Dicaesium tetra­chlorido­dioxido­plutonate(VI)

Marianne P Wilkerson; Brian L Scott

doi:10.1107/S1600536807066354

. 2007 Dec 18;64(Pt 1):i5. doi: 10.1107/S1600536807066354

Dicaesium tetrachloridodioxidoplutonate(VI)

Marianne P Wilkerson ^a,^*, Brian L Scott ^b

PMCID: PMC2914883 PMID: 21200455

Abstract

The anion of the title complex, Cs₂[PuCl₄O₂], adopts a pseudo-octahedral geometry (2/m crystallographic site symmetry) with two plutonyl oxide ligands in axial sites and four chloride ligands occupying the equatorial plane. Charge balance is maintained by two caesium cations per tetrachloridodioxidoplutonate(VI) anion. Principal bond lengths include Pu—O = 1.752 (3) Å and Pu—Cl = 2.6648 (8) Å.

Related literature

For related literature, see: Hall et al. (1966 ▶); Watkin et al. (1991 ▶); Wilkerson et al. (2004 ▶); Wilkerson et al. (2007 ▶); Bean et al. (2004 ▶, 2005 ▶); Grenthe et al. (2006 ▶); Grigoriev et al. (2004 ▶); Runde et al. (2003 ▶); Sessler et al. (2002 ▶).

Experimental

Crystal data

Cs₂[PuCl₄O₂]
M _r = 678.67
Monoclinic,
a = 11.9489 (7) Å
b = 7.7286 (5) Å
c = 5.7855 (4) Å
β = 96.439 (1)°
V = 530.91 (6) Å³
Z = 2
Mo Kα radiation
μ = 13.92 mm⁻¹
T = 141 (2) K
0.22 × 0.18 × 0.12 mm

Data collection

Bruker APEXII CCD diffractometer
Absorption correction: multi-scan (SADABS; Sheldrick, 2001 ▶) T _min = 0.150, T _max = 0.286 (expected range = 0.099–0.188)
3212 measured reflections
711 independent reflections
659 reflections with I > 2σ(I)
R _int = 0.025

Refinement

R[F ² > 2σ(F ²)] = 0.015
wR(F ²) = 0.037
S = 1.26
711 reflections
27 parameters
Δρ_max = 0.78 e Å⁻³
Δρ_min = −0.64 e Å⁻³

Data collection: APEX2 (Bruker, 2003 ▶); cell refinement: SAINT-Plus (Bruker, 2001 ▶); data reduction: SAINT-Plus; program(s) used to solve structure: SHELXS97 (Sheldrick, 1997 ▶); program(s) used to refine structure: SHELXL97 (Sheldrick, 1997 ▶); molecular graphics: SHELXTL (Bruker, 2000 ▶); software used to prepare material for publication: SHELXTL.

Supplementary Material

Crystal structure: contains datablocks global, I. DOI: 10.1107/S1600536807066354/fi2048sup1.cif

e-64-000i5-sup1.cif^{(15.7KB, cif)}

Structure factors: contains datablocks I. DOI: 10.1107/S1600536807066354/fi2048Isup2.hkl

e-64-000i5-Isup2.hkl^{(35.5KB, hkl)}

Additional supplementary materials: crystallographic information; 3D view; checkCIF report

Acknowledgments

We thank Mr Phillip Palmer and Mr Sean D. Reilly for technical assistance. This research at Los Alamos National Laboratory was supported by NA-22, Office of Nonproliferation Research and Engineering, US Department of Energy, National Nuclear Security Administration (NNSA), and Office of Basic Energy Sciences, US Department of Energy. Los Alamos National Laboratory is operated by Los Alamos National Security, LLC for the US Department of Energy, NNSA under contract number DE-AC52-06NA25396.

