Crystal structures of five compounds in the aluminium–ruthenium–silicon system

The crystal structures of five compounds in the Al–Ru–Si system with approximate compositions ∼Ru₁₆(Al_0.78Si_0.22)₄₇ (I), ∼Ru₉(Al_0.70Si_0.30)₃₂ (II), ∼Ru₁₀(Al_0.67Si_0.33)₄₁ (III), ∼Ru(Al_0.57Si_0.43)₅ (IV) and ∼Ru₂(Al_0.46Si_0.54)₉ (V) are presented. Notably, the crystal structure of (I) can be related to that of a cubic rational crystalline approximant to an icosa­hedral quasicrystal through crystallographic shear and then unit-cell twinning.

Abstract

Single crystals of five compounds with approximate compositions ∼Ru₁₆(Al_0.78Si_0.22)₄₇, (I), ∼Ru₉(Al_0.70Si_0.30)₃₂, (II), ∼Ru₁₀(Al_0.67Si_0.33)₄₁, (III), ∼Ru(Al_0.57Si_0.43)₅, (IV), and ∼Ru₂(Al_0.46Si_0.54)₉, (V), were obtained from polycrystalline lumps mainly composed of the target compounds, and their crystal structures were determined by means of single-crystal X-ray diffraction. The crystal structure of (I) can be related to that of a cubic rational crystalline approximant to an icosa­hedral quasicrystal through crystallographic shear and then unit-cell twinning. The crystal structure of (II) is isotypic with that of a phase with composition ∼Fe₉(Al,Si)₃₂. The crystal structure of (III) is comprised of edge-sharing Ru(Al,Si)_9–11 polyhedra with disordered chains along edges of polyhedra. The crystal structure of (IV) is of the LiIrSn₄ type. The crystal structure of (V) can be viewed as a crystallographic shear structure derived from that of (IV).

1. Chemical context

Semiconductors with complex crystal structures have attracted attention as thermoelectric materials (Snyder & Toberer, 2008 ▸; Zhang & Zhao, 2015 ▸; Liu et al., 2017 ▸). To facilitate a search for such materials, knowledge on crystal structures is essential because it serves as a basis for understanding how semiconductivity and structural complexity meet in a material. Recently, a semiconducting compound with a complex crystal structure, which is considered a cubic rational crystalline approximant to an icosa­hedral quasicrystal, was discovered near the composition Al_67.6Ru_23.5Si_8.9 (Iwasaki et al., 2019 ▸). Following this discovery, phase equilibria in the Al–Ru–Si system at 1200 K were thoroughly investigated, and eleven new ternary phases were identified (Kitahara et al., 2023 ▸). In the course of these investigations, single crystals of five new compounds with approximate compositions ∼Ru₁₆(Al_0.78Si_0.22)₄₇ (I), ∼Ru₉(Al_0.70Si_0.30)₃₂ (II), ∼Ru₁₀(Al_0.67Si_0.33)₄₁ (III), ∼Ru(Al_0.57Si_0.43)₅ (IV) and ∼Ru₂(Al_0.46Si_0.54)₉ (V) could be obtained from polycrystalline lumps mainly composed of the target compounds. Here we report the crystal structures of these compounds.

2. Structural commentary

The crystal structure of (I) consists of Ru-centred polyhedra with coordination numbers ranging from nine to eleven [Fig. 1 ▸(a–e, g–i)] and (Si,Ru)-centred icosa­hedra [Fig. 1 ▸(f)]. Each polyhedron is connected to three, four, five, six or fourteen others through face-sharing. A sensible represent­ation of the crystal packing in (I) is obtained by using large structural units (clusters) [Fig. 2 ▸(b)] instead of using coordination polyhedra [Fig. 2 ▸(a)].

Figure 1.

Coordination environments of (a) Ru1, (b) Ru2, (c) Ru3, (d) Ru4, (e) Ru5, (f) Si/Ru6, (g) Ru7, (h) Ru8 and (i) Ru9 in the crystal structure of (I) with displacement ellipsoids plotted at the 99% probability level. Unlabelled atoms in (a–f), (g) and (h) are related to the corresponding labelled atoms by (iii), (i) and (xix), respectively. Only the major disordered components are shown except for Ru8, Al20 and Al28A, for which two split components with equal occupancy are shown. Colour codes: Al and (Al/Si) (light blue); Ru (light brown); Si, (Si/Al) and (Si/Ru) (blue). [Symmetry codes: (i) x, y, −z +  ; (iii) −x, y, z; (v) −x +  , −y +  , z +  ; (vi) −x, −y, −z + 1; (vii) −x +  , −y +  , −z + 1; (ix) −x +  , −y +  , −z; (x) −x +  , y +  , z; (xii) −x, −y + 1, −z; (xiii) −x, −y + 1, z −  ; (xiv) x +  , y −  , −z +  ; (xv) x +  , y −  , z; (xvi) −x +  , y −  , −z +  ; (xvii) −x +  , y −  , z; (xix) −x + 1, y, z; (xx) −x +  , −y +  , z −  .]

Figure 2.

Packing diagrams for (I) based on (a) the coordination polyhedra given in Fig. 1 ▸ and (b) larger structural units (clusters).

The crystal structure of (I) can be related to that of a rational crystalline approximant to an icosa­hedral quasicrystal through crystallographic shear and then unit-cell twinning, as detailed in the following. The crystallographic shear and unit-cell twinning are two of the most important structure building operations by which a recombination structure is derived from a simpler parent structure (Lima-de-Faria et al., 1990 ▸). In this case, the parent structure is a 1/0 cubic approximant to a Mackay-type icosa­hedral quasicrystal. Crystal structures of this type are known for the phases with approximate compositions ∼RhAl_2.63 (ICSD 406525; Grin et al., 1997 ▸), ∼IrAl_2.75 (ICSD 406526; Grin et al., 1997 ▸), ∼Al_20.5Ru_5.1Ni_2.9 (ICSD 230569; Simura et al., 2017 ▸) and ∼Al_5.64Fe_0.96Pd_1.04 (ICSD 45248; Li & Fan, 2019 ▸). The crystal structure of the semiconducting compound ∼Al_67.6Ru_23.5Si_8.9 is also considered to fall into this type (Iwasaki et al., 2019 ▸). Fig. 3 ▸(a) shows an idealized crystal structure of this cubic approximant, which can be viewed as a CsCl-type packing of two types of clusters, icosa­hedral clusters and pseudo-Mackay clusters (Simura et al., 2017 ▸). Fig. 3 ▸(b) shows a crystallographic shear structure derived from the parent structure. The shear planes are (10 ) planes of the parent structure [Fig. 3 ▸(a)], and the shear operation was applied at cluster level. Fig. 3 ▸(c) shows the crystal structure obtained by applying unit-cell twinning to the sheared structure. The twin planes are (001) planes of the sheared structure [Fig. 3 ▸(b)], and the twin operation was applied at the atomic level. Two constituent parts of the twinned structure are related by reflection across the twin planes as the mirror planes. Atoms close to each twin plane were shifted onto the plane prior to the twinning. The twinned structure is comparable to the cluster-based representation of (I) shown in Fig. 2 ▸(b). Note that the shear structure shown in Fig. 3 ▸(b) can also be obtained through so-called linear phason strain (Yamamoto, 1996 ▸) instead of crystallographic shear and hence directly relates to an icosa­hedral quasicrystal as a monoclinic approximant.

Figure 3.

The structural units given in Fig. 2 ▸(b) as derived from (a) the parent cubic approximant structure by applying (b) crystallographic shear and then (c) unit-cell twinning. Shear planes [(10 ) planes of the parent structure] are indicated by arrows in (a). Twin planes [(001) planes of the sheared structure] are indicated by arrows in (b). Colour codes: icosa­hedral clusters (blue); pseudo-Mackay clusters (red).

The crystal structure of (II) consists of two types of Ru-centred polyhedra, RuAl₁₂ cubocta­hedra [Fig. 4 ▸(a)] and Ru(Al,Si)₉ square-face tricapped trigonal prisms [Fig. 4 ▸(b, c)]. Each cubocta­hedron is surrounded by eight square-face tricapped trigonal prisms sharing its eight triangular faces. Each square-face tricapped trigonal prism is in turn connected to others through edge-sharing.

Figure 4.

Coordination environments of (a) Ru1, (b) Ru2 and (c) Ru3 in the crystal structure of (II) with displacement ellipsoids plotted at the 99% probability level. Colour codes: Al and Al/Si (light blue); Ru (light brown); Si (blue). [Symmetry codes: (i) x − y, x, −z + 1; (ii) −x + y, −x, z; (iii) −x, −y, −z + 1; (iv) −y, x − y, z; (v) y, −x + y, −z + 1; (vi) y −  , −x + y −  , −z +  ; (vii) −y +  , x − y +  , z +  ; (viii) x −  , y −  , z +  ; (ix) −x +  , −y +  , −z +  ; (x) x − y +  , x −  , −z +  ; (xi) −x + y −  , −x +  , z +  ; (xii) x − y +  , x +  , −z +  ; (xiii) −x + y +  , −x +  , z −  ; (xiv) −x +  , −y +  , −z +  ; (xv) y, −x + y, −z.]

The crystal structure of (III) is comprised of Ru(Al,Si)₁₀ [Fig. 5 ▸(a, b)], Ru(Al,Si)₉ [Fig. 5 ▸(c)] and Ru(Al,Si)₁₁ [Fig. 5 ▸(d–g)] polyhedra. Unlike the polyhedra in (I) and (II), no faces are shared between these polyhedra. These polyhedra are connected through edge-sharing. As an unusual feature, extensive positional disorder within a chain motif along edges of Ru4- and Ru5-centred polyhedra [Fig. 6 ▸(a)] is found in (III). A similar disordered chain structure [Fig. 6 ▸(b)] was also reported for the phase with approximate composition ∼Fe₂Al₅ (Burkhardt et al., 1994 ▸; Vinokur et al., 2019 ▸).

Figure 5.

Coordination environments of (a) Ru1, (b) Ru2, (c) Ru3, (d) Ru4, (e) Ru5, (f) Ru6 and (g) Ru7 in the crystal structure of (III) with displacement ellipsoids plotted at the 99% probability level. Unlabelled atoms in (a–d) are related to the corresponding labelled atoms by (vii). Only the major disordered components are shown. Colour codes: Al and Al/Si (light blue); Ru (light brown); Si (blue). [Symmetry codes: (i) −x +  , y −  , z +  ; (iii) x −  , y, −z +  ; (iv) x +  , y, −z +  ; (v) x +  , −y +  , −z +  ; (vi) x +  , y, −z +  ; (vii) x, −y +  , z; (viii) −x +  , y −  , z −  ; (x) −x +  , −y, z +  ; (xi) −x, y −  , −z + 1.]

Figure 6.

Disordered chains along polyhedral edges (a) in the crystal structure of (III) and (b) in ∼Fe₂Al₅ (CCDC 1880447; Vinokur et al., 2019 ▸). Colour codes: Al (light blue); Fe (brown); Ru (light brown); Si (blue).

The crystal structures of (IV) and (V) consist of Ru(Al,Si)₁₀ bicapped square anti­prisms [Fig. 7 ▸(a, b)]. In both crystal structures, the two cap positions of each polyhedron [Al2ⁱ and Al2 in Fig. 7 ▸(a); Al6 and Al8^iv in Fig. 7 ▸(b)] are occupied solely by Al, and each polyhedron is connected to four others in the (001) plane through edge-sharing. Along the [001] direction, each polyhedron is connected to two others sharing its vertices at the two cap positions in (IV) [Fig. 8 ▸(a)], while each polyhedron is connected to one another through vertex-sharing and two others through edge-sharing in (V) [Fig. 8 ▸(b)]. The structure of (V) can be viewed as a crystallographic shear structure derived from that of (IV). The corresponding shear planes are (001) planes of (IV) [Fig. 8 ▸(a)].

Figure 7.

Coordination environments of (a) Ru1 in the crystal structure of (IV) [symmetry codes: (i) −x, y, −z +  ; (ii) y − 1, −x, z; (iii) y −  , −x +  , −z +  ; (iv) x, y − 1, z; (v) −x +  , −y +  , −z +  ; (vi) −y +  , x −  , −z +  ; (vii) −y + 1, x, z; (viii) x −  , y −  , −z +  ; (ix) −x, −y + 1, z] and (b) Ru1 in the crystal structure of (V) [symmetry codes: (i) −x +  , −y +  , z −  ; (ii) −x +  , y −  , z; (iv) −x +  , −y +  , −z] with displacement ellipsoids plotted at the 99% probability level. Colour codes: Al (light blue); Ru (light brown); Si and Si/Al (blue).

Figure 8.

Packing diagrams for the crystal structures (a) of (IV) and (b) of (V). Crystallographic shear planes [(001) planes of (IV)] are indicated by arrows in (a). Colour codes: Al (light blue); Ru (light brown); Si (blue).

3. Database survey

Searches for isotypic crystal structures to those of the five compounds were carried out using the Inorganic Crystal Structure Database (ICSD, version 4.9.0; Zagorac et al., 2019 ▸). For (I), (III) and (V), queries for structures with the Pearson symbols oS250–254, oP200–204 and oS88, respectively, were made, but no entries for isotypic crystals were found. For (II), a query for hR41 was made, and three nearly identical structures (ICSD 99169; Sugiyama et al., 2004 ▸; ICSD 423182, 423183; Roger et al., 2011 ▸) of the crystal ∼Fe₉(Al,Si)₃₂ were found. Although isotypism is indicated between (II) and ∼Fe₉(Al,Si)₃₂, unlike in (II), the centres of the cubocta­hedra are not occupied solely by transition-metal atoms in these structures. For (IV), a query for tI24 was made, and some isotypic crystals of the LiIrSn₄ type (ICSD 412252; Wu et al., 2002 ▸) were found. Limiting the results to Al-containing crystal structures, isotypic crystals in the Al–Fe–Si (ICSD 79709; Gueneau et al., 1995 ▸; ICSD 4837, 4839; Zhou et al., 2018 ▸), Al–Fe–Ge (ICSD 235910; Reisinger et al., 2018 ▸) and Al–Ge–Mn (ICSD 8608; Sasaki et al., 2019 ▸) systems were found. In these structures and that of (IV), the Li sites of the LiIrSn₄-type structure are occupied solely by Al, whereas the Sn sites are occupied by (Al,Si) or (Al,Ge).

4. Synthesis and crystallization

Polycrystalline samples with the nominal compositions Al_58.0Ru_25.3Si_16.7 for (I) and Al_37.5Ru_17.8Si_44.7 for (V) were prepared from powders of aluminium (Kojundo Chemical Lab., Japan, 99.9%), ruthenium (Tanaka Kikinzoku Kogyo K. K., Japan, 99.90% or purer) and silicon (Kojundo Chemical Lab., Japan, 99.99% or purer) using arc melting in an argon atmosphere (NEV-ACD-05, Nissin Giken Corporation, Japan). Each sample was then wrapped in tantalum foil, sealed in a silica tube filled with argon and annealed in a furnace at 1200 K for approximately 264 h, followed by water quenching. Powders for polycrystalline samples with the nominal compositions Al_55.5Ru_21.7Si_22.8 for (II), Al_55.0Ru_19.2Si_25.8 for (III) and Al_48.0Ru_16.2Si_35.8 for (IV) were mechanically compacted without melting. Each sample was then placed in an aluminium nitride crucible, sealed in a silica tube filled with argon and reacted in a furnace at 1200 K for approximately 160 h or longer, followed by water quenching. Single crystals were selected from crushed fragments of the polycrystalline samples (lumps), which are mainly composed of the target compounds. The compositions of the target compounds in the samples were analysed as described elsewhere (Kitahara et al., 2023 ▸) using an energy-dispersive spectrometer (X-Max, Oxford Instruments, UK) equipped in a scanning electron microscope (SU6600, Hitachi High-Technologies Corporation, Japan). Determined compositions for equilibria at 1200 K are Al_58.2 (5)Ru_25.1 (4)Si_16.7 (3) for (I), Al_55.2 (6)Ru_21.6 (4)Si_23.1 (7) for (II), Al_54.1 (5)Ru_19.6 (3)Si_26.3 (4) for (III), Al_47.3 (6)Ru_16.3 (3)Si_36.4 (6) for (IV) and Al_38.0 (5)Ru_17.8 (3)Si_44.2 (6) for (V). These compositions are similar to the nominal compositions and consistent with the approximate single-phase regions [from Al₆₂Ru₂₅Si₁₃ to Al₅₆Ru₂₆Si₁₈ for (I), from Al₅₇Ru₂₂Si₂₁ to Al₅₄Ru₂₂Si₂₄ for (II), from Al₅₅Ru₂₀Si₂₅ to Al₅₄Ru₂₀Si₂₆ for (III), from Al₄₉Ru₁₇Si₃₄ to Al₄₇Ru₁₇Si₃₆ for (IV) and from Al₄₁Ru₁₈Si₄₁ to Al₃₇Ru₁₈Si₄₅ for (V)] (Kitahara et al., 2023 ▸).

5. Refinement

Crystal data, data collection and structure refinement details are summarized in Table 1 ▸.

Table 1. Experimental details.

	(I)	(II)	(III)	(IV)	(V)
Crystal data
Chemical formula	∼Ru16(Al0.78Si0.22)47	∼Ru9(Al0.70Si0.30)32	∼Ru10(Al0.67Si0.33)41	∼Ru(Al0.57Si0.43)5	∼Ru2(Al0.46Si0.54)9
M r	2900.59	1783.65	2122.53	238.38	450.41
Crystal system, space group	Orthorhombic, C m c m	Trigonal, R	Orthorhombic, P n m a	Tetragonal, I4/m c m	Orthorhombic, C m c m
Temperature (K)	301	296	298	297	301
a, b, c (Å)	7.6217 (2), 23.4434 (6), 20.6877 (6)	10.4479 (2), 10.4479 (2), 19.6774 (4)	15.0794 (2), 11.8713 (2), 16.9291 (3)	6.20079 (8), 6.20079 (8), 9.6937 (2)	8.63058 (14), 8.79888 (15), 17.4620 (3)
α, β, γ (°)	90, 90, 90	90, 90, 120	90, 90, 90	90, 90, 90	90, 90, 90
V (Å3)	3696.46 (19)	1860.17 (7)	3030.50 (9)	372.72 (1)	1326.05 (4)
Z	4	3	4	4	8
Radiation type	Mo Kα	Mo Kα	Mo Kα	Mo Kα	Mo Kα
μ (mm−1)	7.59	6.59	6.18	5.32	5.88
Crystal size (mm)	0.04 × 0.02 × 0.02	0.03 × 0.03 × 0.03	0.04 × 0.02 × 0.02	0.05 × 0.03 × 0.02	0.05 × 0.04 × 0.04
Data collection
Diffractometer	XtaLAB Synergy R, HyPix	XtaLAB Synergy R, HyPix	XtaLAB Synergy R, HyPix	XtaLAB Synergy R, HyPix	XtaLAB Synergy R, HyPix
Absorption correction	Gaussian (CrysAlis PRO; Matsumoto et al., 2021 ▸)	Gaussian (CrysAlis PRO; Matsumoto et al., 2021 ▸)	Gaussian (CrysAlis PRO; Matsumoto et al., 2021 ▸)	Gaussian (CrysAlis PRO; Matsumoto et al., 2021 ▸)	Gaussian (CrysAlis PRO; Matsumoto et al., 2021 ▸)
T min, T max	0.824, 0.924	0.868, 0.879	0.867, 0.929	0.833, 0.906	0.826, 0.868
No. of measured, independent and observed [I > 2σ(I)] reflections	11822, 2616, 2280	14255, 1193, 1127	33654, 5672, 4940	8063, 295, 279	17672, 1029, 1001
R int	0.020	0.027	0.022	0.029	0.016
(sin θ/λ)max (Å−1)	0.718	0.720	0.781	0.864	0.719
Refinement
R[F 2 > 2σ(F 2)], wR(F 2), S	0.015, 0.032, 1.04	0.013, 0.024, 1.08	0.015, 0.026, 1.01	0.009, 0.021, 1.21	0.011, 0.027, 1.31
No. of reflections	2616	1193	5672	295	1029
No. of parameters	218	66	303	13	61
No. of restraints	5	2	2	2	2
Δρmax, Δρmin (e Å−3)	0.64, −0.69	0.45, −0.53	0.78, −0.74	0.44, −0.42	0.37, −0.42

Computer programs: CrysAlis PRO (Matsumoto et al., 2021 ▸), SHELXT (Sheldrick, 2015a ▸), SHELXL (Sheldrick, 2015b ▸), VESTA (Momma & Izumi, 2011 ▸) and publCIF (Westrip, 2010 ▸).

For (I) and (III), significant residual electron density peaks were found around some sites after routine structure refinement procedures. To account for these peaks, some split sites were introduced for (I) [Ru7B from Ru7A; Ru8 (Wyckoff position changed into 8g from 4c); Al12B from Al12A; Si17B from Al17A; Si26B from Al26A; Al28A (16h from 8f); Al28B and Al28C from Al28A] and (III) [Ru4B from Ru4A; Ru5B from Ru5A; Si9B from Si9A; Al10B from Si10A; Al29B from Al29A; Al30B from Al30A; Al31B and Al31C from Al31A; Al32B from Al32A]. Anisotropic displacement parameters were not introduced for minor split components [Ru7B, Al12B, Si17B, Si26B, Al28B and Al28C in (I); Ru4B, Ru5B, Al10B, Al29B, Al30B, Al31B, Al31C and Al32B in (III)] except for Si9B in (III).

Choices of Al, Si or (Al,Si) mixing were basically based on the site-occupancy factors (SOFs). After routine structure-refinement procedures and adding split sites, the SOF of each site was refined independently one by one. (Al,Si) mixing was introduced for some sites for (I) (Si/Al10, Al/Si14, Al/Si18, Al/Si21 and Al/Si22), (II) (Al/Si6 and Al/Si7), (III) (Al/Si11, Al/Si20, Al/Si21 and Al/Si22), (IV) (Si/Al3) and (V) (Si/Al5 and Si/Al7) because the SOF becomes significantly higher than 1 with Al occupation only and lower than 1 with Si occupation only for these sites. The positions and displacement parameters of mixing components were constrained using EXYZ and EADP instructions of SHELXL (Sheldrick, 2015b ▸). For split sites, (Al,Si) mixing was not introduced, and Al or Si was chosen for each site so that the sum of the SOFs of the split components are close to 1. Choice of Si for Si/Ru6 in (I) is rather arbitrary, and it may be Al or even a vacancy.

After assigning chemical species to each site, the sum of the SOFs for each group of mixed or split sites was constrained to 1 unless it was significantly lower than 1. Sites with SOFs lower than 1 were found for (I) (Al27) and (III) (Al15), and the SOFs for these sites were freely refined. For sites along disordered chains in (III) [Al31A, Al31B, Al31C, Al32A and Al32B; see also Structural commentary and Fig. 6 ▸(a)], there is no a priori expected value for the sum of the SOFs, and therefore the SOFs of these sites were refined without any constraints. For these partially occupied sites, the assignment as Al is by no means justified, and some of them may be occupied by Si.

Since it is generally difficult to distinguish between Al and Si solely from X-ray diffraction data, restraints on the chemical compositions based on the chemical analysis data including their uncertainties (see Synthesis and crystallization) were introduced using SUMP instructions of SHELXL (Sheldrick, 2015b ▸) for the final refinement cycles. The compositions deduced from the final refinement are Al_57.8 (3)Ru_25.6Si_16.6 (3) for (I), Al_54.8 (5)Ru_22.0Si_23.3 (5) for (II), Al_53.6 (3)Ru_19.7Si_26.6 (3) for (III), Al_47.2 (5)Ru_16.7Si_36.1 (5) for (IV) and Al_37.2 (4)Ru_18.2Si_44.6 (4) for (V). These compositions are consistent with the chemical analysis data.

Supplementary Material

CCDC references: 2297119, 2297118, 2297117, 2297116, 2297115

Additional supporting information: crystallographic information; 3D view; checkCIF report

supplementary crystallographic information

Hexatriacontaaluminium hexadecaruthenium decasilicon (I). Crystal data

~Ru16(Al0.78Si0.22)47	Dx = 5.212 Mg m−3
Mr = 2900.59	Mo Kα radiation, λ = 0.71073 Å
Orthorhombic, Cmcm	Cell parameters from 5906 reflections
a = 7.6217 (2) Å	θ = 2.6–30.8°
b = 23.4434 (6) Å	µ = 7.59 mm−1
c = 20.6877 (6) Å	T = 301 K
V = 3696.46 (19) Å3	Prism, metallic light colourless
Z = 4	0.04 × 0.02 × 0.02 mm
F(000) = 5237.80

Hexatriacontaaluminium hexadecaruthenium decasilicon (I). Data collection

XtaLAB Synergy R, HyPix diffractometer	2616 independent reflections
Radiation source: micro-focus sealed X-ray tube, Mova (Mo) X-ray Source	2280 reflections with I > 2σ(I)
Mirror monochromator	Rint = 0.020
Detector resolution: 10.0000 pixels mm-1	θmax = 30.7°, θmin = 1.7°
ω scans	h = −9→7
Absorption correction: gaussian (CrysAlisPro; Matsumoto et al., 2021)	k = −32→33
Tmin = 0.824, Tmax = 0.924	l = −22→27
11822 measured reflections

Hexatriacontaaluminium hexadecaruthenium decasilicon (I). Refinement

Refinement on F2	Primary atom site location: dual
Least-squares matrix: full	Secondary atom site location: difference Fourier map
R[F2 > 2σ(F2)] = 0.015	w = 1/[σ2(Fo2) + (0.015P)2 + 1.7856P] where P = (Fo2 + 2Fc2)/3
wR(F2) = 0.032	(Δ/σ)max = 0.002
S = 1.04	Δρmax = 0.64 e Å−3
2616 reflections	Δρmin = −0.69 e Å−3
218 parameters	Extinction correction: SHELXL-2019/3 (Sheldrick, 2015b), Fc*=kFc[1+0.001xFc2λ3/sin(2θ)]-1/4
5 restraints	Extinction coefficient: 0.000036 (4)

Hexatriacontaaluminium hexadecaruthenium decasilicon (I). Special details

Geometry. All esds (except the esd in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell esds are taken into account individually in the estimation of esds in distances, angles and torsion angles; correlations between esds in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell esds is used for estimating esds involving l.s. planes.

Hexatriacontaaluminium hexadecaruthenium decasilicon (I). Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Ų)

	x	y	z	Uiso*/Ueq	Occ. (<1)
Ru1	0.000000	0.35437 (2)	0.250000	0.00702 (8)
Ru2	0.000000	0.19071 (2)	0.14245 (2)	0.00523 (6)
Ru3	0.000000	0.08703 (2)	0.67676 (2)	0.00497 (6)
Ru4	0.000000	0.46501 (2)	0.06755 (2)	0.00580 (6)
Ru5	0.000000	0.08260 (2)	0.06182 (2)	0.00605 (6)
Si6	0.000000	0.63703 (3)	0.09750 (4)	0.0067 (3)	0.9481 (19)
Ru6	0.000000	0.63703 (3)	0.09750 (4)	0.0067 (3)	0.0519 (19)
Ru7A	0.2872 (5)	0.05250 (15)	0.250000	0.0071 (3)	0.87 (3)
Ru7B	0.308 (2)	0.0461 (8)	0.250000	0.0123 (19)*	0.13 (3)
Ru8	0.4748 (2)	0.24633 (2)	0.250000	0.0057 (4)	0.5
Ru9	0.20167 (2)	0.28208 (2)	0.06561 (2)	0.00560 (5)
Si10	0.000000	0.00419 (5)	0.250000	0.0088 (6)	0.73 (12)
Al10	0.000000	0.00419 (5)	0.250000	0.0088 (6)	0.27 (12)
Al11	0.000000	0.63795 (6)	0.250000	0.0132 (3)
Al12A	0.000000	0.12915 (10)	0.250000	0.0126 (9)	0.856 (12)
Al12B	0.079 (3)	0.1477 (10)	0.250000	0.020 (5)*	0.072 (6)
Si13	0.000000	0.29501 (3)	0.15414 (4)	0.00569 (17)
Al14	0.000000	0.36199 (4)	0.03013 (4)	0.0068 (4)	0.59 (8)
Si14	0.000000	0.36199 (4)	0.03013 (4)	0.0068 (4)	0.41 (8)
Al15	0.000000	0.25809 (4)	0.53285 (5)	0.00662 (19)
Al16	0.000000	0.52766 (5)	0.16337 (5)	0.0189 (2)
Al17A	0.000000	0.19089 (7)	0.63750 (11)	0.0091 (5)	0.908 (9)
Si17B	0.000000	0.1757 (7)	0.6124 (11)	0.012 (4)*	0.092 (9)
Al18	0.32754 (14)	0.33805 (4)	0.250000	0.0126 (5)	0.52 (9)
Si18	0.32754 (14)	0.33805 (4)	0.250000	0.0126 (5)	0.48 (9)
Al19	0.20942 (15)	0.44221 (4)	0.250000	0.0133 (2)
Al20	0.1113 (3)	0.23957 (8)	0.250000	0.0096 (4)	0.5
Al21	0.20919 (10)	0.10789 (3)	0.15319 (3)	0.0089 (3)	0.63 (5)
Si21	0.20919 (10)	0.10789 (3)	0.15319 (3)	0.0089 (3)	0.37 (5)
Al22	0.18810 (10)	0.17255 (3)	0.03759 (4)	0.0119 (3)	0.81 (6)
Si22	0.18810 (10)	0.17255 (3)	0.03759 (4)	0.0119 (3)	0.19 (6)
Al23	0.31517 (10)	0.05413 (3)	0.03152 (3)	0.00897 (14)
Al24	0.31724 (10)	0.49470 (3)	0.13170 (4)	0.01044 (15)
Al25	0.18885 (12)	0.38526 (3)	0.13490 (4)	0.0223 (2)
Al26A	0.3202 (4)	0.21649 (10)	0.1531 (2)	0.0070 (7)	0.593 (13)
Si26B	0.2898 (5)	0.22406 (13)	0.1730 (3)	0.0125 (7)*	0.407 (13)
Al27	0.000000	0.000000	0.000000	0.0161 (6)	0.853 (7)
Al28A	0.0495 (3)	0.10981 (8)	0.55507 (9)	0.0328 (10)	0.445 (3)
Al28B	0.000000	0.0716 (12)	0.5512 (8)	0.008 (6)*	0.064 (7)
Al28C	0.000000	0.0454 (15)	0.5436 (12)	0.011 (9)*	0.046 (7)

Hexatriacontaaluminium hexadecaruthenium decasilicon (I). Atomic displacement parameters (Ų)

	U11	U22	U33	U12	U13	U23
Ru1	0.0119 (2)	0.00458 (16)	0.00454 (16)	0.000	0.000	0.000
Ru2	0.00655 (14)	0.00520 (11)	0.00395 (12)	0.000	0.000	−0.00041 (8)
Ru3	0.00556 (14)	0.00514 (11)	0.00421 (12)	0.000	0.000	0.00000 (9)
Ru4	0.00580 (13)	0.00635 (11)	0.00525 (12)	0.000	0.000	0.00106 (9)
Ru5	0.00665 (14)	0.00574 (11)	0.00577 (12)	0.000	0.000	−0.00051 (9)
Si6	0.0058 (5)	0.0074 (4)	0.0068 (4)	0.000	0.000	0.0002 (3)
Ru6	0.0058 (5)	0.0074 (4)	0.0068 (4)	0.000	0.000	0.0002 (3)
Ru7A	0.0063 (5)	0.0058 (5)	0.0090 (3)	−0.0001 (3)	0.000	0.000
Ru8	0.0052 (11)	0.00544 (18)	0.00647 (19)	0.0004 (2)	0.000	0.000
Ru9	0.00554 (10)	0.00702 (8)	0.00425 (9)	0.00082 (6)	0.00052 (7)	0.00001 (6)
Si10	0.0060 (9)	0.0114 (8)	0.0092 (8)	0.000	0.000	0.000
Al10	0.0060 (9)	0.0114 (8)	0.0092 (8)	0.000	0.000	0.000
Al11	0.0105 (8)	0.0060 (6)	0.0230 (8)	0.000	0.000	0.000
Al12A	0.0192 (17)	0.0135 (11)	0.0053 (9)	0.000	0.000	0.000
Si13	0.0069 (5)	0.0054 (4)	0.0047 (4)	0.000	0.000	−0.0008 (3)
Al14	0.0073 (6)	0.0053 (6)	0.0080 (6)	0.000	0.000	−0.0001 (3)
Si14	0.0073 (6)	0.0053 (6)	0.0080 (6)	0.000	0.000	−0.0001 (3)
Al15	0.0045 (5)	0.0090 (4)	0.0064 (4)	0.000	0.000	0.0019 (3)
Al16	0.0037 (6)	0.0390 (7)	0.0140 (5)	0.000	0.000	−0.0183 (5)
Al17A	0.0124 (7)	0.0060 (7)	0.0090 (10)	0.000	0.000	0.0011 (6)
Al18	0.0091 (7)	0.0167 (6)	0.0120 (6)	0.0067 (4)	0.000	0.000
Si18	0.0091 (7)	0.0167 (6)	0.0120 (6)	0.0067 (4)	0.000	0.000
Al19	0.0138 (6)	0.0084 (5)	0.0178 (5)	−0.0024 (4)	0.000	0.000
Al20	0.0142 (12)	0.0092 (9)	0.0055 (9)	0.0019 (7)	0.000	0.000
Al21	0.0103 (5)	0.0068 (4)	0.0095 (4)	0.0021 (2)	−0.0039 (3)	−0.0005 (2)
Si21	0.0103 (5)	0.0068 (4)	0.0095 (4)	0.0021 (2)	−0.0039 (3)	−0.0005 (2)
Al22	0.0112 (5)	0.0097 (4)	0.0148 (5)	0.0015 (3)	0.0059 (3)	0.0041 (3)
Si22	0.0112 (5)	0.0097 (4)	0.0148 (5)	0.0015 (3)	0.0059 (3)	0.0041 (3)
Al23	0.0091 (4)	0.0088 (3)	0.0090 (3)	0.0011 (2)	0.0030 (3)	0.0015 (2)
Al24	0.0091 (4)	0.0099 (3)	0.0123 (3)	0.0018 (3)	−0.0013 (3)	0.0042 (3)
Al25	0.0262 (5)	0.0121 (4)	0.0285 (5)	−0.0080 (3)	−0.0213 (4)	0.0051 (3)
Al26A	0.0040 (9)	0.0086 (7)	0.0084 (13)	−0.0013 (5)	−0.0024 (8)	0.0017 (7)
Al27	0.0105 (11)	0.0136 (10)	0.0243 (11)	0.000	0.000	−0.0147 (7)
Al28A	0.069 (3)	0.0227 (11)	0.0063 (8)	0.0029 (9)	0.0017 (9)	−0.0007 (6)

Hexatriacontaaluminium hexadecaruthenium decasilicon (I). Geometric parameters (Å, º)

