Table 2.

Standard Deviations and Errors of Floating Rate Constants for Global Fitting of Single Turnover Data to Kinetic Models A1–A3 and B1–B3

	Trial #1 Error, %					Trial #2 Error, %
Model	Standard deviation ×10−8	k1	k3	k5	k6	Standard deviation ×10−8	k1	k3	k5	k6
A1	2.78	31	22	13	n/a	2.88	62	57	9.4	n/a
A2	11.5	>500	>500	>500	n/a	11.5	>500	>500	>500	n/a
A3	8.36	23	>500	>500	n/a	3.30	5.3	>500	>500	n/a
B1	2.19	16	8.3	20	34	2.11	9.6	10	13	22
B2	11.5	>500	>500	>500	>500	11.5	>500	>500	>500	>500
B3	8.36	20	>500	>500	>500	3.3	5.2	>500	>500	>500

In Trial 1, k₂ is set to 1e4 M⁻¹s⁻¹; in trial 2, k₂ is set to 1e5 M⁻¹s⁻¹.