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Kinetic fate of the structured intermediates at different temperatures [15 ° (triangles), 25 ° (circles), 37 ° (squares), and 47 °C (upside-down triangles)] under the same conditions as in Fig. 8. Corresponding observed rate constants are shown in Table 3. As the temperature is increased, I1 becomes more reactive to DTTox and is oxidized to I2 faster than to I3 to form N-ONC. I1 and I3 are populated to a very low extent at higher temperatures.