Ru1—Si13	2.4228 (9)	Ru9—Si26B	2.690 (3)
Ru1—Si13i	2.4228 (9)	Ru9—Al17Axx	2.7899 (10)
Ru1—Si18	2.5255 (10)	Si10—Al19xxi	2.6487 (13)
Ru1—Al18ii	2.5255 (10)	Si10—Al19xvi	2.6487 (13)
Ru1—Al19	2.6055 (11)	Si10—Al24xxi	2.8248 (7)
Ru1—Al19ii	2.6056 (10)	Si10—Al24xvi	2.8248 (7)
Ru1—Al20ii	2.8218 (19)	Si10—Al24xvii	2.8248 (7)
Ru1—Al20	2.8218 (19)	Si10—Al24xxii	2.8248 (7)
Ru1—Al25	2.8750 (10)	Al12A—Al12Bii	0.74 (3)
Ru1—Al25i	2.8750 (10)	Al12A—Al12B	0.74 (3)
Ru1—Al25iii	2.8750 (10)	Al12A—Al21iii	2.6080 (9)
Ru2—Si26B	2.427 (3)	Al12A—Al21i	2.6080 (9)
Ru2—Si26Biii	2.427 (3)	Al12A—Al21ii	2.6080 (9)
Ru2—Si13	2.4571 (8)	Al12A—Al21	2.6080 (9)
Ru2—Al12B	2.515 (9)	Al12A—Al20	2.724 (3)
Ru2—Al12Bii	2.515 (9)	Al12A—Al20ii	2.724 (3)
Ru2—Al21iii	2.5221 (7)	Al12B—Al12Bii	1.20 (5)
Ru2—Al21	2.5222 (7)	Al12B—Al20	2.17 (2)
Ru2—Al26Aiii	2.524 (2)	Al12B—Al21i	2.423 (11)
Ru2—Al26A	2.524 (2)	Al12B—Al21	2.423 (11)
Ru2—Al22	2.6349 (7)	Al12B—Al20ii	2.595 (19)
Ru3—Si17B	2.469 (11)	Al12B—Si26Bi	2.89 (2)
Ru3—Al24iv	2.5456 (7)	Al12B—Si26B	2.89 (2)
Ru3—Al24v	2.5456 (7)	Si13—Al20ii	2.5183 (14)
Ru3—Al17A	2.5668 (13)	Si13—Al20	2.5183 (14)
Ru3—Al28Aiii	2.6011 (18)	Si13—Al25	2.5897 (10)
Ru3—Al28A	2.6011 (18)	Si13—Al25iii	2.5898 (10)
Ru3—Al25iv	2.6069 (8)	Si13—Si26B	2.793 (4)
Ru3—Al25v	2.6069 (8)	Si13—Si26Biii	2.793 (4)
Ru3—Si10vi	2.6207 (11)	Al14—Al25	2.6585 (11)
Ru3—Al28B	2.623 (18)	Al14—Al25iii	2.6585 (11)
Ru3—Al18vii	2.6662 (9)	Al14—Al23ix	2.7345 (10)
Ru3—Al18iv	2.6662 (9)	Al14—Al23viii	2.7345 (10)
Ru4—Al16	2.4671 (11)	Al14—Al15i	2.7624 (13)
Ru4—Al23viii	2.5271 (7)	Al14—Al22viii	2.8756 (9)
Ru4—Al23ix	2.5271 (7)	Al14—Al22ix	2.8756 (9)
Ru4—Al14	2.5361 (9)	Al15—Si17B	2.538 (12)
Ru4—Al23x	2.6278 (7)	Al15—Al17A	2.6774 (16)
Ru4—Al23xi	2.6278 (7)	Al15—Al22ii	2.8634 (11)
Ru4—Al25iii	2.7401 (8)	Al15—Al22i	2.8634 (11)
Ru4—Al25	2.7402 (8)	Al15—Al22v	2.8818 (9)
Ru4—Al24	2.8446 (8)	Al15—Al22iv	2.8818 (9)
Ru4—Al24iii	2.8446 (8)	Al16—Al24	2.6216 (8)
Ru5—Al27	2.3207 (2)	Al16—Al24iii	2.6216 (8)
Ru5—Al28Ci	2.35 (2)	Al16—Al21x	2.9146 (11)
Ru5—Al28Bi	2.352 (16)	Al16—Al21xi	2.9146 (11)
Ru5—Al28Aii	2.5293 (18)	Al17A—Si17B	0.63 (2)
Ru5—Al28Ai	2.5293 (18)	Al17A—Al28Aiii	2.581 (3)
Ru5—Al21	2.5429 (7)	Al17A—Al28A	2.581 (3)
Ru5—Al21iii	2.5429 (7)	Al17A—Al26Av	2.588 (2)
Ru5—Al23iii	2.5708 (7)	Al17A—Al26Aiv	2.588 (2)
Ru5—Al23	2.5708 (7)	Al17A—Si26Bv	2.661 (3)
Ru5—Al22	2.5988 (7)	Al17A—Si26Biv	2.661 (3)
Si6—Al26Ax	2.583 (5)	Al17A—Al18vii	2.7577 (18)
Si6—Al26Axi	2.583 (5)	Al17A—Al18iv	2.7577 (18)
Si6—Al21x	2.5898 (8)	Si17B—Al28Aiii	1.98 (2)
Si6—Al21xi	2.5898 (8)	Si17B—Al28A	1.98 (2)
Si6—Al14xii	2.6404 (12)	Si17B—Al28B	2.75 (4)
Si6—Al23xi	2.7613 (9)	Si17B—Al25iv	2.808 (7)
Si6—Al23x	2.7613 (9)	Si17B—Al25v	2.808 (7)
Si6—Al15xiii	2.7990 (12)	Si18—Al19	2.6026 (14)
Si6—Al22xi	2.8073 (9)	Si18—Al25	2.8305 (10)
Si6—Al22x	2.8073 (9)	Si18—Al25i	2.8305 (9)
Si6—Al16	2.9037 (15)	Si18—Al20	2.837 (2)
Ru7A—Al21	2.460 (3)	Al19—Al25i	2.7344 (10)
Ru7A—Al21i	2.460 (3)	Al19—Al25	2.7344 (10)
Ru7A—Si10	2.465 (2)	Al19—Al24	2.8599 (9)
Ru7A—Al16xiv	2.486 (3)	Al19—Al24i	2.8599 (9)
Ru7A—Al16xv	2.486 (3)	Al20—Al20ii	1.696 (4)
Ru7A—Al11xv	2.5774 (16)	Al20—Si26Bi	2.127 (7)
Ru7A—Al19xvi	2.586 (4)	Al20—Si26B	2.127 (7)
Ru7A—Al12B	2.74 (2)	Al20—Al26A	2.616 (6)
Ru7A—Al12A	2.832 (5)	Al20—Al26Ai	2.616 (6)
Ru7A—Al24xvii	2.9086 (11)	Al21—Al26A	2.6828 (18)
Ru7B—Al16xiv	2.355 (14)	Al21—Al24xvii	2.6980 (10)
Ru7B—Al16xv	2.355 (14)	Al21—Si26B	2.822 (3)
Ru7B—Al19xvi	2.440 (18)	Al21—Al22	2.8362 (10)
Ru7B—Si10	2.543 (13)	Al22—Al28Ai	2.637 (2)
Ru7B—Al21	2.583 (15)	Al22—Al26A	2.791 (4)
Ru7B—Al21i	2.583 (15)	Al22—Al22iii	2.8673 (15)
Ru7B—Al11xv	2.604 (11)	Al23—Al24xvii	2.6935 (10)
Ru7B—Al24xvii	2.890 (6)	Al23—Al27	2.7939 (7)
Ru7B—Al24xvi	2.890 (6)	Al23—Al23xix	2.8174 (15)
Ru7B—Ru7Bxviii	2.93 (4)	Al23—Al23xxiii	2.8534 (13)
Ru8—Ru8xviii	0.384 (4)	Al23—Al28Ci	2.868 (13)
Ru8—Si26Bi	2.191 (4)	Al24—Al28Cxx	2.48 (2)
Ru8—Si26B	2.191 (4)	Al24—Al28Bxx	2.670 (16)
Ru8—Si18	2.4257 (13)	Al24—Al25	2.7467 (10)
Ru8—Al26A	2.428 (3)	Al24—Al24xix	2.7858 (15)
Ru8—Al26Ai	2.428 (3)	Al25—Al28Axx	2.592 (2)
Ru8—Si26Bxviii	2.455 (3)	Al26A—Si26B	0.503 (2)
Ru8—Si26Bxix	2.455 (3)	Al26A—Al26Axix	2.741 (6)
Ru8—Al11xv	2.5478 (14)	Al27—Al28Ci	1.40 (3)
Ru8—Al18xviii	2.6254 (15)	Al27—Al28Cxxiv	1.40 (3)
Ru8—Al26Axviii	2.636 (3)	Al27—Al28Bi	1.98 (3)
Ru9—Si13	2.4102 (7)	Al27—Al28Bxxiv	1.98 (3)
Ru9—Al22ix	2.5287 (7)	Al27—Al28Ai	2.8403 (19)
Ru9—Al14	2.5320 (7)	Al27—Al28Axxiv	2.8403 (19)
Ru9—Al26A	2.5415 (17)	Al28A—Al28Aiii	0.754 (5)
Ru9—Al15xx	2.5526 (5)	Al28A—Al28B	0.98 (2)
Ru9—Al15i	2.6130 (8)	Al28A—Al28C	1.57 (4)
Ru9—Al22	2.6343 (7)	Al28B—Al28C	0.63 (2)
Ru9—Si17Bxx	2.662 (6)	Al28C—Al28Cvi	2.79 (7)
Si13—Ru1—Si13i	109.88 (4)	Ru3—Al17A—Al28Aiii	60.70 (6)
Si13—Ru1—Si18	85.009 (14)	Si17B—Al17A—Al28A	16.0 (9)
Si13i—Ru1—Si18	85.008 (14)	Ru3—Al17A—Al28A	60.69 (6)
Si13—Ru1—Al18ii	85.008 (14)	Al28Aiii—Al17A—Al28A	16.81 (11)
Si13i—Ru1—Al18ii	85.008 (14)	Si17B—Al17A—Al26Av	125.3 (8)
Si18—Ru1—Al18ii	162.57 (5)	Ru3—Al17A—Al26Av	139.14 (13)
Si13—Ru1—Al19	117.000 (18)	Al28Aiii—Al17A—Al26Av	141.06 (11)
Si13i—Ru1—Al19	117.001 (18)	Al28A—Al17A—Al26Av	128.54 (8)
Si18—Ru1—Al19	60.93 (3)	Si17B—Al17A—Al26Aiv	125.3 (8)
Al18ii—Ru1—Al19	136.49 (4)	Ru3—Al17A—Al26Aiv	139.14 (13)
Si13—Ru1—Al19ii	117.000 (18)	Al28Aiii—Al17A—Al26Aiv	128.53 (8)
Si13i—Ru1—Al19ii	117.001 (18)	Al28A—Al17A—Al26Aiv	141.06 (11)
Si18—Ru1—Al19ii	136.49 (4)	Al26Av—Al17A—Al26Aiv	63.95 (14)
Al18ii—Ru1—Al19ii	60.93 (3)	Si17B—Al17A—Si26Bv	130.6 (7)
Al19—Ru1—Al19ii	75.56 (5)	Ru3—Al17A—Si26Bv	128.58 (15)
Si13—Ru1—Al20ii	56.78 (2)	Al28Aiii—Al17A—Si26Bv	145.29 (10)
Si13i—Ru1—Al20ii	56.78 (2)	Al28A—Al17A—Si26Bv	130.25 (9)
Si18—Ru1—Al20ii	98.78 (5)	Al26Av—Al17A—Si26Bv	10.89 (5)
Al18ii—Ru1—Al20ii	63.79 (5)	Al26Aiv—Al17A—Si26Bv	69.85 (14)
Al19—Ru1—Al20ii	159.71 (5)	Si17B—Al17A—Si26Biv	130.6 (7)
Al19ii—Ru1—Al20ii	124.73 (5)	Ru3—Al17A—Si26Biv	128.58 (15)
Si13—Ru1—Al20	56.78 (2)	Al28Aiii—Al17A—Si26Biv	130.25 (9)
Si13i—Ru1—Al20	56.78 (2)	Al28A—Al17A—Si26Biv	145.29 (10)
Si18—Ru1—Al20	63.80 (5)	Al26Av—Al17A—Si26Biv	69.85 (14)
Al18ii—Ru1—Al20	98.78 (5)	Al26Aiv—Al17A—Si26Biv	10.89 (5)
Al19—Ru1—Al20	124.73 (5)	Si26Bv—Al17A—Si26Biv	74.02 (16)
Al19ii—Ru1—Al20	159.71 (5)	Si17B—Al17A—Al15	70.5 (11)
Al20ii—Ru1—Al20	34.98 (9)	Ru3—Al17A—Al15	144.49 (11)
Si13—Ru1—Al25	57.77 (2)	Al28Aiii—Al17A—Al15	84.21 (8)
Si13i—Ru1—Al25	145.35 (2)	Al28A—Al17A—Al15	84.21 (8)
Si18—Ru1—Al25	62.825 (19)	Al26Av—Al17A—Al15	66.88 (12)
Al18ii—Ru1—Al25	122.209 (17)	Al26Aiv—Al17A—Al15	66.88 (12)
Al19—Ru1—Al25	59.618 (17)	Si26Bv—Al17A—Al15	77.42 (14)
Al19ii—Ru1—Al25	96.18 (2)	Si26Biv—Al17A—Al15	77.42 (14)
Al20ii—Ru1—Al25	113.00 (3)	Si17B—Al17A—Al18vii	123.8 (9)
Al20—Ru1—Al25	95.15 (3)	Ru3—Al17A—Al18vii	59.97 (3)
Si13—Ru1—Al25i	145.35 (2)	Al28Aiii—Al17A—Al18vii	116.49 (7)
Si13i—Ru1—Al25i	57.78 (2)	Al28A—Al17A—Al18vii	107.86 (6)
Si18—Ru1—Al25i	62.825 (19)	Al26Av—Al17A—Al18vii	81.29 (14)
Al18ii—Ru1—Al25i	122.210 (17)	Al26Aiv—Al17A—Al18vii	110.69 (12)
Al19—Ru1—Al25i	59.616 (17)	Si26Bv—Al17A—Al18vii	70.40 (15)
Al19ii—Ru1—Al25i	96.18 (2)	Si26Biv—Al17A—Al18vii	103.80 (13)
Al20ii—Ru1—Al25i	113.00 (3)	Al15—Al17A—Al18vii	145.81 (5)
Al20—Ru1—Al25i	95.15 (3)	Si17B—Al17A—Al18iv	123.8 (9)
Al25—Ru1—Al25i	111.83 (3)	Ru3—Al17A—Al18iv	59.97 (3)
Si13—Ru1—Al25iii	57.77 (2)	Al28Aiii—Al17A—Al18iv	107.86 (6)
Si13i—Ru1—Al25iii	145.35 (2)	Al28A—Al17A—Al18iv	116.49 (7)
Si18—Ru1—Al25iii	122.210 (17)	Al26Av—Al17A—Al18iv	110.69 (12)
Al18ii—Ru1—Al25iii	62.825 (19)	Al26Aiv—Al17A—Al18iv	81.29 (14)
Al19—Ru1—Al25iii	96.18 (2)	Si26Bv—Al17A—Al18iv	103.80 (13)
Al19ii—Ru1—Al25iii	59.616 (17)	Si26Biv—Al17A—Al18iv	70.40 (15)
Al20ii—Ru1—Al25iii	95.15 (3)	Al15—Al17A—Al18iv	145.81 (5)
Al20—Ru1—Al25iii	113.00 (3)	Al18vii—Al17A—Al18iv	56.93 (5)
Al25—Ru1—Al25iii	60.08 (3)	Si17B—Al17A—Ru8vii	175.5 (5)
Al25i—Ru1—Al25iii	150.82 (3)	Ru3—Al17A—Ru8vii	103.83 (6)
Si26B—Ru2—Si26Biii	131.1 (3)	Al28Aiii—Al17A—Ru8vii	163.69 (7)
Si26B—Ru2—Si13	69.75 (9)	Al28A—Al17A—Ru8vii	159.96 (7)
Si26Biii—Ru2—Si13	69.75 (9)	Al26Av—Al17A—Ru8vii	53.88 (9)
Si26B—Ru2—Al12B	71.4 (7)	Al26Aiv—Al17A—Ru8vii	58.94 (9)
Si26Biii—Ru2—Al12B	96.7 (5)	Si26Bv—Al17A—Ru8vii	47.63 (10)
Si13—Ru2—Al12B	108.2 (5)	Si26Biv—Al17A—Ru8vii	53.82 (9)
Si26B—Ru2—Al12Bii	96.7 (5)	Al15—Al17A—Ru8vii	111.59 (6)
Si26Biii—Ru2—Al12Bii	71.4 (7)	Al18vii—Al17A—Ru8vii	52.15 (5)
Si13—Ru2—Al12Bii	108.2 (5)	Al18iv—Al17A—Ru8vii	56.82 (6)
Al12B—Ru2—Al12Bii	27.6 (12)	Al17A—Si17B—Al28Aiii	159.0 (12)
Si26B—Ru2—Al21iii	143.17 (6)	Al17A—Si17B—Al28A	159.0 (12)
Si26Biii—Ru2—Al21iii	69.49 (9)	Al28Aiii—Si17B—Al28A	21.9 (3)
Si13—Ru2—Al21iii	139.236 (17)	Al17A—Si17B—Ru3	91.8 (12)
Al12B—Ru2—Al21iii	76.4 (6)	Al28Aiii—Si17B—Ru3	70.5 (5)
Al12Bii—Ru2—Al21iii	57.5 (4)	Al28A—Si17B—Ru3	70.5 (5)
Si26B—Ru2—Al21	69.49 (9)	Al17A—Si17B—Al15	96.0 (12)
Si26Biii—Ru2—Al21	143.17 (6)	Al28Aiii—Si17B—Al15	101.8 (8)
Si13—Ru2—Al21	139.237 (17)	Al28A—Si17B—Al15	101.8 (8)
Al12B—Ru2—Al21	57.5 (4)	Ru3—Si17B—Al15	172.2 (12)
Al12Bii—Ru2—Al21	76.4 (6)	Al17A—Si17B—Ru9iv	95.2 (8)
Al21iii—Ru2—Al21	78.42 (3)	Al28Aiii—Si17B—Ru9iv	84.8 (5)
Si26B—Ru2—Al26Aiii	141.3 (2)	Al28A—Si17B—Ru9iv	103.5 (8)
Si26Biii—Ru2—Al26Aiii	11.46 (6)	Ru3—Si17B—Ru9iv	120.6 (2)
Si13—Ru2—Al26Aiii	75.71 (7)	Al15—Si17B—Ru9iv	58.7 (2)
Al12B—Ru2—Al26Aiii	104.4 (5)	Al17A—Si17B—Ru9v	95.2 (8)
Al12Bii—Ru2—Al26Aiii	77.8 (6)	Al28Aiii—Si17B—Ru9v	103.5 (8)
Al21iii—Ru2—Al26Aiii	64.24 (6)	Al28A—Si17B—Ru9v	84.8 (5)
Al21—Ru2—Al26Aiii	141.99 (5)	Ru3—Si17B—Ru9v	120.6 (2)
Si26B—Ru2—Al26A	11.46 (6)	Al15—Si17B—Ru9v	58.7 (2)
Si26Biii—Ru2—Al26A	141.3 (2)	Ru9iv—Si17B—Ru9v	117.3 (4)
Si13—Ru2—Al26A	75.70 (7)	Al17A—Si17B—Al28B	151.9 (13)
Al12B—Ru2—Al26A	77.8 (6)	Al28Aiii—Si17B—Al28B	14.9 (3)
Al12Bii—Ru2—Al26A	104.4 (5)	Al28A—Si17B—Al28B	14.9 (3)
Al21iii—Ru2—Al26A	141.99 (4)	Ru3—Si17B—Al28B	60.1 (5)
Al21—Ru2—Al26A	64.24 (6)	Al15—Si17B—Al28B	112.1 (9)
Al26Aiii—Ru2—Al26A	150.45 (19)	Ru9iv—Si17B—Al28B	99.3 (7)
Si26B—Ru2—Al22	76.76 (16)	Ru9v—Si17B—Al28B	99.3 (7)
Si26Biii—Ru2—Al22	139.60 (14)	Al17A—Si17B—Al25iv	98.7 (8)
Si13—Ru2—Al22	103.99 (2)	Al28Aiii—Si17B—Al25iv	62.7 (3)
Al12B—Ru2—Al22	122.3 (4)	Al28A—Si17B—Al25iv	82.1 (6)
Al12Bii—Ru2—Al22	142.5 (6)	Ru3—Si17B—Al25iv	58.8 (2)
Al21iii—Ru2—Al22	106.99 (2)	Al15—Si17B—Al25iv	119.7 (3)
Al21—Ru2—Al22	66.69 (2)	Ru9iv—Si17B—Al25iv	61.84 (8)
Al26Aiii—Ru2—Al22	129.56 (11)	Ru9v—Si17B—Al25iv	166.1 (11)
Al26A—Ru2—Al22	65.46 (12)	Al28B—Si17B—Al25iv	67.9 (4)
Si17B—Ru3—Al24iv	115.9 (5)	Al17A—Si17B—Al25v	98.7 (8)
Si17B—Ru3—Al24v	115.9 (5)	Al28Aiii—Si17B—Al25v	82.1 (6)
Al24iv—Ru3—Al24v	66.35 (3)	Al28A—Si17B—Al25v	62.7 (3)
Si17B—Ru3—Al17A	14.2 (6)	Ru3—Si17B—Al25v	58.8 (2)
Al24iv—Ru3—Al17A	126.73 (5)	Al15—Si17B—Al25v	119.7 (3)
Al24v—Ru3—Al17A	126.73 (5)	Ru9iv—Si17B—Al25v	166.1 (11)
Si17B—Ru3—Al28Aiii	46.0 (6)	Ru9v—Si17B—Al25v	61.84 (8)
Al24iv—Ru3—Al28Aiii	73.78 (5)	Al28B—Si17B—Al25v	67.9 (4)
Al24v—Ru3—Al28Aiii	83.07 (5)	Al25iv—Si17B—Al25v	115.3 (5)
Al17A—Ru3—Al28Aiii	59.93 (7)	Ru8—Si18—Ru1	126.28 (6)
Si17B—Ru3—Al28A	46.0 (6)	Ru8—Si18—Al19	172.67 (7)
Al24iv—Ru3—Al28A	83.07 (5)	Ru1—Si18—Al19	61.05 (3)
Al24v—Ru3—Al28A	73.78 (5)	Ru8—Si18—Ru8xviii	7.45 (7)
Al17A—Ru3—Al28A	59.93 (7)	Ru1—Si18—Ru8xviii	133.73 (6)
Al28Aiii—Ru3—Al28A	16.68 (11)	Al19—Si18—Ru8xviii	165.22 (6)
Si17B—Ru3—Al25iv	67.11 (10)	Ru8—Si18—Al18xviii	62.43 (5)
Al24iv—Ru3—Al25iv	64.41 (2)	Ru1—Si18—Al18xviii	171.29 (2)
Al24v—Ru3—Al25iv	124.31 (3)	Al19—Si18—Al18xviii	110.24 (3)
Al17A—Ru3—Al25iv	70.03 (2)	Ru8xviii—Si18—Al18xviii	54.99 (4)
Al28Aiii—Ru3—Al25iv	59.69 (6)	Ru8—Si18—Ru3vii	110.84 (5)
Al28A—Ru3—Al25iv	76.07 (6)	Ru1—Si18—Ru3vii	112.80 (3)
Si17B—Ru3—Al25v	67.11 (10)	Al19—Si18—Ru3vii	63.41 (3)
Al24iv—Ru3—Al25v	124.31 (3)	Ru8xviii—Si18—Ru3vii	104.87 (4)
Al24v—Ru3—Al25v	64.41 (2)	Al18xviii—Si18—Ru3vii	60.46 (2)
Al17A—Ru3—Al25v	70.03 (2)	Ru8—Si18—Ru3xx	110.84 (5)
Al28Aiii—Ru3—Al25v	76.07 (6)	Ru1—Si18—Ru3xx	112.80 (3)
Al28A—Ru3—Al25v	59.69 (6)	Al19—Si18—Ru3xx	63.41 (3)
Al25iv—Ru3—Al25v	130.93 (4)	Ru8xviii—Si18—Ru3xx	104.87 (4)
Si17B—Ru3—Si10vi	177.3 (6)	Al18xviii—Si18—Ru3xx	60.46 (2)
Al24iv—Ru3—Si10vi	66.27 (2)	Ru3vii—Si18—Ru3xx	69.26 (3)
Al24v—Ru3—Si10vi	66.27 (2)	Ru8—Si18—Al17Avii	63.98 (5)
Al17A—Ru3—Si10vi	163.13 (6)	Ru1—Si18—Al17Avii	120.56 (3)
Al28Aiii—Ru3—Si10vi	136.65 (5)	Al19—Si18—Al17Avii	113.31 (5)
Al28A—Ru3—Si10vi	136.64 (5)	Ru8xviii—Si18—Al17Avii	61.64 (5)
Al25iv—Ru3—Si10vi	113.29 (2)	Al18xviii—Si18—Al17Avii	61.53 (3)
Al25v—Ru3—Si10vi	113.29 (2)	Ru3vii—Si18—Al17Avii	56.46 (4)
Si17B—Ru3—Al28B	65.3 (8)	Ru3xx—Si18—Al17Avii	114.00 (4)
Al24iv—Ru3—Al28B	62.2 (5)	Ru8—Si18—Al17Axx	63.98 (5)
Al24v—Ru3—Al28B	62.2 (5)	Ru1—Si18—Al17Axx	120.56 (3)
Al17A—Ru3—Al28B	79.5 (6)	Al19—Si18—Al17Axx	113.31 (5)
Al28Aiii—Ru3—Al28B	21.5 (5)	Ru8xviii—Si18—Al17Axx	61.64 (5)
Al28A—Ru3—Al28B	21.5 (5)	Al18xviii—Si18—Al17Axx	61.53 (3)
Al25iv—Ru3—Al28B	72.86 (18)	Ru3vii—Si18—Al17Axx	114.00 (4)
Al25v—Ru3—Al28B	72.86 (18)	Ru3xx—Si18—Al17Axx	56.46 (4)
Si10vi—Ru3—Al28B	117.4 (6)	Al17Avii—Si18—Al17Axx	115.12 (8)
Si17B—Ru3—Al18vii	75.6 (5)	Ru8—Si18—Al25	121.29 (3)
Al24iv—Ru3—Al18vii	166.84 (2)	Ru1—Si18—Al25	64.64 (3)
Al24v—Ru3—Al18vii	115.73 (3)	Al19—Si18—Al25	60.26 (3)
Al17A—Ru3—Al18vii	63.57 (5)	Ru8xviii—Si18—Al25	122.31 (3)
Al28Aiii—Ru3—Al18vii	119.09 (5)	Al18xviii—Si18—Al25	111.93 (3)
Al28A—Ru3—Al18vii	110.08 (5)	Ru3vii—Si18—Al25	113.87 (4)
Al25iv—Ru3—Al18vii	118.23 (3)	Ru3xx—Si18—Al25	56.53 (2)
Al25v—Ru3—Al18vii	64.92 (3)	Al17Avii—Si18—Al25	169.79 (5)
Si10vi—Ru3—Al18vii	102.06 (2)	Al17Axx—Si18—Al25	64.16 (5)
Al28B—Ru3—Al18vii	130.8 (4)	Ru8—Si18—Al25i	121.29 (3)
Si17B—Ru3—Al18iv	75.6 (5)	Ru1—Si18—Al25i	64.64 (3)
Al24iv—Ru3—Al18iv	115.73 (3)	Al19—Si18—Al25i	60.26 (3)
Al24v—Ru3—Al18iv	166.84 (2)	Ru8xviii—Si18—Al25i	122.31 (3)
Al17A—Ru3—Al18iv	63.57 (5)	Al18xviii—Si18—Al25i	111.93 (3)
Al28Aiii—Ru3—Al18iv	110.07 (5)	Ru3vii—Si18—Al25i	56.53 (2)
Al28A—Ru3—Al18iv	119.09 (5)	Ru3xx—Si18—Al25i	113.86 (4)
Al25iv—Ru3—Al18iv	64.92 (3)	Al17Avii—Si18—Al25i	64.17 (5)
Al25v—Ru3—Al18iv	118.23 (3)	Al17Axx—Si18—Al25i	169.79 (5)
Si10vi—Ru3—Al18iv	102.06 (2)	Al25—Si18—Al25i	114.54 (5)
Al28B—Ru3—Al18iv	130.8 (4)	Ru8—Si18—Al20	63.09 (6)
Al18vii—Ru3—Al18iv	59.08 (4)	Ru1—Si18—Al20	63.19 (5)
Al16—Ru4—Al23viii	139.23 (2)	Al19—Si18—Al20	124.24 (6)
Al16—Ru4—Al23ix	139.23 (2)	Ru8xviii—Si18—Al20	70.54 (6)
Al23viii—Ru4—Al23ix	67.76 (3)	Al18xviii—Si18—Al20	125.52 (5)
Al16—Ru4—Al14	144.31 (4)	Ru3vii—Si18—Al20	145.349 (14)
Al23viii—Ru4—Al14	65.38 (2)	Ru3xx—Si18—Al20	145.349 (14)
Al23ix—Ru4—Al14	65.38 (2)	Al17Avii—Si18—Al20	94.40 (4)
Al16—Ru4—Al23x	75.80 (3)	Al17Axx—Si18—Al20	94.40 (4)
Al23viii—Ru4—Al23x	102.12 (2)	Al25—Si18—Al20	95.81 (4)
Al23ix—Ru4—Al23x	67.19 (3)	Al25i—Si18—Al20	95.81 (4)
Al14—Ru4—Al23x	132.11 (2)	Ru7Bxxv—Al19—Ru7Axxv	3.6 (4)
Al16—Ru4—Al23xi	75.80 (3)	Ru7Bxxv—Al19—Si18	162.8 (5)
Al23viii—Ru4—Al23xi	67.19 (3)	Ru7Axxv—Al19—Si18	159.20 (10)
Al23ix—Ru4—Al23xi	102.12 (2)	Ru7Bxxv—Al19—Ru1	139.2 (5)
Al14—Ru4—Al23xi	132.11 (2)	Ru7Axxv—Al19—Ru1	142.79 (9)
Al23x—Ru4—Al23xi	64.83 (3)	Si18—Al19—Ru1	58.02 (3)
Al16—Ru4—Al25iii	89.86 (3)	Ru7Bxxv—Al19—Si10xxvii	59.8 (5)
Al23viii—Ru4—Al25iii	89.91 (3)	Ru7Axxv—Al19—Si10xxvii	56.17 (9)
Al23ix—Ru4—Al25iii	125.74 (2)	Si18—Al19—Si10xxvii	103.03 (5)
Al14—Ru4—Al25iii	60.36 (2)	Ru1—Al19—Si10xxvii	161.04 (5)
Al23x—Ru4—Al25iii	165.54 (3)	Ru7Bxxv—Al19—Al25i	118.98 (5)
Al23xi—Ru4—Al25iii	113.90 (2)	Ru7Axxv—Al19—Al25i	119.26 (2)
Al16—Ru4—Al25	89.86 (3)	Si18—Al19—Al25i	64.00 (3)
Al23viii—Ru4—Al25	125.74 (2)	Ru1—Al19—Al25i	65.10 (3)
Al23ix—Ru4—Al25	89.91 (3)	Si10xxvii—Al19—Al25i	108.41 (3)
Al14—Ru4—Al25	60.36 (2)	Ru7Bxxv—Al19—Al25	118.98 (5)
Al23x—Ru4—Al25	113.90 (2)	Ru7Axxv—Al19—Al25	119.26 (2)
Al23xi—Ru4—Al25	165.54 (3)	Si18—Al19—Al25	64.00 (3)
Al25iii—Ru4—Al25	63.37 (4)	Ru1—Al19—Al25	65.10 (3)
Al16—Ru4—Al24	58.633 (16)	Si10xxvii—Al19—Al25	108.41 (3)
Al23viii—Ru4—Al24	153.59 (2)	Al25i—Al19—Al25	121.10 (5)
Al23ix—Ru4—Al24	87.02 (2)	Ru7Bxxv—Al19—Ru3vii	106.9 (4)
Al14—Ru4—Al24	112.050 (17)	Ru7Axxv—Al19—Ru3vii	103.87 (7)
Al23x—Ru4—Al24	58.81 (2)	Si18—Al19—Ru3vii	59.41 (3)
Al23xi—Ru4—Al24	113.17 (2)	Ru1—Al19—Ru3vii	107.11 (3)
Al25iii—Ru4—Al24	112.10 (3)	Si10xxvii—Al19—Ru3vii	57.80 (3)
Al25—Ru4—Al24	58.89 (2)	Al25i—Al19—Ru3vii	56.54 (2)
Al16—Ru4—Al24iii	58.634 (16)	Al25—Al19—Ru3vii	113.66 (4)
Al23viii—Ru4—Al24iii	87.02 (2)	Ru7Bxxv—Al19—Ru3xx	106.9 (4)
Al23ix—Ru4—Al24iii	153.59 (2)	Ru7Axxv—Al19—Ru3xx	103.87 (7)
Al14—Ru4—Al24iii	112.049 (17)	Si18—Al19—Ru3xx	59.41 (3)
Al23x—Ru4—Al24iii	113.17 (2)	Ru1—Al19—Ru3xx	107.11 (3)
Al23xi—Ru4—Al24iii	58.81 (2)	Si10xxvii—Al19—Ru3xx	57.80 (3)
Al25iii—Ru4—Al24iii	58.88 (2)	Al25i—Al19—Ru3xx	113.66 (4)
Al25—Ru4—Al24iii	112.10 (3)	Al25—Al19—Ru3xx	56.54 (2)
Al24—Ru4—Al24iii	116.42 (3)	Ru3vii—Al19—Ru3xx	66.33 (3)
Al27—Ru5—Al28Ci	34.8 (9)	Ru7Bxxv—Al19—Al24	65.53 (15)
Al27—Ru5—Al28Bi	50.3 (7)	Ru7Axxv—Al19—Al24	64.34 (3)
Al28Ci—Ru5—Al28Bi	15.5 (6)	Si18—Al19—Al24	107.72 (3)
Al27—Ru5—Al28Aii	71.55 (4)	Ru1—Al19—Al24	121.07 (2)
Al28Ci—Ru5—Al28Aii	37.4 (9)	Si10xxvii—Al19—Al24	61.56 (2)
Al28Bi—Ru5—Al28Aii	22.7 (6)	Al25i—Al19—Al24	166.35 (5)
Al27—Ru5—Al28Ai	71.55 (4)	Al25—Al19—Al24	58.76 (2)
Al28Ci—Ru5—Al28Ai	37.4 (9)	Ru3vii—Al19—Al24	110.17 (4)
Al28Bi—Ru5—Al28Ai	22.7 (6)	Ru3xx—Al19—Al24	53.74 (2)
Al28Aii—Ru5—Al28Ai	17.15 (11)	Ru7Bxxv—Al19—Al24i	65.53 (15)
Al27—Ru5—Al21	127.171 (16)	Ru7Axxv—Al19—Al24i	64.34 (3)
Al28Ci—Ru5—Al21	140.96 (9)	Si18—Al19—Al24i	107.71 (3)
Al28Bi—Ru5—Al21	139.85 (16)	Ru1—Al19—Al24i	121.07 (2)
Al28Aii—Ru5—Al21	138.19 (5)	Si10xxvii—Al19—Al24i	61.56 (2)
Al28Ai—Ru5—Al21	123.94 (6)	Al25i—Al19—Al24i	58.76 (2)
Al27—Ru5—Al21iii	127.172 (16)	Al25—Al19—Al24i	166.35 (5)
Al28Ci—Ru5—Al21iii	140.96 (9)	Ru3vii—Al19—Al24i	53.74 (2)
Al28Bi—Ru5—Al21iii	139.85 (16)	Ru3xx—Al19—Al24i	110.17 (4)
Al28Aii—Ru5—Al21iii	123.94 (6)	Al24—Al19—Al24i	117.69 (4)
Al28Ai—Ru5—Al21iii	138.19 (5)	Al20ii—Al20—Si26Bi	129.78 (9)
Al21—Ru5—Al21iii	77.66 (3)	Al20ii—Al20—Si26B	129.78 (9)
Al27—Ru5—Al23iii	69.449 (16)	Si26Bi—Al20—Si26B	97.04 (16)
Al28Ci—Ru5—Al23iii	71.17 (14)	Al20ii—Al20—Al12B	83.4 (7)
Al28Bi—Ru5—Al23iii	74.28 (16)	Si26Bi—Al20—Al12B	84.5 (4)
Al28Aii—Ru5—Al23iii	72.12 (6)	Si26B—Al20—Al12B	84.5 (4)
Al28Ai—Ru5—Al23iii	88.37 (6)	Al20ii—Al20—Si13i	70.32 (5)
Al21—Ru5—Al23iii	145.86 (2)	Si26Bi—Al20—Si13i	73.37 (7)
Al21iii—Ru5—Al23iii	69.88 (2)	Si26B—Al20—Si13i	153.36 (12)
Al27—Ru5—Al23	69.449 (16)	Al12B—Al20—Si13i	118.3 (3)
Al28Ci—Ru5—Al23	71.17 (14)	Al20ii—Al20—Si13	70.32 (5)
Al28Bi—Ru5—Al23	74.28 (16)	Si26Bi—Al20—Si13	153.36 (12)
Al28Aii—Ru5—Al23	88.38 (6)	Si26B—Al20—Si13	73.37 (7)
Al28Ai—Ru5—Al23	72.12 (6)	Al12B—Al20—Si13	118.3 (3)
Al21—Ru5—Al23	69.88 (2)	Si13i—Al20—Si13	103.91 (8)
Al21iii—Ru5—Al23	145.86 (2)	Al20ii—Al20—Al12Bii	56.1 (6)
Al23iii—Ru5—Al23	138.27 (3)	Si26Bi—Al20—Al12Bii	102.4 (4)
Al27—Ru5—Al22	124.802 (18)	Si26B—Al20—Al12Bii	102.4 (4)
Al28Ci—Ru5—Al22	97.0 (7)	Al12B—Al20—Al12Bii	27.3 (13)
Al28Bi—Ru5—Al22	84.1 (6)	Si13i—Al20—Al12Bii	103.9 (4)
Al28Aii—Ru5—Al22	72.13 (5)	Si13—Al20—Al12Bii	103.9 (4)
Al28Ai—Ru5—Al22	61.87 (5)	Al20ii—Al20—Al26A	127.49 (5)
Al21—Ru5—Al22	66.94 (2)	Si26Bi—Al20—Al26A	98.57 (10)
Al21iii—Ru5—Al22	107.46 (2)	Si26B—Al20—Al26A	2.89 (9)
Al23iii—Ru5—Al22	132.77 (2)	Al12B—Al20—Al26A	82.2 (4)
Al23—Ru5—Al22	69.40 (2)	Si13i—Al20—Al26A	156.21 (10)
Al26Ax—Si6—Al26Axi	64.09 (6)	Si13—Al20—Al26A	73.05 (3)
Al26Ax—Si6—Al21x	62.48 (5)	Al12Bii—Al20—Al26A	99.7 (4)
Al26Axi—Si6—Al21x	116.49 (5)	Al20ii—Al20—Al26Ai	127.49 (5)
Al26Ax—Si6—Al21xi	116.49 (5)	Si26Bi—Al20—Al26Ai	2.89 (9)
Al26Axi—Si6—Al21xi	62.48 (5)	Si26B—Al20—Al26Ai	98.58 (10)
Al21x—Si6—Al21xi	117.71 (4)	Al12B—Al20—Al26Ai	82.2 (4)
Al26Ax—Si6—Al14xii	116.06 (7)	Si13i—Al20—Al26Ai	73.05 (3)
Al26Axi—Si6—Al14xii	116.06 (7)	Si13—Al20—Al26Ai	156.21 (10)
Al21x—Si6—Al14xii	116.56 (2)	Al12Bii—Al20—Al26Ai	99.7 (4)
Al21xi—Si6—Al14xii	116.56 (2)	Al26A—Al20—Al26Ai	100.00 (10)
Al26Ax—Si6—Al23xi	176.81 (7)	Al20ii—Al20—Ru2	71.28 (5)
Al26Axi—Si6—Al23xi	117.20 (3)	Si26Bi—Al20—Ru2	139.65 (11)
Al21x—Si6—Al23xi	118.09 (3)	Si26B—Al20—Ru2	60.02 (8)
Al21xi—Si6—Al23xi	66.27 (2)	Al12B—Al20—Ru2	62.1 (2)
Al14xii—Si6—Al23xi	60.78 (3)	Si13i—Al20—Ru2	141.15 (9)
Al26Ax—Si6—Al23x	117.20 (3)	Si13—Al20—Ru2	56.80 (3)
Al26Axi—Si6—Al23x	176.81 (7)	Al12Bii—Al20—Ru2	57.39 (4)
Al21x—Si6—Al23x	66.27 (2)	Al26A—Al20—Ru2	57.36 (4)
Al21xi—Si6—Al23x	118.09 (3)	Al26Ai—Al20—Ru2	138.65 (8)
Al14xii—Si6—Al23x	60.78 (3)	Al20ii—Al20—Ru2i	71.28 (5)
Al23xi—Si6—Al23x	61.35 (3)	Si26Bi—Al20—Ru2i	60.03 (8)
Al26Ax—Si6—Al15xiii	65.13 (7)	Si26B—Al20—Ru2i	139.65 (11)
Al26Axi—Si6—Al15xiii	65.13 (7)	Al12B—Al20—Ru2i	62.1 (2)
Al21x—Si6—Al15xiii	116.38 (2)	Si13i—Al20—Ru2i	56.80 (3)
Al21xi—Si6—Al15xiii	116.38 (2)	Si13—Al20—Ru2i	141.15 (9)
Al14xii—Si6—Al15xiii	60.96 (3)	Al12Bii—Al20—Ru2i	57.39 (4)
Al23xi—Si6—Al15xiii	112.46 (3)	Al26A—Al20—Ru2i	138.65 (8)
Al23x—Si6—Al15xiii	112.46 (3)	Al26Ai—Al20—Ru2i	57.36 (4)
Al26Ax—Si6—Al22xi	115.60 (5)	Ru2—Al20—Ru2i	114.71 (7)
Al26Axi—Si6—Al22xi	62.20 (5)	Al20ii—Al20—Al12A	71.86 (5)
Al21x—Si6—Al22xi	178.04 (4)	Si26Bi—Al20—Al12A	92.10 (9)
Al21xi—Si6—Al22xi	63.25 (2)	Si26B—Al20—Al12A	92.10 (9)
Al14xii—Si6—Al22xi	63.63 (2)	Al12B—Al20—Al12A	11.6 (7)
Al23xi—Si6—Al22xi	63.80 (2)	Si13i—Al20—Al12A	112.68 (6)
Al23x—Si6—Al22xi	114.99 (3)	Si13—Al20—Al12A	112.68 (6)
Al15xiii—Si6—Al22xi	61.86 (2)	Al12Bii—Al20—Al12A	15.8 (6)
Al26Ax—Si6—Al22x	62.20 (5)	Al26A—Al20—Al12A	89.59 (6)
Al26Axi—Si6—Al22x	115.60 (5)	Al26Ai—Al20—Al12A	89.59 (6)
Al21x—Si6—Al22x	63.25 (2)	Ru2—Al20—Al12A	59.21 (4)
Al21xi—Si6—Al22x	178.04 (4)	Ru2i—Al20—Al12A	59.21 (4)
Al14xii—Si6—Al22x	63.63 (2)	Al12B—Al21—Ru7A	68.3 (4)
Al23xi—Si6—Al22x	114.99 (3)	Al12B—Al21—Ru2	61.1 (4)
Al23x—Si6—Al22x	63.80 (2)	Ru7A—Al21—Ru2	129.12 (10)
Al15xiii—Si6—Al22x	61.86 (2)	Al12B—Al21—Ru5	116.5 (6)
Al22xi—Si6—Al22x	115.73 (4)	Ru7A—Al21—Ru5	129.33 (4)
Al26Ax—Si6—Al16	115.32 (7)	Ru2—Al21—Ru5	73.60 (2)
Al26Axi—Si6—Al16	115.32 (7)	Al12B—Al21—Ru7B	72.2 (6)
Al21x—Si6—Al16	63.79 (2)	Ru7A—Al21—Ru7B	4.0 (4)
Al21xi—Si6—Al16	63.79 (2)	Ru2—Al21—Ru7B	133.1 (4)
Al14xii—Si6—Al16	118.49 (4)	Ru5—Al21—Ru7B	128.9 (2)
Al23xi—Si6—Al16	67.08 (3)	Al12B—Al21—Si6xv	128.1 (7)
Al23x—Si6—Al16	67.08 (3)	Ru7A—Al21—Si6xv	107.13 (8)
Al15xiii—Si6—Al16	179.45 (4)	Ru2—Al21—Si6xv	107.38 (3)
Al22xi—Si6—Al16	117.98 (2)	Ru5—Al21—Si6xv	105.51 (3)
Al22x—Si6—Al16	117.98 (2)	Ru7B—Al21—Si6xv	104.1 (4)
Al21—Ru7A—Al21i	109.01 (17)	Al12B—Al21—Al12A	16.4 (7)
Al21—Ru7A—Si10	91.59 (11)	Ru7A—Al21—Al12A	67.88 (10)
Al21i—Ru7A—Si10	91.59 (11)	Ru2—Al21—Al12A	62.23 (4)
Al21—Ru7A—Al16xiv	150.26 (7)	Ru5—Al21—Al12A	103.42 (3)
Al21i—Ru7A—Al16xiv	72.21 (3)	Ru7B—Al21—Al12A	71.9 (4)
Si10—Ru7A—Al16xiv	118.15 (7)	Si6xv—Al21—Al12A	144.53 (5)
Al21—Ru7A—Al16xv	72.21 (3)	Al12B—Al21—Al26A	76.4 (6)
Al21i—Ru7A—Al16xv	150.26 (7)	Ru7A—Al21—Al26A	115.15 (8)
Si10—Ru7A—Al16xv	118.15 (7)	Ru2—Al21—Al26A	57.91 (6)
Al16xiv—Ru7A—Al16xv	92.25 (16)	Ru5—Al21—Al26A	114.75 (5)
Al21—Ru7A—Al11xv	75.04 (6)	Ru7B—Al21—Al26A	116.1 (2)
Al21i—Ru7A—Al11xv	75.04 (6)	Si6xv—Al21—Al26A	58.64 (11)
Si10—Ru7A—Al11xv	156.3 (2)	Al12A—Al21—Al26A	90.67 (13)
Al16xiv—Ru7A—Al11xv	76.80 (6)	Al12B—Al21—Al24xvii	119.0 (6)
Al16xv—Ru7A—Al11xv	76.80 (6)	Ru7A—Al21—Al24xvii	68.48 (6)
Al21—Ru7A—Al19xvi	122.02 (4)	Ru2—Al21—Al24xvii	134.06 (3)
Al21i—Ru7A—Al19xvi	122.02 (4)	Ru5—Al21—Al24xvii	66.51 (2)
Si10—Ru7A—Al19xvi	63.21 (5)	Ru7B—Al21—Al24xvii	66.3 (3)
Al16xiv—Ru7A—Al19xvi	76.07 (12)	Si6xv—Al21—Al24xvii	104.48 (3)
Al16xv—Ru7A—Al19xvi	76.07 (12)	Al12A—Al21—Al24xvii	105.60 (6)
Al11xv—Ru7A—Al19xvi	140.45 (19)	Al26A—Al21—Al24xvii	163.10 (12)
Al21—Ru7A—Al12B	55.23 (12)	Al12B—Al21—Si26B	66.3 (6)
Al21i—Ru7A—Al12B	55.23 (12)	Ru7A—Al21—Si26B	109.80 (10)
Si10—Ru7A—Al12B	81.9 (6)	Ru2—Al21—Si26B	53.66 (7)
Al16xiv—Ru7A—Al12B	124.7 (3)	Ru5—Al21—Si26B	118.00 (6)
Al16xv—Ru7A—Al12B	124.7 (3)	Ru7B—Al21—Si26B	111.4 (3)
Al11xv—Ru7A—Al12B	74.4 (6)	Si6xv—Al21—Si26B	67.88 (12)
Al19xvi—Ru7A—Al12B	145.1 (6)	Al12A—Al21—Si26B	80.63 (14)
Al21—Ru7A—Al12A	58.55 (10)	Al26A—Al21—Si26B	10.09 (5)
Al21i—Ru7A—Al12A	58.55 (10)	Al24xvii—Al21—Si26B	171.65 (10)
Si10—Ru7A—Al12A	66.73 (11)	Al12B—Al21—Al22	117.9 (4)
Al16xiv—Ru7A—Al12A	130.76 (9)	Ru7A—Al21—Al22	169.24 (9)
Al16xv—Ru7A—Al12A	130.76 (9)	Ru2—Al21—Al22	58.56 (2)
Al11xv—Ru7A—Al12A	89.61 (12)	Ru5—Al21—Al22	57.47 (2)
Al19xvi—Ru7A—Al12A	129.94 (10)	Ru7B—Al21—Al22	165.9 (4)
Al12B—Ru7A—Al12A	15.2 (6)	Si6xv—Al21—Al22	62.12 (3)
Al21—Ru7A—Al24xvii	59.64 (3)	Al12A—Al21—Al22	120.71 (5)
Al21i—Ru7A—Al24xvii	149.86 (17)	Al26A—Al21—Al22	60.68 (8)
Si10—Ru7A—Al24xvii	62.79 (3)	Al24xvii—Al21—Al22	112.49 (3)
Al16xiv—Ru7A—Al24xvii	132.53 (18)	Si26B—Al21—Al22	67.59 (10)
Al16xv—Ru7A—Al24xvii	57.51 (4)	Ru9ix—Al22—Ru5	133.43 (3)
Al11xv—Ru7A—Al24xvii	122.30 (3)	Ru9ix—Al22—Ru9	76.273 (19)
Al19xvi—Ru7A—Al24xvii	62.41 (5)	Ru5—Al22—Ru9	140.36 (3)
Al12B—Ru7A—Al24xvii	102.7 (3)	Ru9ix—Al22—Ru2	143.89 (3)
Al12A—Ru7A—Al24xvii	94.82 (10)	Ru5—Al22—Ru2	70.857 (19)
Al16xiv—Ru7B—Al16xv	99.1 (8)	Ru9—Al22—Ru2	71.503 (19)
Al16xiv—Ru7B—Al19xvi	81.4 (6)	Ru9ix—Al22—Al28Ai	75.76 (5)
Al16xv—Ru7B—Al19xvi	81.4 (6)	Ru5—Al22—Al28Ai	57.77 (5)
Al16xiv—Ru7B—Si10	120.2 (3)	Ru9—Al22—Al28Ai	136.00 (5)
Al16xv—Ru7B—Si10	120.2 (3)	Ru2—Al22—Al28Ai	118.07 (6)
Al19xvi—Ru7B—Si10	64.2 (3)	Ru9ix—Al22—Al26A	116.62 (6)
Al16xiv—Ru7B—Al21	150.9 (5)	Ru5—Al22—Al26A	109.46 (5)
Al16xv—Ru7B—Al21	72.18 (11)	Ru9—Al22—Al26A	55.78 (4)
Al19xvi—Ru7B—Al21	123.0 (2)	Ru2—Al22—Al26A	55.35 (9)
Si10—Ru7B—Al21	87.1 (5)	Al28Ai—Al22—Al26A	166.65 (6)
Al16xiv—Ru7B—Al21i	72.18 (11)	Ru9ix—Al22—Si6xv	102.48 (3)
Al16xv—Ru7B—Al21i	150.9 (5)	Ru5—Al22—Si6xv	98.12 (3)
Al19xvi—Ru7B—Al21i	123.0 (2)	Ru9—Al22—Si6xv	99.13 (3)
Si10—Ru7B—Al21i	87.1 (5)	Ru2—Al22—Si6xv	98.35 (3)
Al21—Ru7B—Al21i	101.7 (8)	Al28Ai—Al22—Si6xv	119.65 (6)
Al16xiv—Ru7B—Al11xv	78.6 (3)	Al26A—Al22—Si6xv	54.96 (8)
Al16xv—Ru7B—Al11xv	78.6 (3)	Ru9ix—Al22—Al21	156.62 (3)
Al19xvi—Ru7B—Al11xv	148.8 (10)	Ru5—Al22—Al21	55.59 (2)
Si10—Ru7B—Al11xv	147.0 (10)	Ru9—Al22—Al21	109.46 (3)
Al21—Ru7B—Al11xv	72.6 (4)	Ru2—Al22—Al21	54.75 (2)
Al21i—Ru7B—Al11xv	72.6 (4)	Al28Ai—Al22—Al21	109.73 (5)
Al16xiv—Ru7B—Al24xvii	140.6 (9)	Al26A—Al22—Al21	56.94 (4)
Al16xv—Ru7B—Al24xvii	58.93 (16)	Si6xv—Al22—Al21	54.63 (2)
Al19xvi—Ru7B—Al24xvii	64.3 (3)	Ru9ix—Al22—Al15i	56.09 (2)
Si10—Ru7B—Al24xvii	62.3 (2)	Ru5—Al22—Al15i	112.97 (3)
Al21—Ru7B—Al24xvii	58.76 (13)	Ru9—Al22—Al15i	56.57 (2)
Al21i—Ru7B—Al24xvii	142.6 (8)	Ru2—Al22—Al15i	91.92 (3)
Al11xv—Ru7B—Al24xvii	122.0 (2)	Al28Ai—Al22—Al15i	79.64 (5)
Al16xiv—Ru7B—Al24xvi	58.93 (16)	Al26A—Al22—Al15i	110.98 (5)
Al16xv—Ru7B—Al24xvi	140.6 (9)	Si6xv—Al22—Al15i	148.91 (3)
Al19xvi—Ru7B—Al24xvi	64.3 (3)	Al21—Al22—Al15i	146.28 (3)
Si10—Ru7B—Al24xvi	62.3 (2)	Ru9ix—Al22—Al22iii	109.401 (18)
Al21—Ru7B—Al24xvi	142.6 (8)	Ru5—Al22—Al22iii	56.521 (16)
Al21i—Ru7B—Al24xvi	58.76 (13)	Ru9—Al22—Al22iii	92.250 (17)
Al11xv—Ru7B—Al24xvi	122.0 (2)	Ru2—Al22—Al22iii	57.038 (17)
Al24xvii—Ru7B—Al24xvi	115.8 (4)	Al28Ai—Al22—Al22iii	66.38 (5)
Al16xiv—Ru7B—Ru7Bxviii	51.5 (3)	Al26A—Al22—Al22iii	111.14 (9)
Al16xv—Ru7B—Ru7Bxviii	51.5 (3)	Si6xv—Al22—Al22iii	147.868 (19)
Al19xvi—Ru7B—Ru7Bxviii	93.1 (4)	Al21—Al22—Al22iii	93.25 (2)
Si10—Ru7B—Ru7Bxviii	157.3 (5)	Al15i—Al22—Al22iii	59.955 (17)
Al21—Ru7B—Ru7Bxviii	106.9 (3)	Ru9ix—Al22—Al14ix	55.43 (2)
Al21i—Ru7B—Ru7Bxviii	106.9 (3)	Ru5—Al22—Al14ix	108.75 (3)
Al11xv—Ru7B—Ru7Bxviii	55.8 (5)	Ru9—Al22—Al14ix	110.44 (3)
Al24xvii—Ru7B—Ru7Bxviii	109.2 (4)	Ru2—Al22—Al14ix	153.68 (4)
Al24xvi—Ru7B—Ru7Bxviii	109.2 (4)	Al28Ai—Al22—Al14ix	79.63 (6)
Ru8xviii—Ru8—Si26Bi	130.06 (17)	Al26A—Al22—Al14ix	102.89 (9)
Ru8xviii—Ru8—Si26B	130.06 (17)	Si6xv—Al22—Al14ix	55.36 (3)
Si26Bi—Ru8—Si26B	93.3 (3)	Al21—Al22—Al14ix	102.32 (3)
Ru8xviii—Ru8—Si18	117.55 (5)	Al15i—Al22—Al14ix	111.30 (3)
Si26Bi—Ru8—Si18	85.04 (12)	Al22iii—Al22—Al14ix	145.76 (2)
Si26B—Ru8—Si18	85.03 (12)	Ru4ix—Al23—Ru5	139.89 (3)
Ru8xviii—Ru8—Al26A	119.05 (12)	Ru4ix—Al23—Ru4xv	77.88 (2)
Si26Bi—Ru8—Al26A	102.7 (2)	Ru5—Al23—Ru4xv	129.65 (3)
Si26B—Ru8—Al26A	11.05 (8)	Ru4ix—Al23—Al24xvii	137.82 (3)
Si18—Ru8—Al26A	91.76 (9)	Ru5—Al23—Al24xvii	66.20 (2)
Ru8xviii—Ru8—Al26Ai	119.05 (12)	Ru4xv—Al23—Al24xvii	64.62 (2)
Si26Bi—Ru8—Al26Ai	11.05 (8)	Ru4ix—Al23—Al14ix	57.47 (2)
Si26B—Ru8—Al26Ai	102.7 (2)	Ru5—Al23—Al14ix	114.11 (3)
Si18—Ru8—Al26Ai	91.76 (9)	Ru4xv—Al23—Al14ix	115.33 (3)
Al26A—Ru8—Al26Ai	111.25 (18)	Al24xvii—Al23—Al14ix	157.49 (4)
Ru8xviii—Ru8—Si26Bxviii	43.07 (15)	Ru4ix—Al23—Si6xv	103.97 (3)
Si26Bi—Ru8—Si26Bxviii	87.0 (3)	Ru5—Al23—Si6xv	99.99 (2)
Si26B—Ru8—Si26Bxviii	153.06 (14)	Ru4xv—Al23—Si6xv	98.39 (3)
Si18—Ru8—Si26Bxviii	121.78 (6)	Al24xvii—Al23—Si6xv	100.07 (3)
Al26A—Ru8—Si26Bxviii	146.00 (8)	Al14ix—Al23—Si6xv	57.43 (3)
Al26Ai—Ru8—Si26Bxviii	76.0 (3)	Ru4ix—Al23—Al27	102.08 (2)
Ru8xviii—Ru8—Si26Bxix	43.07 (15)	Ru5—Al23—Al27	51.056 (15)
Si26Bi—Ru8—Si26Bxix	153.05 (14)	Ru4xv—Al23—Al27	99.56 (2)
Si26B—Ru8—Si26Bxix	87.0 (3)	Al24xvii—Al23—Al27	67.82 (2)
Si18—Ru8—Si26Bxix	121.78 (6)	Al14ix—Al23—Al27	131.35 (3)
Al26A—Ru8—Si26Bxix	76.0 (3)	Si6xv—Al23—Al27	150.89 (3)
Al26Ai—Ru8—Si26Bxix	146.00 (8)	Ru4ix—Al23—Al23xix	56.121 (17)
Si26Bxviii—Ru8—Si26Bxix	80.9 (3)	Ru5—Al23—Al23xix	159.133 (17)
Ru8xviii—Ru8—Al11xv	85.69 (4)	Ru4xv—Al23—Al23xix	57.583 (16)
Si26Bi—Ru8—Al11xv	79.09 (8)	Al24xvii—Al23—Al23xix	112.01 (2)
Si26B—Ru8—Al11xv	79.10 (8)	Al14ix—Al23—Al23xix	58.992 (18)
Si18—Ru8—Al11xv	156.75 (8)	Si6xv—Al23—Al23xix	59.325 (17)
Al26A—Ru8—Al11xv	75.48 (5)	Al27—Al23—Al23xix	149.293 (14)
Al26Ai—Ru8—Al11xv	75.48 (5)	Ru4ix—Al23—Al23xxiii	58.09 (2)
Si26Bxviii—Ru8—Al11xv	74.51 (7)	Ru5—Al23—Al23xxiii	110.021 (16)
Si26Bxix—Ru8—Al11xv	74.51 (7)	Ru4xv—Al23—Al23xxiii	54.723 (19)
Ru8xviii—Ru8—Al18xviii	54.98 (4)	Al24xvii—Al23—Al23xxiii	83.77 (3)
Si26Bi—Ru8—Al18xviii	124.37 (8)	Al14ix—Al23—Al23xxiii	115.24 (4)
Si26B—Ru8—Al18xviii	124.36 (8)	Si6xv—Al23—Al23xxiii	148.424 (19)
Si18—Ru8—Al18xviii	62.58 (5)	Al27—Al23—Al23xxiii	59.293 (14)
Al26A—Ru8—Al18xviii	120.97 (5)	Al23xix—Al23—Al23xxiii	90.0
Al26Ai—Ru8—Al18xviii	120.97 (5)	Ru4ix—Al23—Al28Ci	90.8 (4)
Si26Bxviii—Ru8—Al18xviii	75.82 (12)	Ru5—Al23—Al28Ci	50.8 (4)
Si26Bxix—Ru8—Al18xviii	75.82 (12)	Ru4xv—Al23—Al28Ci	123.1 (7)
Al11xv—Ru8—Al18xviii	140.67 (8)	Al24xvii—Al23—Al28Ci	93.8 (6)
Ru8xviii—Ru8—Al26Axviii	53.64 (11)	Al14ix—Al23—Al28Ci	103.3 (7)
Si26Bi—Ru8—Al26Axviii	76.4 (3)	Si6xv—Al23—Al28Ci	138.2 (7)
Si26B—Ru8—Al26Axviii	150.61 (9)	Al27—Al23—Al28Ci	28.5 (7)
Si18—Ru8—Al26Axviii	120.64 (4)	Al23xix—Al23—Al28Ci	146.9 (4)
Al26A—Ru8—Al26Axviii	147.02 (8)	Al23xxiii—Al23—Al28Ci	71.9 (6)
Al26Ai—Ru8—Al26Axviii	65.4 (2)	Ru4ix—Al23—Al21	158.01 (3)
Si26Bxviii—Ru8—Al26Axviii	10.60 (7)	Ru5—Al23—Al21	54.62 (2)
Si26Bxix—Ru8—Al26Axviii	90.2 (2)	Ru4xv—Al23—Al21	104.25 (3)
Al11xv—Ru8—Al26Axviii	71.98 (4)	Al24xvii—Al23—Al21	57.17 (2)
Al18xviii—Ru8—Al26Axviii	82.95 (9)	Al14ix—Al23—Al21	103.50 (3)
Si13—Ru9—Al22ix	143.18 (3)	Si6xv—Al23—Al21	54.05 (2)
Si13—Ru9—Al14	74.93 (3)	Al27—Al23—Al21	99.14 (3)
Al22ix—Ru9—Al14	69.25 (2)	Al23xix—Al23—Al21	106.01 (2)
Si13—Ru9—Al26A	76.19 (12)	Al23xxiii—Al23—Al21	140.86 (4)
Al22ix—Ru9—Al26A	137.56 (11)	Al28Ci—Al23—Al21	105.4 (4)
Al14—Ru9—Al26A	150.45 (13)	Ru4ix—Al23—Al22	112.68 (3)
Si13—Ru9—Al15xx	144.71 (3)	Ru5—Al23—Al22	55.75 (2)
Al22ix—Ru9—Al15xx	68.60 (3)	Ru4xv—Al23—Al22	156.11 (3)
Al14—Ru9—Al15xx	137.45 (3)	Al24xvii—Al23—Al22	109.38 (3)
Al26A—Ru9—Al15xx	69.48 (11)	Al14ix—Al23—Al22	60.73 (2)
Si13—Ru9—Al15i	104.138 (19)	Si6xv—Al23—Al22	58.86 (2)
Al22ix—Ru9—Al15i	68.15 (2)	Al27—Al23—Al22	98.94 (3)
Al14—Ru9—Al15i	64.92 (3)	Al23xix—Al23—Al22	109.21 (2)
Al26A—Ru9—Al15i	129.36 (6)	Al23xxiii—Al23—Al22	149.15 (4)
Al15xx—Ru9—Al15i	103.749 (11)	Al28Ci—Al23—Al22	79.3 (7)
Si13—Ru9—Al22	105.35 (3)	Al21—Al23—Al22	57.77 (2)
Al22ix—Ru9—Al22	103.725 (19)	Al28Cxx—Al24—Ru3xx	71.1 (7)
Al14—Ru9—Al22	129.31 (2)	Al28Cxx—Al24—Al16	144.5 (3)
Al26A—Ru9—Al22	65.23 (9)	Ru3xx—Al24—Al16	129.42 (4)
Al15xx—Ru9—Al22	67.48 (2)	Al28Cxx—Al24—Al28Bxx	13.5 (6)
Al15i—Ru9—Al22	66.15 (3)	Ru3xx—Al24—Al28Bxx	60.3 (5)
Si13—Ru9—Si17Bxx	102.8 (4)	Al16—Al24—Al28Bxx	144.0 (2)
Al22ix—Ru9—Si17Bxx	82.4 (5)	Al28Cxx—Al24—Al23x	80.9 (7)
Al14—Ru9—Si17Bxx	110.4 (4)	Ru3xx—Al24—Al23x	151.18 (4)
Al26A—Ru9—Si17Bxx	70.2 (5)	Al16—Al24—Al23x	72.20 (4)
Al15xx—Ru9—Si17Bxx	58.2 (2)	Al28Bxx—Al24—Al23x	90.9 (5)
Al15i—Ru9—Si17Bxx	150.0 (5)	Al28Cxx—Al24—Al21x	122.4 (8)
Al22—Ru9—Si17Bxx	118.4 (3)	Ru3xx—Al24—Al21x	136.11 (3)
Si13—Ru9—Si26B	66.13 (13)	Al16—Al24—Al21x	66.43 (3)
Al22ix—Ru9—Si26B	145.78 (11)	Al28Bxx—Al24—Al21x	135.6 (5)
Al14—Ru9—Si26B	139.92 (13)	Al23x—Al24—Al21x	65.80 (3)
Al26A—Ru9—Si26B	10.56 (5)	Al28Cxx—Al24—Al25	82.2 (8)
Al15xx—Ru9—Si26B	79.06 (13)	Ru3xx—Al24—Al25	58.88 (2)
Al15i—Ru9—Si26B	132.98 (6)	Al16—Al24—Al25	86.60 (4)
Al22—Ru9—Si26B	72.46 (10)	Al28Bxx—Al24—Al25	70.0 (5)
Si17Bxx—Ru9—Si26B	71.0 (6)	Al23x—Al24—Al25	111.61 (3)
Si13—Ru9—Al17Axx	94.94 (4)	Al21x—Al24—Al25	152.63 (4)
Al22ix—Ru9—Al17Axx	94.80 (5)	Al28Cxx—Al24—Al24xix	55.8 (3)
Al14—Ru9—Al17Axx	118.76 (4)	Ru3xx—Al24—Al24xix	56.826 (17)
Al26A—Ru9—Al17Axx	57.86 (6)	Al16—Al24—Al24xix	157.27 (3)
Al15xx—Ru9—Al17Axx	59.96 (3)	Al28Bxx—Al24—Al24xix	58.6 (2)
Al15i—Ru9—Al17Axx	160.71 (4)	Al23x—Al24—Al24xix	112.00 (2)
Al22—Ru9—Al17Axx	111.76 (4)	Al21x—Al24—Al24xix	94.28 (2)
Si17Bxx—Ru9—Al17Axx	13.0 (5)	Al25—Al24—Al24xix	110.87 (3)
Si26B—Ru9—Al17Axx	58.07 (8)	Al28Cxx—Al24—Si10xxvii	112.9 (4)
Ru7Aii—Si10—Ru7A	125.3 (2)	Ru3xx—Al24—Si10xxvii	58.14 (3)
Ru7Aii—Si10—Ru7Bii	4.6 (4)	Al16—Al24—Si10xxvii	102.42 (3)
Ru7A—Si10—Ru7Bii	129.9 (6)	Al28Bxx—Al24—Si10xxvii	109.2 (3)
Ru7Aii—Si10—Ru7B	129.9 (6)	Al23x—Al24—Si10xxvii	144.16 (4)
Ru7A—Si10—Ru7B	4.6 (4)	Al21x—Al24—Si10xxvii	79.43 (4)
Ru7Bii—Si10—Ru7B	134.5 (10)	Al25—Al24—Si10xxvii	103.20 (4)
Ru7Aii—Si10—Ru3xxiv	112.02 (9)	Al24xix—Al24—Si10xxvii	60.455 (15)
Ru7A—Si10—Ru3xxiv	112.02 (9)	Al28Cxx—Al24—Ru4	92.4 (3)
Ru7Bii—Si10—Ru3xxiv	108.4 (4)	Ru3xx—Al24—Ru4	116.86 (3)
Ru7B—Si10—Ru3xxiv	108.4 (4)	Al16—Al24—Ru4	53.47 (3)
Ru7Aii—Si10—Ru3vi	112.02 (9)	Al28Bxx—Al24—Ru4	90.57 (19)
Ru7A—Si10—Ru3vi	112.02 (9)	Al23x—Al24—Ru4	56.57 (2)
Ru7Bii—Si10—Ru3vi	108.4 (4)	Al21x—Al24—Ru4	104.72 (3)
Ru7B—Si10—Ru3vi	108.4 (4)	Al25—Al24—Ru4	58.66 (2)
Ru3xxiv—Si10—Ru3vi	70.63 (3)	Al24xix—Al24—Ru4	148.210 (16)
Ru7Aii—Si10—Al19xxi	60.62 (11)	Si10xxvii—Al24—Ru4	147.42 (3)
Ru7A—Si10—Al19xxi	174.09 (12)	Al28Cxx—Al24—Al19	128.9 (8)
Ru7Bii—Si10—Al19xxi	56.0 (5)	Ru3xx—Al24—Al19	61.31 (3)
Ru7B—Si10—Al19xxi	169.5 (5)	Al16—Al24—Al19	69.38 (4)
Ru3xxiv—Si10—Al19xxi	63.41 (3)	Al28Bxx—Al24—Al19	115.7 (5)
Ru3vi—Si10—Al19xxi	63.41 (3)	Al23x—Al24—Al19	140.66 (4)
Ru7Aii—Si10—Al19xvi	174.09 (12)	Al21x—Al24—Al19	105.11 (3)
Ru7A—Si10—Al19xvi	60.62 (11)	Al25—Al24—Al19	58.34 (3)
Ru7Bii—Si10—Al19xvi	169.5 (5)	Al24xix—Al24—Al19	106.70 (3)
Ru7B—Si10—Al19xvi	56.0 (5)	Si10xxvii—Al24—Al19	55.54 (3)
Ru3xxiv—Si10—Al19xvi	63.41 (3)	Ru4—Al24—Al19	92.85 (3)
Ru3vi—Si10—Al19xvi	63.41 (3)	Al28Cxx—Al24—Ru5xxvii	68.3 (8)
Al19xxi—Si10—Al19xvi	113.47 (6)	Ru3xx—Al24—Ru5xxvii	117.27 (3)
Ru7Aii—Si10—Al24xxi	66.31 (4)	Al16—Al24—Ru5xxvii	111.16 (4)
Ru7A—Si10—Al24xxi	118.30 (3)	Al28Bxx—Al24—Ru5xxvii	81.4 (5)
Ru7Bii—Si10—Al24xxi	64.89 (15)	Al23x—Al24—Ru5xxvii	54.85 (2)
Ru7B—Si10—Al24xxi	119.03 (7)	Al21x—Al24—Ru5xxvii	54.16 (2)
Ru3xxiv—Si10—Al24xxi	55.588 (19)	Al25—Al24—Ru5xxvii	148.62 (4)
Ru3vi—Si10—Al24xxi	115.89 (4)	Al24xix—Al24—Ru5xxvii	61.040 (15)
Al19xxi—Si10—Al24xxi	62.902 (19)	Si10xxvii—Al24—Ru5xxvii	98.06 (3)
Al19xvi—Si10—Al24xxi	111.66 (3)	Ru4—Al24—Ru5xxvii	110.63 (2)
Ru7Aii—Si10—Al24xvi	118.31 (3)	Al19—Al24—Ru5xxvii	151.32 (3)
Ru7A—Si10—Al24xvi	66.31 (4)	Si13—Al25—Al28Axx	124.19 (6)
Ru7Bii—Si10—Al24xvi	119.03 (7)	Si13—Al25—Ru3xx	131.16 (3)
Ru7B—Si10—Al24xvi	64.90 (15)	Al28Axx—Al25—Ru3xx	60.04 (5)
Ru3xxiv—Si10—Al24xvi	115.89 (4)	Si13—Al25—Al14	69.92 (3)
Ru3vi—Si10—Al24xvi	55.588 (19)	Al28Axx—Al25—Al14	84.62 (5)
Al19xxi—Si10—Al24xvi	111.66 (3)	Ru3xx—Al25—Al14	144.54 (4)
Al19xvi—Si10—Al24xvi	62.902 (18)	Si13—Al25—Al19	107.28 (4)
Al24xxi—Si10—Al24xvi	170.96 (6)	Al28Axx—Al25—Al19	119.27 (6)
Ru7Aii—Si10—Al24xvii	118.31 (3)	Ru3xx—Al25—Al19	62.41 (3)
Ru7A—Si10—Al24xvii	66.31 (4)	Al14—Al25—Al19	147.27 (5)
Ru7Bii—Si10—Al24xvii	119.03 (7)	Si13—Al25—Ru4	110.10 (3)
Ru7B—Si10—Al24xvii	64.90 (15)	Al28Axx—Al25—Ru4	92.85 (5)
Ru3xxiv—Si10—Al24xvii	55.588 (19)	Ru3xx—Al25—Ru4	118.47 (3)
Ru3vi—Si10—Al24xvii	115.89 (4)	Al14—Al25—Ru4	56.01 (2)
Al19xxi—Si10—Al24xvii	111.66 (3)	Al19—Al25—Ru4	98.03 (3)
Al19xvi—Si10—Al24xvii	62.902 (19)	Si13—Al25—Al24	164.76 (5)
Al24xxi—Si10—Al24xvii	59.09 (3)	Al28Axx—Al25—Al24	70.66 (5)
Al24xvi—Si10—Al24xvii	120.09 (3)	Ru3xx—Al25—Al24	56.71 (2)
Ru7Aii—Si10—Al24xxii	66.31 (4)	Al14—Al25—Al24	111.40 (4)
Ru7A—Si10—Al24xxii	118.30 (3)	Al19—Al25—Al24	62.90 (3)
Ru7Bii—Si10—Al24xxii	64.89 (15)	Ru4—Al25—Al24	62.46 (2)
Ru7B—Si10—Al24xxii	119.03 (7)	Si13—Al25—Si17Bxx	94.5 (4)
Ru3xxiv—Si10—Al24xxii	115.89 (4)	Al28Axx—Al25—Si17Bxx	42.9 (5)
Ru3vi—Si10—Al24xxii	55.588 (19)	Ru3xx—Al25—Si17Bxx	54.1 (2)
Al19xxi—Si10—Al24xxii	62.902 (19)	Al14—Al25—Si17Bxx	102.6 (3)
Al19xvi—Si10—Al24xxii	111.66 (3)	Al19—Al25—Si17Bxx	110.1 (3)
Al24xxi—Si10—Al24xxii	120.09 (3)	Ru4—Al25—Si17Bxx	135.0 (5)
Al24xvi—Si10—Al24xxii	59.09 (3)	Al24—Al25—Si17Bxx	99.8 (3)
Al24xvii—Si10—Al24xxii	170.96 (6)	Si13—Al25—Ru9	52.79 (2)
Ru8xxv—Al11—Ru8xi	8.64 (8)	Al28Axx—Al25—Ru9	71.76 (5)
Ru8xxv—Al11—Ru7Axi	145.33 (12)	Ru3xx—Al25—Ru9	110.61 (3)
Ru8xi—Al11—Ru7Axi	136.69 (12)	Al14—Al25—Ru9	55.04 (2)
Ru8xxv—Al11—Ru7Axxv	136.69 (12)	Al19—Al25—Ru9	149.49 (4)
Ru8xi—Al11—Ru7Axxv	145.33 (12)	Ru4—Al25—Ru9	110.23 (3)
Ru7Axi—Al11—Ru7Axxv	78.0 (2)	Al24—Al25—Ru9	141.11 (4)
Ru8xxv—Al11—Ru7Bxi	150.1 (5)	Si17Bxx—Al25—Ru9	56.5 (2)
Ru8xi—Al11—Ru7Bxi	141.4 (5)	Si13—Al25—Si18	76.05 (3)
Ru7Axi—Al11—Ru7Bxi	4.7 (4)	Al28Axx—Al25—Si18	105.43 (6)
Ru7Axxv—Al11—Ru7Bxi	73.2 (6)	Ru3xx—Al25—Si18	58.55 (3)
Ru8xxv—Al11—Ru7Bxxv	141.4 (5)	Al14—Al25—Si18	143.89 (4)
Ru8xi—Al11—Ru7Bxxv	150.1 (5)	Al19—Al25—Si18	55.73 (3)
Ru7Axi—Al11—Ru7Bxxv	73.2 (6)	Ru4—Al25—Si18	152.96 (4)
Ru7Axxv—Al11—Ru7Bxxv	4.7 (4)	Al24—Al25—Si18	104.62 (4)
Ru7Bxi—Al11—Ru7Bxxv	68.5 (10)	Si17Bxx—Al25—Si18	68.0 (5)
Al12Bii—Al12A—Al12B	108 (3)	Ru9—Al25—Si18	94.56 (3)
Al12Bii—Al12A—Al21iii	67.5 (8)	Si26B—Al26A—Ru8	56.5 (4)
Al12B—Al12A—Al21iii	127.4 (4)	Si26B—Al26A—Ru2	73.2 (4)
Al12Bii—Al12A—Al21i	127.4 (4)	Ru8—Al26A—Ru2	127.6 (2)
Al12B—Al12A—Al21i	67.5 (8)	Si26B—Al26A—Ru9	101.8 (4)
Al21iii—Al12A—Al21i	157.96 (11)	Ru8—Al26A—Ru9	125.89 (10)
Al12Bii—Al12A—Al21ii	67.5 (8)	Ru2—Al26A—Ru9	74.86 (4)
Al12B—Al12A—Al21ii	127.4 (4)	Si26B—Al26A—Si6xv	149.4 (4)
Al21iii—Al12A—Al21ii	100.34 (4)	Ru8—Al26A—Si6xv	108.54 (8)
Al21i—Al12A—Al21ii	75.37 (3)	Ru2—Al26A—Si6xv	107.54 (11)
Al12Bii—Al12A—Al21	127.4 (4)	Ru9—Al26A—Si6xv	107.90 (18)
Al12B—Al12A—Al21	67.5 (8)	Si26B—Al26A—Al17Axx	92.8 (4)
Al21iii—Al12A—Al21	75.37 (3)	Ru8—Al26A—Al17Axx	66.69 (7)
Al21i—Al12A—Al21	100.34 (4)	Ru2—Al26A—Al17Axx	134.59 (9)
Al21ii—Al12A—Al21	157.96 (11)	Ru9—Al26A—Al17Axx	65.89 (6)
Al12Bii—Al12A—Ru2i	71.4 (7)	Si6xv—Al26A—Al17Axx	105.56 (15)
Al12B—Al12A—Ru2i	71.4 (7)	Si26B—Al26A—Al20	12.3 (4)
Al21iii—Al12A—Ru2i	138.44 (5)	Ru8—Al26A—Al20	66.65 (14)
Al21i—Al12A—Ru2i	57.296 (18)	Ru2—Al26A—Al20	61.85 (11)
Al21ii—Al12A—Ru2i	57.296 (18)	Ru9—Al26A—Al20	101.79 (13)
Al21—Al12A—Ru2i	138.44 (5)	Si6xv—Al26A—Al20	144.43 (8)
Al12Bii—Al12A—Ru2	71.4 (7)	Al17Axx—Al26A—Al20	104.15 (16)
Al12B—Al12A—Ru2	71.4 (7)	Si26B—Al26A—Ru8xviii	63.8 (4)
Al21iii—Al12A—Ru2	57.297 (18)	Ru8—Al26A—Ru8xviii	7.31 (7)
Al21i—Al12A—Ru2	138.44 (5)	Ru2—Al26A—Ru8xviii	134.7 (2)
Al21ii—Al12A—Ru2	138.44 (5)	Ru9—Al26A—Ru8xviii	126.28 (8)
Al21—Al12A—Ru2	57.298 (18)	Si6xv—Al26A—Ru8xviii	102.45 (8)
Ru2i—Al12A—Ru2	114.07 (9)	Al17Axx—Al26A—Ru8xviii	63.79 (7)
Al12Bii—Al12A—Al20	72.2 (15)	Al20—Al26A—Ru8xviii	73.95 (14)
Al12B—Al12A—Al20	35.9 (15)	Si26B—Al26A—Al21	100.9 (4)
Al21iii—Al12A—Al20	111.84 (7)	Ru8—Al26A—Al21	115.23 (8)
Al21i—Al12A—Al20	89.50 (5)	Ru2—Al26A—Al21	57.85 (3)
Al21ii—Al12A—Al20	111.84 (7)	Ru9—Al26A—Al21	117.54 (9)
Al21—Al12A—Al20	89.50 (5)	Si6xv—Al26A—Al21	58.88 (8)
Ru2i—Al12A—Al20	58.86 (4)	Al17Axx—Al26A—Al21	164.4 (2)
Ru2—Al12A—Al20	58.86 (4)	Al20—Al26A—Al21	90.24 (11)
Al12Bii—Al12A—Al20ii	35.9 (15)	Ru8xviii—Al26A—Al21	116.01 (7)
Al12B—Al12A—Al20ii	72.2 (15)	Si26B—Al26A—Al26Axix	117.3 (4)
Al21iii—Al12A—Al20ii	89.50 (5)	Ru8—Al26A—Al26Axix	60.96 (12)
Al21i—Al12A—Al20ii	111.84 (7)	Ru2—Al26A—Al26Axix	165.22 (9)
Al21ii—Al12A—Al20ii	89.50 (5)	Ru9—Al26A—Al26Axix	110.82 (8)
Al21—Al12A—Al20ii	111.84 (7)	Si6xv—Al26A—Al26Axix	57.95 (3)
Ru2i—Al12A—Al20ii	58.86 (4)	Al17Axx—Al26A—Al26Axix	58.02 (7)
Ru2—Al12A—Al20ii	58.86 (4)	Al20—Al26A—Al26Axix	127.49 (5)
Al20—Al12A—Al20ii	36.28 (10)	Ru8xviii—Al26A—Al26Axix	53.64 (11)
Al12Bii—Al12A—Ru7A	176.6 (15)	Al21—Al26A—Al26Axix	108.38 (7)
Al12B—Al12A—Ru7A	75.3 (15)	Al26A—Si26B—Al20	164.8 (5)
Al21iii—Al12A—Ru7A	110.57 (6)	Al26A—Si26B—Ru8	112.4 (4)
Al21i—Al12A—Ru7A	53.57 (3)	Al20—Si26B—Ru8	80.0 (2)
Al21ii—Al12A—Ru7A	110.57 (6)	Al26A—Si26B—Ru2	95.3 (4)
Al21—Al12A—Ru7A	53.57 (3)	Al20—Si26B—Ru2	70.59 (14)
Ru2i—Al12A—Ru7A	110.196 (14)	Ru8—Si26B—Ru2	148.4 (3)
Ru2—Al12A—Ru7A	110.197 (14)	Al26A—Si26B—Ru8xviii	105.6 (4)
Al20—Al12A—Ru7A	111.24 (6)	Al20—Si26B—Ru8xviii	86.8 (2)
Al20ii—Al12A—Ru7A	147.52 (8)	Ru8—Si26B—Ru8xviii	6.87 (7)
Al12A—Al12B—Al12Bii	36.0 (15)	Ru2—Si26B—Ru8xviii	154.5 (3)
Al12A—Al12B—Al20	133 (2)	Al26A—Si26B—Al17Axx	76.3 (4)
Al12Bii—Al12B—Al20	96.6 (7)	Al20—Si26B—Al17Axx	117.6 (2)
Al12A—Al12B—Al21i	96.1 (10)	Ru8—Si26B—Al17Axx	68.57 (8)
Al12Bii—Al12B—Al21i	114.2 (6)	Ru2—Si26B—Al17Axx	135.85 (12)
Al20—Al12B—Al21i	109.6 (8)	Ru8xviii—Si26B—Al17Axx	65.16 (8)
Al12A—Al12B—Al21	96.1 (10)	Al26A—Si26B—Ru9	67.6 (4)
Al12Bii—Al12B—Al21	114.2 (6)	Al20—Si26B—Ru9	111.86 (15)
Al20—Al12B—Al21	109.6 (8)	Ru8—Si26B—Ru9	129.86 (10)
Al21i—Al12B—Al21	111.5 (8)	Ru2—Si26B—Ru9	73.78 (8)
Al12A—Al12B—Ru2i	92.4 (10)	Ru8xviii—Si26B—Ru9	127.65 (10)
Al12Bii—Al12B—Ru2i	76.2 (6)	Al17Axx—Si26B—Ru9	62.85 (9)
Al20—Al12B—Ru2i	68.2 (5)	Al26A—Si26B—Si13	117.4 (4)
Al21i—Al12B—Ru2i	61.39 (6)	Al20—Si26B—Si13	59.77 (13)
Al21—Al12B—Ru2i	169.5 (12)	Ru8—Si26B—Si13	117.9 (2)
Al12A—Al12B—Ru2	92.4 (10)	Ru2—Si26B—Si13	55.64 (7)
Al12Bii—Al12B—Ru2	76.2 (6)	Ru8xviii—Si26B—Si13	122.8 (2)
Al20—Al12B—Ru2	68.2 (5)	Al17Axx—Si26B—Si13	89.50 (8)
Al21i—Al12B—Ru2	169.5 (12)	Ru9—Si26B—Si13	52.12 (5)
Al21—Al12B—Ru2	61.39 (6)	Al26A—Si26B—Al21	69.0 (4)
Ru2i—Al12B—Ru2	124.4 (8)	Al20—Si26B—Al21	97.72 (13)
Al12A—Al12B—Al20ii	92.1 (17)	Ru8—Si26B—Al21	118.41 (9)
Al12Bii—Al12B—Al20ii	56.1 (6)	Ru2—Si26B—Al21	56.84 (6)
Al20—Al12B—Al20ii	40.5 (3)	Ru8xviii—Si26B—Al21	117.29 (9)
Al21i—Al12B—Al20ii	123.3 (4)	Al17Axx—Si26B—Al21	144.5 (3)
Al21—Al12B—Al20ii	123.3 (4)	Ru9—Si26B—Al21	108.29 (15)
Ru2i—Al12B—Al20ii	62.3 (4)	Si13—Si26B—Al21	112.48 (9)
Ru2—Al12B—Al20ii	62.3 (4)	Al26A—Si26B—Al12B	119.2 (5)
Al12A—Al12B—Ru7A	89.5 (16)	Al20—Si26B—Al12B	48.4 (3)
Al12Bii—Al12B—Ru7A	125.5 (6)	Ru8—Si26B—Al12B	96.0 (4)
Al20—Al12B—Ru7A	138.0 (12)	Ru2—Si26B—Al12B	55.7 (4)
Al21i—Al12B—Ru7A	56.5 (4)	Ru8xviii—Si26B—Al12B	100.4 (4)
Al21—Al12B—Ru7A	56.5 (4)	Al17Axx—Si26B—Al12B	162.3 (4)
Ru2i—Al12B—Ru7A	117.7 (4)	Ru9—Si26B—Al12B	129.1 (4)
Ru2—Al12B—Ru7A	117.7 (4)	Si13—Si26B—Al12B	90.3 (4)
Al20ii—Al12B—Ru7A	178.5 (12)	Al21—Si26B—Al12B	50.2 (3)
Al12A—Al12B—Si26Bi	144.6 (7)	Al28Ci—Al27—Al28Cxxiv	180 (3)
Al12Bii—Al12B—Si26Bi	123.9 (4)	Al28Ci—Al27—Al28Bi	8.0 (11)
Al20—Al12B—Si26Bi	47.2 (5)	Al28Cxxiv—Al27—Al28Bi	172.0 (11)
Al21i—Al12B—Si26Bi	63.5 (4)	Al28Ci—Al27—Al28Bxxiv	172.0 (11)
Al21—Al12B—Si26Bi	117.8 (10)	Al28Cxxiv—Al27—Al28Bxxiv	8.0 (11)
Ru2i—Al12B—Si26Bi	52.9 (3)	Al28Bi—Al27—Al28Bxxiv	180.0 (13)
Ru2—Al12B—Si26Bi	111.9 (9)	Al28Ci—Al27—Ru5xxviii	106.3 (11)
Al20ii—Al12B—Si26Bi	78.3 (6)	Al28Cxxiv—Al27—Ru5xxviii	73.7 (11)
Ru7A—Al12B—Si26Bi	100.5 (7)	Al28Bi—Al27—Ru5xxviii	114.3 (5)
Al12A—Al12B—Si26B	144.6 (7)	Al28Bxxiv—Al27—Ru5xxviii	65.7 (5)
Al12Bii—Al12B—Si26B	123.9 (4)	Al28Ci—Al27—Ru5	73.7 (11)
Al20—Al12B—Si26B	47.2 (5)	Al28Cxxiv—Al27—Ru5	106.3 (11)
Al21i—Al12B—Si26B	117.8 (10)	Al28Bi—Al27—Ru5	65.7 (5)
Al21—Al12B—Si26B	63.5 (4)	Al28Bxxiv—Al27—Ru5	114.3 (5)
Ru2i—Al12B—Si26B	111.9 (9)	Ru5xxviii—Al27—Ru5	180.0
Ru2—Al12B—Si26B	52.9 (3)	Al28Ci—Al27—Al23xxviii	101.3 (5)
Al20ii—Al12B—Si26B	78.3 (6)	Al28Cxxiv—Al27—Al23xxviii	78.7 (5)
Ru7A—Al12B—Si26B	100.5 (7)	Al28Bi—Al27—Al23xxviii	105.0 (2)
Si26Bi—Al12B—Si26B	67.0 (6)	Al28Bxxiv—Al27—Al23xxviii	75.0 (2)
Ru9—Si13—Ru9iii	79.25 (3)	Ru5xxviii—Al27—Al23xxviii	59.495 (14)
Ru9—Si13—Ru1	133.97 (2)	Ru5—Al27—Al23xxviii	120.505 (14)
Ru9iii—Si13—Ru1	133.97 (2)	Al28Ci—Al27—Al23iii	78.7 (5)
Ru9—Si13—Ru2	78.47 (2)	Al28Cxxiv—Al27—Al23iii	101.3 (5)
Ru9iii—Si13—Ru2	78.46 (2)	Al28Bi—Al27—Al23iii	75.0 (2)
Ru1—Si13—Ru2	130.71 (4)	Al28Bxxiv—Al27—Al23iii	105.0 (2)
Ru9—Si13—Al20ii	138.45 (5)	Ru5xxviii—Al27—Al23iii	120.505 (14)
Ru9iii—Si13—Al20ii	108.59 (4)	Ru5—Al27—Al23iii	59.495 (14)
Ru1—Si13—Al20ii	69.62 (4)	Al23xxviii—Al27—Al23iii	61.41 (3)
Ru2—Si13—Al20ii	64.15 (4)	Al28Ci—Al27—Al23xxiii	101.3 (5)
Ru9—Si13—Al20	108.59 (4)	Al28Cxxiv—Al27—Al23xxiii	78.7 (5)
Ru9iii—Si13—Al20	138.44 (5)	Al28Bi—Al27—Al23xxiii	105.0 (2)
Ru1—Si13—Al20	69.62 (4)	Al28Bxxiv—Al27—Al23xxiii	75.0 (2)
Ru2—Si13—Al20	64.15 (4)	Ru5xxviii—Al27—Al23xxiii	59.495 (14)
Al20ii—Si13—Al20	39.36 (10)	Ru5—Al27—Al23xxiii	120.505 (14)
Ru9—Si13—Al25	68.38 (3)	Al23xxviii—Al27—Al23xxiii	118.59 (3)
Ru9iii—Si13—Al25	109.91 (4)	Al23iii—Al27—Al23xxiii	180.00 (4)
Ru1—Si13—Al25	69.91 (3)	Al28Ci—Al27—Al23	78.7 (5)
Ru2—Si13—Al25	142.93 (3)	Al28Cxxiv—Al27—Al23	101.3 (5)
Al20ii—Si13—Al25	136.87 (5)	Al28Bi—Al27—Al23	75.0 (2)
Al20—Si13—Al25	110.82 (5)	Al28Bxxiv—Al27—Al23	105.0 (2)
Ru9—Si13—Al25iii	109.91 (4)	Ru5xxviii—Al27—Al23	120.505 (14)
Ru9iii—Si13—Al25iii	68.38 (3)	Ru5—Al27—Al23	59.495 (14)
Ru1—Si13—Al25iii	69.91 (3)	Al23xxviii—Al27—Al23	180.0
Ru2—Si13—Al25iii	142.93 (3)	Al23iii—Al27—Al23	118.59 (3)
Al20ii—Si13—Al25iii	110.82 (5)	Al23xxiii—Al27—Al23	61.41 (3)
Al20—Si13—Al25iii	136.87 (5)	Al28Ci—Al27—Al28Ai	18.1 (10)
Al25—Si13—Al25iii	67.53 (4)	Al28Cxxiv—Al27—Al28Ai	161.9 (10)
Ru9—Si13—Si26B	61.75 (12)	Al28Bi—Al27—Al28Ai	11.3 (4)
Ru9iii—Si13—Si26B	122.39 (11)	Al28Bxxiv—Al27—Al28Ai	168.7 (4)
Ru1—Si13—Si26B	103.17 (11)	Ru5xxviii—Al27—Al28Ai	122.36 (4)
Ru2—Si13—Si26B	54.62 (6)	Ru5—Al27—Al28Ai	57.64 (4)
Al20ii—Si13—Si26B	81.32 (11)	Al23xxviii—Al27—Al28Ai	115.61 (5)
Al20—Si13—Si26B	46.86 (13)	Al23iii—Al27—Al28Ai	78.24 (5)
Al25—Si13—Si26B	93.92 (6)	Al23xxiii—Al27—Al28Ai	101.76 (5)
Al25iii—Si13—Si26B	161.39 (6)	Al23—Al27—Al28Ai	64.39 (5)
Ru9—Si13—Si26Biii	122.39 (11)	Al28Ci—Al27—Al28Axxiv	161.9 (10)
Ru9iii—Si13—Si26Biii	61.75 (12)	Al28Cxxiv—Al27—Al28Axxiv	18.1 (10)
Ru1—Si13—Si26Biii	103.17 (11)	Al28Bi—Al27—Al28Axxiv	168.7 (4)
Ru2—Si13—Si26Biii	54.62 (6)	Al28Bxxiv—Al27—Al28Axxiv	11.3 (4)
Al20ii—Si13—Si26Biii	46.86 (13)	Ru5xxviii—Al27—Al28Axxiv	57.64 (4)
Al20—Si13—Si26Biii	81.32 (11)	Ru5—Al27—Al28Axxiv	122.36 (4)
Al25—Si13—Si26Biii	161.40 (6)	Al23xxviii—Al27—Al28Axxiv	64.39 (5)
Al25iii—Si13—Si26Biii	93.93 (6)	Al23iii—Al27—Al28Axxiv	101.76 (5)
Si26B—Si13—Si26Biii	104.56 (11)	Al23xxiii—Al27—Al28Axxiv	78.24 (5)
Ru9—Al14—Ru9iii	74.75 (2)	Al23—Al27—Al28Axxiv	115.61 (5)
Ru9—Al14—Ru4	128.03 (3)	Al28Ai—Al27—Al28Axxiv	180.00 (7)
Ru9iii—Al14—Ru4	128.03 (3)	Al28Aiii—Al28A—Al28B	67.3 (6)
Ru9—Al14—Si6xii	107.23 (3)	Al28Aiii—Al28A—Al28C	76.1 (3)
Ru9iii—Al14—Si6xii	107.23 (3)	Al28B—Al28A—Al28C	9.6 (7)
Ru4—Al14—Si6xii	107.28 (4)	Al28Aiii—Al28A—Si17B	79.04 (15)
Ru9—Al14—Al25	65.59 (2)	Al28B—Al28A—Si17B	133.7 (9)
Ru9iii—Al14—Al25	104.13 (4)	Al28C—Al28A—Si17B	142.3 (8)
Ru4—Al14—Al25	63.62 (3)	Al28Aiii—Al28A—Ru5i	81.43 (6)
Si6xii—Al14—Al25	144.44 (3)	Al28B—Al28A—Ru5i	68.4 (9)
Ru9—Al14—Al25iii	104.13 (4)	Al28C—Al28A—Ru5i	65.1 (8)
Ru9iii—Al14—Al25iii	65.60 (2)	Si17B—Al28A—Ru5i	137.7 (4)
Ru4—Al14—Al25iii	63.62 (3)	Al28Aiii—Al28A—Al17A	81.59 (5)
Si6xii—Al14—Al25iii	144.44 (3)	Al28B—Al28A—Al17A	132.4 (9)
Al25—Al14—Al25iii	65.56 (5)	Al28C—Al28A—Al17A	140.4 (8)
Ru9—Al14—Al23ix	110.764 (16)	Si17B—Al28A—Al17A	5.0 (4)
Ru9iii—Al14—Al23ix	168.52 (4)	Ru5i—Al28A—Al17A	142.71 (9)
Ru4—Al14—Al23ix	57.15 (2)	Al28Aiii—Al28A—Al25v	140.30 (5)
Si6xii—Al14—Al23ix	61.80 (3)	Al28B—Al28A—Al25v	113.0 (7)
Al25—Al14—Al23ix	87.35 (3)	Al28C—Al28A—Al25v	108.9 (6)
Al25iii—Al14—Al23ix	120.77 (4)	Si17B—Al28A—Al25v	74.4 (3)
Ru9—Al14—Al23viii	168.52 (4)	Ru5i—Al28A—Al25v	137.33 (10)
Ru9iii—Al14—Al23viii	110.764 (16)	Al17A—Al28A—Al25v	70.04 (6)
Ru4—Al14—Al23viii	57.15 (2)	Al28Aiii—Al28A—Ru3	81.66 (5)
Si6xii—Al14—Al23viii	61.80 (3)	Al28B—Al28A—Ru3	80.5 (9)
Al25—Al14—Al23viii	120.77 (4)	Al28C—Al28A—Ru3	85.1 (9)
Al25iii—Al14—Al23viii	87.35 (3)	Si17B—Al28A—Ru3	63.5 (4)
Al23ix—Al14—Al23viii	62.02 (4)	Ru5i—Al28A—Ru3	148.43 (9)
Ru9—Al14—Al15i	58.96 (2)	Al17A—Al28A—Ru3	59.38 (5)
Ru9iii—Al14—Al15i	58.95 (2)	Al25v—Al28A—Ru3	60.26 (5)
Ru4—Al14—Al15i	169.63 (4)	Al28Aiii—Al28A—Al22i	113.62 (5)
Si6xii—Al14—Al15i	62.36 (3)	Al28B—Al28A—Al22i	127.4 (10)
Al25—Al14—Al15i	124.44 (3)	Al28C—Al28A—Al22i	121.4 (8)
Al25iii—Al14—Al15i	124.44 (3)	Si17B—Al28A—Al22i	94.4 (3)
Al23ix—Al14—Al15i	114.47 (4)	Ru5i—Al28A—Al22i	60.36 (4)
Al23viii—Al14—Al15i	114.46 (4)	Al17A—Al28A—Al22i	97.35 (7)
Ru9—Al14—Al22viii	115.76 (3)	Al25v—Al28A—Al22i	97.47 (8)
Ru9iii—Al14—Al22viii	55.318 (17)	Ru3—Al28A—Al22i	151.18 (9)
Ru4—Al14—Al22viii	114.64 (2)	Al28Aiii—Al28A—Al27xxix	82.37 (5)
Si6xii—Al14—Al22viii	61.01 (2)	Al28B—Al28A—Al27xxix	23.5 (9)
Al25—Al14—Al22viii	154.49 (4)	Al28C—Al28A—Al27xxix	15.9 (8)
Al25iii—Al14—Al22viii	90.42 (3)	Si17B—Al28A—Al27xxix	157.0 (2)
Al23ix—Al14—Al22viii	113.65 (4)	Ru5i—Al28A—Al27xxix	50.81 (4)
Al23viii—Al14—Al22viii	63.22 (2)	Al17A—Al28A—Al27xxix	155.92 (9)
Al15i—Al14—Al22viii	61.44 (2)	Al25v—Al28A—Al27xxix	113.47 (8)
Ru9—Al14—Al22ix	55.319 (17)	Ru3—Al28A—Al27xxix	100.54 (6)
Ru9iii—Al14—Al22ix	115.76 (3)	Al22i—Al28A—Al27xxix	105.50 (6)
Ru4—Al14—Al22ix	114.64 (2)	Al28C—Al28B—Al28A	155.5 (14)
Si6xii—Al14—Al22ix	61.01 (2)	Al28C—Al28B—Al28Aiii	155.5 (14)
Al25—Al14—Al22ix	90.42 (3)	Al28A—Al28B—Al28Aiii	45.5 (13)
Al25iii—Al14—Al22ix	154.49 (4)	Al28C—Al28B—Al27xxix	18 (2)
Al23ix—Al14—Al22ix	63.22 (2)	Al28A—Al28B—Al27xxix	145.2 (11)
Al23viii—Al14—Al22ix	113.65 (4)	Al28Aiii—Al28B—Al27xxix	145.2 (11)
Al15i—Al14—Al22ix	61.44 (2)	Al28C—Al28B—Ru5i	82 (3)
Al22viii—Al14—Al22ix	111.52 (4)	Al28A—Al28B—Ru5i	88.9 (10)
Si17B—Al15—Ru9iv	63.07 (3)	Al28Aiii—Al28B—Ru5i	88.9 (10)
Si17B—Al15—Ru9v	63.07 (3)	Al27xxix—Al28B—Ru5i	64.0 (6)
Ru9iv—Al15—Ru9v	125.94 (4)	Al28C—Al28B—Ru3	112 (3)
Si17B—Al15—Ru9ii	132.0 (4)	Al28A—Al28B—Ru3	78.0 (11)
Ru9iv—Al15—Ru9ii	76.250 (11)	Al28Aiii—Al28B—Ru3	78.0 (11)
Ru9v—Al15—Ru9ii	144.13 (4)	Al27xxix—Al28B—Ru3	130.2 (10)
Si17B—Al15—Ru9i	132.0 (4)	Ru5i—Al28B—Ru3	165.8 (12)
Ru9iv—Al15—Ru9i	144.13 (4)	Al28C—Al28B—Al24v	66 (2)
Ru9v—Al15—Ru9i	76.250 (11)	Al28A—Al28B—Al24v	106.4 (7)
Ru9ii—Al15—Ru9i	72.07 (3)	Al28Aiii—Al28B—Al24v	133.2 (14)
Si17B—Al15—Al17A	13.5 (5)	Al27xxix—Al28B—Al24v	80.8 (8)
Ru9iv—Al15—Al17A	64.43 (2)	Ru5i—Al28B—Al24v	133.1 (8)
Ru9v—Al15—Al17A	64.43 (2)	Ru3—Al28B—Al24v	57.5 (3)
Ru9ii—Al15—Al17A	139.19 (3)	Al28C—Al28B—Al24iv	66 (2)
Ru9i—Al15—Al17A	139.19 (3)	Al28A—Al28B—Al24iv	133.2 (14)
Si17B—Al15—Al14i	167.7 (6)	Al28Aiii—Al28B—Al24iv	106.4 (7)
Ru9iv—Al15—Al14i	116.772 (19)	Al27xxix—Al28B—Al24iv	80.8 (8)
Ru9v—Al15—Al14i	116.772 (19)	Ru5i—Al28B—Al24iv	133.1 (8)
Ru9ii—Al15—Al14i	56.12 (2)	Ru3—Al28B—Al24iv	57.5 (3)
Ru9i—Al15—Al14i	56.12 (2)	Al24v—Al28B—Al24iv	62.9 (4)
Al17A—Al15—Al14i	154.18 (7)	Al28C—Al28B—Si17B	167 (3)
Si17B—Al15—Si6xxvi	111.0 (6)	Al28A—Al28B—Si17B	31.4 (8)
Ru9iv—Al15—Si6xxvi	101.37 (2)	Al28Aiii—Al28B—Si17B	31.4 (8)
Ru9v—Al15—Si6xxvi	101.37 (2)	Al27xxix—Al28B—Si17B	175.2 (9)
Ru9ii—Al15—Si6xxvi	100.57 (3)	Ru5i—Al28B—Si17B	111.1 (9)
Ru9i—Al15—Si6xxvi	100.57 (3)	Ru3—Al28B—Si17B	54.6 (6)
Al17A—Al15—Si6xxvi	97.50 (6)	Al24v—Al28B—Si17B	103.3 (6)
Al14i—Al15—Si6xxvi	56.68 (3)	Al24iv—Al28B—Si17B	103.3 (6)
Si17B—Al15—Al22ii	78.3 (5)	Al28C—Al28B—Al23ii	74.0 (15)
Ru9iv—Al15—Al22ii	55.306 (19)	Al28A—Al28B—Al23ii	119.0 (11)
Ru9v—Al15—Al22ii	108.83 (3)	Al28Aiii—Al28B—Al23ii	82.0 (5)
Ru9ii—Al15—Al22ii	57.28 (2)	Al27xxix—Al28B—Al23ii	65.0 (4)
Ru9i—Al15—Al22ii	92.78 (3)	Ru5i—Al28B—Al23ii	56.2 (3)
Al17A—Al15—Al22ii	89.97 (5)	Ru3—Al28B—Al23ii	126.0 (3)
Al14i—Al15—Al22ii	112.18 (4)	Al24v—Al28B—Al23ii	134.4 (9)
Si6xxvi—Al15—Al22ii	149.13 (2)	Al24iv—Al28B—Al23ii	81.8 (3)
Si17B—Al15—Al22i	78.3 (5)	Si17B—Al28B—Al23ii	112.8 (6)
Ru9iv—Al15—Al22i	108.83 (3)	Al28C—Al28B—Al23i	74.0 (15)
Ru9v—Al15—Al22i	55.306 (19)	Al28A—Al28B—Al23i	82.0 (5)
Ru9ii—Al15—Al22i	92.78 (3)	Al28Aiii—Al28B—Al23i	119.0 (11)
Ru9i—Al15—Al22i	57.28 (2)	Al27xxix—Al28B—Al23i	65.0 (4)
Al17A—Al15—Al22i	89.97 (5)	Ru5i—Al28B—Al23i	56.2 (3)
Al14i—Al15—Al22i	112.18 (4)	Ru3—Al28B—Al23i	126.0 (3)
Si6xxvi—Al15—Al22i	149.13 (2)	Al24v—Al28B—Al23i	81.8 (3)
Al22ii—Al15—Al22i	60.09 (3)	Al24iv—Al28B—Al23i	134.4 (9)
Si17B—Al15—Al22v	114.0 (3)	Si17B—Al28B—Al23i	112.8 (6)
Ru9iv—Al15—Al22v	159.05 (4)	Al23ii—Al28B—Al23i	107.6 (6)
Ru9v—Al15—Al22v	57.609 (15)	Al28B—Al28C—Al27xxix	154 (4)
Ru9ii—Al15—Al22v	112.97 (3)	Al28B—Al28C—Al28A	14.9 (8)
Ru9i—Al15—Al22v	54.534 (18)	Al27xxix—Al28C—Al28A	146.0 (16)
Al17A—Al15—Al22v	107.73 (4)	Al28B—Al28C—Al28Aiii	14.9 (8)
Al14i—Al15—Al22v	61.21 (2)	Al27xxix—Al28C—Al28Aiii	146.0 (16)
Si6xxvi—Al15—Al22v	59.21 (2)	Al28A—Al28C—Al28Aiii	27.7 (7)
Al22ii—Al15—Al22v	145.63 (3)	Al28B—Al28C—Ru5i	83 (3)
Al22i—Al15—Al22v	89.97 (2)	Al27xxix—Al28C—Ru5i	71.5 (10)
Si17B—Al15—Al22iv	114.0 (3)	Al28A—Al28C—Ru5i	77.5 (11)
Ru9iv—Al15—Al22iv	57.609 (15)	Al28Aiii—Al28C—Ru5i	77.5 (11)
Ru9v—Al15—Al22iv	159.05 (4)	Al28B—Al28C—Al24v	101 (2)
Ru9ii—Al15—Al22iv	54.534 (18)	Al27xxix—Al28C—Al24v	100.7 (14)
Ru9i—Al15—Al22iv	112.97 (3)	Al28A—Al28C—Al24v	96.8 (10)
Al17A—Al15—Al22iv	107.73 (4)	Al28Aiii—Al28C—Al24v	112.8 (14)
Al14i—Al15—Al22iv	61.21 (2)	Ru5i—Al28C—Al24v	145.4 (4)
Si6xxvi—Al15—Al22iv	59.21 (2)	Al28B—Al28C—Al24iv	101 (2)
Al22ii—Al15—Al22iv	89.97 (2)	Al27xxix—Al28C—Al24iv	100.7 (14)
Al22i—Al15—Al22iv	145.63 (3)	Al28A—Al28C—Al24iv	112.8 (14)
Al22v—Al15—Al22iv	111.16 (4)	Al28Aiii—Al28C—Al24iv	96.8 (10)
Ru7Bxxv—Al16—Ru7Bxi	77.0 (6)	Ru5i—Al28C—Al24iv	145.4 (4)
Ru7Bxxv—Al16—Ru4	136.1 (2)	Al24v—Al28C—Al24iv	68.4 (6)
Ru7Bxi—Al16—Ru4	136.1 (2)	Al28B—Al28C—Al28Cvi	154 (4)
Ru7Bxxv—Al16—Ru7Axxv	4.1 (4)	Al27xxix—Al28C—Al28Cvi	0.0 (8)
Ru7Bxi—Al16—Ru7Axxv	79.3 (3)	Al28A—Al28C—Al28Cvi	146.0 (16)
Ru4—Al16—Ru7Axxv	135.94 (4)	Al28Aiii—Al28C—Al28Cvi	146.0 (16)
Ru7Bxxv—Al16—Ru7Axi	79.3 (3)	Ru5i—Al28C—Al28Cvi	71.5 (10)
Ru7Bxi—Al16—Ru7Axi	4.1 (4)	Al24v—Al28C—Al28Cvi	100.7 (14)
Ru4—Al16—Ru7Axi	135.94 (4)	Al24iv—Al28C—Al28Cvi	100.7 (14)
Ru7Axxv—Al16—Ru7Axi	81.43 (11)	Al28B—Al28C—Al23ii	93.7 (16)
Ru7Bxxv—Al16—Al24	70.8 (3)	Al27xxix—Al28C—Al23ii	72.8 (7)
Ru7Bxi—Al16—Al24	144.9 (4)	Al28A—Al28C—Al23ii	102.4 (11)
Ru4—Al16—Al24	67.90 (3)	Al28Aiii—Al28C—Al23ii	79.2 (6)
Ru7Axxv—Al16—Al24	69.37 (4)	Ru5i—Al28C—Al23ii	58.0 (4)
Ru7Axi—Al16—Al24	148.30 (9)	Al24v—Al28C—Al23ii	153.6 (10)
Ru7Bxxv—Al16—Al24iii	144.9 (4)	Al24iv—Al28C—Al23ii	87.4 (2)
Ru7Bxi—Al16—Al24iii	70.8 (3)	Al28Cvi—Al28C—Al23ii	72.8 (7)
Ru4—Al16—Al24iii	67.90 (3)	Al28B—Al28C—Al23i	93.7 (16)
Ru7Axxv—Al16—Al24iii	148.30 (9)	Al27xxix—Al28C—Al23i	72.8 (7)
Ru7Axi—Al16—Al24iii	69.37 (4)	Al28A—Al28C—Al23i	79.2 (6)
Al24—Al16—Al24iii	134.53 (5)	Al28Aiii—Al28C—Al23i	102.4 (11)
Ru7Bxxv—Al16—Si6	101.2 (5)	Ru5i—Al28C—Al23i	58.0 (4)
Ru7Bxi—Al16—Si6	101.2 (5)	Al24v—Al28C—Al23i	87.4 (2)
Ru4—Al16—Si6	98.54 (4)	Al24iv—Al28C—Al23i	153.6 (10)
Ru7Axxv—Al16—Si6	97.56 (9)	Al28Cvi—Al28C—Al23i	72.8 (7)
Ru7Axi—Al16—Si6	97.56 (9)	Al23ii—Al28C—Al23i	113.7 (8)
Al24—Al16—Si6	98.22 (3)	Al28B—Al28C—Ru3	56 (3)
Al24iii—Al16—Si6	98.22 (3)	Al27xxix—Al28C—Ru3	149.8 (17)
Ru7Bxxv—Al16—Al21x	57.5 (5)	Al28A—Al28C—Ru3	62.5 (10)
Ru7Bxi—Al16—Al21x	114.2 (3)	Al28Aiii—Al28C—Ru3	62.5 (10)
Ru4—Al16—Al21x	109.03 (3)	Ru5i—Al28C—Ru3	138.7 (15)
Ru7Axxv—Al16—Al21x	53.48 (9)	Al24v—Al28C—Ru3	55.5 (5)
Ru7Axi—Al16—Al21x	113.39 (5)	Al24iv—Al28C—Ru3	55.5 (5)
Al24—Al16—Al21x	58.04 (2)	Al28Cvi—Al28C—Ru3	149.8 (17)
Al24iii—Al16—Al21x	150.87 (5)	Al23ii—Al28C—Ru3	119.1 (7)
Si6—Al16—Al21x	52.86 (3)	Al23i—Al28C—Ru3	119.1 (7)
Ru7Bxxv—Al16—Al21xi	114.2 (3)	Al28B—Al28C—Ru5xxix	159 (3)
Ru7Bxi—Al16—Al21xi	57.5 (5)	Al27xxix—Al28C—Ru5xxix	47.4 (10)
Ru4—Al16—Al21xi	109.03 (3)	Al28A—Al28C—Ru5xxix	158.9 (10)
Ru7Axxv—Al16—Al21xi	113.39 (5)	Al28Aiii—Al28C—Ru5xxix	158.9 (10)
Ru7Axi—Al16—Al21xi	53.48 (9)	Ru5i—Al28C—Ru5xxix	118.9 (13)
Al24—Al16—Al21xi	150.87 (5)	Al24v—Al28C—Ru5xxix	62.1 (7)
Al24iii—Al16—Al21xi	58.04 (2)	Al24iv—Al28C—Ru5xxix	62.1 (7)
Si6—Al16—Al21xi	52.86 (3)	Al28Cvi—Al28C—Ru5xxix	47.4 (10)
Al21x—Al16—Al21xi	99.01 (5)	Al23ii—Al28C—Ru5xxix	97.9 (8)
Si17B—Al17A—Ru3	74.0 (11)	Al23i—Al28C—Ru5xxix	97.9 (8)
Si17B—Al17A—Al28Aiii	16.0 (9)	Ru3—Al28C—Ru5xxix	102.3 (7)

