| Crystal data |
| Chemical formula |
(C16H36N)2[MnCl4]·2CH2Cl2
|
|
M
r
|
851.50 |
| Crystal system, space group |
Tetragonal, I
2d
|
| Temperature (K) |
173 |
|
a, c (Å) |
14.0775 (3), 24.3492 (8) |
|
V (Å3) |
4825.4 (3) |
|
Z
|
4 |
| Radiation type |
Cu Kα |
| μ (mm−1) |
6.46 |
| Crystal size (mm) |
0.38 × 0.28 × 0.13 |
| |
| Data collection |
| Diffractometer |
ROD, Synergy Custom system, HyPix-Arc 150 |
| Absorption correction |
Analytical (CrysAlis PRO; Rigaku OD, 2021 ▸) |
|
T
min, T
max
|
0.060, 0.359 |
| No. of measured, independent and observed [I > 2σ(I)] reflections |
9265, 2334, 1567 |
|
R
int
|
0.038 |
| (sin θ/λ)max (Å−1) |
0.624 |
| |
| Refinement |
|
R[F
2 > 2σ(F
2)], wR(F
2), S
|
0.075, 0.222, 1.06 |
| No. of reflections |
2334 |
| No. of parameters |
108 |
| No. of restraints |
47 |
| H-atom treatment |
H atoms treated by a mixture of independent and constrained refinement |
| Δρmax, Δρmin (e Å−3) |
0.35, −0.32 |
| Absolute structure |
Flack x determined using 458 quotients [(I
+)-(I
-)]/[(I
+)+(I
-)] (Parsons et al., 2013 ▸) |
| Absolute structure parameter |
−0.018 (8) |
