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. 2022 Apr 26;144(17):7949–7950. doi: 10.1021/jacs.2c03696

Correction to “Sugar-Based Polymers with Stereochemistry Dependent Degradability and Mechanical Properties”

Connor J Stubbs, Joshua C Worch, Hannah Prydderch, Zilu Wang, Robert T Mathers, Andrey V Dobrynin, Matthew L Becker , Andrew P Dove
PMCID: PMC11216749  PMID: 35471005

Due to a production error, panel f was omitted from Figure 3 in the original publication. The complete Figure 3 is presented here.

Figure 3.

Figure 3

(a) Image of heat compressed IIPU, IMPU, co-II50IM50, and bl-II50IM50 to illustrate crystallinity differences. (b) Bulk system simulations of co-II50IM50 and bl-II50IM50 illustrating the separation of isoidide (white) and isomannide (red) regions. (c) DSC thermograms of the first heating cycle of annealed IIPU, IMPU, co-II50IM50, and bl-II50IM50 at 10 K·min–1. Total enthalpy of melting (ΔHm) calculated from integration of all melting transitions. (d) Representative stress vs strain tensile curves of annealed IIPU, IMPU, and both statistical copolymers and the physical blend at 50/50 II/IM (n > 3). Mechanical testing was performed at 10 mm·min–1. (e) Normalized weight loss of IIPU, IMPU, co-II50IM50, and bl-II50IM50 discs in 1 M NaOH(aq) over 45 days at 25 °C. n = 3. (f) Table summarizing thermomechanical properties of blend and copolymer in comparison to IIPU and IMPU homopolymers: aYoung’s modulus. bUltimate tensile strength (UTS). cStrain at break.


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