Symmetry codes: (i) x, y, −z+1/2; (ii) −x, y, −z+1/2; (iii) −x, y, z; (iv) x−1/2, −y+1/2, z+1/2; (v) −x+1/2, −y+1/2, z+1/2; (vi) −x, −y, −z+1; (vii) −x+1/2, −y+1/2, −z+1; (viii) x−1/2, −y+1/2, −z; (ix) −x+1/2, −y+1/2, −z; (x) −x+1/2, y+1/2, z; (xi) x−1/2, y+1/2, z; (xii) −x, −y+1, −z; (xiii) −x, −y+1, z−1/2; (xiv) x+1/2, y−1/2, −z+1/2; (xv) x+1/2, y−1/2, z; (xvi) −x+1/2, y−1/2, −z+1/2; (xvii) −x+1/2, y−1/2, z; (xviii) −x+1, y, −z+1/2; (xix) −x+1, y, z; (xx) −x+1/2, −y+1/2, z−1/2; (xxi) x−1/2, y−1/2, z; (xxii) x−1/2, y−1/2, −z+1/2; (xxiii) x, −y, −z; (xxiv) −x, −y, z−1/2; (xxv) −x+1/2, y+1/2, −z+1/2; (xxvi) −x, −y+1, z+1/2; (xxvii) x+1/2, y+1/2, z; (xxviii) −x, −y, −z; (xxix) −x, −y, z+1/2.

