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. 1969 May;9(5):700–728. doi: 10.1016/S0006-3495(69)86413-1

Electroosmosis in Membranes: Effects of Unstirred Layers and Transport Numbers

I. Theory

P H Barry, A B Hope
PMCID: PMC1367749  PMID: 5786317

Abstract

When a current is passed through a membrane system, differences in transport numbers between the membrane and the adjacent solutions will, in general, result in depletion and enhancement of concentrations at the membrane-solution interfaces. This will be balanced by diffusion back into the bulk solution, diffusion of solute back across the membrane itself, and osmosis resulting from these local concentration gradients. The two main results of such a phenomenon are (1) that there is a current-induced volume flow, which may be mistaken for electroosmosis, and (2) that there will generally develop transient changes in potential difference (PD) across membranes during and after the passage of current through them.

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Selected References

These references are in PubMed. This may not be the complete list of references from this article.

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