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. 2024 Nov 9;29(22):5294. doi: 10.3390/molecules29225294

Table 1.

Experimental solubility of SMR (3) (104x3) in {MeCN (1) + EtOH (2)} mixtures expressed as mole fraction at several temperatures. Experimental pressure p: 0.096 MPa a.

w1b Temperature (K) c
278.15 283.15 288.15 293.15 298.15
0.00 1.360 ± 0.024 1.767 ± 0.015 2.2 ± 0.03 2.74 ± 0.06 d 3.41 ± 0.10 d
0.05 1.505 ± 0.024 1.94 ± 0.05 2.412 ± 0.026 3.01 ± 0.07 3.831 ± 0.032
0.10 1.69 ± 0.04 2.14 ± 0.06 2.66 ± 0.07 3.4 ± 0.05 4.19 ± 0.04
0.15 1.92 ± 0.016 2.386 ± 0.022 2.974 ± 0.021 3.69 ± 0.05 4.54 ± 0.06
0.20 2.13 ± 0.03 2.634 ± 0.023 3.30 ± 0.08 4.07 ± 0.09 4.93 ± 0.06
0.25 2.386 ± 0.008 2.99 ± 0.04 3.66 ± 0.09 4.6 ± 0.08 5.48 ± 0.11
0.30 2.66 ± 0.04 3.30 ± 0.06 4.02 ± 0.06 5.00 ± 0.08 5.89 ± 0.04
0.35 3.04 ± 0.05 3.69 ± 0.07 4.56 ± 0.09 5.53 ± 0.04 6.68 ± 0.07
0.40 3.41 ± 0.04 4.145 ± 0.033 4.96 ± 0.10 6.20 ± 0.05 7.33 ± 0.15
0.45 3.78 ± 0.08 4.61 ± 0.09 5.56 ± 0.07 6.709 ± 0.022 8.06 ± 0.15
0.50 4.28 ± 0.05 5.08 ± 0.06 6.08 ± 0.06 7.38 ± 0.05 8.69 ± 0.13
0.55 4.69 ± 0.008 5.63 ± 0.13 6.92 ± 0.02 8.19 ± 0.2 9.71 ± 0.11
0.60 5.26 ± 0.04 6.32 ± 0.11 7.567 ± 0.027 9.14 ± 0.19 10.81 ± 0.15
0.65 6.03 ± 0.06 7.06 ± 0.09 8.45 ± 0.25 9.95 ± 0.04 11.87 ± 0.30
0.70 6.62 ± 0.07 7.93 ± 0.10 9.28 ± 0.26 11.06 ± 0.22 13.12 ± 0.16
0.75 7.45 ± 0.16 8.74 ± 0.14 10.132 ± 0.03 12.14 ± 0.08 14.13 ± 0.24
0.80 8.30 ± 0.13 9.84 ± 0.19 11.62 ± 0.13 13.16 ± 0.07 15.6 ± 0.4
0.85 9.30 ± 0.11 10.84 ± 0.16 12.91 ± 0.26 15.07 ± 0.12 17.07 ± 0.28
0.90 10.59 ± 0.04 12.1 ± 0.22 14.03 ± 0.33 16.46 ± 0.16 19.0 ± 0.5
0.95 11.84 ± 0.13 13.58 ± 0.29 15.43 ± 0.12 18.37 ± 0.23 20.6 ± 0.5
1.00 13.09 ± 0.10 e 15.10 ± 0.07 e 17.40 ± 0.09 e 20.09 ± 0.18 e 22.86 ± 0.27 e
w1b Temperature (K) c
303.15 308.15 313.15 318.15
0.00 4.09 ± 0.09 d 4.95 ± 0.04 d 6.36 ± 0.11 d 7.49 ± 0.14
0.05 4.45 ± 0.04 5.45 ± 0.06 7.06 ± 0.21 8.26 ± 0.17
0.10 4.97 ± 0.1 5.92 ± 0.11 7.69 ± 0.14 9.08 ± 0.18
0.15 5.38 ± 0.11 6.52 ± 0.07 8.49 ± 0.21 10.15 ± 0.19
0.20 5.93 ± 0.06 7.38 ± 0.12 9.28 ± 0.25 11.11 ± 0.2
0.25 6.61 ± 0.09 8.08 ± 0.22 10.23 ± 0.17 12.36 ± 0.31
0.30 7.14 ± 0.13 8.81 ± 0.23 11.34 ± 0.31 13.9 ± 0.26
0.35 8.00 ± 0.11 9.71 ± 0.09 12.4 ± 0.3 15.12 ± 0.26
0.40 8.58 ± 0.10 10.62 ± 0.07 13.64 ± 0.22 16.9 ± 0.4
0.45 9.67 ± 0.19 11.93 ± 0.18 15.0 ± 0.4 18.59 ± 0.29
0.50 10.62 ± 0.03 12.9 ± 0.06 16.5 ± 0.4 20.5 ± 0.4
0.55 11.57 ± 0.19 14.6 ± 0.4 18.17 ± 0.19 22.8 ± 0.7
0.60 12.64 ± 0.27 15.8 ± 0.4 20.1 ± 0.3 25.3 ± 0.6
0.65 13.92 ± 0.4 17.69 ± 0.2 21.7 ± 0.14 28.31 ± 0.35
0.70 15.3 ± 0.27 19.05 ± 0.09 24.0 ± 0.5 31.5 ± 0.5
0.75 16.7 ± 0.19 21.67 ± 0.31 27.0 ± 0.9 34.4 ± 0.7
0.80 18.8 ± 0.24 23.87 ± 0.29 30.0 ± 0.5 37.8 ± 0.7
0.85 20.56 ± 0.06 25.9 ± 0.4 32.2 ± 0.6 42.1 ± 1.2
0.90 22.51 ± 0.32 28.6 ± 0.7 35.7 ± 0.8 46.7 ± 0.5
0.95 24.88 ± 0.4 31.9 ± 0.4 39.5 ± 0.5 52.9 ± 0.4
1.00 27.14 ± 0.14 e 34.7 ± 0.5 e 43.9 ± 0.32 e 57.2 ± 0.9 e

a Standard uncertainty in pressure u(p) = 0.001 MPa; b w1 is the mass fraction of MeCN (1) in the MeCN (1) + EtOH (2) mixtures free of SMR (3); c standard uncertainty in temperature is u(T) = 0.05 K; d from Delgado and Martínez [25]; e from Blanco-Márquez et al. [29].