Docosaaluminium nonaruthenium decasilicon (II). Crystal data

~Ru9(Al0.70Si0.30)32	Dx = 4.777 Mg m−3
Mr = 1783.65	Mo Kα radiation, λ = 0.71073 Å
Trigonal, R3	Cell parameters from 10605 reflections
a = 10.4479 (2) Å	θ = 3.9–30.7°
c = 19.6774 (4) Å	µ = 6.59 mm−1
V = 1860.17 (7) Å3	T = 296 K
Z = 3	Irregular, metallic light silver
F(000) = 2436.84	0.03 × 0.03 × 0.03 mm

Docosaaluminium nonaruthenium decasilicon (II). Data collection

XtaLAB Synergy R, HyPix diffractometer	1193 independent reflections
Radiation source: micro-focus sealed X-ray tube, Mova (Mo) X-ray Source	1127 reflections with I > 2σ(I)
Mirror monochromator	Rint = 0.027
Detector resolution: 10.0000 pixels mm-1	θmax = 30.8°, θmin = 3.9°
ω scans	h = −14→14
Absorption correction: gaussian (CrysAlisPro; Matsumoto et al., 2021)	k = −14→14
Tmin = 0.868, Tmax = 0.879	l = −27→28
14255 measured reflections

Docosaaluminium nonaruthenium decasilicon (II). Refinement

Refinement on F2	Primary atom site location: dual
Least-squares matrix: full	w = 1/[σ2(Fo2) + (0.0111P)2 + 0.5812P] where P = (Fo2 + 2Fc2)/3
R[F2 > 2σ(F2)] = 0.013	(Δ/σ)max = 0.002
wR(F2) = 0.024	Δρmax = 0.45 e Å−3
S = 1.08	Δρmin = −0.53 e Å−3
1193 reflections	Extinction correction: SHELXL-2019/3 (Sheldrick, 2015b), Fc*=kFc[1+0.001xFc2λ3/sin(2θ)]-1/4
66 parameters	Extinction coefficient: 0.000262 (16)
2 restraints

Docosaaluminium nonaruthenium decasilicon (II). Special details

Geometry. All esds (except the esd in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell esds are taken into account individually in the estimation of esds in distances, angles and torsion angles; correlations between esds in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell esds is used for estimating esds involving l.s. planes.

Docosaaluminium nonaruthenium decasilicon (II). Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Ų)

	x	y	z	Uiso*/Ueq	Occ. (<1)
Ru1	0.000000	0.000000	0.500000	0.00463 (7)
Ru2	0.000000	0.000000	0.28833 (2)	0.00519 (6)
Ru3	0.24368 (2)	0.24916 (2)	0.09171 (2)	0.00467 (5)
Al4	0.000000	0.000000	0.12554 (5)	0.01068 (17)
Si5	0.06845 (5)	0.25394 (5)	0.29541 (2)	0.00880 (9)
Al6	0.22915 (5)	0.16512 (5)	0.21432 (2)	0.0079 (2)	0.58 (4)
Si6	0.22915 (5)	0.16512 (5)	0.21432 (2)	0.0079 (2)	0.42 (4)
Al7	0.00143 (5)	0.21088 (5)	0.03958 (2)	0.0076 (2)	0.82 (4)
Si7	0.00143 (5)	0.21088 (5)	0.03958 (2)	0.0076 (2)	0.18 (4)
Al8	0.16504 (5)	0.12448 (5)	0.39021 (2)	0.00948 (10)
Al9	0.12627 (6)	0.37148 (6)	0.16275 (2)	0.01084 (11)

Docosaaluminium nonaruthenium decasilicon (II). Atomic displacement parameters (Ų)

	U11	U22	U33	U12	U13	U23
Ru1	0.00464 (9)	0.00464 (9)	0.00459 (13)	0.00232 (5)	0.000	0.000
Ru2	0.00444 (7)	0.00444 (7)	0.00667 (10)	0.00222 (4)	0.000	0.000
Ru3	0.00486 (7)	0.00394 (7)	0.00529 (7)	0.00224 (5)	0.00054 (4)	0.00006 (4)
Al4	0.0066 (2)	0.0066 (2)	0.0189 (4)	0.00329 (12)	0.000	0.000
Si5	0.0109 (2)	0.0054 (2)	0.0101 (2)	0.00405 (18)	−0.00401 (16)	−0.00003 (16)
Al6	0.0076 (3)	0.0096 (3)	0.0073 (3)	0.0048 (2)	0.00127 (16)	0.00249 (17)
Si6	0.0076 (3)	0.0096 (3)	0.0073 (3)	0.0048 (2)	0.00127 (16)	0.00249 (17)
Al7	0.0059 (3)	0.0102 (3)	0.0061 (3)	0.0036 (2)	0.00001 (16)	−0.00019 (17)
Si7	0.0059 (3)	0.0102 (3)	0.0061 (3)	0.0036 (2)	0.00001 (16)	−0.00019 (17)
Al8	0.0074 (2)	0.0088 (2)	0.0076 (2)	0.00063 (19)	−0.00180 (18)	−0.00055 (17)
Al9	0.0098 (2)	0.0097 (2)	0.0121 (2)	0.0042 (2)	0.00506 (18)	−0.00117 (19)

Docosaaluminium nonaruthenium decasilicon (II). Geometric parameters (Å, º)

Ru1—Al8i	2.6625 (5)	Ru3—Al7xv	2.6119 (5)
Ru1—Al8ii	2.6625 (5)	Ru3—Al4	2.6597 (3)
Ru1—Al8iii	2.6625 (5)	Ru3—Al7ii	2.6643 (5)
Ru1—Al8iv	2.6626 (5)	Al4—Al6iv	2.7622 (7)
Ru1—Al8v	2.6626 (5)	Al4—Al6ii	2.7622 (7)
Ru1—Al8	2.6626 (5)	Al4—Al6	2.7622 (7)
Ru1—Al9vi	2.7432 (5)	Al4—Al7	2.7718 (7)
Ru1—Al9vii	2.7432 (5)	Al4—Al7iv	2.7718 (7)
Ru1—Al9viii	2.7432 (5)	Al4—Al7ii	2.7718 (7)
Ru1—Al9ix	2.7432 (5)	Si5—Si5ix	2.4056 (9)
Ru1—Al9x	2.7433 (5)	Si5—Al8ix	2.6749 (6)
Ru1—Al9xi	2.7433 (5)	Si5—Al6iv	2.7560 (6)
Ru2—Si5ii	2.3817 (4)	Si5—Al8	2.7736 (6)
Ru2—Si5	2.3817 (4)	Si5—Al6	2.7899 (6)
Ru2—Si5iv	2.3817 (4)	Si5—Al9	2.8188 (7)
Ru2—Al8	2.5380 (5)	Si5—Al8iv	2.8319 (7)
Ru2—Al8ii	2.5380 (5)	Al6—Al7xii	2.6531 (6)
Ru2—Al8iv	2.5381 (5)	Al6—Al9xii	2.8394 (7)
Ru2—Al6ii	2.5880 (5)	Al6—Al6xiv	2.8614 (9)
Ru2—Al6iv	2.5880 (5)	Al7—Al7xvi	2.6922 (6)
Ru2—Al6	2.5881 (5)	Al7—Al7xv	2.6922 (6)
Ru3—Si5xii	2.4214 (4)	Al7—Al9	2.8639 (7)
Ru3—Al8xiii	2.5175 (5)	Al8—Al9vii	2.6172 (7)
Ru3—Al6	2.5459 (5)	Al8—Al8ii	2.6956 (8)
Ru3—Al7	2.5702 (5)	Al8—Al8iv	2.6957 (8)
Ru3—Al9xii	2.5708 (5)	Al8—Al9ix	2.7562 (7)
Ru3—Al9	2.5806 (5)	Al9—Al9xii	2.7465 (5)
Ru3—Al6xiv	2.6110 (5)	Al9—Al9xvii	2.7465 (5)
Al8i—Ru1—Al8ii	180.0	Si5ix—Si5—Al8ix	65.93 (2)
Al8i—Ru1—Al8iii	60.824 (17)	Ru3xvii—Si5—Al8ix	58.956 (14)
Al8ii—Ru1—Al8iii	119.176 (17)	Ru2—Si5—Al6iv	59.969 (14)
Al8i—Ru1—Al8iv	119.176 (17)	Si5ix—Si5—Al6iv	177.02 (3)
Al8ii—Ru1—Al8iv	60.824 (17)	Ru3xvii—Si5—Al6iv	60.159 (14)
Al8iii—Ru1—Al8iv	119.176 (17)	Al8ix—Si5—Al6iv	115.87 (2)
Al8i—Ru1—Al8v	60.824 (17)	Ru2—Si5—Al8	58.394 (14)
Al8ii—Ru1—Al8v	119.176 (17)	Si5ix—Si5—Al8	61.71 (2)
Al8iii—Ru1—Al8v	60.824 (17)	Ru3xvii—Si5—Al8	159.94 (2)
Al8iv—Ru1—Al8v	180.000 (12)	Al8ix—Si5—Al8	127.637 (19)
Al8i—Ru1—Al8	119.177 (17)	Al6iv—Si5—Al8	116.45 (2)
Al8ii—Ru1—Al8	60.823 (17)	Ru2—Si5—Al6	59.434 (14)
Al8iii—Ru1—Al8	179.999 (12)	Si5ix—Si5—Al6	97.84 (3)
Al8iv—Ru1—Al8	60.824 (17)	Ru3xvii—Si5—Al6	119.201 (19)
Al8v—Ru1—Al8	119.176 (17)	Al8ix—Si5—Al6	109.51 (2)
Al8i—Ru1—Al9vi	89.014 (15)	Al6iv—Si5—Al6	83.85 (2)
Al8ii—Ru1—Al9vi	90.986 (15)	Al8—Si5—Al6	78.242 (18)
Al8iii—Ru1—Al9vi	57.891 (14)	Ru2—Si5—Al9	108.102 (19)
Al8iv—Ru1—Al9vi	61.286 (14)	Si5ix—Si5—Al9	110.55 (3)
Al8v—Ru1—Al9vi	118.714 (14)	Ru3xvii—Si5—Al9	58.171 (14)
Al8—Ru1—Al9vi	122.110 (14)	Al8ix—Si5—Al9	60.157 (17)
Al8i—Ru1—Al9vii	90.986 (15)	Al6iv—Si5—Al9	72.378 (18)
Al8ii—Ru1—Al9vii	89.014 (15)	Al8—Si5—Al9	141.66 (2)
Al8iii—Ru1—Al9vii	122.109 (14)	Al6—Si5—Al9	65.278 (17)
Al8iv—Ru1—Al9vii	118.714 (14)	Ru2—Si5—Al8iv	57.488 (14)
Al8v—Ru1—Al9vii	61.286 (14)	Si5ix—Si5—Al8iv	99.22 (3)
Al8—Ru1—Al9vii	57.890 (14)	Ru3xvii—Si5—Al8iv	103.669 (19)
Al9vi—Ru1—Al9vii	180.0	Al8ix—Si5—Al8iv	134.55 (2)
Al8i—Ru1—Al9viii	122.109 (14)	Al6iv—Si5—Al8iv	77.825 (18)
Al8ii—Ru1—Al9viii	57.891 (14)	Al8—Si5—Al8iv	57.48 (2)
Al8iii—Ru1—Al9viii	61.285 (14)	Al6—Si5—Al8iv	115.13 (2)
Al8iv—Ru1—Al9viii	89.013 (15)	Al9—Si5—Al8iv	150.02 (2)
Al8v—Ru1—Al9viii	90.987 (15)	Ru3—Al6—Ru2	129.707 (19)
Al8—Ru1—Al9viii	118.714 (14)	Ru3—Al6—Ru3xiv	112.612 (17)
Al9vi—Ru1—Al9viii	60.077 (1)	Ru2—Al6—Ru3xiv	106.091 (16)
Al9vii—Ru1—Al9viii	119.923 (1)	Ru3—Al6—Al7xii	116.69 (2)
Al8i—Ru1—Al9ix	57.891 (14)	Ru2—Al6—Al7xii	109.655 (19)
Al8ii—Ru1—Al9ix	122.109 (14)	Ru3xiv—Al6—Al7xii	60.806 (14)
Al8iii—Ru1—Al9ix	118.715 (14)	Ru3—Al6—Si5ii	143.99 (2)
Al8iv—Ru1—Al9ix	90.987 (15)	Ru2—Al6—Si5ii	52.818 (13)
Al8v—Ru1—Al9ix	89.013 (15)	Ru3xiv—Al6—Si5ii	53.554 (13)
Al8—Ru1—Al9ix	61.286 (14)	Al7xii—Al6—Si5ii	86.919 (19)
Al9vi—Ru1—Al9ix	119.923 (1)	Ru3—Al6—Al4	59.976 (17)
Al9vii—Ru1—Al9ix	60.077 (1)	Ru2—Al6—Al4	73.471 (19)
Al9viii—Ru1—Al9ix	180.0	Ru3xiv—Al6—Al4	119.885 (18)
Al8i—Ru1—Al9x	118.713 (14)	Al7xii—Al6—Al4	176.66 (3)
Al8ii—Ru1—Al9x	61.287 (14)	Si5ii—Al6—Al4	96.03 (2)
Al8iii—Ru1—Al9x	89.012 (15)	Ru3—Al6—Si5	111.671 (19)
Al8iv—Ru1—Al9x	122.111 (14)	Ru2—Al6—Si5	52.410 (13)
Al8v—Ru1—Al9x	57.889 (14)	Ru3xiv—Al6—Si5	133.10 (2)
Al8—Ru1—Al9x	90.987 (15)	Al7xii—Al6—Si5	85.969 (18)
Al9vi—Ru1—Al9x	119.921 (1)	Si5ii—Al6—Si5	95.90 (2)
Al9vii—Ru1—Al9x	60.079 (1)	Al4—Al6—Si5	95.257 (19)
Al9viii—Ru1—Al9x	60.079 (1)	Ru3—Al6—Al9xii	56.713 (13)
Al9ix—Ru1—Al9x	119.921 (1)	Ru2—Al6—Al9xii	144.13 (2)
Al8i—Ru1—Al9xi	61.287 (14)	Ru3xiv—Al6—Al9xii	99.795 (18)
Al8ii—Ru1—Al9xi	118.713 (14)	Al7xii—Al6—Al9xii	62.748 (17)
Al8iii—Ru1—Al9xi	90.988 (15)	Si5ii—Al6—Al9xii	148.12 (2)
Al8iv—Ru1—Al9xi	57.889 (14)	Al4—Al6—Al9xii	114.07 (2)
Al8v—Ru1—Al9xi	122.111 (14)	Si5—Al6—Al9xii	91.741 (19)
Al8—Ru1—Al9xi	89.013 (15)	Ru3—Al6—Al6xiv	57.391 (15)
Al9vi—Ru1—Al9xi	60.079 (1)	Ru2—Al6—Al6xiv	145.22 (3)
Al9vii—Ru1—Al9xi	119.921 (1)	Ru3xiv—Al6—Al6xiv	55.221 (15)
Al9viii—Ru1—Al9xi	119.921 (1)	Al7xii—Al6—Al6xiv	87.39 (2)
Al9ix—Ru1—Al9xi	60.079 (1)	Si5ii—Al6—Al6xiv	100.23 (2)
Al9x—Ru1—Al9xi	180.0	Al4—Al6—Al6xiv	90.54 (2)
Si5ii—Ru2—Si5	119.661 (2)	Si5—Al6—Al6xiv	162.19 (3)
Si5ii—Ru2—Si5iv	119.662 (2)	Al9xii—Al6—Al6xiv	70.54 (2)
Si5—Ru2—Si5iv	119.659 (2)	Ru3—Al7—Ru3xvi	117.649 (18)
Si5ii—Ru2—Al8	70.202 (16)	Ru3—Al7—Al6xvii	116.63 (2)
Si5—Ru2—Al8	68.549 (15)	Ru3xvi—Al7—Al6xvii	119.15 (2)
Si5iv—Ru2—Al8	124.453 (17)	Ru3—Al7—Ru3iv	116.862 (18)
Si5ii—Ru2—Al8ii	68.549 (15)	Ru3xvi—Al7—Ru3iv	114.346 (17)
Si5—Ru2—Al8ii	124.452 (17)	Al6xvii—Al7—Ru3iv	58.818 (14)
Si5iv—Ru2—Al8ii	70.202 (16)	Ru3—Al7—Al7xvi	134.381 (13)
Al8—Ru2—Al8ii	64.153 (18)	Ru3xvi—Al7—Al7xvi	57.944 (19)
Si5ii—Ru2—Al8iv	124.453 (17)	Al6xvii—Al7—Al7xvi	99.12 (2)
Si5—Ru2—Al8iv	70.202 (16)	Ru3iv—Al7—Al7xvi	58.365 (12)
Si5iv—Ru2—Al8iv	68.548 (15)	Ru3—Al7—Al7xv	59.461 (12)
Al8—Ru2—Al8iv	64.153 (18)	Ru3xvi—Al7—Al7xv	60.283 (19)
Al8ii—Ru2—Al8iv	64.152 (18)	Al6xvii—Al7—Al7xv	168.67 (2)
Si5ii—Ru2—Al6ii	68.158 (15)	Ru3iv—Al7—Al7xv	132.432 (13)
Si5—Ru2—Al6ii	149.111 (17)	Al7xvi—Al7—Al7xv	89.88 (2)
Si5iv—Ru2—Al6ii	67.213 (15)	Ru3—Al7—Al4	59.578 (10)
Al8—Ru2—Al6ii	135.530 (15)	Ru3xvi—Al7—Al4	135.92 (2)
Al8ii—Ru2—Al6ii	86.437 (15)	Al6xvii—Al7—Al4	94.86 (2)
Al8iv—Ru2—Al6ii	132.991 (15)	Ru3iv—Al7—Al4	58.545 (10)
Si5ii—Ru2—Al6iv	149.112 (17)	Al7xvi—Al7—Al4	91.721 (15)
Si5—Ru2—Al6iv	67.211 (15)	Al7xv—Al7—Al4	91.721 (15)
Si5iv—Ru2—Al6iv	68.157 (15)	Ru3—Al7—Al9	56.394 (14)
Al8—Ru2—Al6iv	132.990 (15)	Ru3xvi—Al7—Al9	142.61 (2)
Al8ii—Ru2—Al6iv	135.529 (15)	Al6xvii—Al7—Al9	61.810 (17)
Al8iv—Ru2—Al6iv	86.436 (15)	Ru3iv—Al7—Al9	97.917 (17)
Al6ii—Ru2—Al6iv	91.441 (15)	Al7xvi—Al7—Al9	156.03 (3)
Si5ii—Ru2—Al6	67.213 (15)	Al7xv—Al7—Al9	111.07 (2)
Si5—Ru2—Al6	68.157 (15)	Al4—Al7—Al9	76.65 (2)
Si5iv—Ru2—Al6	149.112 (17)	Ru3vii—Al8—Ru2	143.54 (2)
Al8—Ru2—Al6	86.435 (15)	Ru3vii—Al8—Al9vii	60.306 (15)
Al8ii—Ru2—Al6	132.991 (15)	Ru2—Al8—Al9vii	145.45 (2)
Al8iv—Ru2—Al6	135.529 (15)	Ru3vii—Al8—Ru1	109.918 (17)
Al6ii—Ru2—Al6	91.442 (15)	Ru2—Al8—Ru1	106.409 (17)
Al6iv—Ru2—Al6	91.441 (15)	Al9vii—Al8—Ru1	62.599 (15)
Si5xii—Ru3—Al8xiii	65.551 (15)	Ru3vii—Al8—Si5ix	55.492 (14)
Si5xii—Ru3—Al6	120.406 (15)	Ru2—Al8—Si5ix	104.439 (19)
Al8xiii—Ru3—Al6	124.414 (16)	Al9vii—Al8—Si5ix	109.63 (2)
Si5xii—Ru3—Al7	122.217 (15)	Ru1—Al8—Si5ix	117.12 (2)
Al8xiii—Ru3—Al7	73.932 (16)	Ru3vii—Al8—Al8ii	149.08 (3)
Al6—Ru3—Al7	116.122 (15)	Ru2—Al8—Al8ii	57.924 (9)
Si5xii—Ru3—Al9xii	68.678 (16)	Al9vii—Al8—Al8ii	91.00 (2)
Al8xiii—Ru3—Al9xii	65.586 (16)	Ru1—Al8—Al8ii	59.587 (8)
Al6—Ru3—Al9xii	67.410 (16)	Si5ix—Al8—Al8ii	155.06 (3)
Al7—Ru3—Al9xii	127.455 (16)	Ru3vii—Al8—Al8iv	143.73 (3)
Si5xii—Ru3—Al9	119.665 (16)	Ru2—Al8—Al8iv	57.925 (9)
Al8xiii—Ru3—Al9	61.760 (16)	Al9vii—Al8—Al8iv	122.187 (15)
Al6—Ru3—Al9	72.324 (16)	Ru1—Al8—Al8iv	59.588 (8)
Al7—Ru3—Al9	67.560 (16)	Si5ix—Al8—Al8iv	96.24 (3)
Al9xii—Ru3—Al9	64.436 (17)	Al8ii—Al8—Al8iv	60.0
Si5xii—Ru3—Al6xiv	66.289 (14)	Ru3vii—Al8—Al9ix	58.136 (15)
Al8xiii—Ru3—Al6xiv	127.640 (16)	Ru2—Al8—Al9ix	145.13 (2)
Al6—Ru3—Al6xiv	67.389 (17)	Al9vii—Al8—Al9ix	61.411 (12)
Al7—Ru3—Al6xiv	153.459 (16)	Ru1—Al8—Al9ix	60.799 (14)
Al9xii—Ru3—Al6xiv	78.881 (16)	Si5ix—Al8—Al9ix	62.510 (18)
Al9—Ru3—Al6xiv	133.370 (16)	Al8ii—Al8—Al9ix	120.386 (14)
Si5xii—Ru3—Al7xv	71.465 (15)	Al8iv—Al8—Al9ix	90.01 (2)
Al8xiii—Ru3—Al7xv	80.729 (15)	Ru3vii—Al8—Si5	104.754 (19)
Al6—Ru3—Al7xv	154.440 (16)	Ru2—Al8—Si5	53.057 (13)
Al7—Ru3—Al7xv	62.594 (14)	Al9vii—Al8—Si5	161.49 (2)
Al9xii—Ru3—Al7xv	135.585 (16)	Ru1—Al8—Si5	118.64 (2)
Al9—Ru3—Al7xv	123.870 (16)	Si5ix—Al8—Si5	52.363 (19)
Al6xiv—Ru3—Al7xv	102.325 (15)	Al8ii—Al8—Si5	105.493 (16)
Si5xii—Ru3—Al4	156.665 (16)	Al8iv—Al8—Si5	62.348 (19)
Al8xiii—Ru3—Al4	133.431 (13)	Al9ix—Al8—Si5	102.09 (2)
Al6—Ru3—Al4	64.05 (2)	Ru3vii—Al8—Si5ii	111.11 (2)
Al7—Ru3—Al4	63.982 (15)	Ru2—Al8—Si5ii	52.311 (13)
Al9xii—Ru3—Al4	127.93 (2)	Al9vii—Al8—Si5ii	101.04 (2)
Al9—Ru3—Al4	83.669 (15)	Ru1—Al8—Si5ii	116.598 (19)
Al6xiv—Ru3—Al4	98.593 (12)	Si5ix—Al8—Si5ii	125.72 (2)
Al7xv—Ru3—Al4	96.13 (2)	Al8ii—Al8—Si5ii	60.177 (19)
Si5xii—Ru3—Al7ii	93.941 (15)	Al8iv—Al8—Si5ii	103.902 (16)
Al8xiii—Ru3—Al7ii	141.416 (15)	Al9ix—Al8—Si5ii	162.00 (2)
Al6—Ru3—Al7ii	94.038 (15)	Si5—Al8—Si5ii	94.55 (2)
Al7—Ru3—Al7ii	93.18 (2)	Ru3xvii—Al9—Ru3	147.99 (2)
Al9xii—Ru3—Al7ii	139.245 (16)	Ru3xvii—Al9—Al8xiii	148.40 (2)
Al9—Ru3—Al7ii	146.275 (16)	Ru3—Al9—Al8xiii	57.934 (15)
Al6xiv—Ru3—Al7ii	60.377 (15)	Ru3xvii—Al9—Ru1xviii	105.884 (17)
Al7xv—Ru3—Al7ii	61.353 (14)	Ru3—Al9—Ru1xviii	105.607 (17)
Al4—Ru3—Al7ii	62.748 (15)	Al8xiii—Al9—Ru1xviii	59.509 (15)
Ru3—Al4—Ru3iv	113.957 (15)	Ru3xvii—Al9—Al9xii	138.86 (3)
Ru3—Al4—Ru3ii	113.956 (15)	Ru3—Al9—Al9xii	57.609 (18)
Ru3iv—Al4—Ru3ii	113.956 (15)	Al8xiii—Al9—Al9xii	61.789 (18)
Ru3—Al4—Al6iv	109.230 (14)	Ru1xviii—Al9—Al9xii	59.959 (1)
Ru3iv—Al4—Al6iv	55.974 (11)	Ru3xvii—Al9—Al9xvii	57.955 (19)
Ru3ii—Al4—Al6iv	134.84 (2)	Ru3—Al9—Al9xvii	148.22 (3)
Ru3—Al4—Al6ii	134.84 (2)	Al8xiii—Al9—Al9xvii	91.89 (2)
Ru3iv—Al4—Al6ii	109.230 (14)	Ru1xviii—Al9—Al9xvii	60.0
Ru3ii—Al4—Al6ii	55.974 (11)	Al9xii—Al9—Al9xvii	119.687 (4)
Al6iv—Al4—Al6ii	84.26 (3)	Ru3xvii—Al9—Al8ix	56.276 (14)
Ru3—Al4—Al6	55.973 (11)	Ru3—Al9—Al8ix	143.01 (2)
Ru3iv—Al4—Al6	134.84 (2)	Al8xiii—Al9—Al8ix	117.42 (3)
Ru3ii—Al4—Al6	109.231 (14)	Ru1xviii—Al9—Al8ix	57.913 (14)
Al6iv—Al4—Al6	84.26 (3)	Al9xii—Al9—Al8ix	87.05 (2)
Al6ii—Al4—Al6	84.26 (3)	Al9xvii—Al9—Al8ix	56.799 (18)
Ru3—Al4—Al7	56.440 (13)	Ru3xvii—Al9—Si5	53.152 (13)
Ru3iv—Al4—Al7	58.708 (14)	Ru3—Al9—Si5	109.71 (2)
Ru3ii—Al4—Al7	127.88 (3)	Al8xiii—Al9—Si5	154.89 (3)
Al6iv—Al4—Al7	87.091 (13)	Ru1xviii—Al9—Si5	109.909 (19)
Al6ii—Al4—Al7	167.862 (14)	Al9xii—Al9—Si5	93.10 (3)
Al6—Al4—Al7	103.356 (14)	Al9xvii—Al9—Si5	102.00 (3)
Ru3—Al4—Al7iv	127.88 (3)	Al8ix—Al9—Si5	57.332 (16)
Ru3iv—Al4—Al7iv	56.439 (13)	Ru3xvii—Al9—Al6xvii	55.877 (14)
Ru3ii—Al4—Al7iv	58.708 (14)	Ru3—Al9—Al6xvii	110.10 (2)
Al6iv—Al4—Al7iv	103.357 (14)	Al8xiii—Al9—Al6xvii	105.54 (2)
Al6ii—Al4—Al7iv	87.091 (13)	Ru1xviii—Al9—Al6xvii	121.90 (2)
Al6—Al4—Al7iv	167.862 (14)	Al9xii—Al9—Al6xvii	165.26 (3)
Al7—Al4—Al7iv	86.64 (2)	Al9xvii—Al9—Al6xvii	65.56 (2)
Ru3—Al4—Al7ii	58.708 (14)	Al8ix—Al9—Al6xvii	106.35 (2)
Ru3iv—Al4—Al7ii	127.88 (3)	Si5—Al9—Al6xvii	99.26 (2)
Ru3ii—Al4—Al7ii	56.439 (13)	Ru3xvii—Al9—Al7	108.93 (2)
Al6iv—Al4—Al7ii	167.862 (14)	Ru3—Al9—Al7	56.047 (14)
Al6ii—Al4—Al7ii	103.357 (14)	Al8xiii—Al9—Al7	67.695 (18)
Al6—Al4—Al7ii	87.091 (13)	Ru1xviii—Al9—Al7	123.68 (2)
Al7—Al4—Al7ii	86.64 (2)	Al9xii—Al9—Al7	110.49 (3)
Al7iv—Al4—Al7ii	86.64 (2)	Al9xvii—Al9—Al7	105.97 (3)
Ru2—Si5—Si5ix	118.81 (3)	Al8ix—Al9—Al7	160.85 (2)
Ru2—Si5—Ru3xvii	119.762 (18)	Si5—Al9—Al7	126.36 (2)
Si5ix—Si5—Ru3xvii	120.64 (3)	Al6xvii—Al9—Al7	55.443 (16)
Ru2—Si5—Al8ix	167.65 (2)

Symmetry codes: (i) x−y, x, −z+1; (ii) −x+y, −x, z; (iii) −x, −y, −z+1; (iv) −y, x−y, z; (v) y, −x+y, −z+1; (vi) y−2/3, −x+y−1/3, −z+2/3; (vii) −y+2/3, x−y+1/3, z+1/3; (viii) x−1/3, y−2/3, z+1/3; (ix) −x+1/3, −y+2/3, −z+2/3; (x) x−y+1/3, x−1/3, −z+2/3; (xi) −x+y−1/3, −x+1/3, z+1/3; (xii) x−y+2/3, x+1/3, −z+1/3; (xiii) −x+y+1/3, −x+2/3, z−1/3; (xiv) −x+2/3, −y+1/3, −z+1/3; (xv) y, −x+y, −z; (xvi) x−y, x, −z; (xvii) y−1/3, −x+y+1/3, −z+1/3; (xviii) x+1/3, y+2/3, z−1/3.

Heptacosaaluminium decaruthenium tridecasilicon (III). Crystal data

~Ru10(Al0.67Si0.33)41	Dx = 4.652 Mg m−3
Mr = 2122.53	Mo Kα radiation, λ = 0.71073 Å
Orthorhombic, Pnma	Cell parameters from 16783 reflections
a = 15.0794 (2) Å	θ = 3.4–33.8°
b = 11.8713 (2) Å	µ = 6.18 mm−1
c = 16.9291 (3) Å	T = 298 K
V = 3030.50 (9) Å3	Irregular, metallic light silver
Z = 4	0.04 × 0.02 × 0.02 mm
F(000) = 3888.20

Heptacosaaluminium decaruthenium tridecasilicon (III). Data collection

XtaLAB Synergy R, HyPix diffractometer	5672 independent reflections
Radiation source: micro-focus sealed X-ray tube, Mova (Mo) X-ray Source	4940 reflections with I > 2σ(I)
Mirror monochromator	Rint = 0.022
Detector resolution: 10.0000 pixels mm-1	θmax = 33.7°, θmin = 3.2°
ω scans	h = −23→21
Absorption correction: gaussian (CrysAlisPro; Matsumoto et al., 2021)	k = −17→18
Tmin = 0.867, Tmax = 0.929	l = −25→24
33654 measured reflections

Heptacosaaluminium decaruthenium tridecasilicon (III). Refinement

Refinement on F2	Primary atom site location: dual
Least-squares matrix: full	Secondary atom site location: difference Fourier map
R[F2 > 2σ(F2)] = 0.015	w = 1/[σ2(Fo2) + (0.0093P)2 + 1.1293P] where P = (Fo2 + 2Fc2)/3
wR(F2) = 0.026	(Δ/σ)max = 0.003
S = 1.01	Δρmax = 0.78 e Å−3
5672 reflections	Δρmin = −0.74 e Å−3
303 parameters	Extinction correction: SHELXL-2019/3 (Sheldrick, 2015b), Fc*=kFc[1+0.001xFc2λ3/sin(2θ)]-1/4
2 restraints	Extinction coefficient: 0.000039 (4)

Heptacosaaluminium decaruthenium tridecasilicon (III). Special details

Geometry. All esds (except the esd in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell esds are taken into account individually in the estimation of esds in distances, angles and torsion angles; correlations between esds in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell esds is used for estimating esds involving l.s. planes.

