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. 1989 Feb;79:15–34. doi: 10.1289/ehp.897915

Acidic sulfate aerosols: characterization and exposure.

P J Lioy 1, J M Waldman 1
PMCID: PMC1567580  PMID: 2651103

Abstract

Exposures to acidic aerosol in the atmosphere are calculated from data reported in the scientific literature. The majority of date was not derived from studies necessarily designed to examine human exposures. Most of the studies were designed to investigate the characteristics of the atmosphere. However, the measurements were useful in defining two potential exposure situations: regional stagnation and transport conditions and local plume impacts. Levels of acidic aerosol in excess of 20 to 40 micrograms/m3 (as H2SO4) have been observed for time durations ranging from 1 to 12 hr. These were associated with high, but not necessarily the highest, atmospheric SO4(2)- levels. Exposures of 100 to 900 micrograms/m3/hr were calculated for the acid events that were monitored. In contrast, earlier London studies indicated that apparent acidity in excess of 100 micrograms/m3 (as H2SO4) was present in the atmosphere, and exposures less than 2000 micrograms/m3/hr were possible. Our present knowledge about the frequency, magnitude, and duration of acidic sulfate aerosol events and episodes is insufficient. Efforts must be made to gather more data, but these should be done in such a way that evaluation of human exposure is the focus of the research. In addition, further data are required on the mechanisms of formation of H2SO4 and on what factors can be used to predict acidic sulfate episodes.

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Selected References

These references are in PubMed. This may not be the complete list of references from this article.

  1. Brosset C., Ferm M. Man-made airborne acidity and its determination. Atmos Environ. 1978;12(4):909–916. doi: 10.1016/0004-6981(78)90029-x. [DOI] [PubMed] [Google Scholar]
  2. Charlson R. J., Vanderpol A. H., Covert D. S., Waggoner A. P., Ahlquist N. C. H2SO4/(NH4)2SO4 background aerosol: optical detection in St. Louis region. Atmos Environ. 1974 Dec;8(12):1257–1267. doi: 10.1016/0004-6981(74)90005-5. [DOI] [PubMed] [Google Scholar]
  3. Ferris B. G., Jr, Spengler J. D. Problems in the estimation of human exposure to components of acid precipitation precursors. Environ Health Perspect. 1985 Nov;63:5–9. doi: 10.1289/ehp.85635. [DOI] [PMC free article] [PubMed] [Google Scholar]
  4. Huygen C. A simple photometric determination of sulphuric acid aerosol. Atmos Environ. 1975 Mar;9(3):315–319. doi: 10.1016/0004-6981(75)90142-0. [DOI] [PubMed] [Google Scholar]
  5. Junge C., Scheich G. Determination of the acid content of aerosol particles. Atmos Environ. 1971 Mar;5(3):165–175. doi: 10.1016/0004-6981(71)90080-1. [DOI] [PubMed] [Google Scholar]
  6. Leahy D., Siegel R., Klotz P., Newman L. The separation and characterization of sulfate aerosol. Atmos Environ. 1975 Feb;9(2):219–229. doi: 10.1016/0004-6981(75)90070-0. [DOI] [PubMed] [Google Scholar]
  7. Scaringelli F. P., Rehme K. A. Determination of atmospheric concentrations of sulfuric acid aerosol by spectrophotometry, coulometry, and flame photometry. Anal Chem. 1969 May;41(6):707–713. doi: 10.1021/ac60275a001. [DOI] [PubMed] [Google Scholar]
  8. Schlesinger R. B. Comparative irritant potency of inhaled sulfate aerosols--effects on bronchial mucociliary clearance. Environ Res. 1984 Aug;34(2):268–279. doi: 10.1016/0013-9351(84)90095-1. [DOI] [PubMed] [Google Scholar]
  9. Spektor D. M., Yen B. M., Lippmann M. Effect of concentration and cumulative exposure of inhaled sulfuric acid on tracheobronchial particle clearance in healthy humans. Environ Health Perspect. 1989 Feb;79:167–172. doi: 10.1289/ehp.8979167. [DOI] [PMC free article] [PubMed] [Google Scholar]
  10. THOMAS M. D. Sulfur dioxide, sulfuric acid aerosol and visibility in Los Angeles. Air Water Pollut. 1962 Nov-Dec;6:443–454. [PubMed] [Google Scholar]
  11. Wolff G. T., Kelly N. A., Ferman M. A. On the sources of summertime haze in the eastern United States. Science. 1981 Feb 13;211(4483):703–705. doi: 10.1126/science.211.4483.703. [DOI] [PubMed] [Google Scholar]
  12. Wolff R. K. Effects of airborne pollutants on mucociliary clearance. Environ Health Perspect. 1986 Apr;66:223–237. doi: 10.1289/ehp.8666223. [DOI] [PMC free article] [PubMed] [Google Scholar]

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