Skip to main content
NCBI home page
Science Progress logoLink to Science Progress
. 2019 Feb 27;84(4):311–334. doi: 10.3184/003685001783238925

Hydrogenation Properties of Supported Nanosized Gold Particles

Christian Mohr 1, Peter Claus 1,✉
PMCID: PMC10367522  PMID: 11838240

Full Text

The Full Text of this article is available as a PDF (274.3 KB).

References

  • 1.Che M., & Bennett C.O. (1989) The influence of particle size on the catalytic properties of supported metals. Advances in Catalysis [Review]: 36, 55–172. [Google Scholar]
  • 2.Bond G.C., & Thompson D.T. (1999) Catalysis by Gold [Review]. Catalysis Reviews. -Science & Engineering 41 (3 & 4), 319–388. [Google Scholar]
  • 3.Haruta M. (1997) Size- and support dependency in the catalysis of gold [Review]. Catalysis Today, 36, 1, 153–166. [Google Scholar]
  • 4.Mohr C., Hofmeister H., Lucas M., & Claus P. (2000) Gold catalysts for the partial hydrogenation of acrolein. Chemical Engineering Technology, 23(4), 324–328. [Google Scholar]
  • 5.Ertl G., Knözinger H., & Weitkamp J. (1997) Handbook of Heterogeneous Catalysis, VCH Weinheim. [Google Scholar]
  • 6.Beeck O. (1945) Catalysis – A Challenge to the Physicist [Review]. Rev. Mod. Phys., 17, 61. [Google Scholar]
  • 7.Bond G.C., Sermon P.A., Webb G., Buchanan D.A., & Wells P.B. (1973) Hydrogenation over supported gold catalysts: JCS Chemical Communications, 444–445.
  • 8.Shibata M., Kawata N., Masumoto T., & Kimura H. (1988) Selective hydrogenation of unsaturated carbonyl compounds over an oxidized gold-zirconium alloy: JCS Chemical Communications, 154–156. [Google Scholar]
  • 9.Schimpf S., Lucas M., & Claus P. (2001) Selective hydrogenation of 1,3-buta-diene over supported gold nanoparticles. DGMK Conference Creating Value from Light Olefins, Oct. 10-12th, Hamburg, Proc. ISBN 3-931850-84-6. [Google Scholar]
  • 10.Chastain J., & King R. J. Jr. (eds) Handbook of X-ray Photonelectron Spectroscopy, Phys. Electr., Inc., 1995. [Google Scholar]
  • 11.(a) Augustine R. L. (1995) Heterogeneous Catalysts in Organic Synthesis, Dekker, New York; (b) Bauer, K. & Garbe, D. (2000) In: Ullmann's Encyclopedia of Industrial Chemistry, 6th edn., Electronic Release. [Google Scholar]
  • 12.Claus P. (1998) Selective hydrogenation of α,β-unsaturated aldehydes and other C = O and C = C bonds containing compounds [Review]. Topics in Catalysis, 5(1-4): 51–62. [Google Scholar]
  • 13.Gallezot P., & Richard D. (1998) Selective hydrogenation of α,β-unsaturated aldehydes [Review]. Catalytic Review-Science Engineering 40, 81–126. [Google Scholar]
  • 14.Ponec V. (1997) On the role of promoters in hydrogenations on metals: α,β-unsaturated aldehydes and ketons. Applied Catalysis A: General 149, 27–48. [Google Scholar]
  • 15.(a) Claus P., & Hofmeister H. (1999) Electron microscopy and catalytic study of silver catalysts: Structure sensitivity of the hydrogenation of crotonaldehyde. Journal of Physical Chemistry B 103, 14, 2766–2775; (b) Claus, P., Kraak, P. & Schödel, R. (1997) Selective hydrogenation of α,β-unsaturated aldehydes to allylic alcohols over supported monometallic and bimetallic Ag catalysts. Studies in Surface Science and Catalysis, 108: Heterogeneous Catalysis and Fine Chemicals IV (H.-U. Blaser, A. Baiker, R. Prins, eds), Elsevier, Amsterdam, 281-288. [Google Scholar]
  • 16.Claus P., & Hofmeister H. (1998) Silber-Nanopartikel als selektive Hydrierkatalysatoren, Proc. DECHEMA-Workshop Funktionalisierte Nanopartikel, 23.–24.04.1998, Frankfurt/Main, p. 3.2.
  • 17.Tauster S. J., Fung S. C., & Garten R. L. (1978), Strong Metal-Support Interactions. Group 8 noble metals supported on TiO2. Journal of the American Chemical Society, 100, 170. [Google Scholar]