Heptacosaaluminium decaruthenium tridecasilicon (III). Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Ų)

	x	y	z	Uiso*/Ueq	Occ. (<1)
Ru1	0.15195 (2)	0.250000	0.76146 (2)	0.00513 (3)
Ru2	0.41069 (2)	0.250000	0.87752 (2)	0.00474 (3)
Ru3	0.45013 (2)	0.250000	0.16946 (2)	0.00542 (3)
Ru4A	0.1834 (2)	0.250000	0.02174 (3)	0.00665 (15)	0.933 (16)
Ru4B	0.1655 (15)	0.250000	0.0209 (4)	0.0036 (13)*	0.067 (16)
Ru5A	0.42722 (8)	0.0630 (2)	0.38435 (7)	0.00501 (13)	0.74 (2)
Ru5B	0.4253 (3)	0.0509 (5)	0.3844 (2)	0.0052 (4)*	0.26 (2)
Ru6	0.17223 (2)	0.06068 (2)	0.25159 (2)	0.00500 (3)
Ru7	0.15518 (2)	0.05637 (2)	0.52078 (2)	0.00672 (3)
Si8	0.20752 (4)	0.250000	0.31440 (3)	0.00625 (11)
Si9A	0.37913 (7)	0.250000	0.62569 (5)	0.0103 (3)	0.727 (3)
Si9B	0.43672 (17)	0.250000	0.59893 (13)	0.0095 (7)	0.273 (3)
Si10A	0.3512 (4)	0.250000	0.38677 (9)	0.0081 (6)	0.85 (2)
Al10B	0.3758 (16)	0.250000	0.3830 (5)	0.0082 (18)*	0.15 (2)
Al11	0.19544 (4)	0.250000	0.47722 (4)	0.0089 (3)	0.65 (6)
Si11	0.19544 (4)	0.250000	0.47722 (4)	0.0089 (3)	0.35 (6)
Al12	0.48579 (4)	0.250000	0.74245 (4)	0.00666 (12)
Al13	0.16461 (4)	0.250000	0.16972 (4)	0.00748 (12)
Al14	0.08651 (5)	0.250000	0.60711 (4)	0.01395 (15)
Al15	0.33501 (5)	0.250000	0.07842 (5)	0.0183 (3)	0.950 (4)
Si16	0.05763 (3)	0.56298 (4)	0.31273 (2)	0.00608 (8)
Si17	0.41912 (3)	0.56490 (4)	0.26431 (2)	0.00638 (8)
Si18	0.19988 (3)	0.62931 (4)	0.45426 (2)	0.00859 (8)
Si19	0.02383 (3)	0.14871 (4)	0.21915 (2)	0.00739 (8)
Al20	0.21386 (3)	0.63959 (4)	0.30297 (3)	0.0109 (2)	0.55 (5)
Si20	0.21386 (3)	0.63959 (4)	0.30297 (3)	0.0109 (2)	0.45 (5)
Al21	0.42109 (3)	0.04580 (4)	0.12868 (3)	0.0072 (2)	0.64 (5)
Si21	0.42109 (3)	0.04580 (4)	0.12868 (3)	0.0072 (2)	0.36 (5)
Al22	0.33859 (3)	0.11923 (4)	0.51409 (3)	0.0115 (2)	0.67 (5)
Si22	0.33859 (3)	0.11923 (4)	0.51409 (3)	0.0115 (2)	0.33 (5)
Al23	0.33880 (3)	0.12822 (4)	0.25123 (3)	0.00721 (9)
Al24	0.25334 (3)	0.04455 (4)	0.38472 (3)	0.00724 (9)
Al25	0.07288 (3)	0.54572 (4)	0.15156 (3)	0.00777 (9)
Al26	0.08203 (3)	0.13043 (4)	0.38371 (3)	0.00734 (9)
Al27	0.21669 (3)	0.06506 (4)	0.09349 (3)	0.01224 (10)
Al28	0.02308 (3)	0.59649 (5)	0.46632 (3)	0.01334 (10)
Al29A	0.3572 (3)	0.64190 (10)	0.3938 (2)	0.0077 (5)	0.79 (2)
Al29B	0.3742 (7)	0.6377 (5)	0.4074 (7)	0.0109 (11)*	0.21 (2)
Al30A	0.28629 (14)	0.6034 (3)	0.16459 (9)	0.0188 (6)	0.754 (11)
Al30B	0.2701 (3)	0.6380 (5)	0.1547 (2)	0.0136 (8)*	0.246 (11)
Al31A	0.01771 (7)	0.250000	0.07942 (7)	0.0153 (5)	0.728 (5)
Al31B	0.0308 (4)	0.1965 (6)	0.0529 (4)	0.015 (2)*	0.104 (3)
Al31C	0.0457 (8)	0.1351 (13)	0.0372 (7)	0.016 (4)*	0.047 (3)
Al32A	0.06370 (5)	0.06801 (7)	0.01653 (4)	0.0151 (3)	0.716 (3)
Al32B	0.0186 (3)	0.0224 (4)	0.0048 (3)	0.0129 (15)*	0.121 (3)

Heptacosaaluminium decaruthenium tridecasilicon (III). Atomic displacement parameters (Ų)

	U11	U22	U33	U12	U13	U23
Ru1	0.00431 (7)	0.00457 (8)	0.00651 (7)	0.000	−0.00060 (6)	0.000
Ru2	0.00433 (7)	0.00403 (7)	0.00587 (7)	0.000	−0.00033 (5)	0.000
Ru3	0.00414 (7)	0.00694 (8)	0.00517 (7)	0.000	−0.00026 (6)	0.000
Ru4A	0.0081 (5)	0.00790 (13)	0.00392 (11)	0.000	0.00035 (13)	0.000
Ru5A	0.00401 (16)	0.0042 (3)	0.00676 (16)	−0.00089 (18)	0.00098 (7)	−0.00108 (17)
Ru6	0.00449 (5)	0.00601 (6)	0.00452 (5)	−0.00090 (4)	−0.00053 (4)	0.00048 (4)
Ru7	0.00645 (5)	0.00859 (6)	0.00513 (5)	0.00172 (4)	−0.00042 (4)	−0.00090 (4)
Si8	0.0067 (3)	0.0055 (3)	0.0065 (3)	0.000	−0.0001 (2)	0.000
Si9A	0.0154 (5)	0.0066 (4)	0.0088 (4)	0.000	−0.0050 (3)	0.000
Si9B	0.0144 (15)	0.0052 (11)	0.0091 (11)	0.000	−0.0036 (9)	0.000
Si10A	0.0098 (14)	0.0055 (4)	0.0090 (4)	0.000	−0.0013 (4)	0.000
Al11	0.0091 (4)	0.0069 (4)	0.0108 (4)	0.000	−0.0005 (2)	0.000
Si11	0.0091 (4)	0.0069 (4)	0.0108 (4)	0.000	−0.0005 (2)	0.000
Al12	0.0060 (3)	0.0063 (3)	0.0076 (3)	0.000	0.0008 (2)	0.000
Al13	0.0108 (3)	0.0065 (3)	0.0051 (3)	0.000	0.0012 (2)	0.000
Al14	0.0090 (3)	0.0204 (4)	0.0124 (3)	0.000	0.0002 (3)	0.000
Al15	0.0172 (5)	0.0158 (5)	0.0219 (5)	0.000	−0.0147 (3)	0.000
Si16	0.00579 (18)	0.00568 (19)	0.00676 (18)	0.00030 (15)	−0.00049 (14)	−0.00084 (14)
Si17	0.00719 (18)	0.00518 (19)	0.00678 (18)	0.00049 (15)	0.00114 (14)	0.00033 (14)
Si18	0.0088 (2)	0.0083 (2)	0.00861 (19)	0.00025 (16)	−0.00109 (15)	0.00063 (15)
Si19	0.00649 (18)	0.0067 (2)	0.00891 (19)	0.00029 (16)	0.00037 (14)	−0.00100 (15)
Al20	0.0094 (3)	0.0074 (3)	0.0159 (3)	−0.00202 (17)	0.00544 (17)	−0.00150 (17)
Si20	0.0094 (3)	0.0074 (3)	0.0159 (3)	−0.00202 (17)	0.00544 (17)	−0.00150 (17)
Al21	0.0072 (3)	0.0072 (3)	0.0072 (3)	−0.00030 (17)	0.00040 (15)	−0.00223 (16)
Si21	0.0072 (3)	0.0072 (3)	0.0072 (3)	−0.00030 (17)	0.00040 (15)	−0.00223 (16)
Al22	0.0143 (3)	0.0126 (3)	0.0075 (3)	−0.00185 (19)	−0.00166 (17)	0.00134 (17)
Si22	0.0143 (3)	0.0126 (3)	0.0075 (3)	−0.00185 (19)	−0.00166 (17)	0.00134 (17)
Al23	0.0067 (2)	0.0077 (2)	0.0072 (2)	0.00081 (17)	0.00118 (16)	0.00033 (16)
Al24	0.0070 (2)	0.0080 (2)	0.0068 (2)	−0.00033 (17)	−0.00041 (16)	0.00027 (16)
Al25	0.0073 (2)	0.0074 (2)	0.0086 (2)	−0.00030 (17)	0.00002 (16)	0.00109 (17)
Al26	0.0060 (2)	0.0076 (2)	0.0085 (2)	−0.00025 (17)	−0.00033 (16)	0.00000 (16)
Al27	0.0154 (2)	0.0077 (2)	0.0135 (2)	−0.0003 (2)	0.00641 (19)	−0.00069 (18)
Al28	0.0115 (2)	0.0150 (3)	0.0135 (2)	−0.0029 (2)	0.00047 (18)	0.00552 (19)
Al29A	0.0139 (8)	0.0046 (4)	0.0047 (6)	0.0026 (3)	0.0010 (6)	−0.0011 (3)
Al30A	0.0182 (6)	0.0278 (11)	0.0103 (4)	−0.0093 (7)	0.0000 (4)	−0.0088 (5)
Al31A	0.0090 (5)	0.0215 (9)	0.0155 (6)	0.000	−0.0021 (4)	0.000
Al32A	0.0167 (5)	0.0181 (5)	0.0105 (4)	0.0000 (3)	0.0052 (3)	0.0019 (3)

Heptacosaaluminium decaruthenium tridecasilicon (III). Geometric parameters (Å, º)

