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Proceedings of the National Academy of Sciences of the United States of America logoLink to Proceedings of the National Academy of Sciences of the United States of America
. 1969 Jul;63(3):612–614. doi: 10.1073/pnas.63.3.612

NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY: 13C SPECTRA OF UNSUBSTITUTED INOSITOLS*

Douglas E Dorman 1,2,†, S J Angyal 1,2, J D Roberts 1,2
PMCID: PMC223493  PMID: 5259753

Abstract

The chemical shifts of 13C in natural abundance have been obtained from nuclear magnetic resonance spectra of scyllo-, myo-, chiro-, and epi-inositols at 15.1 MHz. A set of empirical substitutent parameters were derived and shown to be moderately successful in correlating the 13C resonance-line positions for these substances. The substituent parameters conform generally to the idea that steric hindrance or porximity effects are of special importance in influencing chemical shifts of carbons in cyclohexane systems.

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Selected References

These references are in PubMed. This may not be the complete list of references from this article.

  1. Weigert F. J., Jautelat M., Roberts J. D. Natural-abundance C nuclear magnetic resonance spectra of medium-molecular-weight organic compounds. Proc Natl Acad Sci U S A. 1968 Aug;60(4):1152–1155. doi: 10.1073/pnas.60.4.1152. [DOI] [PMC free article] [PubMed] [Google Scholar]
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