Table 1.
Crystallographic data for Cuttpa and Mnttpa.
| Cuttpa | Mnttpa | |
|---|---|---|
| Formula | C32H30CuN10O4 | C64H46Mn2N22O14 |
| Fw | 682.20 | 1457.11 |
| T/K | 188 (2) | 189 (2) |
| Crystal system | Monoclinic | Triclinic |
| Space group | P21/c | |
| a/Å | 14.7579 (10) | 11.5963 (8) |
| b/Å | 18.6867 (13) | 17.6243 (11) |
| c/Å | 11.5203 (9) | 19.6708 (12) |
| α (°) | 90 | 113.519 (2) |
| β (°) | 100.047 (2) | 94.839 (2) |
| γ (°) | 90 | 104.434 (2) |
| V /Å3 | 3128.3 (4) | 3492.6 (4) |
| F(000) | 1412 | 1492 |
| Z | 4 | 2 |
| ρcalcd (g cm−3) | 1.448 | 1.386 |
| µ(mm−1) | 0.753 | 0.440 |
| Reflections collected | 60030 | 68,021 |
| Unique reflections | 7209 [R(int) = 0.0894] | 15,953 [R(int) = 0.0951] |
| Parameter | 424 | 939 |
| Goodness of fit | 1.050 | 1.050 |
| R1 [I > 2σ(I)] | 0.0541 | 0.0591 |
| wR2 (all data) | 0.1519 | 0.1797 |