  • 18.Coq B., & Figueras F. (1998) Structure-activity relationships in catalysis by metals: some aspects of particle size, bimetallic and support effects [Review]. Coordination Chemistry Reviews, 178-180, 1753–1783. [Google Scholar]
  • 19.Neri G., Mercadante L., Milone C., Pietropaolo R., & Galvagno S. (1996) Hydrogenation of citral and cinnamaldehyde over bimetallic Ru-Me/Al2O3 catalysts. Journal of Molecular Catalysis A: Chemical 108, 41–50. [Google Scholar]
  • 20.Claus P., Lucas M., & Münzner H. DE 195 33 578 C1, 29.08.1995.
  • 21.Bailie J.E., & Hutchings G.J. (1999) Promotion by sulfur of gold catalysts for crotyl alcohol formation from crotonaldehyde hydrogenation: Chemical Communications, 21, 2151–2152. [Google Scholar]
  • 22.Shibata M., Kimura H., & Masumoto T. (1990) Partial hydrogenations of unsaturated carbonyl compounds and unsaturated hydrocarbons over an oxidized gold-zirconium alloy. Journal of Chemical Society of Japan 6, 628–635. [Google Scholar]
  • 23.Claus P., Brückner A., Mohr C., Hofmeister H. (2000) Supported gold nanoparticles from quantum dot to mesoscopic size scale: Effect of electronic and structural properties on catalytic hydrogenation of conjugated functional groups. Journal of the American Chemical Society, 122(46), 11430–11439. [Google Scholar]
  • 24.van Hardefeld R., Hartog F. (1969) Statistics of surface atoms and surface sites on metal crystals. Surface Science, 15(2): 189–230. [Google Scholar]
  • 25.Henry C.R. (1998) Surface studies of supported model catalysts [Review]. Surface Science Reports 31, 235–325. [Google Scholar]
  • 26.Bond G.C. (1991) Supported metal catalysts – Some unsolved problems [Review]. Chemical Society Reviews, 20(4): 441–475. [Google Scholar]
  • 27.Mohr C., Radnik J., Hofmeister H., & Claus P. (2001) Effect of indium addition on selective hydrogenation of acrolein on supported gold catalysts, in preparation.
  • 28.Radnik J., Mohr C., & Claus P. (2001) Influence of preparation and kind of support on the electronic state of supported gold nanoparticles, in preparation.
  • 29.Stobinski L., Zommer L., Dus R. (1999) Molecular hydrogen interactions with discontinuous and continuous thin gold films. Applied Surface Science, 141(3-4), 319–325. [Google Scholar]
  • 30.Mohr C., Hofmeister H., & Claus P. (2001) Structure sensitivity and influence of multiply twinned particles on partial hydrogenation of acrolein on Au/ZrO2 catalysts, in preparation.
  • 31.Valden M., Lai X., & Goodman D.W. (1998) Onset of catalytic activity of gold clusters on titania with the appearence of nonmetallic properties. Science 281, 1647–1650. [DOI] [PubMed] [Google Scholar]
  • 32.Akita M., Osaka N., & Itoh K. (1997) Infra-red reflection absorption spectro-scopic study on adsorption structures of acrolein on polycrystalline gold and Au(111) surfaces under ultra-high vacuum conditions. Surface Science 405, 172–181. [Google Scholar]
  • 33.Somorjai G.A., & Rupprechter G. (1998) The flexible surface. Journal of Chemical Education 75, 2, 161–176. [Google Scholar]
  • 34.van Santen R.A., & Neurock M. (1995) Concepts in theoretical heterogeneous catalytic reactivity. Catalytic Review-Science Engineering, 37, 557–698. [Google Scholar]
  • 35.Delbecq F., & Sautet P. (1996) Competitive C=C and C=O adsorption of α,β-unsaturated aldehydes on Pt and Pd surfaces in relation with the selectivity of hydrogentation reactions – A theoretical approach. Journal of Catalysis, 164, 152–165. [Google Scholar]
  • 36.Claus P., & Lucas M. (2001) Selective hydrogenation of acrolein to allyl alcohol over Ag-In/SiO2 catalysts, 5th European Congress on Catalysis, Symposium 19. Catalysis by silver and gold, Limerick, 02-07 Sept. 2001, submitted.

Articles from Science Progress are provided here courtesy of SAGE Publications

RESOURCES