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Journal of Automated Methods and Management in Chemistry logoLink to Journal of Automated Methods and Management in Chemistry
. 1999;21(1):1–9. doi: 10.1155/S1463924699000012

A submersible battery-powered flow injection (FI) sensor for the determination of nitrate in estuarine and coastal waters

Anthony R J David 1, Trevor McCormack 1, Paul J Worsfold 1
PMCID: PMC2548166  PMID: 18924837

Abstract

The design, construction and performance of a remotely deployed submersible flow injection-based nutrient (total oxidized nitrogen) sensor are described. The sensor featured a custom-built microcomputer and a solid-state, flow-through spectrophotometric detector, and the derivatization chemistry was based on in-line coppercadmium reduction of nitrate to nitrite, and diazotization with N1NED and sulphanilamide. The limit of detection was 0.0014 mg l-1 NO3-N and the linear range was 0.0014- 0.77 mg l-1 with a 260 μl sample volume and a 20 mm path length flow cell. Results from submersed deployments in the Tamar estuary and North Sea are also reported.

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