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. 2022 Oct 7;8(40):eade5909. doi: 10.1126/sciadv.ade5909

Erratum for the Research Article: “Ketones and Aldehydes as Alkyl Radical Equivalents for C–H Functionalization of Heteroarenes” by Dong et al.

PMCID: PMC10923580  PMID: 36206349

In the article “Ketones and Aldehydes as Alkyl Radical Equivalents for C–H Functionalization of Heteroarenes,” the authors had the incorrect regioselectivity for the products 46a, 46b, 47 and 48 listed in Table 2. The recently corrected article from Glorius’ research group reported that the addition of alkyl radical to 6-chloroimidazo[1,2-b]pyridazine should be at C8 in Minisci reaction by the crystal structure analysis (ACS Catal. 2022, 12, 6640−6640). The authors of this Science Advances manuscript compared their NMR with Glorius’ paper and determined they had the same NMR, so they were able to unequivocally reassign the structure. Thus, the corrected structures, regioisomers of the originally proposed structures, are now in Table 2 for 46a, 46b, 47, and 48.

Additionally, the structures of 46a, 46b, 47, and 48 have been updated in the Supplementary Materials PDF file (on pages 20-21) to reflect that the isopropyl group of these products should be at C8 position.

The HTML and PDF versions of the paper have been corrected. The supplementary materials PDF file has been updated as well.


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