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Proceedings of the National Academy of Sciences of the United States of America logoLink to Proceedings of the National Academy of Sciences of the United States of America
. 1969 Dec;64(4):1329–1330. doi: 10.1073/pnas.64.4.1329

RELATIVE DIFFUSIVITIES OF METHANE IN WATER AND CARBON TETRACHLORIDE

Joel H Hildebrand 1
PMCID: PMC223287  PMID: 16591808

Abstract

Methane diffuses in water at 25°C 3/5 as fast as it does in carbon tetrachloride. Since diffusivity depends mainly upon temperature, viscosity of the solvent, and molecular cross section of the diffusant, and since viscosities of H2O and CCl4 at 25°C are almost identical, one may infer that molecules of CH4 in H2O are not imprisoned in “icebergs,” and are retarded only by hydrogen bonds, not by encounters with “ice-like” aggregates.

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