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. 1977 Dec;20(3):377–382. doi: 10.1016/S0006-3495(77)85556-2

Electronic structure of polyenes related to the visual chromophore. A simple model for the observed band shapes.

R Hemley, B E Kohler
PMCID: PMC1473364  PMID: 922126

Abstract

A model is presented which attributes the widths of absorption bands in carotenoids to conformational disorder induced by the beta-ionylidene moiety. With reasonable parameter choices, the model gives a good quantitative fit to the spectra observed for four carotenoids and at the same time accounts for the lack of structure in the long-wavelength absorption of retinal.

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Selected References

These references are in PubMed. This may not be the complete list of references from this article.

  1. Warshel A., Karplus M. Calculation of pi-pi excited state conformations and vibronic structure of retinal and related molecules. J Am Chem Soc. 1974 Sep 4;96(18):5677–5689. doi: 10.1021/ja00825a001. [DOI] [PubMed] [Google Scholar]

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