Ru1—Si17i	2.4453 (4)	Si9B—Al25ii	2.5876 (10)
Ru1—Si17ii	2.4453 (4)	Si9B—Al25i	2.5876 (10)
Ru1—Al12iii	2.5063 (7)	Si10A—Al31Avi	2.576 (5)
Ru1—Al20ii	2.5113 (5)	Si10A—Al22vii	2.6631 (16)
Ru1—Al20i	2.5113 (5)	Si10A—Al22	2.6631 (16)
Ru1—Al30Bi	2.534 (3)	Si10A—Al23vii	2.7183 (11)
Ru1—Al30Bii	2.534 (3)	Si10A—Al23	2.7183 (11)
Ru1—Al30Ai	2.5661 (12)	Si10A—Al11	2.803 (5)
Ru1—Al30Aii	2.5661 (12)	Al10B—Al31Avi	2.23 (2)
Ru1—Al29Aii	2.585 (4)	Al10B—Al31Bv	2.65 (2)
Ru1—Al29Ai	2.585 (4)	Al10B—Al31Bvi	2.65 (2)
Ru1—Al14	2.7932 (7)	Al10B—Al23vii	2.716 (7)
Ru2—Si16i	2.5220 (4)	Al10B—Al23	2.716 (7)
Ru2—Si16ii	2.5220 (4)	Al10B—Al22vii	2.766 (10)
Ru2—Al12	2.5516 (6)	Al10B—Al22	2.766 (10)
Ru2—Si18i	2.5536 (5)	Al11—Al26vii	2.7287 (7)
Ru2—Si18ii	2.5536 (4)	Al11—Al26	2.7288 (7)
Ru2—Al28ii	2.5649 (5)	Al11—Al22vii	2.7310 (7)
Ru2—Al28i	2.5649 (5)	Al11—Al22	2.7310 (7)
Ru2—Al20i	2.6150 (5)	Al11—Al14	2.7447 (9)
Ru2—Al20ii	2.6150 (5)	Al12—Si16ii	2.6025 (5)
Ru2—Al14iv	2.6640 (7)	Al12—Si16i	2.6025 (5)
Ru3—Al15	2.3213 (8)	Al12—Si17xii	2.6263 (6)
Ru3—Si19v	2.4975 (4)	Al12—Si17xiii	2.6263 (6)
Ru3—Si19vi	2.4975 (4)	Al12—Al14iv	2.9652 (10)
Ru3—Al21vii	2.5582 (5)	Al13—Si19vii	2.5792 (7)
Ru3—Al21	2.5582 (5)	Al13—Si19	2.5793 (7)
Ru3—Al26v	2.6041 (5)	Al13—Al27	2.6650 (6)
Ru3—Al26vi	2.6041 (5)	Al13—Al27vii	2.6650 (6)
Ru3—Al23vii	2.6124 (5)	Al13—Al31A	2.6914 (12)
Ru3—Al23	2.6124 (5)	Al13—Al31B	2.896 (6)
Ru4A—Al31B	2.445 (6)	Al13—Al31Bvii	2.896 (6)
Ru4A—Al31Bvii	2.445 (6)	Al14—Al30Bii	2.663 (3)
Ru4A—Al15	2.479 (3)	Al14—Al30Bi	2.663 (3)
Ru4A—Al31Cvii	2.498 (12)	Al14—Al28xi	2.7563 (7)
Ru4A—Al31C	2.498 (12)	Al14—Al28xiv	2.7563 (7)
Ru4A—Al29Bviii	2.505 (6)	Al14—Al30Aii	2.7665 (17)
Ru4A—Al29Bix	2.505 (6)	Al14—Al30Ai	2.7665 (16)
Ru4A—Al13	2.5211 (8)	Al15—Si18viii	2.5976 (8)
Ru4A—Si18ix	2.541 (2)	Al15—Si18ix	2.5976 (8)
Ru4A—Si18viii	2.541 (2)	Al15—Al27vii	2.8406 (7)
Ru4A—Al27	2.5588 (9)	Al15—Al27	2.8406 (7)
Ru4A—Al27vii	2.5588 (9)	Al15—Al21	2.8784 (6)
Ru4B—Al31B	2.20 (2)	Al15—Al21vii	2.8784 (6)
Ru4B—Al31Bvii	2.20 (2)	Si16—Si17xv	2.4623 (6)
Ru4B—Al31Cvii	2.28 (2)	Si16—Al20	2.5307 (6)
Ru4B—Al31C	2.28 (2)	Si16—Al26vii	2.6175 (6)
Ru4B—Al29Bviii	2.413 (11)	Si16—Al21xvi	2.6250 (6)
Ru4B—Al29Bix	2.413 (11)	Si16—Al28	2.6816 (6)
Ru4B—Al31A	2.44 (2)	Si16—Al25	2.7456 (6)
Ru4B—Al13	2.520 (7)	Si17—Al29A	2.5512 (15)
Ru4B—Al29Aviii	2.529 (7)	Si17—Al23vii	2.6024 (6)
Ru4B—Al29Aix	2.529 (7)	Si17—Al21vii	2.6456 (6)
Ru4B—Al27	2.632 (8)	Si17—Al30A	2.659 (3)
Ru4B—Al27vii	2.632 (8)	Si17—Al29B	2.660 (8)
Ru5A—Al10B	2.352 (9)	Si17—Al25vi	2.7306 (6)
Ru5A—Al32Bvi	2.377 (5)	Si18—Al24vii	2.5092 (6)
Ru5A—Al31Cvi	2.385 (12)	Si18—Al20	2.5727 (6)
Ru5A—Al32Bx	2.419 (5)	Si18—Al29A	2.589 (3)
Ru5A—Al31Bvi	2.466 (6)	Si18—Al28	2.7022 (7)
Ru5A—Si19vi	2.4958 (19)	Si18—Al29B	2.748 (7)
Ru5A—Si10A	2.499 (4)	Si18—Al27xvii	2.7785 (6)
Ru5A—Si17vii	2.5395 (19)	Si19—Si19vii	2.4048 (9)
Ru5A—Al29Bvii	2.543 (7)	Si19—Al31A	2.6552 (12)
Ru5A—Al25v	2.6190 (16)	Si19—Al25vii	2.6803 (6)
Ru5A—Al24	2.6311 (14)	Si19—Al23xv	2.8453 (6)
Ru5A—Al29Avii	2.656 (4)	Si19—Al31B	2.874 (6)
Ru5B—Al32Bvi	2.368 (6)	Al20—Al30A	2.6202 (10)
Ru5B—Al32Bx	2.372 (6)	Al20—Al20xviii	2.6215 (10)
Ru5B—Al29Bvii	2.400 (9)	Al20—Al30B	2.650 (3)
Ru5B—Si17vii	2.456 (5)	Al20—Al29A	2.653 (6)
Ru5B—Al31Cvi	2.460 (13)	Al20—Al24vii	2.6549 (7)
Ru5B—Al10B	2.479 (9)	Al20—Al29B	2.996 (14)
Ru5B—Al29Avii	2.513 (7)	Al21—Al23	2.6080 (6)
Ru5B—Si19vi	2.575 (5)	Al21—Al26vi	2.6350 (6)
Ru5B—Al25v	2.576 (4)	Al21—Al30Avii	2.764 (3)
Ru5B—Al31Bvi	2.578 (8)	Al21—Al28v	2.7938 (7)
Ru5B—Al24	2.594 (4)	Al21—Al28viii	2.9369 (7)
Ru5B—Si10A	2.615 (6)	Al22—Al32Ax	2.6670 (10)
Ru6—Si16vii	2.4926 (4)	Al22—Al24	2.6898 (6)
Ru6—Si19	2.5300 (4)	Al22—Al27x	2.6996 (7)
Ru6—Si8	2.5426 (3)	Al22—Al32Bx	2.737 (5)
Ru6—Al24	2.5715 (5)	Al23—Al24	2.7846 (6)
Ru6—Al25vii	2.5898 (5)	Al24—Al29Avii	2.716 (3)
Ru6—Al20vii	2.6083 (5)	Al24—Al26	2.7772 (6)
Ru6—Al23	2.6367 (5)	Al25—Al32Avii	2.6586 (8)
Ru6—Al13	2.6429 (4)	Al25—Al27vii	2.7200 (7)
Ru6—Al26	2.7455 (5)	Al25—Al32Bvii	2.738 (4)
Ru6—Al27	2.7596 (5)	Al26—Al26vii	2.8388 (10)
Ru6—Al30Avii	2.987 (2)	Al27—Al30Avii	2.5594 (16)
Ru7—Al21x	2.4760 (5)	Al27—Al32A	2.6497 (10)
Ru7—Al11	2.4892 (3)	Al27—Al30Bvii	2.744 (4)
Ru7—Si18vii	2.5655 (5)	Al28—Al28xiv	2.6519 (10)
Ru7—Al30Ai	2.6492 (8)	Al29A—Al32Axvii	2.551 (5)
Ru7—Al27x	2.7068 (5)	Al29A—Al29Axviii	2.567 (2)
Ru7—Al30Bi	2.711 (3)	Al29A—Al29Bxviii	2.639 (6)
Ru7—Al26	2.7156 (5)	Al29B—Al32Axvii	2.229 (14)
Ru7—Al28xi	2.7385 (5)	Al29B—Al31Cxvii	2.507 (19)
Ru7—Al24	2.7416 (5)	Al29B—Al29Bxviii	2.666 (12)
Ru7—Al28vii	2.8479 (5)	Al29B—Al32Bxvii	2.684 (15)
Ru7—Al22	2.8669 (5)	Al30A—Al30B	0.507 (4)
Si8—Si10A	2.489 (5)	Al30B—Al30Bxviii	2.659 (12)
Si8—Al13	2.5334 (8)	Al31A—Al31Bvii	0.802 (8)
Si8—Al26vii	2.6404 (7)	Al31A—Al31B	0.802 (8)
Si8—Al26	2.6404 (7)	Al31A—Al31C	1.596 (16)
Si8—Al23vii	2.6744 (7)	Al31A—Al31Cvii	1.596 (16)
Si8—Al23	2.6744 (7)	Al31A—Al32Avii	2.5064 (11)
Si8—Al11	2.7624 (9)	Al31A—Al32A	2.5064 (11)
Si8—Al10B	2.79 (2)	Al31B—Al31C	0.808 (15)
Si8—Al24vii	2.8005 (5)	Al31B—Al31Bvii	1.269 (15)
Si9A—Si9B	0.979 (3)	Al31B—Al32A	1.718 (8)
Si9A—Al22vii	2.5205 (8)	Al31B—Al31Cvii	2.028 (19)
Si9A—Al22	2.5205 (8)	Al31B—Al32B	2.229 (9)
Si9A—Al12	2.5484 (10)	Al31C—Al32A	0.912 (16)
Si9A—Al25ii	2.5683 (6)	Al31C—Al32B	1.503 (16)
Si9A—Al25i	2.5683 (6)	Al31C—Al32Bxix	2.223 (15)
Si9A—Al30Bi	2.659 (7)	Al31C—Al31Cvii	2.73 (3)
Si9A—Al30Bii	2.659 (7)	Al32A—Al32B	0.892 (4)
Si9B—Al12	2.540 (2)	Al32A—Al32Bxix	1.680 (5)
Si9B—Al22vii	2.5812 (19)	Al32A—Al32Axix	2.5713 (17)
Si9B—Al22	2.5812 (19)	Al32B—Al32Bxix	0.790 (9)
Si17i—Ru1—Si17ii	127.96 (2)	Ru2ix—Si18—Al15ii	88.28 (2)
Si17i—Ru1—Al12iii	64.049 (11)	Ru7vii—Si18—Al15ii	93.755 (17)
Si17ii—Ru1—Al12iii	64.049 (11)	Al20—Si18—Al15ii	142.75 (2)
Si17i—Ru1—Al20ii	144.754 (15)	Al29A—Si18—Al15ii	118.30 (8)
Si17ii—Ru1—Al20ii	83.029 (15)	Al24vii—Si18—Al28	103.52 (2)
Al12iii—Ru1—Al20ii	144.381 (13)	Ru4Aii—Si18—Al28	136.96 (5)
Si17i—Ru1—Al20i	83.029 (15)	Ru2ix—Si18—Al28	58.339 (14)
Si17ii—Ru1—Al20i	144.754 (15)	Ru7vii—Si18—Al28	65.395 (15)
Al12iii—Ru1—Al20i	144.381 (14)	Al20—Si18—Al28	99.38 (2)
Al20ii—Ru1—Al20i	62.92 (2)	Al29A—Si18—Al28	160.49 (10)
Si17i—Ru1—Al30Bi	75.28 (17)	Al15ii—Si18—Al28	79.54 (2)
Si17ii—Ru1—Al30Bi	133.55 (13)	Al24vii—Si18—Ru4Bii	112.7 (3)
Al12iii—Ru1—Al30Bi	116.43 (11)	Ru4Aii—Si18—Ru4Bii	4.2 (3)
Al20ii—Ru1—Al30Bi	95.71 (13)	Ru2ix—Si18—Ru4Bii	113.67 (18)
Al20i—Ru1—Al30Bi	63.37 (8)	Ru7vii—Si18—Ru4Bii	117.73 (11)
Si17i—Ru1—Al30Bii	133.55 (13)	Al20—Si18—Ru4Bii	109.0 (2)
Si17ii—Ru1—Al30Bii	75.28 (17)	Al29A—Si18—Ru4Bii	56.7 (3)
Al12iii—Ru1—Al30Bii	116.43 (11)	Al15ii—Si18—Ru4Bii	61.8 (3)
Al20ii—Ru1—Al30Bii	63.37 (8)	Al28—Si18—Ru4Bii	141.1 (3)
Al20i—Ru1—Al30Bii	95.71 (13)	Al24vii—Si18—Al29B	65.62 (12)
Al30Bi—Ru1—Al30Bii	63.3 (3)	Ru4Aii—Si18—Al29B	56.4 (2)
Si17i—Ru1—Al30Ai	64.04 (9)	Ru2ix—Si18—Al29B	117.2 (3)
Si17ii—Ru1—Al30Ai	141.35 (6)	Ru7vii—Si18—Al29B	114.16 (19)
Al12iii—Ru1—Al30Ai	110.24 (6)	Al20—Si18—Al29B	68.5 (3)
Al20ii—Ru1—Al30Ai	103.90 (7)	Al29A—Si18—Al29B	6.68 (19)
Al20i—Ru1—Al30Ai	62.12 (2)	Al15ii—Si18—Al29B	114.0 (2)
Al30Bi—Ru1—Al30Ai	11.38 (9)	Al28—Si18—Al29B	166.2 (2)
Al30Bii—Ru1—Al30Ai	74.4 (3)	Ru4Bii—Si18—Al29B	52.3 (4)
Si17i—Ru1—Al30Aii	141.35 (6)	Al24vii—Si18—Al27xvii	91.53 (2)
Si17ii—Ru1—Al30Aii	64.04 (9)	Ru4Aii—Si18—Al27xvii	57.299 (16)
Al12iii—Ru1—Al30Aii	110.24 (6)	Ru2ix—Si18—Al27xvii	151.80 (2)
Al20ii—Ru1—Al30Aii	62.12 (2)	Ru7vii—Si18—Al27xvii	60.707 (14)
Al20i—Ru1—Al30Aii	103.90 (7)	Al20—Si18—Al27xvii	145.13 (2)
Al30Bi—Ru1—Al30Aii	74.4 (3)	Al29A—Si18—Al27xvii	86.36 (11)
Al30Bii—Ru1—Al30Aii	11.38 (9)	Al15ii—Si18—Al27xvii	63.69 (2)
Al30Ai—Ru1—Al30Aii	85.39 (18)	Al28—Si18—Al27xvii	110.06 (2)
Si17i—Ru1—Al29Aii	113.93 (8)	Ru4Bii—Si18—Al27xvii	57.10 (11)
Si17ii—Ru1—Al29Aii	60.88 (3)	Al29B—Si18—Al27xvii	79.7 (3)
Al12iii—Ru1—Al29Aii	88.24 (10)	Si19vii—Si19—Ru5Axv	114.07 (6)
Al20ii—Ru1—Al29Aii	62.72 (10)	Si19vii—Si19—Ru3xv	61.220 (10)
Al20i—Ru1—Al29Aii	93.44 (7)	Ru5Axv—Si19—Ru3xv	117.82 (4)
Al30Bi—Ru1—Al29Aii	154.64 (12)	Si19vii—Si19—Ru6	114.396 (10)
Al30Bii—Ru1—Al29Aii	112.49 (16)	Ru5Axv—Si19—Ru6	120.02 (5)
Al30Ai—Ru1—Al29Aii	155.48 (6)	Ru3xv—Si19—Ru6	115.378 (16)
Al30Aii—Ru1—Al29Aii	103.68 (10)	Si19vii—Si19—Ru5Bxv	116.81 (12)
Si17i—Ru1—Al29Ai	60.88 (3)	Ru5Axv—Si19—Ru5Bxv	2.78 (10)
Si17ii—Ru1—Al29Ai	113.93 (8)	Ru3xv—Si19—Ru5Bxv	118.33 (8)
Al12iii—Ru1—Al29Ai	88.24 (10)	Ru6—Si19—Ru5Bxv	118.15 (10)
Al20ii—Ru1—Al29Ai	93.44 (7)	Si19vii—Si19—Al13	62.212 (12)
Al20i—Ru1—Al29Ai	62.72 (10)	Ru5Axv—Si19—Al13	116.28 (4)
Al30Bi—Ru1—Al29Ai	112.49 (15)	Ru3xv—Si19—Al13	112.756 (19)
Al30Bii—Ru1—Al29Ai	154.64 (12)	Ru6—Si19—Al13	62.290 (14)
Al30Ai—Ru1—Al29Ai	103.68 (10)	Ru5Bxv—Si19—Al13	117.66 (10)
Al30Aii—Ru1—Al29Ai	155.48 (6)	Si19vii—Si19—Al31A	63.073 (15)
Al29Aii—Ru1—Al29Ai	59.54 (7)	Ru5Axv—Si19—Al31A	62.54 (5)
Si17i—Ru1—Al14	82.158 (12)	Ru3xv—Si19—Al31A	116.05 (2)
Si17ii—Ru1—Al14	82.158 (12)	Ru6—Si19—Al31A	114.28 (3)
Al12iii—Ru1—Al14	67.80 (2)	Ru5Bxv—Si19—Al31A	65.01 (12)
Al20ii—Ru1—Al14	123.122 (17)	Al13—Si19—Al31A	61.86 (3)
Al20i—Ru1—Al14	123.122 (17)	Si19vii—Si19—Al25vii	149.448 (13)
Al30Bi—Ru1—Al14	59.76 (8)	Ru5Axv—Si19—Al25vii	60.67 (5)
Al30Bii—Ru1—Al14	59.76 (8)	Ru3xv—Si19—Al25vii	149.29 (2)
Al30Ai—Ru1—Al14	61.99 (3)	Ru6—Si19—Al25vii	59.526 (14)
Al30Aii—Ru1—Al14	61.99 (3)	Ru5Bxv—Si19—Al25vii	58.67 (10)
Al29Aii—Ru1—Al14	142.33 (5)	Al13—Si19—Al25vii	92.054 (18)
Al29Ai—Ru1—Al14	142.33 (5)	Al31A—Si19—Al25vii	91.10 (2)
Si16i—Ru2—Si16ii	123.36 (2)	Si19vii—Si19—Al23xv	94.905 (13)
Si16i—Ru2—Al12	61.718 (10)	Ru5Axv—Si19—Al23xv	61.08 (3)
Si16ii—Ru2—Al12	61.718 (10)	Ru3xv—Si19—Al23xv	58.108 (13)
Si16i—Ru2—Si18i	81.434 (14)	Ru6—Si19—Al23xv	142.54 (2)
Si16ii—Ru2—Si18i	147.022 (15)	Ru5Bxv—Si19—Al23xv	61.03 (8)
Al12—Ru2—Si18i	138.220 (13)	Al13—Si19—Al23xv	154.71 (2)
Si16i—Ru2—Si18ii	147.022 (15)	Al31A—Si19—Al23xv	99.30 (3)
Si16ii—Ru2—Si18ii	81.434 (14)	Al25vii—Si19—Al23xv	105.80 (2)
Al12—Ru2—Si18ii	138.220 (13)	Si19vii—Si19—Al31B	78.60 (16)
Si18i—Ru2—Si18ii	68.26 (2)	Ru5Axv—Si19—Al31B	54.13 (13)
Si16i—Ru2—Al28ii	143.769 (17)	Ru3xv—Si19—Al31B	131.36 (16)
Si16ii—Ru2—Al28ii	63.620 (15)	Ru6—Si19—Al31B	105.19 (13)
Al12—Ru2—Al28ii	110.636 (16)	Ru5Bxv—Si19—Al31B	56.15 (17)
Si18i—Ru2—Al28ii	110.775 (16)	Al13—Si19—Al31B	63.90 (11)
Si18ii—Ru2—Al28ii	63.730 (15)	Al31A—Si19—Al31B	16.07 (16)
Si16i—Ru2—Al28i	63.620 (15)	Al25vii—Si19—Al31B	75.04 (16)
Si16ii—Ru2—Al28i	143.769 (17)	Al23xv—Si19—Al31B	103.02 (11)
Al12—Ru2—Al28i	110.636 (16)	Ru1ix—Al20—Si16	162.93 (2)
Si18i—Ru2—Al28i	63.730 (15)	Ru1ix—Al20—Si18	111.67 (2)
Si18ii—Ru2—Al28i	110.775 (16)	Si16—Al20—Si18	80.894 (18)
Al28ii—Ru2—Al28i	90.55 (2)	Ru1ix—Al20—Ru6vii	125.197 (19)
Si16i—Ru2—Al20i	58.997 (14)	Si16—Al20—Ru6vii	58.004 (14)
Si16ii—Ru2—Al20i	111.555 (15)	Si18—Al20—Ru6vii	105.61 (2)
Al12—Ru2—Al20i	83.470 (17)	Ru1ix—Al20—Ru2ix	116.882 (18)
Si18i—Ru2—Al20i	59.691 (15)	Si16—Al20—Ru2ix	58.669 (14)
Si18ii—Ru2—Al20i	93.313 (15)	Si18—Al20—Ru2ix	58.968 (14)
Al28ii—Ru2—Al20i	156.733 (17)	Ru6vii—Al20—Ru2ix	116.420 (18)
Al28i—Ru2—Al20i	101.912 (16)	Ru1ix—Al20—Al30A	59.97 (3)
Si16i—Ru2—Al20ii	111.555 (15)	Si16—Al20—Al30A	112.80 (3)
Si16ii—Ru2—Al20ii	58.997 (14)	Si18—Al20—Al30A	156.41 (9)
Al12—Ru2—Al20ii	83.470 (17)	Ru6vii—Al20—Al30A	69.68 (6)
Si18i—Ru2—Al20ii	93.313 (15)	Ru2ix—Al20—Al30A	144.39 (9)
Si18ii—Ru2—Al20ii	59.691 (15)	Ru1ix—Al20—Al20xviii	58.538 (11)
Al28ii—Ru2—Al20ii	101.912 (16)	Si16—Al20—Al20xviii	111.059 (14)
Al28i—Ru2—Al20ii	156.733 (17)	Si18—Al20—Al20xviii	92.718 (15)
Al20i—Ru2—Al20ii	60.16 (2)	Ru6vii—Al20—Al20xviii	155.712 (11)
Si16i—Ru2—Al14iv	81.602 (12)	Ru2ix—Al20—Al20xviii	59.918 (10)
Si16ii—Ru2—Al14iv	81.602 (12)	Al30A—Al20—Al20xviii	99.43 (8)
Al12—Ru2—Al14iv	69.26 (2)	Ru1ix—Al20—Al30B	58.73 (7)
Si18i—Ru2—Al14iv	126.881 (15)	Si16—Al20—Al30B	110.92 (8)
Si18ii—Ru2—Al14iv	126.881 (15)	Si18—Al20—Al30B	165.71 (13)
Al28ii—Ru2—Al14iv	63.592 (15)	Ru6vii—Al20—Al30B	75.79 (10)
Al28i—Ru2—Al14iv	63.592 (15)	Ru2ix—Al20—Al30B	133.67 (16)
Al20i—Ru2—Al14iv	139.634 (15)	Al30A—Al20—Al30B	11.01 (8)
Al20ii—Ru2—Al14iv	139.634 (15)	Al20xviii—Al20—Al30B	90.41 (13)
Al15—Ru3—Si19v	146.524 (15)	Ru1ix—Al20—Al29A	60.00 (3)
Al15—Ru3—Si19vi	146.524 (15)	Si16—Al20—Al29A	136.44 (3)
Si19v—Ru3—Si19vi	57.56 (2)	Si18—Al20—Al29A	59.37 (3)
Al15—Ru3—Al21vii	72.113 (11)	Ru6vii—Al20—Al29A	113.50 (3)
Si19v—Ru3—Al21vii	79.846 (14)	Ru2ix—Al20—Al29A	107.50 (3)
Si19vi—Ru3—Al21vii	137.403 (15)	Al30A—Al20—Al29A	100.36 (6)
Al15—Ru3—Al21	72.112 (11)	Al20xviii—Al20—Al29A	89.41 (3)
Si19v—Ru3—Al21	137.404 (15)	Al30B—Al20—Al29A	106.75 (11)
Si19vi—Ru3—Al21	79.847 (14)	Ru1ix—Al20—Al24vii	113.26 (2)
Al21vii—Ru3—Al21	142.73 (2)	Si16—Al20—Al24vii	83.043 (19)
Al15—Ru3—Al26v	109.98 (2)	Si18—Al20—Al24vii	57.344 (17)
Si19v—Ru3—Al26v	70.039 (14)	Ru6vii—Al20—Al24vii	58.487 (14)
Si19vi—Ru3—Al26v	100.573 (15)	Ru2ix—Al20—Al24vii	108.797 (19)
Al21vii—Ru3—Al26v	61.378 (15)	Al30A—Al20—Al24vii	103.75 (9)
Al21—Ru3—Al26v	123.640 (16)	Al20xviii—Al20—Al24vii	145.427 (14)
Al15—Ru3—Al26vi	109.98 (2)	Al30B—Al20—Al24vii	114.60 (16)
Si19v—Ru3—Al26vi	100.573 (15)	Al29A—Al20—Al24vii	61.56 (3)
Si19vi—Ru3—Al26vi	70.039 (14)	Ru1ix—Al20—Al29B	61.22 (13)
Al21vii—Ru3—Al26vi	123.640 (16)	Si16—Al20—Al29B	135.26 (13)
Al21—Ru3—Al26vi	61.378 (15)	Si18—Al20—Al29B	58.55 (11)
Al26v—Ru3—Al26vi	66.06 (2)	Ru6vii—Al20—Al29B	112.61 (11)
Al15—Ru3—Al23vii	82.61 (2)	Ru2ix—Al20—Al29B	107.37 (10)
Si19v—Ru3—Al23vii	67.631 (14)	Al30A—Al20—Al29B	100.96 (12)
Si19vi—Ru3—Al23vii	98.759 (15)	Al20xviii—Al20—Al29B	90.42 (11)
Al21vii—Ru3—Al23vii	60.570 (14)	Al30B—Al20—Al29B	107.52 (16)
Al21—Ru3—Al23vii	123.873 (15)	Al29A—Al20—Al29B	1.27 (13)
Al26v—Ru3—Al23vii	111.863 (15)	Al24vii—Al20—Al29B	60.35 (12)
Al26vi—Ru3—Al23vii	167.327 (15)	Ru7xx—Al21—Ru3	137.97 (2)
Al15—Ru3—Al23	82.61 (2)	Ru7xx—Al21—Al23	123.35 (2)
Si19v—Ru3—Al23	98.760 (15)	Ru3—Al21—Al23	60.742 (15)
Si19vi—Ru3—Al23	67.632 (14)	Ru7xx—Al21—Si16v	113.707 (19)
Al21vii—Ru3—Al23	123.873 (16)	Ru3—Al21—Si16v	103.294 (18)
Al21—Ru3—Al23	60.570 (14)	Al23—Al21—Si16v	104.90 (2)
Al26v—Ru3—Al23	167.328 (15)	Ru7xx—Al21—Al26vi	123.77 (2)
Al26vi—Ru3—Al23	111.862 (15)	Ru3—Al21—Al26vi	60.167 (15)
Al23vii—Ru3—Al23	67.20 (2)	Al23—Al21—Al26vi	111.01 (2)
Al31B—Ru4A—Al31Bvii	30.1 (4)	Si16v—Al21—Al26vi	59.684 (17)
Al31B—Ru4A—Al15	141.68 (13)	Ru7xx—Al21—Si17vii	113.06 (2)
Al31Bvii—Ru4A—Al15	141.68 (13)	Ru3—Al21—Si17vii	103.791 (18)
Al31B—Ru4A—Al31Cvii	48.4 (5)	Al23—Al21—Si17vii	59.380 (16)
Al31Bvii—Ru4A—Al31Cvii	18.8 (3)	Si16v—Al21—Si17vii	55.701 (16)
Al15—Ru4A—Al31Cvii	136.5 (3)	Al26vi—Al21—Si17vii	105.59 (2)
Al31B—Ru4A—Al31C	18.8 (3)	Ru7xx—Al21—Al30Avii	60.44 (5)
Al31Bvii—Ru4A—Al31C	48.4 (5)	Ru3—Al21—Al30Avii	132.37 (5)
Al15—Ru4A—Al31C	136.5 (3)	Al23—Al21—Al30Avii	73.48 (6)
Al31Cvii—Ru4A—Al31C	66.2 (7)	Si16v—Al21—Al30Avii	100.28 (3)
Al31B—Ru4A—Al29Bviii	72.6 (4)	Al26vi—Al21—Al30Avii	159.92 (3)
Al31Bvii—Ru4A—Al29Bviii	88.7 (3)	Si17vii—Al21—Al30Avii	58.84 (3)
Al15—Ru4A—Al29Bviii	128.2 (2)	Ru7xx—Al21—Al28v	62.275 (15)
Al31Cvii—Ru4A—Al29Bviii	94.8 (3)	Ru3—Al21—Al28v	129.35 (2)
Al31C—Ru4A—Al29Bviii	60.1 (4)	Al23—Al21—Al28v	161.21 (2)
Al31B—Ru4A—Al29Bix	88.7 (3)	Si16v—Al21—Al28v	59.224 (16)
Al31Bvii—Ru4A—Al29Bix	72.6 (4)	Al26vi—Al21—Al28v	71.198 (18)
Al15—Ru4A—Al29Bix	128.2 (2)	Si17vii—Al21—Al28v	101.86 (2)
Al31Cvii—Ru4A—Al29Bix	60.1 (4)	Al30Avii—Al21—Al28v	98.28 (5)
Al31C—Ru4A—Al29Bix	94.8 (3)	Ru7xx—Al21—Al15	89.143 (19)
Al29Bviii—Ru4A—Al29Bix	64.3 (3)	Ru3—Al21—Al15	50.129 (15)
Al31B—Ru4A—Al13	71.34 (15)	Al23—Al21—Al15	72.82 (2)
Al31Bvii—Ru4A—Al13	71.34 (15)	Si16v—Al21—Al15	151.61 (2)
Al15—Ru4A—Al13	73.69 (5)	Al26vi—Al21—Al15	94.05 (2)
Al31Cvii—Ru4A—Al13	78.6 (3)	Si17vii—Al21—Al15	132.05 (3)
Al31C—Ru4A—Al13	78.6 (3)	Al30Avii—Al21—Al15	105.85 (3)
Al29Bviii—Ru4A—Al13	136.8 (3)	Al28v—Al21—Al15	125.96 (3)
Al29Bix—Ru4A—Al13	136.8 (3)	Ru7xx—Al21—Al28viii	62.811 (15)
Al31B—Ru4A—Si18ix	153.56 (16)	Ru3—Al21—Al28viii	90.535 (18)
Al31Bvii—Ru4A—Si18ix	127.1 (2)	Al23—Al21—Al28viii	143.52 (2)
Al15—Ru4A—Si18ix	62.31 (7)	Si16v—Al21—Al28viii	103.27 (2)
Al31Cvii—Ru4A—Si18ix	108.4 (4)	Al26vi—Al21—Al28viii	65.378 (17)
Al31C—Ru4A—Si18ix	158.6 (3)	Si17vii—Al21—Al28viii	156.51 (2)
Al29Bviii—Ru4A—Si18ix	101.1 (3)	Al30Avii—Al21—Al28viii	123.23 (5)
Al29Bix—Ru4A—Si18ix	66.0 (2)	Al28v—Al21—Al28viii	55.06 (2)
Al13—Ru4A—Si18ix	121.64 (8)	Al15—Al21—Al28viii	71.34 (2)
Al31B—Ru4A—Si18viii	127.1 (2)	Si9A—Al22—Si9B	22.09 (6)
Al31Bvii—Ru4A—Si18viii	153.56 (16)	Si9A—Al22—Ru5A	130.73 (6)
Al15—Ru4A—Si18viii	62.31 (7)	Si9B—Al22—Ru5A	108.84 (7)
Al31Cvii—Ru4A—Si18viii	158.6 (3)	Si9A—Al22—Si10A	103.32 (3)
Al31C—Ru4A—Si18viii	108.4 (4)	Si9B—Al22—Si10A	93.38 (8)
Al29Bviii—Ru4A—Si18viii	66.0 (2)	Ru5A—Al22—Si10A	56.05 (10)
Al29Bix—Ru4A—Si18viii	101.1 (3)	Si9A—Al22—Al32Ax	111.57 (3)
Al13—Ru4A—Si18viii	121.64 (8)	Si9B—Al22—Al32Ax	100.13 (4)
Si18ix—Ru4A—Si18viii	68.65 (6)	Ru5A—Al22—Al32Ax	61.66 (6)
Al31B—Ru4A—Al27	81.93 (16)	Si10A—Al22—Al32Ax	117.32 (9)
Al31Bvii—Ru4A—Al27	107.8 (2)	Si9A—Al22—Ru5B	132.98 (12)
Al15—Ru4A—Al27	68.62 (6)	Si9B—Al22—Ru5B	110.98 (13)
Al31Cvii—Ru4A—Al27	125.6 (4)	Ru5A—Al22—Ru5B	3.10 (10)
Al31C—Ru4A—Al27	69.2 (3)	Si10A—Al22—Ru5B	58.60 (13)
Al29Bviii—Ru4A—Al27	88.75 (18)	Al32Ax—Al22—Ru5B	59.40 (10)
Al29Bix—Ru4A—Al27	153.02 (17)	Si9A—Al22—Al24	158.31 (3)
Al13—Ru4A—Al27	63.279 (16)	Si9B—Al22—Al24	157.71 (5)
Si18ix—Ru4A—Al27	124.15 (11)	Ru5A—Al22—Al24	58.96 (3)
Si18viii—Ru4A—Al27	66.03 (4)	Si10A—Al22—Al24	64.35 (6)
Al31B—Ru4A—Al27vii	107.8 (2)	Al32Ax—Al22—Al24	90.11 (2)
Al31Bvii—Ru4A—Al27vii	81.93 (16)	Ru5B—Al22—Al24	57.77 (10)
Al15—Ru4A—Al27vii	68.62 (6)	Si9A—Al22—Al27x	101.59 (2)
Al31Cvii—Ru4A—Al27vii	69.2 (3)	Si9B—Al22—Al27x	112.79 (4)
Al31C—Ru4A—Al27vii	125.6 (4)	Ru5A—Al22—Al27x	111.30 (7)
Al29Bviii—Ru4A—Al27vii	153.02 (17)	Si10A—Al22—Al27x	153.82 (6)
Al29Bix—Ru4A—Al27vii	88.75 (18)	Al32Ax—Al22—Al27x	59.17 (2)
Al13—Ru4A—Al27vii	63.280 (16)	Ru5B—Al22—Al27x	108.24 (13)
Si18ix—Ru4A—Al27vii	66.03 (4)	Al24—Al22—Al27x	89.47 (2)
Si18viii—Ru4A—Al27vii	124.15 (11)	Si9A—Al22—Al11	90.74 (3)
Al27—Ru4A—Al27vii	118.19 (6)	Si9B—Al22—Al11	103.79 (4)
Al31B—Ru4B—Al31Bvii	33.6 (5)	Ru5A—Al22—Al11	110.59 (4)
Al31B—Ru4B—Al31Cvii	53.9 (7)	Si10A—Al22—Al11	62.61 (12)
Al31Bvii—Ru4B—Al31Cvii	20.7 (4)	Al32Ax—Al22—Al11	156.05 (3)
Al31B—Ru4B—Al31C	20.7 (4)	Ru5B—Al22—Al11	111.75 (8)
Al31Bvii—Ru4B—Al31C	53.9 (7)	Al24—Al22—Al11	67.886 (18)
Al31Cvii—Ru4B—Al31C	73.5 (10)	Al27x—Al22—Al11	109.29 (2)
Al31B—Ru4B—Al29Bviii	78.9 (6)	Si9A—Al22—Al32Bx	103.33 (10)
Al31Bvii—Ru4B—Al29Bviii	97.3 (8)	Si9B—Al22—Al32Bx	87.15 (11)
Al31Cvii—Ru4B—Al29Bviii	103.3 (8)	Ru5A—Al22—Al32Bx	53.28 (10)
Al31C—Ru4B—Al29Bviii	64.5 (6)	Si10A—Al22—Al32Bx	104.81 (14)
Al31B—Ru4B—Al29Bix	97.3 (8)	Al32Ax—Al22—Al32Bx	18.94 (9)
Al31Bvii—Ru4B—Al29Bix	78.9 (6)	Ru5B—Al22—Al32Bx	51.91 (12)
Al31Cvii—Ru4B—Al29Bix	64.5 (6)	Al24—Al22—Al32Bx	97.29 (10)
Al31C—Ru4B—Al29Bix	103.3 (8)	Al27x—Al22—Al32Bx	76.92 (10)
Al29Bviii—Ru4B—Al29Bix	67.1 (5)	Al11—Al22—Al32Bx	163.34 (9)
Al31B—Ru4B—Al31A	19.0 (3)	Si9A—Al22—Al10B	101.92 (15)
Al31Bvii—Ru4B—Al31A	19.0 (3)	Si9B—Al22—Al10B	89.6 (3)
Al31Cvii—Ru4B—Al31A	39.4 (5)	Ru5A—Al22—Al10B	51.4 (3)
Al31C—Ru4B—Al31A	39.4 (5)	Si10A—Al22—Al10B	7.7 (4)
Al29Bviii—Ru4B—Al31A	95.5 (7)	Al32Ax—Al22—Al10B	111.6 (4)
Al29Bix—Ru4B—Al31A	95.5 (7)	Ru5B—Al22—Al10B	54.1 (3)
Al31B—Ru4B—Al13	75.4 (4)	Al24—Al22—Al10B	68.2 (3)
Al31Bvii—Ru4B—Al13	75.4 (4)	Al27x—Al22—Al10B	156.49 (16)
Al31Cvii—Ru4B—Al13	82.8 (5)	Al11—Al22—Al10B	70.0 (5)
Al31C—Ru4B—Al13	82.8 (5)	Al32Bx—Al22—Al10B	98.0 (4)
Al29Bviii—Ru4B—Al13	142.6 (5)	Si17vii—Al23—Al21	61.029 (17)
Al29Bix—Ru4B—Al13	142.6 (5)	Si17vii—Al23—Ru3	103.499 (18)
Al31A—Ru4B—Al13	65.7 (3)	Al21—Al23—Ru3	58.687 (14)
Al31B—Ru4B—Al29Aviii	86.4 (6)	Si17vii—Al23—Ru6	100.099 (19)
Al31Bvii—Ru4B—Al29Aviii	103.4 (8)	Al21—Al23—Ru6	109.94 (2)
Al31Cvii—Ru4B—Al29Aviii	107.4 (8)	Ru3—Al23—Ru6	141.414 (19)
Al31C—Ru4B—Al29Aviii	72.1 (5)	Si17vii—Al23—Si8	141.88 (2)
Al29Bviii—Ru4B—Al29Aviii	7.6 (2)	Al21—Al23—Si8	150.82 (2)
Al29Bix—Ru4B—Al29Aviii	64.5 (3)	Ru3—Al23—Si8	112.858 (19)
Al31A—Ru4B—Al29Aviii	102.8 (7)	Ru6—Al23—Si8	57.201 (13)
Al13—Ru4B—Al29Aviii	148.2 (3)	Si17vii—Al23—Al10B	107.7 (3)
Al31B—Ru4B—Al29Aix	103.4 (8)	Al21—Al23—Al10B	139.1 (5)
Al31Bvii—Ru4B—Al29Aix	86.4 (6)	Ru3—Al23—Al10B	90.5 (4)
Al31Cvii—Ru4B—Al29Aix	72.1 (5)	Ru6—Al23—Al10B	110.8 (5)
Al31C—Ru4B—Al29Aix	107.4 (8)	Si8—Al23—Al10B	62.3 (5)
Al29Bviii—Ru4B—Al29Aix	64.5 (3)	Si17vii—Al23—Si10A	111.40 (6)
Al29Bix—Ru4B—Al29Aix	7.6 (2)	Al21—Al23—Si10A	146.97 (12)
Al31A—Ru4B—Al29Aix	102.8 (7)	Ru3—Al23—Si10A	96.25 (9)
Al13—Ru4B—Al29Aix	148.2 (3)	Ru6—Al23—Si10A	103.01 (12)
Al29Aviii—Ru4B—Al29Aix	61.0 (2)	Si8—Al23—Si10A	54.96 (11)
Al31B—Ru4B—Al27	85.1 (3)	Al10B—Al23—Si10A	7.9 (4)
Al31Bvii—Ru4B—Al27	113.4 (5)	Si17vii—Al23—Ru5A	56.81 (5)
Al31Cvii—Ru4B—Al27	132.4 (7)	Al21—Al23—Ru5A	108.53 (4)
Al31C—Ru4B—Al27	71.1 (4)	Ru3—Al23—Ru5A	106.29 (5)
Al29Bviii—Ru4B—Al27	89.08 (17)	Ru6—Al23—Ru5A	112.15 (4)
Al29Bix—Ru4B—Al27	154.9 (4)	Si8—Al23—Ru5A	100.65 (4)
Al31A—Ru4B—Al27	94.5 (3)	Al10B—Al23—Ru5A	51.2 (2)
Al13—Ru4B—Al27	62.25 (17)	Si10A—Al23—Ru5A	54.60 (8)
Al29Aviii—Ru4B—Al27	90.80 (10)	Si17vii—Al23—Ru5B	54.40 (11)
Al29Aix—Ru4B—Al27	149.4 (3)	Al21—Al23—Ru5B	107.46 (8)
Al31B—Ru4B—Al27vii	113.4 (5)	Ru3—Al23—Ru5B	108.24 (11)
Al31Bvii—Ru4B—Al27vii	85.1 (3)	Ru6—Al23—Ru5B	110.30 (10)
Al31Cvii—Ru4B—Al27vii	71.1 (4)	Si8—Al23—Ru5B	101.71 (8)
Al31C—Ru4B—Al27vii	132.4 (7)	Al10B—Al23—Ru5B	53.8 (2)
Al29Bviii—Ru4B—Al27vii	154.9 (4)	Si10A—Al23—Ru5B	57.00 (12)
Al29Bix—Ru4B—Al27vii	89.08 (17)	Ru5A—Al23—Ru5B	2.98 (10)
Al31A—Ru4B—Al27vii	94.5 (3)	Si17vii—Al23—Al24	80.338 (18)
Al13—Ru4B—Al27vii	62.25 (17)	Al21—Al23—Al24	137.05 (2)
Al29Aviii—Ru4B—Al27vii	149.4 (3)	Ru3—Al23—Al24	157.64 (2)
Al29Aix—Ru4B—Al27vii	90.80 (10)	Ru6—Al23—Al24	56.553 (13)
Al27—Ru4B—Al27vii	113.0 (5)	Si8—Al23—Al24	61.690 (16)
Al10B—Ru5A—Al32Bvi	113.0 (3)	Al10B—Al23—Al24	67.6 (4)
Al10B—Ru5A—Al31Cvi	85.0 (6)	Si10A—Al23—Al24	62.38 (8)
Al32Bvi—Ru5A—Al31Cvi	36.8 (4)	Ru5A—Al23—Al24	56.98 (4)
Al10B—Ru5A—Al32Bx	121.0 (2)	Ru5B—Al23—Al24	55.77 (9)
Al32Bvi—Ru5A—Al32Bx	18.9 (2)	Si17vii—Al23—Si19vi	66.662 (17)
Al31Cvi—Ru5A—Al32Bx	55.1 (4)	Al21—Al23—Si19vi	72.882 (17)
Al10B—Ru5A—Al31Bvi	66.8 (5)	Ru3—Al23—Si19vi	54.261 (13)
Al32Bvi—Ru5A—Al31Bvi	54.8 (2)	Ru6—Al23—Si19vi	163.70 (2)
Al31Cvi—Ru5A—Al31Bvi	19.1 (4)	Si8—Al23—Si19vi	127.53 (2)
Al32Bx—Ru5A—Al31Bvi	72.1 (2)	Al10B—Al23—Si19vi	67.0 (5)
Al10B—Ru5A—Si19vi	78.5 (5)	Si10A—Al23—Si19vi	74.84 (12)
Al32Bvi—Ru5A—Si19vi	107.37 (12)	Ru5A—Al23—Si19vi	53.13 (4)
Al31Cvi—Ru5A—Si19vi	78.9 (3)	Ru5B—Al23—Si19vi	54.65 (10)
Al32Bx—Ru5A—Si19vi	124.43 (12)	Al24—Al23—Si19vi	109.956 (19)
Al31Bvi—Ru5A—Si19vi	70.77 (16)	Si18vii—Al24—Ru6	108.644 (19)
Al10B—Ru5A—Si10A	8.2 (5)	Si18vii—Al24—Ru5B	110.23 (12)
Al32Bvi—Ru5A—Si10A	115.65 (14)	Ru6—Al24—Ru5B	118.14 (8)
Al31Cvi—Ru5A—Si10A	90.9 (4)	Si18vii—Al24—Ru5A	112.93 (6)
Al32Bx—Ru5A—Si10A	120.89 (13)	Ru6—Al24—Ru5A	117.76 (3)
Al31Bvi—Ru5A—Si10A	73.3 (2)	Ru5B—Al24—Ru5A	3.11 (10)
Si19vi—Ru5A—Si10A	85.24 (13)	Si18vii—Al24—Al20vii	59.685 (17)
Al10B—Ru5A—Si17vii	122.7 (2)	Ru6—Al24—Al20vii	59.851 (14)
Al32Bvi—Ru5A—Si17vii	122.58 (15)	Ru5B—Al24—Al20vii	104.30 (12)
Al31Cvi—Ru5A—Si17vii	134.1 (3)	Ru5A—Al24—Al20vii	106.90 (6)
Al32Bx—Ru5A—Si17vii	116.12 (16)	Si18vii—Al24—Al22	92.44 (2)
Al31Bvi—Ru5A—Si17vii	139.43 (14)	Ru6—Al24—Al22	156.41 (2)
Si19vi—Ru5A—Si17vii	73.14 (3)	Ru5B—Al24—Al22	60.94 (9)
Si10A—Ru5A—Si17vii	121.47 (7)	Ru5A—Al24—Al22	59.89 (3)
Al10B—Ru5A—Al29Bvii	141.5 (6)	Al20vii—Al24—Al22	143.42 (2)
Al32Bvi—Ru5A—Al29Bvii	82.6 (4)	Si18vii—Al24—Al29Avii	59.24 (4)
Al31Cvi—Ru5A—Al29Bvii	119.1 (5)	Ru6—Al24—Al29Avii	112.61 (10)
Al32Bx—Ru5A—Al29Bvii	65.4 (4)	Ru5B—Al24—Al29Avii	56.43 (16)
Al31Bvi—Ru5A—Al29Bvii	137.3 (4)	Ru5A—Al24—Al29Avii	59.53 (11)
Si19vi—Ru5A—Al29Bvii	132.33 (18)	Al20vii—Al24—Al29Avii	59.19 (11)
Si10A—Ru5A—Al29Bvii	133.3 (2)	Al22—Al24—Al29Avii	86.96 (11)
Si17vii—Ru5A—Al29Bvii	63.1 (3)	Si18vii—Al24—Ru7	58.295 (14)
Al10B—Ru5A—Al25v	137.7 (6)	Ru6—Al24—Ru7	118.408 (17)
Al32Bvi—Ru5A—Al25v	66.26 (12)	Ru5B—Al24—Ru7	122.67 (8)
Al31Cvi—Ru5A—Al25v	71.2 (3)	Ru5A—Al24—Ru7	122.40 (3)
Al32Bx—Ru5A—Al25v	72.90 (12)	Al20vii—Al24—Ru7	111.042 (19)
Al31Bvi—Ru5A—Al25v	83.44 (16)	Al22—Al24—Ru7	63.710 (14)
Si19vi—Ru5A—Al25v	63.15 (3)	Al29Avii—Al24—Ru7	107.81 (4)
Si10A—Ru5A—Al25v	145.72 (16)	Si18vii—Al24—Al26	90.35 (2)
Si17vii—Ru5A—Al25v	63.90 (5)	Ru6—Al24—Al26	61.627 (14)
Al29Bvii—Ru5A—Al25v	80.65 (16)	Ru5B—Al24—Al26	156.80 (13)
Al10B—Ru5A—Al24	75.5 (6)	Ru5A—Al24—Al26	153.69 (7)
Al32Bvi—Ru5A—Al24	123.97 (13)	Al20vii—Al24—Al26	95.19 (2)
Al31Cvi—Ru5A—Al24	140.8 (3)	Al22—Al24—Al26	109.18 (2)
Al32Bx—Ru5A—Al24	107.45 (13)	Al29Avii—Al24—Al26	146.73 (8)
Al31Bvi—Ru5A—Al24	133.11 (16)	Ru7—Al24—Al26	58.949 (13)
Si19vi—Ru5A—Al24	128.12 (6)	Si18vii—Al24—Al23	145.37 (2)
Si10A—Ru5A—Al24	67.45 (12)	Ru6—Al24—Al23	58.819 (13)
Si17vii—Ru5A—Al24	84.51 (5)	Ru5B—Al24—Al23	61.68 (8)
Al29Bvii—Ru5A—Al24	67.0 (2)	Ru5A—Al24—Al23	60.48 (4)
Al25v—Ru5A—Al24	142.69 (11)	Al20vii—Al24—Al23	88.534 (19)
Al10B—Ru5A—Al29Avii	137.2 (6)	Al22—Al24—Al23	108.79 (2)
Al32Bvi—Ru5A—Al29Avii	89.86 (18)	Al29Avii—Al24—Al23	93.98 (3)
Al31Cvi—Ru5A—Al29Avii	126.4 (4)	Ru7—Al24—Al23	155.98 (2)
Al32Bx—Ru5A—Al29Avii	72.55 (17)	Al26—Al24—Al23	107.13 (2)
Al31Bvi—Ru5A—Al29Avii	144.5 (2)	Si18vii—Al24—Si8	146.78 (2)
Si19vi—Ru5A—Al29Avii	130.35 (8)	Ru6—Al24—Si8	56.304 (14)
Si10A—Ru5A—Al29Avii	129.07 (15)	Ru5B—Al24—Si8	102.75 (12)
Si17vii—Ru5A—Al29Avii	58.77 (8)	Ru5A—Al24—Si8	99.93 (6)
Al29Bvii—Ru5A—Al29Avii	7.3 (2)	Al20vii—Al24—Si8	116.11 (2)
Al25v—Ru5A—Al29Avii	84.03 (10)	Al22—Al24—Si8	100.20 (2)
Al24—Ru5A—Al29Avii	61.83 (10)	Al29Avii—Al24—Si8	151.16 (3)
Al32Bvi—Ru5B—Al32Bx	19.2 (2)	Ru7—Al24—Si8	100.331 (19)
Al32Bvi—Ru5B—Al29Bvii	85.9 (4)	Al26—Al24—Si8	56.507 (18)
Al32Bx—Ru5B—Al29Bvii	68.5 (4)	Al23—Al24—Si8	57.219 (18)
Al32Bvi—Ru5B—Si17vii	126.7 (2)	Si9Aix—Al25—Ru5Bxvi	128.55 (13)
Al32Bx—Ru5B—Si17vii	121.3 (3)	Si9Aix—Al25—Si9Bix	21.90 (6)
Al29Bvii—Ru5B—Si17vii	66.4 (3)	Ru5Bxvi—Al25—Si9Bix	106.70 (14)
Al32Bvi—Ru5B—Al31Cvi	36.2 (4)	Si9Aix—Al25—Ru6vii	114.15 (3)
Al32Bx—Ru5B—Al31Cvi	54.7 (4)	Ru5Bxvi—Al25—Ru6vii	115.92 (12)
Al29Bvii—Ru5B—Al31Cvi	121.9 (5)	Si9Bix—Al25—Ru6vii	135.61 (6)
Si17vii—Ru5B—Al31Cvi	134.6 (3)	Si9Aix—Al25—Ru5Axvi	131.44 (7)
Al32Bvi—Ru5B—Al10B	108.8 (4)	Ru5Bxvi—Al25—Ru5Axvi	3.09 (11)
Al32Bx—Ru5B—Al10B	117.8 (3)	Si9Bix—Al25—Ru5Axvi	109.56 (8)
Al29Bvii—Ru5B—Al10B	142.6 (6)	Ru6vii—Al25—Ru5Axvi	113.37 (6)
Si17vii—Ru5B—Al10B	120.9 (2)	Si9Aix—Al25—Al32Avii	110.33 (3)
Al31Cvi—Ru5B—Al10B	80.8 (6)	Ru5Bxvi—Al25—Al32Avii	61.68 (10)
Al32Bvi—Ru5B—Al29Avii	93.6 (2)	Si9Bix—Al25—Al32Avii	100.19 (5)
Al32Bx—Ru5B—Al29Avii	76.0 (2)	Ru6vii—Al25—Al32Avii	110.16 (3)
Al29Bvii—Ru5B—Al29Avii	7.7 (2)	Ru5Axvi—Al25—Al32Avii	60.43 (4)
Si17vii—Ru5B—Al29Avii	61.77 (15)	Si9Aix—Al25—Si19vii	164.51 (3)
Al31Cvi—Ru5B—Al29Avii	129.6 (4)	Ru5Bxvi—Al25—Si19vii	58.62 (11)
Al10B—Ru5B—Al29Avii	138.2 (6)	Si9Bix—Al25—Si19vii	159.82 (6)
Al32Bvi—Ru5B—Si19vi	105.1 (2)	Ru6vii—Al25—Si19vii	57.349 (14)
Al32Bx—Ru5B—Si19vi	123.0 (2)	Ru5Axvi—Al25—Si19vii	56.18 (5)
Al29Bvii—Ru5B—Si19vi	135.8 (3)	Al32Avii—Al25—Si19vii	85.14 (2)
Si17vii—Ru5B—Si19vi	73.17 (10)	Si9Aix—Al25—Al27vii	99.80 (3)
Al31Cvi—Ru5B—Si19vi	76.0 (3)	Ru5Bxvi—Al25—Al27vii	112.82 (13)
Al10B—Ru5B—Si19vi	74.8 (5)	Si9Bix—Al25—Al27vii	111.92 (5)
Al29Avii—Ru5B—Si19vi	133.56 (19)	Ru6vii—Al25—Al27vii	62.571 (15)
Al32Bvi—Ru5B—Al25v	67.10 (14)	Ru5Axvi—Al25—Al27vii	110.28 (5)
Al32Bx—Ru5B—Al25v	74.45 (15)	Al32Avii—Al25—Al27vii	59.01 (2)
Al29Bvii—Ru5B—Al25v	84.3 (2)	Si19vii—Al25—Al27vii	87.59 (2)
Si17vii—Ru5B—Al25v	65.67 (11)	Si9Aix—Al25—Si17xv	104.45 (3)
Al31Cvi—Ru5B—Al25v	70.8 (3)	Ru5Bxvi—Al25—Si17xv	55.05 (10)
Al10B—Ru5B—Al25v	133.0 (6)	Si9Bix—Al25—Si17xv	93.09 (5)
Al29Avii—Ru5B—Al25v	87.84 (18)	Ru6vii—Al25—Si17xv	100.998 (18)
Si19vi—Ru5B—Al25v	62.70 (9)	Ru5Axvi—Al25—Si17xv	56.63 (4)
Al32Bvi—Ru5B—Al31Bvi	53.4 (2)	Al32Avii—Al25—Si17xv	116.53 (3)
Al32Bx—Ru5B—Al31Bvi	70.9 (2)	Si19vii—Al25—Si17xv	67.345 (17)
Al29Bvii—Ru5B—Al31Bvi	139.2 (4)	Al27vii—Al25—Si17xv	154.93 (2)
Si17vii—Ru5B—Al31Bvi	137.7 (2)	Si9Aix—Al25—Al32Bvii	102.03 (10)
Al31Cvi—Ru5B—Al31Bvi	18.3 (3)	Ru5Bxvi—Al25—Al32Bvii	52.82 (12)
Al10B—Ru5B—Al31Bvi	63.3 (5)	Si9Bix—Al25—Al32Bvii	87.00 (11)
Al29Avii—Ru5B—Al31Bvi	146.8 (3)	Ru6vii—Al25—Al32Bvii	128.48 (10)
Si19vi—Ru5B—Al31Bvi	67.8 (2)	Ru5Axvi—Al25—Al32Bvii	52.63 (10)
Al25v—Ru5B—Al31Bvi	82.13 (19)	Al32Avii—Al25—Al32Bvii	18.95 (9)
Al32Bvi—Ru5B—Al24	126.01 (19)	Si19vii—Al25—Al32Bvii	92.89 (10)
Al32Bx—Ru5B—Al24	110.14 (19)	Al27vii—Al25—Al32Bvii	76.56 (10)
Al29Bvii—Ru5B—Al24	69.6 (3)	Si17xv—Al25—Al32Bvii	104.12 (10)
Si17vii—Ru5B—Al24	86.99 (15)	Si9Aix—Al25—Si16	97.04 (3)
Al31Cvi—Ru5B—Al24	138.4 (3)	Ru5Bxvi—Al25—Si16	101.30 (8)
Al10B—Ru5B—Al24	74.1 (6)	Si9Bix—Al25—Si16	105.52 (5)
Al29Avii—Ru5B—Al24	64.23 (16)	Ru6vii—Al25—Si16	55.609 (13)
Si19vi—Ru5B—Al24	126.23 (15)	Ru5Axvi—Al25—Si16	101.37 (3)
Al25v—Ru5B—Al24	148.3 (3)	Al32Avii—Al25—Si16	152.62 (3)
Al31Bvi—Ru5B—Al24	129.4 (2)	Si19vii—Al25—Si16	67.479 (16)
Al32Bvi—Ru5B—Si10A	111.8 (2)	Al27vii—Al25—Si16	117.52 (2)
Al32Bx—Ru5B—Si10A	118.1 (2)	Si17xv—Al25—Si16	53.440 (15)
Al29Bvii—Ru5B—Si10A	134.7 (3)	Al32Bvii—Al25—Si16	153.98 (10)
Si17vii—Ru5B—Si10A	120.13 (14)	Si9Aix—Al25—Al22xxi	55.52 (2)
Al31Cvi—Ru5B—Si10A	86.6 (4)	Ru5Bxvi—Al25—Al22xxi	110.56 (8)
Al10B—Ru5B—Si10A	7.9 (4)	Si9Bix—Al25—Al22xxi	56.81 (5)
Al29Avii—Ru5B—Si10A	130.4 (2)	Ru6vii—Al25—Al22xxi	114.61 (2)
Si19vi—Ru5B—Si10A	81.33 (19)	Ru5Axvi—Al25—Al22xxi	110.96 (3)
Al25v—Ru5B—Si10A	140.8 (3)	Al32Avii—Al25—Al22xxi	58.16 (2)
Al31Bvi—Ru5B—Si10A	69.6 (2)	Si19vii—Al25—Al22xxi	138.51 (2)
Al24—Ru5B—Si10A	66.34 (15)	Al27vii—Al25—Al22xxi	58.274 (17)
Si16vii—Ru6—Si19	73.752 (14)	Si17xv—Al25—Al22xxi	143.73 (2)
Si16vii—Ru6—Si8	119.473 (16)	Al32Bvii—Al25—Al22xxi	58.96 (10)
Si19—Ru6—Si8	84.882 (16)	Si16—Al25—Al22xxi	146.74 (2)
Si16vii—Ru6—Al24	85.523 (14)	Ru3xv—Al26—Si16vii	102.244 (18)
Si19—Ru6—Al24	129.919 (14)	Ru3xv—Al26—Al21xv	58.455 (14)
Si8—Ru6—Al24	66.403 (16)	Si16vii—Al26—Al21xv	59.966 (17)
Si16vii—Ru6—Al25vii	65.368 (14)	Ru3xv—Al26—Si8	95.784 (19)
Si19—Ru6—Al25vii	63.124 (14)	Si16vii—Al26—Si8	111.61 (2)
Si8—Ru6—Al25vii	145.654 (17)	Al21xv—Al26—Si8	146.06 (2)
Al24—Ru6—Al25vii	144.281 (16)	Ru3xv—Al26—Ru7	141.451 (19)
Si16vii—Ru6—Al20vii	59.439 (14)	Si16vii—Al26—Ru7	99.520 (18)
Si19—Ru6—Al20vii	131.436 (15)	Al21xv—Al26—Ru7	108.583 (19)
Si8—Ru6—Al20vii	128.011 (16)	Si8—Al26—Ru7	105.23 (2)
Al24—Ru6—Al20vii	61.662 (15)	Ru3xv—Al26—Al11	113.311 (19)
Al25vii—Ru6—Al20vii	84.991 (15)	Si16vii—Al26—Al11	144.17 (2)
Si16vii—Ru6—Al23	147.194 (14)	Al21xv—Al26—Al11	145.26 (2)
Si19—Ru6—Al23	135.764 (15)	Si8—Al26—Al11	61.90 (2)
Si8—Ru6—Al23	62.146 (17)	Ru7—Al26—Al11	54.412 (12)
Al24—Ru6—Al23	64.628 (14)	Ru3xv—Al26—Ru6	105.140 (16)
Al25vii—Ru6—Al23	134.258 (15)	Si16vii—Al26—Ru6	55.329 (13)
Al20vii—Ru6—Al23	92.788 (15)	Al21xv—Al26—Ru6	106.047 (19)
Si16vii—Ru6—Al13	133.510 (18)	Si8—Al26—Ru6	56.299 (13)
Si19—Ru6—Al13	59.769 (18)	Ru7—Al26—Ru6	113.409 (17)
Si8—Ru6—Al13	58.452 (17)	Al11—Al26—Ru6	108.61 (2)
Al24—Ru6—Al13	122.930 (17)	Ru3xv—Al26—Al24	155.88 (2)
Al25vii—Ru6—Al13	92.680 (17)	Si16vii—Al26—Al24	79.141 (18)
Al20vii—Ru6—Al13	163.833 (17)	Al21xv—Al26—Al24	135.83 (2)
Al23—Ru6—Al13	77.385 (18)	Si8—Al26—Al24	62.192 (16)
Si16vii—Ru6—Al26	59.727 (14)	Ru7—Al26—Al24	59.871 (13)
Si19—Ru6—Al26	67.301 (13)	Al11—Al26—Al24	66.696 (18)
Si8—Ru6—Al26	59.762 (16)	Ru6—Al26—Al24	55.497 (13)
Al24—Ru6—Al26	62.875 (14)	Ru3xv—Al26—Al26vii	56.970 (11)
Al25vii—Ru6—Al26	113.153 (15)	Si16vii—Al26—Al26vii	151.308 (13)
Al20vii—Ru6—Al26	97.033 (15)	Al21xv—Al26—Al26vii	112.414 (15)
Al23—Ru6—Al26	112.461 (14)	Si8—Al26—Al26vii	57.481 (12)
Al13—Ru6—Al26	98.582 (17)	Ru7—Al26—Al26vii	108.889 (11)
Si16vii—Ru6—Al27	125.610 (15)	Al11—Al26—Al26vii	58.656 (12)
Si19—Ru6—Al27	89.805 (15)	Ru6—Al26—Al26vii	107.552 (10)
Si8—Ru6—Al27	109.764 (16)	Al24—Al26—Al26vii	111.536 (14)
Al24—Ru6—Al27	137.383 (16)	Ru4A—Al27—Al30Avii	166.95 (10)
Al25vii—Ru6—Al27	61.026 (15)	Ru4A—Al27—Ru4B	5.8 (4)
Al20vii—Ru6—Al27	106.387 (15)	Al30Avii—Al27—Ru4B	172.7 (5)
Al23—Ru6—Al27	76.151 (15)	Ru4A—Al27—Al32A	65.45 (6)
Al13—Ru6—Al27	59.067 (16)	Al30Avii—Al27—Al32A	126.77 (9)
Al26—Ru6—Al27	154.792 (15)	Ru4B—Al27—Al32A	60.3 (4)
Si16vii—Ru6—Al30Avii	102.70 (7)	Ru4A—Al27—Al13	57.67 (2)
Si19—Ru6—Al30Avii	132.20 (5)	Al30Avii—Al27—Al13	122.47 (7)
Si8—Ru6—Al30Avii	131.46 (8)	Ru4B—Al27—Al13	56.81 (15)
Al24—Ru6—Al30Avii	96.30 (4)	Al32A—Al27—Al13	88.32 (3)
Al25vii—Ru6—Al30Avii	72.10 (7)	Ru4A—Al27—Al22xx	113.48 (4)
Al20vii—Ru6—Al30Avii	55.35 (3)	Al30Avii—Al27—Al22xx	74.19 (9)
Al23—Ru6—Al30Avii	69.43 (8)	Ru4B—Al27—Al22xx	110.7 (3)
Al13—Ru6—Al30Avii	108.73 (4)	Al32A—Al27—Al22xx	59.81 (2)
Al26—Ru6—Al30Avii	152.08 (3)	Al13—Al27—Al22xx	144.86 (3)
Al27—Ru6—Al30Avii	52.71 (2)	Ru4A—Al27—Ru7xx	112.40 (5)
Al21x—Ru7—Al11	141.649 (18)	Al30Avii—Al27—Ru7xx	60.33 (2)
Al21x—Ru7—Si18vii	91.431 (15)	Ru4B—Al27—Ru7xx	116.2 (3)
Al11—Ru7—Si18vii	126.820 (18)	Al32A—Al27—Ru7xx	113.89 (2)
Al21x—Ru7—Al30Ai	65.17 (9)	Al13—Al27—Ru7xx	150.38 (3)
Al11—Ru7—Al30Ai	89.79 (9)	Al22xx—Al27—Ru7xx	64.048 (15)
Si18vii—Ru7—Al30Ai	119.80 (5)	Ru4A—Al27—Al25vii	115.47 (7)
Al21x—Ru7—Al27x	74.643 (15)	Al30Avii—Al27—Al25vii	77.24 (6)
Al11—Ru7—Al27x	116.895 (19)	Ru4B—Al27—Al25vii	109.8 (5)
Si18vii—Ru7—Al27x	63.540 (14)	Al32A—Al27—Al25vii	59.34 (2)
Al30Ai—Ru7—Al27x	57.08 (4)	Al13—Al27—Al25vii	89.33 (2)
Al21x—Ru7—Al30Bi	75.60 (15)	Al22xx—Al27—Al25vii	62.742 (18)
Al11—Ru7—Al30Bi	79.40 (15)	Ru7xx—Al27—Al25vii	118.42 (2)
Si18vii—Ru7—Al30Bi	124.40 (8)	Ru4A—Al27—Al30Bvii	172.03 (8)
Al30Ai—Ru7—Al30Bi	10.77 (8)	Al30Avii—Al27—Al30Bvii	10.21 (7)
Al27x—Ru7—Al30Bi	60.87 (9)	Ru4B—Al27—Al30Bvii	174.26 (18)
Al21x—Ru7—Al26	126.897 (15)	Al32A—Al27—Al30Bvii	116.91 (14)
Al11—Ru7—Al26	63.063 (18)	Al13—Al27—Al30Bvii	128.85 (10)
Si18vii—Ru7—Al26	90.562 (14)	Al22xx—Al27—Al30Bvii	64.32 (14)
Al30Ai—Ru7—Al26	148.47 (7)	Ru7xx—Al27—Al30Bvii	59.63 (7)
Al27x—Ru7—Al26	148.316 (15)	Al25vii—Al27—Al30Bvii	70.90 (10)
Al30Bi—Ru7—Al26	140.15 (13)	Ru4A—Al27—Ru6	115.40 (3)
Al21x—Ru7—Al28xi	64.563 (16)	Al30Avii—Al27—Ru6	68.21 (4)
Al11—Ru7—Al28xi	95.882 (19)	Ru4B—Al27—Ru6	113.4 (2)
Si18vii—Ru7—Al28xi	116.253 (15)	Al32A—Al27—Ru6	105.41 (2)
Al30Ai—Ru7—Al28xi	102.54 (4)	Al13—Al27—Ru6	58.283 (15)
Al27x—Ru7—Al28xi	139.202 (16)	Al22xx—Al27—Ru6	113.12 (2)
Al30Bi—Ru7—Al28xi	106.22 (9)	Ru7xx—Al27—Ru6	127.19 (2)
Al26—Ru7—Al28xi	67.242 (15)	Al25vii—Al27—Ru6	56.403 (14)
Al21x—Ru7—Al24	147.730 (15)	Al30Bvii—Al27—Ru6	71.86 (8)
Al11—Ru7—Al24	70.529 (17)	Ru4A—Al27—Si18viii	56.67 (4)
Si18vii—Ru7—Al24	56.314 (14)	Al30Avii—Al27—Si18viii	115.33 (3)
Al30Ai—Ru7—Al24	127.09 (6)	Ru4B—Al27—Si18viii	60.5 (3)
