Table 6.
entry | monomer | [M]0/1 | Mn (×103g/mol) | Mn (theo) (×103 g/mol) | PDI | % yield |
---|---|---|---|---|---|---|
20 | 6a | 200 | 41 | 43 | 1.06 | 68 |
21 | 6a | 400 | 110 | 87 | 1.03 | 82 |
22 | 6a | 600 | 163 | 130 | 1.03 | 88 |
23 | 6a | 800 | 200 | 173 | 1.02 | 84 |
24 | 6a | 1000 | 266 | 216 | 1.02 | 93 |
25 | 6b | 200 | 55 | 48 | 1.02 | 48 |
26 | 6b | 400 | 117 | 96 | 1.02 | 93 |
27 | 6b | 600 | 170 | 144 | 1.02 | 85 |
28 | 6b | 800 | 249 | 192 | 1.02 | 85 |
29 | 6b | 1000 | 321 | 240 | 1.02 | 93 |
Polymerization conducted with PPh3/1 = 60, [M]0 = 0.25 M, at 23°C for 5 min.