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. 2023 Jul 28;28(15):5710. doi: 10.3390/molecules28155710

Table 1.

Microplastic-extraction abilities of different hypersaline solutions. The + and − signs indicate the adequate (+) or inadequate (−) technique for that type of microplastics. Reference numbers are given in brackets. Typical densities of different polymers are reported in the first row. Prices refer to Merck website (update July 2023).

Salt Density
g/cm3
PET HD
PE
PVC LD
PE
PP PS PA Remarks Price
EUR/kg
1.32–1.41 0.94–0.96 1.14–1.46 0.91–0.92 0.85–0.92 1.04–1.08 1.12–1.15
Milli-Q water 1 + + 1. Easy to use
2. Low recovery rate
32.20
NaCl 1.2 + ± + + + + 1. Easy to use, non-toxic
2. Low recovery rate, requires multiple washings
46.50
ZnCl2 1.5–1.8 + + + + + + [46] + 1. Reusable
2. Corrosive, strong foaming with organic samples [47,48]
3. Toxic to aquatic life [49]
139.00
NaI 1.55–1.8 + + ± + + + + 1. Reusable
2. Reacts with cellulose fibers, hygroscopic, multistep method
3. Eye irritant
396
Sodium
Polytungstate
1.4–1.65 + + + + + + 1. Eye irritant
2. Toxic to aquatic life
266/100 g
Sodium Dihydrogen Phosphate monohydrate 1.4–1.45 + + + + + + 1. Hazard free
2. Heating is required to achieve desired density [50]
96.60
CaCl2 1.3–1.35 + + + + + + [51] 1.Organic matter settles slowly due to high viscosity [32]
2. Ca2+ caused flocculation of organic substances through ion bridging; thus, it is not suggested for organic rich samples [48]
3. Eye irritant
97.60
ZnBr2 dihydrate 1.7 + + + + + + + 1. Toxic to aquatic life, eye irritant 344.00
NaBr 1.37 + + + + + + + [52] 1. Eye irritant 80.60
Lithium tungstate 1.62 + + + + + + + 1. Recommended by NOAA 79.90/25 g
Potassium iodide 1.7 + + + + 1. Eye irritant
2. Toxic to aquatic life [53]
298.00
K(HCOO) 1.5 + + + + + + + 1. Reusable 96/L
NaCl/NaI 1.2/1.8 + + + + + + + 1. High recovery rate
2. Pretreatment required [54]