Al27x—Ru7—Al24	88.245 (15)	Al32A—Al27—Si18viii	88.48 (2)
Al30Bi—Ru7—Al24	119.75 (13)	Al13—Al27—Si18viii	108.54 (2)
Al26—Ru7—Al24	61.180 (14)	Al22xx—Al27—Si18viii	86.554 (19)
Al28xi—Ru7—Al24	127.289 (15)	Ru7xx—Al27—Si18viii	55.752 (13)
Al21x—Ru7—Al28vii	66.535 (15)	Al25vii—Al27—Si18viii	143.16 (2)
Al11—Ru7—Al28vii	131.540 (19)	Al30Bvii—Al27—Si18viii	115.37 (7)
Si18vii—Ru7—Al28vii	59.617 (14)	Ru6—Al27—Si18viii	159.70 (2)
Al30Ai—Ru7—Al28vii	131.67 (9)	Ru4A—Al27—Al15	54.37 (6)
Al27x—Ru7—Al28vii	107.887 (16)	Al30Avii—Al27—Al15	112.87 (9)
Al30Bi—Ru7—Al28vii	142.13 (15)	Ru4B—Al27—Al15	59.8 (4)
Al26—Ru7—Al28vii	69.242 (15)	Al32A—Al27—Al15	119.51 (3)
Al28xi—Ru7—Al28vii	56.639 (19)	Al13—Al27—Al15	65.91 (2)
Al24—Ru7—Al28vii	94.190 (14)	Al22xx—Al27—Al15	140.86 (3)
Al21x—Ru7—Al22	127.209 (14)	Ru7xx—Al27—Al15	85.55 (2)
Al11—Ru7—Al22	60.831 (18)	Al25vii—Al27—Al15	155.08 (3)
Si18vii—Ru7—Al22	87.294 (15)	Al30Bvii—Al27—Al15	121.91 (13)
Al30Ai—Ru7—Al22	70.12 (7)	Ru6—Al27—Al15	104.73 (2)
Al27x—Ru7—Al22	57.854 (15)	Si18viii—Al27—Al15	55.05 (2)
Al30Bi—Ru7—Al22	62.53 (12)	Ru2ix—Al28—Al28xiv	165.46 (3)
Al26—Ru7—Al22	105.892 (14)	Ru2ix—Al28—Si16	57.410 (14)
Al28xi—Ru7—Al22	154.796 (16)	Al28xiv—Al28—Si16	109.86 (3)
Al24—Ru7—Al22	57.266 (13)	Ru2ix—Al28—Si18	57.930 (14)
Al28vii—Ru7—Al22	145.875 (15)	Al28xiv—Al28—Si18	114.58 (3)
Si10A—Si8—Al13	134.29 (9)	Si16—Al28—Si18	75.902 (18)
Si10A—Si8—Ru6	112.83 (3)	Ru2ix—Al28—Ru7xxii	123.54 (2)
Al13—Si8—Ru6	62.754 (12)	Al28xiv—Al28—Ru7xxii	63.76 (2)
Si10A—Si8—Ru6vii	112.83 (3)	Si16—Al28—Ru7xxii	104.017 (19)
Al13—Si8—Ru6vii	62.754 (12)	Si18—Al28—Ru7xxii	178.26 (2)
Ru6—Si8—Ru6vii	124.23 (2)	Ru2ix—Al28—Al14xiv	59.956 (18)
Si10A—Si8—Al26vii	113.89 (8)	Al28xiv—Al28—Al14xiv	127.43 (3)
Al13—Si8—Al26vii	104.28 (2)	Si16—Al28—Al14xiv	77.13 (2)
Ru6—Si8—Al26vii	120.73 (2)	Si18—Al28—Al14xiv	117.52 (2)
Ru6vii—Si8—Al26vii	63.940 (13)	Ru7xxii—Al28—Al14xiv	64.053 (17)
Si10A—Si8—Al26	113.90 (8)	Ru2ix—Al28—Al21xvi	107.85 (2)
Al13—Si8—Al26	104.28 (2)	Al28xiv—Al28—Al21xvi	65.21 (2)
Ru6—Si8—Al26	63.940 (13)	Si16—Al28—Al21xvi	57.251 (16)
Ru6vii—Si8—Al26	120.73 (2)	Si18—Al28—Al21xvi	125.93 (2)
Al26vii—Si8—Al26	65.04 (2)	Ru7xxii—Al28—Al21xvi	53.162 (13)
Si10A—Si8—Al23vii	63.42 (7)	Al14xiv—Al28—Al21xvi	79.051 (19)
Al13—Si8—Al23vii	78.61 (2)	Ru2ix—Al28—Ru7vii	111.722 (19)
Ru6—Si8—Al23vii	117.74 (2)	Al28xiv—Al28—Ru7vii	59.60 (2)
Ru6vii—Si8—Al23vii	60.654 (13)	Si16—Al28—Ru7vii	94.790 (19)
Al26vii—Si8—Al23vii	114.682 (15)	Si18—Al28—Ru7vii	54.988 (14)
Al26—Si8—Al23vii	177.11 (3)	Ru7xxii—Al28—Ru7vii	123.361 (19)
Si10A—Si8—Al23	63.42 (7)	Al14xiv—Al28—Ru7vii	170.62 (2)
Al13—Si8—Al23	78.61 (2)	Al21xvi—Al28—Ru7vii	100.73 (2)
Ru6—Si8—Al23	60.653 (13)	Ru2ix—Al28—Al21xvii	125.63 (2)
Ru6vii—Si8—Al23	117.74 (2)	Al28xiv—Al28—Al21xvii	59.73 (2)
Al26vii—Si8—Al23	177.11 (3)	Si16—Al28—Al21xvii	145.22 (2)
Al26—Si8—Al23	114.681 (15)	Si18—Al28—Al21xvii	79.480 (18)
Al23vii—Si8—Al23	65.44 (2)	Ru7xxii—Al28—Al21xvii	99.854 (18)
Si10A—Si8—Al11	64.29 (9)	Al14xiv—Al28—Al21xvii	136.84 (3)
Al13—Si8—Al11	161.43 (3)	Al21xvi—Al28—Al21xvii	124.94 (2)
Ru6—Si8—Al11	113.799 (13)	Ru7vii—Al28—Al21xvii	50.654 (12)
Ru6vii—Si8—Al11	113.799 (13)	Ru5Bvii—Al29A—Ru4Bii	124.8 (3)
Al26vii—Si8—Al11	60.621 (19)	Ru5Bvii—Al29A—Si17	58.02 (9)
Al26—Si8—Al11	60.621 (19)	Ru4Bii—Al29A—Si17	164.2 (5)
Al23vii—Si8—Al11	116.60 (2)	Ru5Bvii—Al29A—Al32Axvii	63.08 (13)
Al23—Si8—Al11	116.60 (2)	Ru4Bii—Al29A—Al32Axvii	62.9 (3)
Si10A—Si8—Al10B	4.9 (2)	Si17—Al29A—Al32Axvii	113.93 (14)
Al13—Si8—Al10B	129.4 (3)	Ru5Bvii—Al29A—Al29Axviii	155.59 (12)
Ru6—Si8—Al10B	111.37 (10)	Ru4Bii—Al29A—Al29Axviii	59.50 (11)
Ru6vii—Si8—Al10B	111.37 (10)	Si17—Al29A—Al29Axviii	110.99 (3)
Al26vii—Si8—Al10B	117.8 (2)	Al32Axvii—Al29A—Al29Axviii	110.11 (4)
Al26—Si8—Al10B	117.8 (2)	Ru5Bvii—Al29A—Ru1ix	114.81 (10)
Al23vii—Si8—Al10B	59.6 (2)	Ru4Bii—Al29A—Ru1ix	118.55 (12)
Al23—Si8—Al10B	59.6 (2)	Si17—Al29A—Ru1ix	56.86 (6)
Al11—Si8—Al10B	69.2 (3)	Al32Axvii—Al29A—Ru1ix	154.35 (16)
Si10A—Si8—Al24vii	64.91 (3)	Al29Axviii—Al29A—Ru1ix	60.23 (4)
Al13—Si8—Al24vii	118.294 (14)	Ru5Bvii—Al29A—Si18	110.29 (9)
Ru6—Si8—Al24vii	177.69 (3)	Ru4Bii—Al29A—Si18	64.4 (5)
Ru6vii—Si8—Al24vii	57.293 (10)	Si17—Al29A—Si18	130.88 (19)
Al26vii—Si8—Al24vii	61.302 (15)	Al32Axvii—Al29A—Si18	94.94 (7)
Al26—Si8—Al24vii	117.14 (2)	Al29Axviii—Al29A—Si18	93.31 (3)
Al23vii—Si8—Al24vii	61.091 (15)	Ru1ix—Al29A—Si18	108.8 (2)
Al23—Si8—Al24vii	117.26 (2)	Ru5Bvii—Al29A—Ru4Aii	126.87 (19)
Al11—Si8—Al24vii	65.928 (15)	Ru4Bii—Al29A—Ru4Aii	5.9 (4)
Al10B—Si8—Al24vii	66.34 (10)	Si17—Al29A—Ru4Aii	169.12 (12)
Si9B—Si9A—Al22vii	82.44 (11)	Al32Axvii—Al29A—Ru4Aii	66.40 (11)
Si9B—Si9A—Al22	82.44 (11)	Al29Axviii—Al29A—Ru4Aii	60.32 (4)
Al22vii—Si9A—Al22	76.04 (3)	Ru1ix—Al29A—Ru4Aii	117.76 (8)
Si9B—Si9A—Al12	78.41 (14)	Si18—Al29A—Ru4Aii	58.74 (7)
Al22vii—Si9A—Al12	137.27 (3)	Ru5Bvii—Al29A—Al29Bxviii	150.30 (15)
Al22—Si9A—Al12	137.26 (3)	Ru4Bii—Al29A—Al29Bxviii	55.6 (2)
Si9B—Si9A—Al25ii	80.16 (5)	Si17—Al29A—Al29Bxviii	113.27 (16)
Al22vii—Si9A—Al25ii	67.335 (17)	Al32Axvii—Al29A—Al29Bxviii	102.94 (18)
Al22—Si9A—Al25ii	141.05 (4)	Al29Axviii—Al29A—Al29Bxviii	7.53 (19)
Al12—Si9A—Al25ii	71.93 (2)	Ru1ix—Al29A—Al29Bxviii	65.7 (2)
Si9B—Si9A—Al25i	80.16 (5)	Si18—Al29A—Al29Bxviii	96.40 (12)
Al22vii—Si9A—Al25i	141.05 (4)	Ru4Aii—Al29A—Al29Bxviii	57.23 (17)
Al22—Si9A—Al25i	67.334 (17)	Ru5Bvii—Al29A—Al20	106.68 (14)
Al12—Si9A—Al25i	71.93 (2)	Ru4Bii—Al29A—Al20	112.8 (5)
Al25ii—Si9A—Al25i	141.54 (4)	Si17—Al29A—Al20	78.27 (13)
Si9B—Si9A—Al30Bi	146.67 (10)	Al32Axvii—Al29A—Al20	148.12 (6)
Al22vii—Si9A—Al30Bi	103.95 (10)	Al29Axviii—Al29A—Al20	90.59 (3)
Al22—Si9A—Al30Bi	67.98 (7)	Ru1ix—Al29A—Al20	57.28 (11)
Al12—Si9A—Al30Bi	113.01 (9)	Si18—Al29A—Al20	58.77 (11)
Al25ii—Si9A—Al30Bi	132.77 (9)	Ru4Aii—Al29A—Al20	107.26 (14)
Al25i—Si9A—Al30Bi	74.62 (10)	Al29Bxviii—Al29A—Al20	98.07 (17)
Si9B—Si9A—Al30Bii	146.67 (10)	Ru5Bvii—Al29A—Ru5Avii	0.72 (11)
Al22vii—Si9A—Al30Bii	67.98 (7)	Ru4Bii—Al29A—Ru5Avii	124.7 (3)
Al22—Si9A—Al30Bii	103.95 (10)	Si17—Al29A—Ru5Avii	58.34 (4)
Al12—Si9A—Al30Bii	113.01 (9)	Al32Axvii—Al29A—Ru5Avii	63.15 (10)
Al25ii—Si9A—Al30Bii	74.62 (10)	Al29Axviii—Al29A—Ru5Avii	156.31 (8)
Al25i—Si9A—Al30Bii	132.77 (9)	Ru1ix—Al29A—Ru5Avii	115.09 (6)
Al30Bi—Si9A—Al30Bii	60.00 (18)	Si18—Al29A—Ru5Avii	109.57 (5)
Si9A—Si9B—Al12	79.39 (14)	Ru4Aii—Al29A—Ru5Avii	126.69 (16)
Si9A—Si9B—Al22vii	75.46 (12)	Al29Bxviii—Al29A—Ru5Avii	150.99 (13)
Al12—Si9B—Al22vii	134.37 (7)	Al20—Al29A—Ru5Avii	106.24 (11)
Si9A—Si9B—Al22	75.46 (12)	Al32Axvii—Al29B—Ru5Bvii	69.7 (3)
Al12—Si9B—Al22	134.37 (7)	Al32Axvii—Al29B—Ru4Bii	69.5 (4)
Al22vii—Si9B—Al22	73.94 (6)	Ru5Bvii—Al29B—Ru4Bii	136.4 (6)
Si9A—Si9B—Al25ii	77.95 (7)	Al32Axvii—Al29B—Ru4Aii	72.7 (3)
Al12—Si9B—Al25ii	71.75 (5)	Ru5Bvii—Al29B—Ru4Aii	137.2 (5)
Al22vii—Si9B—Al25ii	66.16 (3)	Ru4Bii—Al29B—Ru4Aii	5.9 (4)
Al22—Si9B—Al25ii	136.32 (9)	Al32Axvii—Al29B—Al31Cxvii	21.2 (4)
Si9A—Si9B—Al25i	77.95 (7)	Ru5Bvii—Al29B—Al31Cxvii	88.6 (6)
Al12—Si9B—Al25i	71.75 (5)	Ru4Bii—Al29B—Al31Cxvii	55.2 (6)
Al22vii—Si9B—Al25i	136.32 (9)	Ru4Aii—Al29B—Al31Cxvii	59.8 (4)
Al22—Si9B—Al25i	66.16 (3)	Al32Axvii—Al29B—Ru5Avii	69.4 (3)
Al25ii—Si9B—Al25i	139.17 (10)	Ru5Bvii—Al29B—Ru5Avii	0.67 (12)
Si8—Si10A—Ru5Avii	113.04 (8)	Ru4Bii—Al29B—Ru5Avii	135.9 (5)
Si8—Si10A—Ru5A	113.04 (8)	Ru4Aii—Al29B—Ru5Avii	136.6 (5)
Ru5Avii—Si10A—Ru5A	125.3 (3)	Al31Cxvii—Al29B—Ru5Avii	88.4 (5)
Si8—Si10A—Al31Avi	163.35 (15)	Al32Axvii—Al29B—Al29Axviii	118.8 (3)
Ru5Avii—Si10A—Al31Avi	63.66 (12)	Ru5Bvii—Al29B—Al29Axviii	160.4 (3)
Ru5A—Si10A—Al31Avi	63.66 (12)	Ru4Bii—Al29B—Al29Axviii	59.88 (17)
Si8—Si10A—Ru5B	111.39 (12)	Ru4Aii—Al29B—Al29Axviii	60.44 (13)
Ru5Avii—Si10A—Ru5B	127.3 (3)	Al31Cxvii—Al29B—Al29Axviii	97.8 (4)
Ru5A—Si10A—Ru5B	2.00 (11)	Ru5Avii—Al29B—Al29Axviii	161.1 (3)
Al31Avi—Si10A—Ru5B	65.58 (16)	Al32Axvii—Al29B—Si17	121.8 (3)
Si8—Si10A—Ru5Bvii	111.39 (12)	Ru5Bvii—Al29B—Si17	57.81 (15)
Ru5Avii—Si10A—Ru5Bvii	2.00 (11)	Ru4Bii—Al29B—Si17	165.4 (4)
Ru5A—Si10A—Ru5Bvii	127.3 (3)	Ru4Aii—Al29B—Si17	164.7 (5)
Al31Avi—Si10A—Ru5Bvii	65.58 (16)	Al31Cxvii—Al29B—Si17	132.2 (5)
Ru5B—Si10A—Ru5Bvii	129.3 (3)	Ru5Avii—Al29B—Si17	58.37 (12)
Si8—Si10A—Al22vii	109.66 (18)	Al29Axviii—Al29B—Si17	105.5 (3)
Ru5Avii—Si10A—Al22vii	61.84 (4)	Al32Axvii—Al29B—Al29Bxviii	111.79 (14)
Ru5A—Si10A—Al22vii	124.32 (7)	Ru5Bvii—Al29B—Al29Bxviii	158.92 (15)
Al31Avi—Si10A—Al22vii	83.66 (8)	Ru4Bii—Al29B—Al29Bxviii	56.5 (2)
Ru5B—Si10A—Al22vii	124.72 (10)	Ru4Aii—Al29B—Al29Bxviii	57.86 (17)
Ru5Bvii—Si10A—Al22vii	61.04 (8)	Al31Cxvii—Al29B—Al29Bxviii	90.7 (4)
Si8—Si10A—Al22	109.66 (18)	Ru5Avii—Al29B—Al29Bxviii	159.53 (12)
Ru5Avii—Si10A—Al22	124.32 (7)	Al29Axviii—Al29B—Al29Bxviii	7.53 (19)
Ru5A—Si10A—Al22	61.84 (4)	Si17—Al29B—Al29Bxviii	108.96 (16)
Al31Avi—Si10A—Al22	83.66 (8)	Al32Axvii—Al29B—Al32Bxvii	18.05 (14)
Ru5B—Si10A—Al22	61.04 (8)	Ru5Bvii—Al29B—Al32Bxvii	55.3 (3)
Ru5Bvii—Si10A—Al22	124.72 (10)	Ru4Bii—Al29B—Al32Bxvii	86.7 (5)
Al22vii—Si10A—Al22	71.31 (5)	Ru4Aii—Al29B—Al32Bxvii	90.3 (4)
Si8—Si10A—Al23vii	61.62 (5)	Al31Cxvii—Al29B—Al32Bxvii	33.4 (4)
Ru5Avii—Si10A—Al23vii	62.95 (5)	Ru5Avii—Al29B—Al32Bxvii	55.1 (2)
Ru5A—Si10A—Al23vii	119.35 (13)	Al29Axviii—Al29B—Al32Bxvii	128.2 (3)
Al31Avi—Si10A—Al23vii	104.74 (17)	Si17—Al29B—Al32Bxvii	103.9 (3)
Ru5B—Si10A—Al23vii	119.82 (14)	Al29Bxviii—Al29B—Al32Bxvii	120.67 (17)
Ru5Bvii—Si10A—Al23vii	62.35 (9)	Al32Axvii—Al29B—Si18	98.6 (3)
Al22vii—Si10A—Al23vii	111.61 (3)	Ru5Bvii—Al29B—Si18	108.7 (2)
Al22—Si10A—Al23vii	171.2 (2)	Ru4Bii—Al29B—Si18	63.5 (5)
Si8—Si10A—Al23	61.62 (5)	Ru4Aii—Al29B—Si18	57.63 (13)
Ru5Avii—Si10A—Al23	119.35 (13)	Al31Cxvii—Al29B—Si18	102.0 (4)
Ru5A—Si10A—Al23	62.95 (5)	Ru5Avii—Al29B—Si18	108.11 (18)
Al31Avi—Si10A—Al23	104.74 (17)	Al29Axviii—Al29B—Si18	88.2 (2)
Ru5B—Si10A—Al23	62.35 (9)	Si17—Al29B—Si18	119.6 (5)
Ru5Bvii—Si10A—Al23	119.82 (14)	Al29Bxviii—Al29B—Si18	92.09 (12)
Al22vii—Si10A—Al23	171.2 (2)	Al32Bxvii—Al29B—Si18	112.4 (3)
Al22—Si10A—Al23	111.61 (3)	Al32Axvii—Al29B—Ru1ix	162.7 (3)
Al23vii—Si10A—Al23	64.26 (3)	Ru5Bvii—Al29B—Ru1ix	110.0 (3)
Si8—Si10A—Al11	62.60 (13)	Ru4Bii—Al29B—Ru1ix	113.5 (4)
Ru5Avii—Si10A—Al11	113.16 (11)	Ru4Aii—Al29B—Ru1ix	112.0 (3)
Ru5A—Si10A—Al11	113.16 (11)	Al31Cxvii—Al29B—Ru1ix	146.8 (4)
Al31Avi—Si10A—Al11	134.05 (5)	Ru5Avii—Al29B—Ru1ix	110.5 (3)
Ru5B—Si10A—Al11	111.49 (14)	Al29Axviii—Al29B—Ru1ix	56.21 (15)
Ru5Bvii—Si10A—Al11	111.49 (14)	Si17—Al29B—Ru1ix	52.7 (2)
Al22vii—Si10A—Al11	59.88 (9)	Al29Bxviii—Al29B—Ru1ix	61.96 (12)
Al22—Si10A—Al11	59.88 (9)	Al32Bxvii—Al29B—Ru1ix	149.2 (2)
Al23vii—Si10A—Al11	113.80 (16)	Si18—Al29B—Ru1ix	97.8 (4)
Al23—Si10A—Al11	113.80 (16)	Al30B—Al30A—Al27vii	106.2 (4)
Al31Avi—Al10B—Ru5Avii	71.4 (5)	Al30B—Al30A—Ru1ix	80.6 (4)
Al31Avi—Al10B—Ru5A	71.4 (5)	Al27vii—Al30A—Ru1ix	168.32 (11)
Ru5Avii—Al10B—Ru5A	141.5 (11)	Al30B—Al30A—Al20	87.8 (4)
Al31Avi—Al10B—Ru5B	73.0 (5)	Al27vii—Al30A—Al20	112.19 (5)
Ru5Avii—Al10B—Ru5B	143.2 (11)	Ru1ix—Al30A—Al20	57.91 (2)
Ru5A—Al10B—Ru5B	1.72 (12)	Al30B—Al30A—Ru7xxi	91.6 (4)
Al31Avi—Al10B—Ru5Bvii	73.0 (5)	Al27vii—Al30A—Ru7xxi	62.59 (3)
Ru5Avii—Al10B—Ru5Bvii	1.72 (12)	Ru1ix—Al30A—Ru7xxi	127.54 (4)
Ru5A—Al10B—Ru5Bvii	143.2 (11)	Al20—Al30A—Ru7xxi	174.32 (4)
Ru5B—Al10B—Ru5Bvii	144.9 (11)	Al30B—Al30A—Si17	135.5 (5)
Al31Avi—Al10B—Al31Bv	16.12 (19)	Al27vii—Al30A—Si17	118.23 (16)
Ru5Avii—Al10B—Al31Bv	58.7 (4)	Ru1ix—Al30A—Si17	55.77 (3)
Ru5A—Al10B—Al31Bv	86.1 (7)	Al20—Al30A—Si17	76.97 (5)
Ru5B—Al10B—Al31Bv	87.6 (6)	Ru7xxi—Al30A—Si17	107.23 (10)
Ru5Bvii—Al10B—Al31Bv	60.2 (4)	Al30B—Al30A—Al21vii	143.3 (4)
Al31Avi—Al10B—Al31Bvi	16.12 (19)	Al27vii—Al30A—Al21vii	72.38 (8)
Ru5Avii—Al10B—Al31Bvi	86.1 (7)	Ru1ix—Al30A—Al21vii	107.95 (8)
Ru5A—Al10B—Al31Bvi	58.7 (4)	Al20—Al30A—Al21vii	127.46 (14)
Ru5B—Al10B—Al31Bvi	60.2 (4)	Ru7xxi—Al30A—Al21vii	54.39 (5)
Ru5Bvii—Al10B—Al31Bvi	87.6 (6)	Si17—Al30A—Al21vii	58.36 (8)
Al31Bv—Al10B—Al31Bvi	27.7 (4)	Al30B—Al30A—Al14ix	73.0 (4)
Al31Avi—Al10B—Al23vii	115.5 (7)	Al27vii—Al30A—Al14ix	127.62 (4)
Ru5Avii—Al10B—Al23vii	64.74 (13)	Ru1ix—Al30A—Al14ix	63.04 (4)
Ru5A—Al10B—Al23vii	125.3 (4)	Al20—Al30A—Al14ix	120.03 (7)
Ru5B—Al10B—Al23vii	125.3 (4)	Ru7xxi—Al30A—Al14ix	65.06 (3)
Ru5Bvii—Al10B—Al23vii	64.05 (14)	Si17—Al30A—Al14ix	79.00 (4)
Al31Bv—Al10B—Al23vii	112.9 (6)	Al21vii—Al30A—Al14ix	79.39 (4)
Al31Bvi—Al10B—Al23vii	130.1 (8)	Al30B—Al30A—Ru6vii	114.5 (4)
Al31Avi—Al10B—Al23	115.5 (7)	Al27vii—Al30A—Ru6vii	59.08 (4)
Ru5Avii—Al10B—Al23	125.3 (4)	Ru1ix—Al30A—Ru6vii	109.64 (4)
Ru5A—Al10B—Al23	64.74 (13)	Al20—Al30A—Ru6vii	54.97 (3)
Ru5B—Al10B—Al23	64.05 (14)	Ru7xxi—Al30A—Ru6vii	120.50 (8)
Ru5Bvii—Al10B—Al23	125.3 (4)	Si17—Al30A—Ru6vii	90.49 (10)
Al31Bv—Al10B—Al23	130.1 (8)	Al21vii—Al30A—Ru6vii	96.54 (12)
Al31Bvi—Al10B—Al23	112.9 (6)	Al14ix—Al30A—Ru6vii	169.37 (11)
Al23vii—Al10B—Al23	64.31 (19)	Al30A—Al30B—Ru1ix	88.0 (5)
Al31Avi—Al10B—Al22vii	88.0 (3)	Al30A—Al30B—Al20	81.1 (4)
Ru5Avii—Al10B—Al22vii	61.92 (12)	Ru1ix—Al30B—Al20	57.90 (7)
Ru5A—Al10B—Al22vii	126.1 (3)	Al30A—Al30B—Al30Bxviii	144.1 (4)
Ru5B—Al10B—Al22vii	126.1 (3)	Ru1ix—Al30B—Al30Bxviii	58.35 (17)
Ru5Bvii—Al10B—Al22vii	61.19 (13)	Al20—Al30B—Al30Bxviii	89.59 (13)
Al31Bv—Al10B—Al22vii	73.5 (3)	Al30A—Al30B—Si9Aix	151.0 (5)
Al31Bvi—Al10B—Al22vii	89.1 (3)	Ru1ix—Al30B—Si9Aix	105.2 (2)
Al23vii—Al10B—Al22vii	108.6 (3)	Al20—Al30B—Si9Aix	84.30 (13)
Al23—Al10B—Al22vii	156.4 (10)	Al30Bxviii—Al30B—Si9Aix	60.00 (9)
Al31Avi—Al10B—Al22	88.0 (3)	Al30A—Al30B—Al14ix	96.5 (5)
Ru5Avii—Al10B—Al22	126.1 (3)	Ru1ix—Al30B—Al14ix	64.97 (8)
Ru5A—Al10B—Al22	61.92 (12)	Al20—Al30B—Al14ix	122.86 (13)
Ru5B—Al10B—Al22	61.19 (13)	Al30Bxviii—Al30B—Al14ix	60.05 (14)
Ru5Bvii—Al10B—Al22	126.1 (3)	Si9Aix—Al30B—Al14ix	112.4 (2)
Al31Bv—Al10B—Al22	89.1 (3)	Al30A—Al30B—Ru7xxi	77.7 (4)
Al31Bvi—Al10B—Al22	73.5 (3)	Ru1ix—Al30B—Ru7xxi	126.25 (15)
Al23vii—Al10B—Al22	156.4 (10)	Al20—Al30B—Ru7xxi	158.1 (3)
Al23—Al10B—Al22	108.6 (3)	Al30Bxviii—Al30B—Ru7xxi	110.95 (13)
Al22vii—Al10B—Al22	68.3 (3)	Si9Aix—Al30B—Ru7xxi	112.11 (19)
Ru7—Al11—Ru7vii	134.87 (3)	Al14ix—Al30B—Ru7xxi	65.67 (7)
Ru7—Al11—Al26vii	119.96 (3)	Al30A—Al30B—Al27vii	63.6 (4)
Ru7vii—Al11—Al26vii	62.525 (13)	Ru1ix—Al30B—Al27vii	150.0 (3)
Ru7—Al11—Al26	62.525 (14)	Al20—Al30B—Al27vii	105.66 (16)
Ru7vii—Al11—Al26	119.96 (3)	Al30Bxviii—Al30B—Al27vii	151.45 (14)
Al26vii—Al11—Al26	62.69 (2)	Si9Aix—Al30B—Al27vii	96.97 (13)
Ru7—Al11—Al22vii	130.54 (3)	Al14ix—Al30B—Al27vii	124.23 (15)
Ru7vii—Al11—Al22vii	66.435 (13)	Ru7xxi—Al30B—Al27vii	59.49 (8)
Al26vii—Al11—Al22vii	109.406 (16)	Al30A—Al30B—Al22xxi	118.9 (5)
Al26—Al11—Al22vii	157.46 (3)	Ru1ix—Al30B—Al22xxi	152.7 (3)
Ru7—Al11—Al22	66.435 (13)	Al20—Al30B—Al22xxi	126.71 (16)
Ru7vii—Al11—Al22	130.54 (3)	Al30Bxviii—Al30B—Al22xxi	94.41 (13)
Al26vii—Al11—Al22	157.46 (3)	Si9Aix—Al30B—Al22xxi	53.74 (12)
Al26—Al11—Al22	109.406 (16)	Al14ix—Al30B—Al22xxi	104.43 (15)
Al22vii—Al11—Al22	69.28 (3)	Ru7xxi—Al30B—Al22xxi	61.37 (7)
Ru7—Al11—Al14	67.460 (14)	Al27vii—Al30B—Al22xxi	57.09 (7)
Ru7vii—Al11—Al14	67.460 (14)	Al31Bvii—Al31A—Al31B	104.6 (8)
Al26vii—Al11—Al14	95.15 (2)	Al31Bvii—Al31A—Al31C	111.1 (6)
Al26—Al11—Al14	95.15 (2)	Al31B—Al31A—Al31C	7.5 (6)
Al22vii—Al11—Al14	106.85 (2)	Al31Bvii—Al31A—Al31Cvii	7.5 (6)
Al22—Al11—Al14	106.85 (2)	Al31B—Al31A—Al31Cvii	111.1 (6)
Ru7—Al11—Si8	108.159 (15)	Al31C—Al31A—Al31Cvii	117.4 (8)
Ru7vii—Al11—Si8	108.160 (15)	Al31Bvii—Al31A—Al10Bxv	113.3 (4)
Al26vii—Al11—Si8	57.477 (18)	Al31B—Al31A—Al10Bxv	113.3 (4)
Al26—Al11—Si8	57.478 (18)	Al31C—Al31A—Al10Bxv	112.4 (4)
Al22vii—Al11—Si8	100.13 (2)	Al31Cvii—Al31A—Al10Bxv	112.4 (4)
Al22—Al11—Si8	100.13 (2)	Al31Bvii—Al31A—Ru4B	63.1 (4)
Al14—Al11—Si8	147.02 (3)	Al31B—Al31A—Ru4B	63.1 (4)
Ru7—Al11—Si10A	111.479 (16)	Al31C—Al31A—Ru4B	65.0 (4)
Ru7vii—Al11—Si10A	111.479 (16)	Al31Cvii—Al31A—Ru4B	65.0 (4)
Al26vii—Al11—Si10A	102.01 (5)	Al10Bxv—Al31A—Ru4B	172.6 (4)
Al26—Al11—Si10A	102.01 (5)	Al31Bvii—Al31A—Al32Avii	8.9 (4)
Al22vii—Al11—Si10A	57.51 (4)	Al31B—Al31A—Al32Avii	112.1 (4)
Al22—Al11—Si10A	57.51 (4)	Al31C—Al31A—Al32Avii	118.2 (4)
Al14—Al11—Si10A	159.87 (6)	Al31Cvii—Al31A—Al32Avii	1.6 (4)
Si8—Al11—Si10A	53.11 (5)	Al10Bxv—Al31A—Al32Avii	112.72 (12)
Ru1iv—Al12—Si9B	105.42 (6)	Ru4B—Al31A—Al32Avii	64.82 (9)
Ru1iv—Al12—Si9A	127.62 (3)	Al31Bvii—Al31A—Al32A	112.1 (4)
Si9B—Al12—Si9A	22.19 (6)	Al31B—Al31A—Al32A	8.9 (4)
Ru1iv—Al12—Ru2	117.87 (3)	Al31C—Al31A—Al32A	1.6 (4)
Si9B—Al12—Ru2	136.71 (7)	Al31Cvii—Al31A—Al32A	118.2 (4)
Si9A—Al12—Ru2	114.52 (3)	Al10Bxv—Al31A—Al32A	112.72 (12)
Ru1iv—Al12—Si16ii	105.283 (19)	Ru4B—Al31A—Al32A	64.82 (9)
Si9B—Al12—Si16ii	111.35 (3)	Al32Avii—Al31A—Al32A	119.08 (6)
Si9A—Al12—Si16ii	101.29 (2)	Al31Bvii—Al31A—Si10Axv	111.3 (4)
Ru2—Al12—Si16ii	58.581 (15)	Al31B—Al31A—Si10Axv	111.3 (4)
Ru1iv—Al12—Si16i	105.283 (19)	Al31C—Al31A—Si10Axv	110.9 (4)
Si9B—Al12—Si16i	111.35 (3)	Al31Cvii—Al31A—Si10Axv	110.9 (4)
Si9A—Al12—Si16i	101.29 (2)	Al10Bxv—Al31A—Si10Axv	3.7 (3)
Ru2—Al12—Si16i	58.581 (15)	Ru4B—Al31A—Si10Axv	168.9 (3)
Si16ii—Al12—Si16i	117.10 (3)	Al32Avii—Al31A—Si10Axv	111.36 (4)
Ru1iv—Al12—Si17xii	56.847 (15)	Al32A—Al31A—Si10Axv	111.36 (4)
Si9B—Al12—Si17xii	96.74 (4)	Al31Bvii—Al31A—Si19vii	97.6 (4)
Si9A—Al12—Si17xii	108.10 (2)	Al31B—Al31A—Si19vii	148.1 (4)
Ru2—Al12—Si17xii	106.339 (18)	Al31C—Al31A—Si19vii	140.9 (4)
Si16ii—Al12—Si17xii	56.184 (13)	Al31Cvii—Al31A—Si19vii	90.2 (4)
Si16i—Al12—Si17xii	150.58 (3)	Al10Bxv—Al31A—Si19vii	77.3 (3)
Ru1iv—Al12—Si17xiii	56.847 (15)	Ru4B—Al31A—Si19vii	109.3 (2)
Si9B—Al12—Si17xiii	96.74 (4)	Al32Avii—Al31A—Si19vii	88.77 (2)
Si9A—Al12—Si17xiii	108.10 (2)	Al32A—Al31A—Si19vii	139.39 (4)
Ru2—Al12—Si17xiii	106.339 (18)	Si10Axv—Al31A—Si19vii	80.56 (6)
Si16ii—Al12—Si17xiii	150.58 (3)	Al31Bvii—Al31A—Si19	148.1 (4)
Si16i—Al12—Si17xiii	56.184 (13)	Al31B—Al31A—Si19	97.6 (4)
Si17xii—Al12—Si17xiii	113.59 (3)	Al31C—Al31A—Si19	90.2 (4)
Ru1iv—Al12—Al14iv	60.71 (2)	Al31Cvii—Al31A—Si19	140.9 (4)
Si9B—Al12—Al14iv	166.13 (7)	Al10Bxv—Al31A—Si19	77.3 (3)
Si9A—Al12—Al14iv	171.68 (4)	Ru4B—Al31A—Si19	109.3 (2)
Ru2—Al12—Al14iv	57.157 (19)	Al32Avii—Al31A—Si19	139.39 (4)
Si16ii—Al12—Al14iv	74.706 (18)	Al32A—Al31A—Si19	88.77 (2)
Si16i—Al12—Al14iv	74.706 (18)	Si10Axv—Al31A—Si19	80.55 (6)
Si17xii—Al12—Al14iv	75.984 (18)	Si19vii—Al31A—Si19	53.85 (3)
Si17xiii—Al12—Al14iv	75.984 (18)	Al31Bvii—Al31A—Ru5Axv	155.4 (4)
Ru4B—Al13—Ru4A	6.2 (4)	Al31B—Al31A—Ru5Axv	66.3 (4)
Ru4B—Al13—Si8	164.9 (5)	Al31C—Al31A—Ru5Axv	61.9 (4)
Ru4A—Al13—Si8	158.75 (8)	Al31Cvii—Al31A—Ru5Axv	161.0 (4)
Ru4B—Al13—Si19vii	109.2 (4)	Al10Bxv—Al31A—Ru5Axv	56.37 (5)
Ru4A—Al13—Si19vii	114.51 (6)	Ru4B—Al31A—Ru5Axv	123.97 (4)
Si8—Al13—Si19vii	84.06 (2)	Al32Avii—Al31A—Ru5Axv	162.40 (5)
Ru4B—Al13—Si19	109.2 (4)	Al32A—Al31A—Ru5Axv	61.54 (4)
Ru4A—Al13—Si19	114.51 (6)	Si10Axv—Al31A—Ru5Axv	56.78 (4)
Si8—Al13—Si19	84.06 (2)	Si19vii—Al31A—Ru5Axv	100.90 (5)
Si19vii—Al13—Si19	55.57 (2)	Si19—Al31A—Ru5Axv	55.81 (3)
Ru4B—Al13—Ru6vii	121.61 (3)	Al31A—Al31B—Al31C	165.1 (12)
Ru4A—Al13—Ru6vii	121.078 (15)	Al31A—Al31B—Al31Bvii	37.7 (4)
Si8—Al13—Ru6vii	58.794 (12)	Al31C—Al31B—Al31Bvii	154.5 (10)
Si19vii—Al13—Ru6vii	57.940 (13)	Al31A—Al31B—Al32A	166.9 (6)
Si19—Al13—Ru6vii	105.19 (2)	Al31C—Al31B—Al32A	2.0 (9)
Ru4B—Al13—Ru6	121.61 (3)	Al31Bvii—Al31B—Al32A	152.61 (19)
Ru4A—Al13—Ru6	121.078 (15)	Al31A—Al31B—Al31Cvii	47.2 (5)
Si8—Al13—Ru6	58.794 (12)	Al31C—Al31B—Al31Cvii	144.7 (13)
Si19vii—Al13—Ru6	105.19 (2)	Al31Bvii—Al31B—Al31Cvii	9.9 (4)
Si19—Al13—Ru6	57.941 (13)	Al32A—Al31B—Al31Cvii	142.7 (5)
Ru6vii—Al13—Ru6	116.50 (2)	Al31A—Al31B—Ru4B	97.9 (5)
Ru4B—Al13—Al27	60.94 (17)	Al31C—Al31B—Ru4B	85.6 (10)
Ru4A—Al13—Al27	59.05 (2)	Al31Bvii—Al31B—Ru4B	73.2 (3)
Si8—Al13—Al27	113.14 (2)	Al32A—Al31B—Ru4B	84.3 (3)
Si19vii—Al13—Al27	141.60 (3)	Al31Cvii—Al31B—Ru4B	65.2 (4)
Si19—Al13—Al27	90.892 (17)	Al31A—Al31B—Al32B	156.6 (6)
Ru6vii—Al13—Al27	160.34 (3)	Al31C—Al31B—Al32B	20.9 (9)
Ru6—Al13—Al27	62.650 (11)	Al31Bvii—Al31B—Al32B	158.02 (18)
Ru4B—Al13—Al27vii	60.94 (17)	Al32A—Al31B—Al32B	21.53 (15)
Ru4A—Al13—Al27vii	59.05 (2)	Al31Cvii—Al31B—Al32B	151.1 (5)
Si8—Al13—Al27vii	113.14 (2)	Ru4B—Al31B—Al32B	104.7 (4)
Si19vii—Al13—Al27vii	90.892 (16)	Al31A—Al31B—Ru4A	98.4 (5)
Si19—Al13—Al27vii	141.60 (3)	Al31C—Al31B—Ru4A	84.4 (10)
Ru6vii—Al13—Al27vii	62.650 (11)	Al31Bvii—Al31B—Ru4A	74.96 (19)
Ru6—Al13—Al27vii	160.34 (3)	Al32A—Al31B—Ru4A	83.2 (3)
Al27—Al13—Al27vii	110.94 (3)	Al31Cvii—Al31B—Ru4A	67.2 (4)
Ru4B—Al13—Al31A	55.7 (5)	Ru4B—Al31B—Ru4A	2.6 (2)
Ru4A—Al13—Al31A	61.84 (7)	Al32B—Al31B—Ru4A	103.9 (3)
Si8—Al13—Al31A	139.41 (4)	Al31A—Al31B—Ru5Axv	96.4 (4)
Si19vii—Al13—Al31A	60.45 (3)	Al31C—Al31B—Ru5Axv	74.8 (10)
Si19—Al13—Al31A	60.45 (3)	Al31Bvii—Al31B—Ru5Axv	130.0 (2)
Ru6vii—Al13—Al31A	109.49 (2)	Al32A—Al31B—Ru5Axv	76.5 (2)
Ru6—Al13—Al31A	109.49 (2)	Al31Cvii—Al31B—Ru5Axv	139.5 (5)
Al27—Al13—Al31A	88.14 (2)	Ru4B—Al31B—Ru5Axv	151.4 (4)
Al27vii—Al13—Al31A	88.14 (2)	Al32B—Al31B—Ru5Axv	60.6 (2)
Ru4B—Al13—Al31B	47.2 (5)	Ru4A—Al31B—Ru5Axv	148.9 (3)
Ru4A—Al13—Al31B	53.11 (14)	Al31A—Al31B—Ru5Bxv	98.5 (5)
Si8—Al13—Al31B	146.96 (12)	Al31C—Al31B—Ru5Bxv	72.6 (10)
Si19vii—Al13—Al31B	75.54 (16)	Al31Bvii—Al31B—Ru5Bxv	132.1 (2)
Si19—Al13—Al31B	62.99 (11)	Al32A—Al31B—Ru5Bxv	74.3 (2)
Ru6vii—Al13—Al31B	125.08 (16)	Al31Cvii—Al31B—Ru5Bxv	141.5 (5)
Ru6—Al13—Al31B	101.66 (13)	Ru4B—Al31B—Ru5Bxv	150.0 (4)
Al27—Al13—Al31B	72.19 (16)	Al32B—Al31B—Ru5Bxv	58.5 (2)
Al27vii—Al13—Al31B	93.16 (12)	Ru4A—Al31B—Ru5Bxv	147.5 (3)
Al31A—Al13—Al31B	15.97 (15)	Ru5Axv—Al31B—Ru5Bxv	2.15 (10)
Ru4B—Al13—Al31Bvii	47.2 (5)	Al31A—Al31B—Al10Bxv	50.6 (4)
Ru4A—Al13—Al31Bvii	53.11 (14)	Al31C—Al31B—Al10Bxv	126.5 (10)
Si8—Al13—Al31Bvii	146.96 (12)	Al31Bvii—Al31B—Al10Bxv	76.16 (19)
Si19vii—Al13—Al31Bvii	62.99 (11)	Al32A—Al31B—Al10Bxv	127.8 (3)
Si19—Al13—Al31Bvii	75.53 (16)	Al31Cvii—Al31B—Al10Bxv	85.1 (4)
Ru6vii—Al13—Al31Bvii	101.66 (13)	Ru4B—Al31B—Al10Bxv	147.8 (4)
Ru6—Al13—Al31Bvii	125.08 (16)	Al32B—Al31B—Al10Bxv	107.4 (3)
Al27—Al13—Al31Bvii	93.16 (12)	Ru4A—Al31B—Al10Bxv	148.8 (4)
Al27vii—Al13—Al31Bvii	72.19 (16)	Ru5Axv—Al31B—Al10Bxv	54.54 (15)
Al31A—Al13—Al31Bvii	15.97 (15)	Ru5Bxv—Al31B—Al10Bxv	56.55 (17)
Al31B—Al13—Al31Bvii	25.3 (3)	Al31A—Al31B—Si19	66.3 (4)
Al30Bii—Al14—Al30Bi	59.9 (3)	Al31C—Al31B—Si19	98.8 (9)
Al30Bii—Al14—Ru2iii	141.14 (16)	Al31Bvii—Al31B—Si19	101.39 (16)
Al30Bi—Al14—Ru2iii	141.14 (16)	Al32A—Al31B—Si19	100.7 (2)
Al30Bii—Al14—Al11	75.89 (12)	Al31Cvii—Al31B—Si19	109.1 (4)
Al30Bi—Al14—Al11	75.89 (12)	Ru4B—Al31B—Si19	109.4 (3)
Ru2iii—Al14—Al11	132.37 (3)	Al32B—Al31B—Si19	99.9 (2)
Al30Bii—Al14—Al28xi	162.41 (16)	Ru4A—Al31B—Si19	107.26 (19)
Al30Bi—Al14—Al28xi	107.05 (13)	Ru5Axv—Al31B—Si19	55.09 (12)
Ru2iii—Al14—Al28xi	56.454 (17)	Ru5Bxv—Al31B—Si19	56.06 (14)
Al11—Al14—Al28xi	89.86 (2)	Al10Bxv—Al31B—Si19	67.3 (3)
Al30Bii—Al14—Al28xiv	107.05 (13)	Al31B—Al31C—Al32A	176.2 (17)
Al30Bi—Al14—Al28xiv	162.41 (16)	Al31B—Al31C—Al32B	148.0 (14)
Ru2iii—Al14—Al28xiv	56.454 (17)	Al32A—Al31C—Al32B	33.2 (5)
Al11—Al14—Al28xiv	89.86 (2)	Al31B—Al31C—Al31A	7.4 (6)
Al28xi—Al14—Al28xiv	82.78 (3)	Al32A—Al31C—Al31A	175.7 (11)
Al30Bii—Al14—Al30Aii	10.48 (9)	Al32B—Al31C—Al31A	148.5 (9)
Al30Bi—Al14—Al30Aii	69.2 (2)	Al31B—Al31C—Al31Bvii	15.6 (6)
Ru2iii—Al14—Al30Aii	130.97 (8)	Al32A—Al31C—Al31Bvii	160.7 (11)
Al11—Al14—Al30Aii	82.35 (6)	Al32B—Al31C—Al31Bvii	153.5 (8)
Al28xi—Al14—Al30Aii	171.95 (7)	Al31A—Al31C—Al31Bvii	21.6 (2)
Al28xiv—Al14—Al30Aii	99.12 (7)	Al31B—Al31C—Al32Bxix	138.0 (12)
Al30Bii—Al14—Al30Ai	69.2 (2)	Al32A—Al31C—Al32Bxix	43.3 (6)
Al30Bi—Al14—Al30Ai	10.48 (9)	Al32B—Al31C—Al32Bxix	10.2 (3)
Ru2iii—Al14—Al30Ai	130.97 (8)	Al31A—Al31C—Al32Bxix	138.3 (7)
Al11—Al14—Al30Ai	82.35 (6)	Al31Bvii—Al31C—Al32Bxix	145.3 (7)
Al28xi—Al14—Al30Ai	99.12 (7)	Al31B—Al31C—Ru4B	73.8 (10)
Al28xiv—Al14—Al30Ai	171.95 (7)	Al32A—Al31C—Ru4B	103.9 (9)
Al30Aii—Al14—Al30Ai	77.95 (15)	Al32B—Al31C—Ru4B	134.7 (9)
Al30Bii—Al14—Ru1	55.27 (7)	Al31A—Al31C—Ru4B	75.7 (6)
Al30Bi—Al14—Ru1	55.27 (7)	Al31Bvii—Al31C—Ru4B	61.0 (5)
Ru2iii—Al14—Ru1	105.08 (2)	Al32Bxix—Al31C—Ru4B	144.0 (7)
Al11—Al14—Ru1	122.55 (3)	Al31B—Al31C—Ru5Axv	86.2 (10)
Al28xi—Al14—Ru1	129.33 (2)	Al32A—Al31C—Ru5Axv	97.1 (9)
Al28xiv—Al14—Ru1	129.33 (2)	Al32B—Al31C—Ru5Axv	71.3 (5)
Al30Aii—Al14—Ru1	54.97 (2)	Al31A—Al31C—Ru5Axv	81.9 (5)
Al30Ai—Al14—Ru1	54.97 (2)	Al31Bvii—Al31C—Ru5Axv	101.4 (6)
Al30Bii—Al14—Ru7vii	57.95 (8)	Al32Bxix—Al31C—Ru5Axv	63.2 (3)
Al30Bi—Al14—Ru7vii	104.88 (16)	Ru4B—Al31C—Ru5Axv	151.1 (7)
Ru2iii—Al14—Ru7vii	113.742 (17)	Al31B—Al31C—Ru5Bxv	89.1 (10)
Al11—Al14—Ru7vii	52.088 (11)	Al32A—Al31C—Ru5Bxv	94.1 (9)
Al28xi—Al14—Ru7vii	120.55 (3)	Al32B—Al31C—Ru5Bxv	68.6 (5)
Al28xiv—Al14—Ru7vii	57.677 (13)	Al31A—Al31C—Ru5Bxv	84.9 (5)
Al30Aii—Al14—Ru7vii	55.52 (2)	Al31Bvii—Al31C—Ru5Bxv	104.4 (6)
Al30Ai—Al14—Ru7vii	115.22 (9)	Al32Bxix—Al31C—Ru5Bxv	60.6 (3)
Ru1—Al14—Ru7vii	110.100 (17)	Ru4B—Al31C—Ru5Bxv	153.2 (6)
Al30Bii—Al14—Ru7	104.88 (16)	Ru5Axv—Al31C—Ru5Bxv	2.97 (11)
Al30Bi—Al14—Ru7	57.95 (8)	Al31B—Al31C—Ru4A	76.9 (10)
Ru2iii—Al14—Ru7	113.743 (17)	Al32A—Al31C—Ru4A	100.9 (9)
Al11—Al14—Ru7	52.087 (11)	Al32B—Al31C—Ru4A	132.4 (8)
Al28xi—Al14—Ru7	57.677 (13)	Al31A—Al31C—Ru4A	78.5 (5)
Al28xiv—Al14—Ru7	120.55 (3)	Al31Bvii—Al31C—Ru4A	64.4 (4)
Al30Aii—Al14—Ru7	115.22 (9)	Al32Bxix—Al31C—Ru4A	142.0 (7)
Al30Ai—Al14—Ru7	55.52 (2)	Ru4B—Al31C—Ru4A	3.9 (3)
Ru1—Al14—Ru7	110.100 (17)	Ru5Axv—Al31C—Ru4A	151.3 (6)
Ru7vii—Al14—Ru7	104.15 (2)	Ru5Bxv—Al31C—Ru4A	153.1 (6)
Ru3—Al15—Ru4A	161.17 (5)	Al31B—Al31C—Al29Bviii	114.2 (11)
Ru3—Al15—Si18viii	133.53 (3)	Al32A—Al31C—Al29Bviii	62.0 (7)
Ru4A—Al15—Si18viii	60.00 (3)	Al32B—Al31C—Al29Bviii	79.7 (6)
Ru3—Al15—Si18ix	133.53 (3)	Al31A—Al31C—Al29Bviii	120.6 (7)
Ru4A—Al15—Si18ix	60.00 (3)	Al31Bvii—Al31C—Al29Bviii	99.0 (6)
Si18viii—Al15—Si18ix	66.95 (3)	Al32Bxix—Al31C—Al29Bviii	86.6 (5)
Ru3—Al15—Ru4B	159.3 (2)	Ru4B—Al31C—Al29Bviii	60.3 (4)
Ru4A—Al15—Ru4B	1.90 (19)	Ru5Axv—Al31C—Al29Bviii	148.5 (6)
Si18viii—Al15—Ru4B	61.48 (16)	Ru5Bxv—Al31C—Al29Bviii	146.4 (6)
Si18ix—Al15—Ru4B	61.48 (16)	Ru4A—Al31C—Al29Bviii	60.1 (3)
Ru3—Al15—Al27vii	114.21 (2)	Al31B—Al31C—Al31Cvii	25.5 (10)
Ru4A—Al15—Al27vii	57.01 (2)	Al32A—Al31C—Al31Cvii	150.9 (7)
Si18viii—Al15—Al27vii	111.82 (3)	Al32B—Al31C—Al31Cvii	152.9 (5)
Si18ix—Al15—Al27vii	61.257 (17)	Al31A—Al31C—Al31Cvii	31.3 (4)
Ru4B—Al15—Al27vii	56.29 (8)	Al31Bvii—Al31C—Al31Cvii	9.9 (4)
Ru3—Al15—Al27	114.21 (2)	Al32Bxix—Al31C—Al31Cvii	147.3 (3)
Ru4A—Al15—Al27	57.01 (2)	Ru4B—Al31C—Al31Cvii	53.3 (5)
Si18viii—Al15—Al27	61.258 (17)	Ru5Axv—Al31C—Al31Cvii	111.0 (4)
Si18ix—Al15—Al27	111.82 (3)	Ru5Bxv—Al31C—Al31Cvii	114.0 (4)
Ru4B—Al15—Al27	56.29 (8)	Ru4A—Al31C—Al31Cvii	56.9 (4)
Al27vii—Al15—Al27	101.23 (3)	Al29Bviii—Al31C—Al31Cvii	89.3 (4)
Ru3—Al15—Al21	57.760 (15)	Al32B—Al32A—Al31C	112.8 (8)
Ru4A—Al15—Al21	122.019 (17)	Al32B—Al32A—Al32Bxix	2.4 (5)
Si18viii—Al15—Al21	82.302 (16)	Al31C—Al32A—Al32Bxix	114.9 (8)
Si18ix—Al15—Al21	142.66 (3)	Al32B—Al32A—Al31B	113.5 (4)
Ru4B—Al15—Al21	121.78 (3)	Al31C—Al32A—Al31B	1.8 (8)
Al27vii—Al15—Al21	155.18 (4)	Al32Bxix—Al32A—Al31B	115.5 (2)
Al27—Al15—Al21	66.782 (15)	Al32B—Al32A—Al29Bviii	111.2 (3)
Ru3—Al15—Al21vii	57.759 (15)	Al31C—Al32A—Al29Bviii	96.8 (7)
Ru4A—Al15—Al21vii	122.019 (17)	Al32Bxix—Al32A—Al29Bviii	111.7 (2)
Si18viii—Al15—Al21vii	142.66 (3)	Al31B—Al32A—Al29Bviii	95.1 (2)
Si18ix—Al15—Al21vii	82.302 (16)	Al32B—Al32A—Al31A	114.0 (3)
Ru4B—Al15—Al21vii	121.78 (3)	Al31C—Al32A—Al31A	2.7 (7)
Al27vii—Al15—Al21vii	66.782 (15)	Al32Bxix—Al32A—Al31A	115.96 (16)
Al27—Al15—Al21vii	155.18 (4)	Al31B—Al32A—Al31A	4.16 (18)
Al21—Al15—Al21vii	114.74 (3)	Al29Bviii—Al32A—Al31A	98.51 (15)
Ru3—Al15—Al13	107.37 (3)	Al32B—Al32A—Al29Aviii	112.6 (3)
Ru4A—Al15—Al13	53.79 (3)	Al31C—Al32A—Al29Aviii	98.7 (7)
Si18viii—Al15—Al13	104.09 (3)	Al32Bxix—Al32A—Al29Aviii	112.93 (15)
Si18ix—Al15—Al13	104.09 (3)	Al31B—Al32A—Al29Aviii	96.98 (19)
Ru4B—Al15—Al13	51.9 (2)	Al29Bviii—Al32A—Al29Aviii	3.24 (15)
Al27vii—Al15—Al13	54.228 (18)	Al31A—Al32A—Al29Aviii	100.31 (5)
Al27—Al15—Al13	54.228 (18)	Al32B—Al32A—Al32Axix	1.5 (3)
Al21—Al15—Al13	103.53 (2)	Al31C—Al32A—Al32Axix	114.2 (7)
Al21vii—Al15—Al13	103.53 (2)	Al32Bxix—Al32A—Al32Axix	0.82 (16)
Si17xv—Si16—Ru6vii	111.935 (18)	Al31B—Al32A—Al32Axix	114.81 (19)
Si17xv—Si16—Ru2ix	112.514 (19)	Al29Bviii—Al32A—Al32Axix	111.50 (14)
Ru6vii—Si16—Ru2ix	124.595 (17)	Al31A—Al32A—Al32Axix	115.28 (5)
Si17xv—Si16—Al20	138.74 (2)	Al29Aviii—Al32A—Al32Axix	112.81 (5)
Ru6vii—Si16—Al20	62.558 (15)	Al32B—Al32A—Ru5Bxx	62.4 (3)
Ru2ix—Si16—Al20	62.335 (15)	Al31C—Al32A—Ru5Bxx	143.9 (7)
Si17xv—Si16—Al12ix	62.396 (19)	Al32Bxix—Al32A—Ru5Bxx	61.60 (19)
Ru6vii—Si16—Al12ix	119.15 (2)	Al31B—Al32A—Ru5Bxx	142.5 (2)
Ru2ix—Si16—Al12ix	59.702 (15)	Al29Bviii—Al32A—Ru5Bxx	58.16 (18)
Al20—Si16—Al12ix	84.14 (2)	Al31A—Al32A—Ru5Bxx	146.61 (11)
Si17xv—Si16—Al26vii	111.74 (2)	Al29Aviii—Al32A—Ru5Bxx	57.75 (13)
Ru6vii—Si16—Al26vii	64.944 (14)	Al32Axix—Al32A—Ru5Bxx	61.87 (11)
Ru2ix—Si16—Al26vii	123.088 (19)	Al32B—Al32A—Al27	140.0 (3)
Al20—Si16—Al26vii	102.37 (2)	Al31C—Al32A—Al27	94.7 (7)
Al12ix—Si16—Al26vii	173.49 (2)	Al32Bxix—Al32A—Al27	137.76 (16)
Si17xv—Si16—Al21xvi	62.572 (17)	Al31B—Al32A—Al27	95.01 (18)
Ru6vii—Si16—Al21xvi	114.263 (19)	Al29Bviii—Al32A—Al27	92.69 (15)
Ru2ix—Si16—Al21xvi	114.665 (18)	Al31A—Al32A—Al27	92.49 (4)
Al20—Si16—Al21xvi	158.69 (2)	Al29Aviii—Al32A—Al27	89.91 (6)
Al12ix—Si16—Al21xvi	113.27 (2)	Al32Axix—Al32A—Al27	138.53 (5)
Al26vii—Si16—Al21xvi	60.348 (17)	Ru5Bxx—Al32A—Al27	110.71 (8)
Si17xv—Si16—Al28	110.33 (2)	Al32B—Al32A—Ru4B	160.5 (5)
Ru6vii—Si16—Al28	128.66 (2)	Al31C—Al32A—Ru4B	56.6 (8)
Ru2ix—Si16—Al28	58.969 (15)	Al32Bxix—Al32A—Ru4B	162.6 (4)
Al20—Si16—Al28	101.00 (2)	Al31B—Al32A—Ru4B	55.5 (4)
Al12ix—Si16—Al28	105.54 (2)	Al29Bviii—Al32A—Ru4B	58.5 (2)
Al26vii—Si16—Al28	73.278 (18)	Al31A—Al32A—Ru4B	56.4 (3)
Al21xvi—Si16—Al28	63.524 (17)	Al29Aviii—Al32A—Ru4B	58.12 (17)
Si17xv—Si16—Al25	62.967 (17)	Al32Axix—Al32A—Ru4B	161.9 (3)
Ru6vii—Si16—Al25	59.025 (13)	Ru5Bxx—Al32A—Ru4B	114.9 (2)
Ru2ix—Si16—Al25	118.817 (19)	Al27—Al32A—Ru4B	59.5 (3)
Al20—Si16—Al25	83.338 (19)	Al32B—Al32A—Ru5Axv	62.3 (3)
Al12ix—Si16—Al25	68.317 (19)	Al31C—Al32A—Ru5Axv	63.0 (7)
Al26vii—Si16—Al25	112.27 (2)	Al32Bxix—Al32A—Ru5Axv	63.20 (16)
Al21xvi—Si16—Al25	113.86 (2)	Al31B—Al32A—Ru5Axv	64.5 (2)
Al28—Si16—Al25	172.26 (2)	Al29Bviii—Al32A—Ru5Axv	148.96 (17)
Ru1ix—Si17—Ru5Bvii	122.40 (13)	Al31A—Al32A—Ru5Axv	62.40 (7)
Ru1ix—Si17—Si16vi	111.692 (19)	Al29Aviii—Al32A—Ru5Axv	152.17 (8)
Ru5Bvii—Si17—Si16vi	113.65 (11)	Al32Axix—Al32A—Ru5Axv	62.89 (6)
Ru1ix—Si17—Ru5Avii	125.02 (6)	Ru5Bxx—Al32A—Ru5Axv	124.72 (10)
Ru5Bvii—Si17—Ru5Avii	2.76 (11)	Al27—Al32A—Ru5Axv	111.33 (4)
Si16vi—Si17—Ru5Avii	112.18 (4)	Ru4B—Al32A—Ru5Axv	116.7 (3)
Ru1ix—Si17—Al29A	62.27 (8)	Al32Bxix—Al32B—Al32A	175.0 (10)
Ru5Bvii—Si17—Al29A	60.21 (15)	Al32Bxix—Al32B—Al31C	150.2 (10)
Si16vi—Si17—Al29A	140.22 (10)	Al32A—Al32B—Al31C	34.0 (5)
Ru5Avii—Si17—Al29A	62.89 (9)	Al32Bxix—Al32B—Al32Axix	2.7 (5)
Ru1ix—Si17—Al23vii	125.87 (2)	Al32A—Al32B—Al32Axix	177.6 (5)
Ru5Bvii—Si17—Al23vii	66.12 (10)	Al31C—Al32B—Al32Axix	148.0 (6)
Si16vi—Si17—Al23vii	109.97 (2)	Al32Bxix—Al32B—Al31Cxix	19.6 (7)
Ru5Avii—Si17—Al23vii	64.14 (5)	Al32A—Al32B—Al31Cxix	156.1 (5)
Al29A—Si17—Al23vii	102.62 (5)	Al31C—Al32B—Al31Cxix	169.8 (3)
Ru1ix—Si17—Al12xii	59.105 (16)	Al32Axix—Al32B—Al31Cxix	21.8 (4)
Ru5Bvii—Si17—Al12xii	118.91 (10)	Al32Bxix—Al32B—Al31B	139.3 (8)
Si16vi—Si17—Al12xii	61.419 (18)	Al32A—Al32B—Al31B	45.0 (3)
Ru5Avii—Si17—Al12xii	120.58 (5)	Al31C—Al32B—Al31B	11.1 (5)
Al29A—Si17—Al12xii	86.41 (5)	Al32Axix—Al32B—Al31B	137.0 (3)
Al23vii—Si17—Al12xii	170.93 (2)	Al31Cxix—Al32B—Al31B	158.9 (4)
Ru1ix—Si17—Al21vii	115.734 (19)	Al32Bxix—Al32B—Ru5Bxv	80.7 (6)
Ru5Bvii—Si17—Al21vii	116.11 (12)	Al32A—Al32B—Ru5Bxv	101.0 (3)
Si16vi—Si17—Al21vii	61.723 (16)	Al31C—Al32B—Ru5Bxv	75.2 (5)
Ru5Avii—Si17—Al21vii	113.40 (6)	Al32Axix—Al32B—Ru5Bxv	79.8 (2)
Al29A—Si17—Al21vii	158.05 (10)	Al31Cxix—Al32B—Ru5Bxv	96.6 (4)
Al23vii—Si17—Al21vii	59.590 (16)	Al31B—Al32B—Ru5Bxv	68.1 (2)
Al12xii—Si17—Al21vii	111.82 (2)	Al32Bxix—Al32B—Ru5Bxx	80.2 (6)
Ru1ix—Si17—Al30A	60.19 (7)	Al32A—Al32B—Ru5Bxx	98.1 (4)
Ru5Bvii—Si17—Al30A	130.58 (10)	Al31C—Al32B—Ru5Bxx	122.9 (5)
Si16vi—Si17—Al30A	107.71 (3)	Al32Axix—Al32B—Ru5Bxx	81.0 (2)
Ru5Avii—Si17—Al30A	130.32 (5)	Al31Cxix—Al32B—Ru5Bxx	64.7 (4)
Al29A—Si17—Al30A	102.02 (13)	Al31B—Al32B—Ru5Bxx	128.6 (3)
Al23vii—Si17—Al30A	75.34 (7)	Ru5Bxv—Al32B—Ru5Bxx	160.8 (2)
Al12xii—Si17—Al30A	103.87 (6)	Al32Bxix—Al32B—Ru5Axv	83.6 (6)
Al21vii—Si17—Al30A	62.80 (5)	Al32A—Al32B—Ru5Axv	98.3 (3)
Ru1ix—Si17—Al29B	67.3 (2)	Al31C—Al32B—Ru5Axv	71.9 (5)
Ru5Bvii—Si17—Al29B	55.8 (2)	Al32Axix—Al32B—Ru5Axv	82.59 (19)
Si16vi—Si17—Al29B	134.5 (2)	Al31Cxix—Al32B—Ru5Axv	99.8 (4)
Ru5Avii—Si17—Al29B	58.5 (2)	Al31B—Al32B—Ru5Axv	64.6 (2)
Al29A—Si17—Al29B	7.30 (18)	Ru5Bxv—Al32B—Ru5Axv	3.53 (12)
Al23vii—Si17—Al29B	104.21 (11)	Ru5Bxx—Al32B—Ru5Axv	163.6 (3)
Al12xii—Si17—Al29B	84.64 (11)	Al32Bxix—Al32B—Ru5Axx	77.5 (6)
Al21vii—Si17—Al29B	162.70 (15)	Al32A—Al32B—Ru5Axx	100.6 (3)
Al30A—Si17—Al29B	109.3 (3)	Al31C—Al32B—Ru5Axx	126.1 (5)
Ru1ix—Si17—Al25vi	117.214 (19)	Al32Axix—Al32B—Ru5Axx	78.50 (18)
Ru5Bvii—Si17—Al25vi	59.29 (9)	Al31Cxix—Al32B—Ru5Axx	61.7 (3)
Si16vi—Si17—Al25vi	63.594 (17)	Al31B—Al32B—Ru5Axx	131.9 (3)
Ru5Avii—Si17—Al25vi	59.47 (3)	Ru5Bxv—Al32B—Ru5Axx	158.1 (2)
Al29A—Si17—Al25vi	83.82 (13)	Ru5Bxx—Al32B—Ru5Axx	3.31 (12)
Al23vii—Si17—Al25vi	111.48 (2)	Ru5Axv—Al32B—Ru5Axx	161.1 (2)
Al12xii—Si17—Al25vi	68.218 (19)	Al32Bxix—Al32B—Al29Bviii	130.1 (7)
Al21vii—Si17—Al25vi	113.69 (2)	Al32A—Al32B—Al29Bviii	50.8 (3)
Al30A—Si17—Al25vi	170.09 (4)	Al31C—Al32B—Al29Bviii	66.8 (5)
Al29B—Si17—Al25vi	76.6 (3)	Al32Axix—Al32B—Al29Bviii	129.7 (3)
Al24vii—Si18—Ru4Aii	116.89 (5)	Al31Cxix—Al32B—Al29Bviii	119.7 (4)
Al24vii—Si18—Ru2ix	115.631 (19)	Al31B—Al32B—Al29Bviii	72.6 (2)
Ru4Aii—Si18—Ru2ix	111.39 (3)	Ru5Bxv—Al32B—Al29Bviii	140.5 (3)
Al24vii—Si18—Ru7vii	65.391 (15)	Ru5Bxx—Al32B—Al29Bviii	56.3 (2)
Ru4Aii—Si18—Ru7vii	117.981 (18)	Ru5Axv—Al32B—Al29Bviii	136.9 (3)
Ru2ix—Si18—Ru7vii	122.264 (17)	Ru5Axx—Al32B—Al29Bviii	59.51 (19)
Al24vii—Si18—Al20	62.973 (18)	Al32Bxix—Al32B—Al22xx	99.0 (7)
Ru4Aii—Si18—Al20	111.35 (3)	Al32A—Al32B—Al22xx	76.1 (3)
Ru2ix—Si18—Al20	61.341 (15)	Al31C—Al32B—Al22xx	108.2 (5)
Ru7vii—Si18—Al20	119.95 (2)	Al32Axix—Al32B—Al22xx	101.6 (2)
Al24vii—Si18—Al29A	64.36 (3)	Al31Cxix—Al32B—Al22xx	81.1 (4)
Ru4Aii—Si18—Al29A	60.69 (9)	Al31B—Al32B—Al22xx	118.9 (2)
Ru2ix—Si18—Al29A	111.40 (10)	Ru5Bxv—Al32B—Al22xx	120.6 (2)
Ru7vii—Si18—Al29A	117.65 (6)	Ru5Bxx—Al32B—Al22xx	62.83 (14)
Al20—Si18—Al29A	61.85 (11)	Ru5Axv—Al32B—Al22xx	122.35 (18)
Al24vii—Si18—Al15ii	153.95 (2)	Ru5Axx—Al32B—Al22xx	61.65 (11)
Ru4Aii—Si18—Al15ii	57.69 (5)	Al29Bviii—Al32B—Al22xx	82.81 (18)

