lond., 67, 816–857. [Google Scholar]
  • 4.Cavendish H. (1921) Theory of boiling. The scientific papers of the Honourable Henry Cavendish, F.R.S., Vol. 2, Chemical and dynamical, Thorpe Edward (ed.), pp. 354–362. Cambridge: Cambridge University Press. [Google Scholar]
  • 5.De Luc J.-A. (1772) Recherches sur les modifications de l'atmosphère, Vol. 2. pp. 227–438. Geneva. [Google Scholar]
  • 6.Gay-Lussac J.-L. (1818) Notice respecting the fixedness of the boiling point of fluids. Annls. Philos., 12, 129–131. [Google Scholar]
  • 7.Biot J.-B. (1816) Traité de physique expérimentale et mathématique, vol. 1, pp. 41–43. Deterville, Paris. [Google Scholar]
  • 8.Marcet F. (1842) Recherches sur certaines circonstances qui influent sur la température du point d'ébullition des liquides. Biblioth. Univers., New Ser., 38, 388–411. [Google Scholar]
  • 9.Donny F. (1846) Mémoire sur la cohésion des liquides, et sur leur adhérence aux corps solides. Annls. Chim. Phys., 3rd Ser., 16, 167–190. [Google Scholar]
  • 10.Dufour L. (1861) Recherches sur l'ébullition des liquids. Arch. Sci. Phys. Natur., 12, 210–266. [Google Scholar]
  • 11.Gernez D. (1875) Recherches sur l'ébullition. Annls. Chim. Phys., 5th Ser., 4, 335–401. [Google Scholar]
  • 12. http://www.ucl.ac.uk/sts/chang/boiling
  • 13. http://www.phys.unsw.edu.au/∼jw/superheating.html
  • 14.Incropera F. P., and DeWitt D. P. (1996) Fundamentals of heat and mass transfer, 4th edn. John Wiley and Sons, New York. [Google Scholar]
  • 15.Hewitt G. F., Shires G. L., and Polezhaev Y. V. (eds.), (1997) International encyclopedia of heat and mass transfer. CRC Press, Boca Raton. [Google Scholar]
  • 16.Kandlikar S. G. (ed.), (1999) Handbook of phase change: boiling and condensation. Taylor & Francis, London. [Google Scholar]
  • 17.Kuhn T. S. (1962) The structure of scientific revolutions. University of Chicago Press, Chicago. [Google Scholar]

Articles from Science Progress are provided here courtesy of SAGE Publications

RESOURCES