Symmetry codes: (i) −x+1/2, y−1/2, z+1/2; (ii) −x+1/2, −y+1, z+1/2; (iii) x−1/2, y, −z+3/2; (iv) x+1/2, y, −z+3/2; (v) x+1/2, −y+1/2, −z+1/2; (vi) x+1/2, y, −z+1/2; (vii) x, −y+1/2, z; (viii) −x+1/2, y−1/2, z−1/2; (ix) −x+1/2, −y+1, z−1/2; (x) −x+1/2, −y, z+1/2; (xi) −x, y−1/2, −z+1; (xii) −x+1, −y+1, −z+1; (xiii) −x+1, y−1/2, −z+1; (xiv) −x, −y+1, −z+1; (xv) x−1/2, y, −z+1/2; (xvi) x−1/2, −y+1/2, −z+1/2; (xvii) −x+1/2, y+1/2, z+1/2; (xviii) x, −y+3/2, z; (xix) −x, −y, −z; (xx) −x+1/2, −y, z−1/2; (xxi) −x+1/2, y+1/2, z−1/2; (xxii) −x, y+1/2, −z+1.

Trialuminium ruthenium disilicon (IV). Crystal data

~Ru(Al0.57Si0.43)5	Dx = 4.248 Mg m−3
Mr = 238.38	Mo Kα radiation, λ = 0.71073 Å
Tetragonal, I4/mcm	Cell parameters from 5393 reflections
a = 6.20079 (8) Å	θ = 4.2–38.2°
c = 9.6937 (2) Å	µ = 5.32 mm−1
V = 372.72 (1) Å3	T = 297 K
Z = 4	Irregular, metallic light silver
F(000) = 440.99	0.05 × 0.03 × 0.02 mm

Trialuminium ruthenium disilicon (IV). Data collection

XtaLAB Synergy R, HyPix diffractometer	295 independent reflections
Radiation source: micro-focus sealed X-ray tube, Mova (Mo) X-ray Source	279 reflections with I > 2σ(I)
Mirror monochromator	Rint = 0.029
Detector resolution: 10.0000 pixels mm-1	θmax = 37.9°, θmin = 4.2°
ω scans	h = −10→10
Absorption correction: gaussian (CrysAlisPro; Matsumoto et al., 2021)	k = −10→10
Tmin = 0.833, Tmax = 0.906	l = −16→16
8063 measured reflections

Trialuminium ruthenium disilicon (IV). Refinement

Refinement on F2	Primary atom site location: dual
Least-squares matrix: full	w = 1/[σ2(Fo2) + (0.0084P)2 + 0.2167P] where P = (Fo2 + 2Fc2)/3
R[F2 > 2σ(F2)] = 0.009	(Δ/σ)max < 0.001
wR(F2) = 0.021	Δρmax = 0.44 e Å−3
S = 1.21	Δρmin = −0.42 e Å−3
295 reflections	Extinction correction: SHELXL-2019/3 (Sheldrick, 2015b), Fc*=kFc[1+0.001xFc2λ3/sin(2θ)]-1/4
13 parameters	Extinction coefficient: 0.0037 (3)
2 restraints

Trialuminium ruthenium disilicon (IV). Special details

Geometry. All esds (except the esd in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell esds are taken into account individually in the estimation of esds in distances, angles and torsion angles; correlations between esds in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell esds is used for estimating esds involving l.s. planes.

Trialuminium ruthenium disilicon (IV). Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Ų)

	x	y	z	Uiso*/Ueq	Occ. (<1)
Ru1	0.000000	0.000000	0.250000	0.00545 (5)
Al2	0.000000	0.000000	0.000000	0.01321 (14)
Si3	0.14854 (4)	0.64854 (4)	0.14385 (4)	0.01122 (8)	0.542 (6)
Al3	0.14854 (4)	0.64854 (4)	0.14385 (4)	0.01122 (8)	0.458 (6)

Trialuminium ruthenium disilicon (IV). Atomic displacement parameters (Ų)

	U11	U22	U33	U12	U13	U23
Ru1	0.00611 (6)	0.00611 (6)	0.00414 (7)	0.000	0.000	0.000
Al2	0.0174 (2)	0.0174 (2)	0.0048 (3)	0.000	0.000	0.000
Si3	0.01030 (10)	0.01030 (10)	0.01304 (15)	0.00364 (11)	0.00111 (8)	0.00111 (8)
Al3	0.01030 (10)	0.01030 (10)	0.01304 (15)	0.00364 (11)	0.00111 (8)	0.00111 (8)

Trialuminium ruthenium disilicon (IV). Geometric parameters (Å, º)

Ru1—Al2i	2.4234 (1)	Ru1—Si3ix	2.5800 (2)
Ru1—Al2	2.4234 (1)	Al2—Si3x	2.7463 (2)
Ru1—Si3ii	2.5800 (2)	Al2—Si3vii	2.7463 (2)
Ru1—Si3iii	2.5800 (2)	Al2—Si3xi	2.7463 (2)
Ru1—Si3iv	2.5800 (2)	Al2—Si3ix	2.7463 (2)
Ru1—Si3v	2.5800 (2)	Al2—Si3xii	2.7463 (2)
Ru1—Si3vi	2.5800 (2)	Al2—Si3ii	2.7463 (2)
Ru1—Si3vii	2.5800 (2)	Al2—Si3xiii	2.7463 (2)
Ru1—Si3viii	2.5800 (2)	Al2—Si3iv	2.7463 (2)
Al2i—Ru1—Al2	180.0	Si3vii—Al2—Si3xii	61.029 (13)
Al2i—Ru1—Si3ii	113.504 (7)	Si3xi—Al2—Si3xii	75.060 (6)
Al2—Ru1—Si3ii	66.496 (7)	Si3ix—Al2—Si3xii	104.940 (6)
Al2i—Ru1—Si3iii	66.496 (7)	Ru1xiv—Al2—Si3ii	120.514 (7)
Al2—Ru1—Si3iii	113.504 (7)	Ru1—Al2—Si3ii	59.486 (7)
Si3ii—Ru1—Si3iii	139.656 (16)	Si3x—Al2—Si3ii	61.029 (13)
Al2i—Ru1—Si3iv	113.504 (7)	Si3vii—Al2—Si3ii	118.971 (13)
Al2—Ru1—Si3iv	66.496 (7)	Si3xi—Al2—Si3ii	104.940 (6)
Si3ii—Ru1—Si3iv	80.848 (5)	Si3ix—Al2—Si3ii	75.060 (6)
Si3iii—Ru1—Si3iv	138.167 (15)	Si3xii—Al2—Si3ii	180.000 (17)
Al2i—Ru1—Si3v	66.496 (7)	Ru1xiv—Al2—Si3xiii	59.486 (7)
Al2—Ru1—Si3v	113.504 (7)	Ru1—Al2—Si3xiii	120.514 (7)
Si3ii—Ru1—Si3v	138.167 (15)	Si3x—Al2—Si3xiii	75.060 (6)
Si3iii—Ru1—Si3v	80.848 (5)	Si3vii—Al2—Si3xiii	104.940 (6)
Si3iv—Ru1—Si3v	63.637 (14)	Si3xi—Al2—Si3xiii	118.971 (13)
Al2i—Ru1—Si3vi	66.496 (7)	Si3ix—Al2—Si3xiii	61.029 (13)
Al2—Ru1—Si3vi	113.504 (7)	Si3xii—Al2—Si3xiii	75.060 (6)
Si3ii—Ru1—Si3vi	63.637 (14)	Si3ii—Al2—Si3xiii	104.940 (6)
Si3iii—Ru1—Si3vi	132.991 (15)	Ru1xiv—Al2—Si3iv	120.514 (7)
Si3iv—Ru1—Si3vi	64.724 (16)	Ru1—Al2—Si3iv	59.486 (7)
Si3v—Ru1—Si3vi	80.848 (5)	Si3x—Al2—Si3iv	104.940 (6)
Al2i—Ru1—Si3vii	113.504 (7)	Si3vii—Al2—Si3iv	75.060 (6)
Al2—Ru1—Si3vii	66.496 (7)	Si3xi—Al2—Si3iv	61.029 (13)
Si3ii—Ru1—Si3vii	132.991 (15)	Si3ix—Al2—Si3iv	118.971 (13)
Si3iii—Ru1—Si3vii	63.637 (14)	Si3xii—Al2—Si3iv	104.940 (6)
Si3iv—Ru1—Si3vii	80.848 (5)	Si3ii—Al2—Si3iv	75.060 (6)
Si3v—Ru1—Si3vii	64.724 (16)	Si3xiii—Al2—Si3iv	180.000 (13)
Si3vi—Ru1—Si3vii	139.656 (16)	Ru1xv—Al3—Ru1v	116.363 (14)
Al2i—Ru1—Si3viii	66.496 (7)	Ru1xv—Al3—Si3ix	110.173 (8)
Al2—Ru1—Si3viii	113.504 (7)	Ru1v—Al3—Si3ix	110.173 (8)
Si3ii—Ru1—Si3viii	64.724 (16)	Ru1xv—Al3—Si3xvi	58.182 (7)
Si3iii—Ru1—Si3viii	80.848 (5)	Ru1v—Al3—Si3xvi	58.182 (7)
Si3iv—Ru1—Si3viii	139.656 (16)	Si3ix—Al3—Si3xvi	130.850 (15)
Si3v—Ru1—Si3viii	132.991 (15)	Ru1xv—Al3—Al2xv	54.019 (3)
Si3vi—Ru1—Si3viii	80.848 (5)	Ru1v—Al3—Al2xv	140.272 (15)
Si3vii—Ru1—Si3viii	138.167 (15)	Si3ix—Al3—Al2xv	108.902 (7)
Al2i—Ru1—Si3ix	113.504 (7)	Si3xvi—Al3—Al2xv	99.916 (13)
Al2—Ru1—Si3ix	66.496 (7)	Ru1xv—Al3—Al2xvii	140.272 (15)
Si3ii—Ru1—Si3ix	80.848 (5)	Ru1v—Al3—Al2xvii	54.019 (3)
Si3iii—Ru1—Si3ix	64.724 (16)	Si3ix—Al3—Al2xvii	108.902 (7)
Si3iv—Ru1—Si3ix	132.991 (15)	Si3xvi—Al3—Al2xvii	99.916 (13)
Si3v—Ru1—Si3ix	139.656 (16)	Al2xv—Al3—Al2xvii	105.930 (12)
Si3vi—Ru1—Si3ix	138.167 (15)	Ru1xv—Al3—Si3xviii	57.638 (8)
Si3vii—Ru1—Si3ix	80.848 (5)	Ru1v—Al3—Si3xviii	105.441 (17)
Si3viii—Ru1—Si3ix	63.637 (14)	Si3ix—Al3—Si3xviii	61.861 (8)
Ru1xiv—Al2—Ru1	180.0	Si3xvi—Al3—Si3xviii	75.218 (17)
Ru1xiv—Al2—Si3x	59.486 (7)	Al2xv—Al3—Si3xviii	98.895 (8)
Ru1—Al2—Si3x	120.514 (7)	Al2xvii—Al3—Si3xviii	155.175 (11)
Ru1xiv—Al2—Si3vii	120.514 (7)	Ru1xv—Al3—Si3iii	105.441 (17)
Ru1—Al2—Si3vii	59.486 (7)	Ru1v—Al3—Si3iii	57.638 (8)
Si3x—Al2—Si3vii	180.000 (13)	Si3ix—Al3—Si3iii	61.861 (8)
Ru1xiv—Al2—Si3xi	59.486 (7)	Si3xvi—Al3—Si3iii	75.218 (17)
Ru1—Al2—Si3xi	120.514 (7)	Al2xv—Al3—Si3iii	155.175 (11)
Si3x—Al2—Si3xi	75.060 (6)	Al2xvii—Al3—Si3iii	98.895 (8)
Si3vii—Al2—Si3xi	104.940 (6)	Si3xviii—Al3—Si3iii	56.280 (15)
Ru1xiv—Al2—Si3ix	120.514 (7)	Ru1xv—Al3—Si3xix	113.504 (7)
Ru1—Al2—Si3ix	59.486 (7)	Ru1v—Al3—Si3xix	113.504 (7)
Si3x—Al2—Si3ix	104.940 (6)	Si3ix—Al3—Si3xix	90.0
Si3vii—Al2—Si3ix	75.060 (6)	Si3xvi—Al3—Si3xix	139.151 (15)
Si3xi—Al2—Si3ix	180.00 (2)	Al2xv—Al3—Si3xix	59.485 (7)
Ru1xiv—Al2—Si3xii	59.486 (7)	Al2xvii—Al3—Si3xix	59.485 (7)
Ru1—Al2—Si3xii	120.514 (7)	Si3xviii—Al3—Si3xix	138.167 (13)
Si3x—Al2—Si3xii	118.971 (13)	Si3iii—Al3—Si3xix	138.167 (13)

Symmetry codes: (i) −x, y, −z+1/2; (ii) y−1, −x, z; (iii) y−1/2, −x+1/2, −z+1/2; (iv) x, y−1, z; (v) −x+1/2, −y+1/2, −z+1/2; (vi) −y+1/2, x−1/2, −z+1/2; (vii) −y+1, x, z; (viii) x−1/2, y−1/2, −z+1/2; (ix) −x, −y+1, z; (x) y−1, −x, −z; (xi) x, y−1, −z; (xii) −y+1, x, −z; (xiii) −x, −y+1, −z; (xiv) −x, −y, −z; (xv) x, y+1, z; (xvi) −x+1/2, −y+3/2, −z+1/2; (xvii) −x+1/2, y+1/2, −z; (xviii) −y+1/2, x+1/2, −z+1/2; (xix) x, y, −z.

Tetraaluminium diruthenium pentasilicon (V). Crystal data

~Ru2(Al0.46Si0.54)9	Dx = 4.512 Mg m−3
Mr = 450.41	Mo Kα radiation, λ = 0.71073 Å
Orthorhombic, Cmcm	Cell parameters from 11544 reflections
a = 8.63058 (14) Å	θ = 2.3–30.7°
b = 8.79888 (15) Å	µ = 5.88 mm−1
c = 17.4620 (3) Å	T = 301 K
V = 1326.05 (4) Å3	Irregular, metallic light silver
Z = 8	0.05 × 0.04 × 0.04 mm
F(000) = 1664.17

Tetraaluminium diruthenium pentasilicon (V). Data collection

XtaLAB Synergy R, HyPix diffractometer	1029 independent reflections
Radiation source: micro-focus sealed X-ray tube, Mova (Mo) X-ray Source	1001 reflections with I > 2σ(I)
Mirror monochromator	Rint = 0.016
Detector resolution: 10.0000 pixels mm-1	θmax = 30.8°, θmin = 2.3°
ω scans	h = −12→11
Absorption correction: gaussian (CrysAlisPro; Matsumoto et al., 2021)	k = −11→11
Tmin = 0.826, Tmax = 0.868	l = −22→24
17672 measured reflections

Tetraaluminium diruthenium pentasilicon (V). Refinement

Refinement on F2	Primary atom site location: dual
Least-squares matrix: full	w = 1/[σ2(Fo2) + (0.0114P)2 + 0.7123P] where P = (Fo2 + 2Fc2)/3
R[F2 > 2σ(F2)] = 0.011	(Δ/σ)max = 0.001
wR(F2) = 0.027	Δρmax = 0.37 e Å−3
S = 1.31	Δρmin = −0.42 e Å−3
1029 reflections	Extinction correction: SHELXL-2019/3 (Sheldrick, 2015b), Fc*=kFc[1+0.001xFc2λ3/sin(2θ)]-1/4
61 parameters	Extinction coefficient: 0.00053 (3)
2 restraints

Tetraaluminium diruthenium pentasilicon (V). Special details

Geometry. All esds (except the esd in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell esds are taken into account individually in the estimation of esds in distances, angles and torsion angles; correlations between esds in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell esds is used for estimating esds involving l.s. planes.

Tetraaluminium diruthenium pentasilicon (V). Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Ų)

	x	y	z	Uiso*/Ueq	Occ. (<1)
Ru1	0.25176 (2)	0.12442 (2)	0.11292 (2)	0.00469 (5)
Si2	0.000000	0.50890 (5)	0.16887 (2)	0.00820 (9)
Si3	0.000000	0.28515 (5)	0.56422 (2)	0.00938 (9)
Si4	0.000000	0.10304 (5)	0.04648 (3)	0.01097 (9)
Si5	0.000000	0.23256 (5)	0.17514 (2)	0.0069 (2)	0.65 (4)
Al5	0.000000	0.23256 (5)	0.17514 (2)	0.0069 (2)	0.35 (4)
Al6	0.26445 (6)	0.13651 (5)	0.250000	0.01175 (12)
Si7	0.35637 (4)	0.38251 (3)	0.17041 (2)	0.00739 (13)	0.63 (2)
Al7	0.35637 (4)	0.38251 (3)	0.17041 (2)	0.00739 (13)	0.37 (2)
Al8	0.18469 (5)	0.37313 (3)	0.04292 (2)	0.01109 (9)

Tetraaluminium diruthenium pentasilicon (V). Atomic displacement parameters (Ų)

	U11	U22	U33	U12	U13	U23
Ru1	0.00473 (7)	0.00517 (7)	0.00417 (7)	0.00013 (3)	−0.00034 (2)	0.00002 (2)
Si2	0.00592 (18)	0.00705 (19)	0.0116 (2)	0.000	0.000	0.00072 (14)
Si3	0.00535 (18)	0.0126 (2)	0.01020 (19)	0.000	0.000	−0.00283 (15)
Si4	0.00543 (19)	0.0197 (2)	0.00778 (19)	0.000	0.000	−0.00166 (15)
Si5	0.0065 (3)	0.0070 (3)	0.0073 (3)	0.000	0.000	−0.00015 (14)
Al5	0.0065 (3)	0.0070 (3)	0.0073 (3)	0.000	0.000	−0.00015 (14)
Al6	0.0146 (3)	0.0162 (3)	0.0045 (2)	0.00041 (17)	0.000	0.000
Si7	0.0068 (2)	0.00576 (18)	0.00963 (19)	0.00060 (10)	−0.00059 (11)	0.00062 (9)
Al7	0.0068 (2)	0.00576 (18)	0.00963 (19)	0.00060 (10)	−0.00059 (11)	0.00062 (9)
Al8	0.0175 (2)	0.00624 (17)	0.00951 (17)	0.00015 (11)	−0.00498 (14)	0.00012 (10)

Tetraaluminium diruthenium pentasilicon (V). Geometric parameters (Å, º)

Ru1—Al6	2.3986 (1)	Si3—Si7x	2.6742 (5)
Ru1—Si3i	2.4385 (2)	Si3—Si7xi	2.6742 (5)
Ru1—Si4	2.4703 (2)	Si4—Si4xii	2.4337 (9)
Ru1—Si7ii	2.5317 (3)	Si4—Si5	2.5192 (6)
Ru1—Si2iii	2.5647 (2)	Si4—Al8xiii	2.8622 (5)
Ru1—Al8	2.5727 (3)	Si4—Al8	2.8622 (5)
Ru1—Al8ii	2.5853 (3)	Si5—Si5viii	2.6144 (8)
Ru1—Si5	2.6091 (2)	Si5—Al6ix	2.7626 (5)
Ru1—Si7	2.6420 (3)	Si5—Al6	2.7626 (5)
Ru1—Al8iv	2.7759 (4)	Al6—Si7viii	2.6918 (5)
Si2—Si5	2.4339 (6)	Al6—Si7	2.6918 (5)
Si2—Si3v	2.5736 (6)	Al6—Si7ii	2.8309 (5)
Si2—Al6vi	2.7204 (5)	Al6—Si7xiv	2.8309 (5)
Si2—Al6vii	2.7204 (5)	Si7—Si7xv	2.4792 (7)
Si2—Si2viii	2.8334 (8)	Si7—Al8	2.6755 (5)
Si3—Si4viii	2.5108 (6)	Si7—Si7viii	2.7796 (6)
Si3—Al8ix	2.5768 (5)	Al8—Al8xvi	2.6890 (6)
Si3—Al8viii	2.5768 (5)	Al8—Al8iv	2.8658 (7)
Al6—Ru1—Si3i	107.063 (16)	Si4—Si5—Ru1xiii	57.561 (8)
Al6—Ru1—Si4	120.811 (16)	Ru1—Si5—Ru1xiii	112.774 (15)
Si3i—Ru1—Si4	129.335 (13)	Si2—Si5—Si5viii	92.579 (13)
Al6—Ru1—Si7ii	70.025 (14)	Si4—Si5—Si5viii	153.104 (14)
Si3i—Ru1—Si7ii	137.435 (12)	Ru1—Si5—Si5viii	114.611 (8)
Si4—Ru1—Si7ii	78.346 (13)	Ru1xiii—Si5—Si5viii	114.612 (8)
Al6—Ru1—Si2iii	66.376 (15)	Si2—Si5—Al6ix	109.080 (15)
Si3i—Ru1—Si2iii	61.852 (12)	Si4—Si5—Al6ix	106.475 (13)
Si4—Ru1—Si2iii	152.066 (14)	Ru1—Si5—Al6ix	140.67 (2)
Si7ii—Ru1—Si2iii	79.843 (11)	Ru1xiii—Si5—Al6ix	52.949 (6)
Al6—Ru1—Al8	116.532 (14)	Si5viii—Si5—Al6ix	61.760 (9)
Si3i—Ru1—Al8	75.784 (12)	Si2—Si5—Al6	109.080 (15)
Si4—Ru1—Al8	69.127 (14)	Si4—Si5—Al6	106.475 (13)
Si7ii—Ru1—Al8	145.151 (12)	Ru1—Si5—Al6	52.948 (6)
Si2iii—Ru1—Al8	134.919 (12)	Ru1xiii—Si5—Al6	140.67 (2)
Al6—Ru1—Al8ii	120.008 (14)	Si5viii—Si5—Al6	61.760 (9)
Si3i—Ru1—Al8ii	85.859 (13)	Al6ix—Si5—Al6	111.41 (2)
Si4—Ru1—Al8ii	84.229 (14)	Ru1—Al6—Ru1viii	172.70 (3)
Si7ii—Ru1—Al8ii	63.042 (11)	Ru1—Al6—Si7viii	124.360 (19)
Si2iii—Ru1—Al8ii	70.363 (13)	Ru1viii—Al6—Si7viii	62.218 (9)
Al8—Ru1—Al8ii	123.409 (15)	Ru1—Al6—Si7	62.216 (9)
Al6—Ru1—Si5	66.810 (15)	Ru1viii—Al6—Si7	124.362 (19)
Si3i—Ru1—Si5	139.280 (14)	Si7viii—Al6—Si7	62.170 (17)
Si4—Ru1—Si5	59.392 (12)	Ru1—Al6—Si2xix	122.379 (19)
Si7ii—Ru1—Si5	80.473 (12)	Ru1viii—Al6—Si2xix	59.741 (10)
Si2iii—Ru1—Si5	132.966 (13)	Si7viii—Al6—Si2xix	80.955 (15)
Al8—Ru1—Si5	72.557 (13)	Si7—Al6—Si2xix	112.37 (2)
Al8ii—Ru1—Si5	133.275 (12)	Ru1—Al6—Si2iii	59.741 (10)
Al6—Ru1—Si7	64.344 (14)	Ru1viii—Al6—Si2iii	122.378 (19)
Si3i—Ru1—Si7	63.371 (12)	Si7viii—Al6—Si2iii	112.37 (2)
Si4—Ru1—Si7	122.988 (13)	Si7—Al6—Si2iii	80.955 (15)
Si7ii—Ru1—Si7	134.263 (14)	Si2xix—Al6—Si2iii	62.768 (19)
Si2iii—Ru1—Si7	84.862 (11)	Ru1—Al6—Si5	60.241 (11)
Al8—Ru1—Si7	61.722 (10)	Ru1viii—Al6—Si5	116.619 (19)
Al8ii—Ru1—Si7	147.382 (11)	Si7viii—Al6—Si5	103.993 (19)
Si5—Ru1—Si7	79.214 (11)	Si7—Al6—Si5	75.712 (14)
Al6—Ru1—Al8iv	165.673 (16)	Si2xix—Al6—Si5	171.91 (2)
Si3i—Ru1—Al8iv	58.803 (12)	Si2iii—Al6—Si5	119.817 (12)
Si4—Ru1—Al8iv	73.383 (12)	Ru1—Al6—Si5viii	116.620 (19)
Si7ii—Ru1—Al8iv	117.911 (10)	Ru1viii—Al6—Si5viii	60.241 (11)
Si2iii—Ru1—Al8iv	102.208 (12)	Si7viii—Al6—Si5viii	75.712 (14)
Al8—Ru1—Al8iv	64.665 (12)	Si7—Al6—Si5viii	103.993 (19)
Al8ii—Ru1—Al8iv	60.083 (11)	Si2xix—Al6—Si5viii	119.817 (12)
Si5—Ru1—Al8iv	124.747 (12)	Si2iii—Al6—Si5viii	171.91 (2)
Si7—Ru1—Al8iv	107.354 (10)	Si5—Al6—Si5viii	56.480 (18)
Si5—Si2—Ru1xvii	114.396 (11)	Ru1—Al6—Si7ii	57.194 (10)
Si5—Si2—Ru1vii	114.396 (11)	Ru1viii—Al6—Si7ii	115.982 (18)
Ru1xvii—Si2—Ru1vii	113.304 (16)	Si7viii—Al6—Si7ii	175.46 (2)
Si5—Si2—Si3v	137.34 (2)	Si7—Al6—Si7ii	119.334 (12)
Ru1xvii—Si2—Si3v	56.663 (8)	Si2xix—Al6—Si7ii	101.833 (18)
Ru1vii—Si2—Si3v	56.663 (8)	Si2iii—Al6—Si7ii	72.165 (13)
Si5—Si2—Al6vi	112.887 (16)	Si5—Al6—Si7ii	72.836 (15)
Ru1xvii—Si2—Al6vi	53.884 (7)	Si5viii—Al6—Si7ii	99.76 (2)
Ru1vii—Si2—Al6vi	131.23 (2)	Ru1—Al6—Si7xiv	115.982 (18)
Si3v—Si2—Al6vi	94.539 (15)	Ru1viii—Al6—Si7xiv	57.194 (10)
Si5—Si2—Al6vii	112.887 (16)	Si7viii—Al6—Si7xiv	119.335 (12)
Ru1xvii—Si2—Al6vii	131.23 (2)	Si7—Al6—Si7xiv	175.46 (2)
Ru1vii—Si2—Al6vii	53.884 (7)	Si2xix—Al6—Si7xiv	72.165 (13)
Si3v—Si2—Al6vii	94.539 (15)	Si2iii—Al6—Si7xiv	101.833 (18)
Al6vi—Si2—Al6vii	96.71 (2)	Si5—Al6—Si7xiv	99.76 (2)
Si5—Si2—Si2viii	87.421 (13)	Si5viii—Al6—Si7xiv	72.836 (15)
Ru1xvii—Si2—Si2viii	112.394 (9)	Si7ii—Al6—Si7xiv	58.805 (16)
Ru1vii—Si2—Si2viii	112.394 (9)	Si7xv—Si7—Ru1xvii	111.632 (8)
Si3v—Si2—Si2viii	135.240 (14)	Si7xv—Si7—Ru1	109.982 (7)
Al6vi—Si2—Si2viii	58.617 (10)	Ru1xvii—Si7—Ru1	116.489 (12)
Al6vii—Si2—Si2viii	58.617 (10)	Si7xv—Si7—Si3i	62.385 (8)
Ru1x—Si3—Ru1xi	122.944 (17)	Ru1xvii—Si7—Si3i	111.082 (14)
Ru1x—Si3—Si4viii	118.472 (9)	Ru1—Si7—Si3i	54.602 (9)
Ru1xi—Si3—Si4viii	118.472 (9)	Si7xv—Si7—Al8	123.630 (11)
Ru1x—Si3—Si2xviii	61.485 (9)	Ru1xvii—Si7—Al8	59.457 (9)
Ru1xi—Si3—Si2xviii	61.485 (9)	Ru1—Si7—Al8	57.864 (9)
Si4viii—Si3—Si2xviii	174.90 (2)	Si3i—Si7—Al8	70.290 (12)
Ru1x—Si3—Al8ix	134.314 (19)	Si7xv—Si7—Al6	107.139 (13)
Ru1xi—Si3—Al8ix	67.148 (10)	Ru1xvii—Si7—Al6	140.547 (17)
Si4viii—Si3—Al8ix	68.456 (15)	Ru1—Si7—Al6	53.439 (8)
Si2xviii—Si3—Al8ix	107.696 (16)	Si3i—Si7—Al6	92.927 (14)
Ru1x—Si3—Al8viii	67.148 (10)	Al8—Si7—Al6	103.982 (14)
Ru1xi—Si3—Al8viii	134.314 (19)	Si7xv—Si7—Si7viii	89.999 (1)
Si4viii—Si3—Al8viii	68.456 (15)	Ru1xvii—Si7—Si7viii	113.363 (7)
Si2xviii—Si3—Al8viii	107.696 (17)	Ru1—Si7—Si7viii	112.333 (7)
Al8ix—Si3—Al8viii	76.42 (2)	Si3i—Si7—Si7viii	133.900 (10)
Ru1x—Si3—Si7x	62.028 (9)	Al8—Si7—Si7viii	146.312 (11)
Ru1xi—Si3—Si7x	110.212 (16)	Al6—Si7—Si7viii	58.914 (9)
Si4viii—Si3—Si7x	100.475 (18)	Si7xv—Si7—Al6vi	111.613 (13)
Si2xviii—Si3—Si7x	84.035 (16)	Ru1xvii—Si7—Al6vi	52.782 (8)
Al8ix—Si3—Si7x	162.921 (18)	Ru1—Si7—Al6vi	137.671 (17)
Al8viii—Si3—Si7x	112.484 (11)	Si3i—Si7—Al6vi	161.207 (16)
Ru1x—Si3—Si7xi	110.212 (16)	Al8—Si7—Al6vi	103.230 (14)
Ru1xi—Si3—Si7xi	62.028 (9)	Al6—Si7—Al6vi	105.829 (11)
Si4viii—Si3—Si7xi	100.475 (18)	Si7viii—Si7—Al6vi	60.597 (8)
Si2xviii—Si3—Si7xi	84.035 (16)	Ru1—Al8—Si3viii	103.213 (14)
Al8ix—Si3—Si7xi	112.484 (11)	Ru1—Al8—Ru1xvii	117.073 (14)
Al8viii—Si3—Si7xi	162.921 (18)	Si3viii—Al8—Ru1xvii	137.009 (16)
Si7x—Si3—Si7xi	55.233 (16)	Ru1—Al8—Si7	60.413 (10)
Si4xii—Si4—Ru1xiii	111.712 (13)	Si3viii—Al8—Si7	162.927 (17)
Si4xii—Si4—Ru1	111.713 (13)	Ru1xvii—Al8—Si7	57.501 (9)
Ru1xiii—Si4—Ru1	123.183 (18)	Ru1—Al8—Al8xvi	166.190 (12)
Si4xii—Si4—Si3viii	87.82 (2)	Si3viii—Al8—Al8xvi	81.071 (16)
Ru1xiii—Si4—Si3viii	108.238 (13)	Ru1xvii—Al8—Al8xvi	63.478 (11)
Ru1—Si4—Si3viii	108.238 (13)	Si7—Al8—Al8xvi	115.988 (15)
Si4xii—Si4—Si5	158.73 (3)	Ru1—Al8—Ru1iv	115.335 (12)
Ru1xiii—Si4—Si5	63.047 (10)	Si3viii—Al8—Ru1iv	54.048 (10)
Ru1—Si4—Si5	63.046 (10)	Ru1xvii—Al8—Ru1iv	114.514 (12)
Si3viii—Si4—Si5	113.45 (2)	Si7—Al8—Ru1iv	134.909 (17)
Si4xii—Si4—Al8xiii	127.17 (2)	Al8xvi—Al8—Ru1iv	56.439 (12)
Ru1xiii—Si4—Al8xiii	57.123 (9)	Ru1—Al8—Si4	53.750 (9)
Ru1—Si4—Al8xiii	115.901 (18)	Si3viii—Al8—Si4	54.678 (14)
Si3viii—Si4—Al8xiii	56.864 (14)	Ru1xvii—Al8—Si4	144.883 (17)
Si5—Si4—Al8xiii	69.132 (14)	Si7—Al8—Si4	108.417 (15)
Si4xii—Si4—Al8	127.17 (2)	Al8xvi—Al8—Si4	134.546 (16)
Ru1xiii—Si4—Al8	115.902 (18)	Ru1iv—Al8—Si4	97.920 (13)
Ru1—Si4—Al8	57.123 (9)	Ru1—Al8—Al8iv	61.104 (11)
Si3viii—Si4—Al8	56.864 (14)	Si3viii—Al8—Al8iv	68.684 (15)
Si5—Si4—Al8	69.132 (14)	Ru1xvii—Al8—Al8iv	144.14 (2)
Al8xiii—Si4—Al8	67.682 (18)	Si7—Al8—Al8iv	103.923 (19)
Si2—Si5—Si4	114.32 (2)	Al8xvi—Al8—Al8iv	109.65 (2)
Si2—Si5—Ru1	110.218 (11)	Ru1iv—Al8—Al8iv	54.231 (12)
Si4—Si5—Ru1	57.562 (8)	Si4—Al8—Al8iv	66.587 (13)
Si2—Si5—Ru1xiii	110.218 (11)

Symmetry codes: (i) −x+1/2, −y+1/2, z−1/2; (ii) −x+1/2, y−1/2, z; (iii) x+1/2, y−1/2, z; (iv) −x+1/2, −y+1/2, −z; (v) −x, −y+1, z−1/2; (vi) −x+1/2, y+1/2, −z+1/2; (vii) x−1/2, y+1/2, z; (viii) x, y, −z+1/2; (ix) −x, y, −z+1/2; (x) −x+1/2, −y+1/2, z+1/2; (xi) x−1/2, −y+1/2, z+1/2; (xii) −x, −y, −z; (xiii) −x, y, z; (xiv) −x+1/2, y−1/2, −z+1/2; (xv) −x+1, y, z; (xvi) x, −y+1, −z; (xvii) −x+1/2, y+1/2, z; (xviii) −x, −y+1, z+1/2; (xix) x+1/2, y−1/2, −z+1/2.

Funding Statement

Funding for this research was provided by: JSPS KAKENHI (grant No. JP19H05818, JP19H05819 and JP19K15274).