supplementary crystallographic information

Comment

The title compound, (1), is isostructural with the uranium analogue Cs2U(VI)O2Cl4 and the neptunium analogue Cs2Np(VI)O2Cl4, which crystallize in the space group C2/m (Hall et al., 1966; Watkin et al., 1991; Wilkerson et al., 2007). The Pu atom sits on a site of 2/m crystallographic symmetry; the twofold rotation axis bisects the Cl—U—Cl angle, and the plutonyl axis lies in the mirror plane. The plutonium metal is coordinated in a pseudo-octahedral fashion by two oxo groups and four chloride ligands. The oxo groups of the plutonyl ion lie trans to one another with a bond angle of 180.0 (3). This angle is equivalent within 3 σ to those reported for the limited number of plutonyl structures published (range 178.0 (4)–179.4 (2)) (Bean et al., 2004; Bean et al., 2005; Grigoriev et al., 2004; Runde et al., 2003). This value is within the range reported for the majority of actinyl compounds (Grenthe et al., 2006). The Pu—O(oxo) distances are 1.752 (3) Å. Although there are no reported six coordinate plutonyl structures with which to compare, this value is within range of Pu—O(oxo) bond lengths reported for seven coordinate plutonyl structures (1.727 (4)–1.771 (11) Å) (Bean et al., 2004; Bean et al., 2005; Grigoriev et al., 2004; Runde et al., 2003). The chloride ligands lie in the equatorial plane of the plutonyl ion, and the Pu—Cl bond distances are 2.6648 (8) Å. Although there are no plutonyl chloride structures reported, these values are longer than Np—Cl bond lengths reported for six-coordinate Cs₂NpO₂Cl₄ (2.653 (3) Å) (Wilkerson et al., 2004).

Experimental

Caesium chloride (0.021 g, 0.12 mmol; Aldrich, 99.999%) was dissolved in 2M HCl (0.5 ml; Aldrich, ACS reagent, 37%), and this solution was added to a stock solution of 0.063 M Pu(VI)O₂²⁺ in 2M HCl (1 ml, 0.063 mmol; Fisher, Certified ACS Plus) (Sessler et al., 2002). The vial containing the solution was covered loosely with parafilm and allowed to stand for 2 weeks at room temperature. Following evaporation of the solvent, dark golden-brown blocks formed. A dark golden-brown block of 0.22 x 0.18 x 0.12 mm was cut from a larger crystal, and then thinly coated with epoxy and placed in a capillary. The capillary was coated with a thin film of acrylic dissolved in ethyl acetate. (Note: this triple containment was necessitated by the health hazards of transuranic materials.)

Figures

Fig. 1. — Molecular structure (70% probability displacement ellipsoids) of Cs2PuO2Cl4 and the atom-numbering scheme used in Table 1. Symmetry codes as in Table 1.

Crystal data

Cs₂[PuCl₄O₂]	Z = 2
M_r = 678.67	F₀₀₀ = 576
Monoclinic, C2/m	D_x = 4.245 Mg m⁻³
Hall symbol: -C 2y	Mo Kα radiation λ = 0.71073 Å
a = 11.9489 (7) Å	θ = 3.2–28.7º
b = 7.7286 (5) Å	µ = 13.92 mm⁻¹
c = 5.7855 (4) Å	T = 141 (2) K
β = 96.4390 (10)º	Irregular, golden brown
V = 530.91 (6) Å³	0.22 × 0.18 × 0.12 mm

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Data collection

Bruker D8 with APEXII CCD diffractometer	711 independent reflections
Radiation source: fine-focus sealed tube	659 reflections with I > 2σ(I)
Monochromator: graphite	R_int = 0.025
T = 141(2) K	θ_max = 28.7º
ω scans	θ_min = 3.2º
Absorption correction: multi-scan(SADABS; Sheldrick, 2001)	h = −15→15
T_min = 0.150, T_max = 0.286	k = −10→10
3212 measured reflections	l = −7→7

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Refinement

Refinement on F²	Secondary atom site location: difference Fourier map
Least-squares matrix: full	w = 1/[σ²(F_o²) + (0.0151P)²] where P = (F_o² + 2F_c²)/3
R[F² > 2σ(F²)] = 0.015	(Δ/σ)_max = 0.001
wR(F²) = 0.037	Δρ_max = 0.78 e Å⁻³
S = 1.26	Δρ_min = −0.64 e Å⁻³
711 reflections	Extinction correction: SHELXL97 (Sheldrick, 1997), Fc^*=kFc[1+0.001xFc²λ³/sin(2θ)]^-1/4
27 parameters	Extinction coefficient: 0.0050 (2)
Primary atom site location: structure-invariant direct methods

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Special details

Geometry. All e.s.d.'s (except the e.s.d. in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell e.s.d.'s are taken into account individually in the estimation of e.s.d.'s in distances, angles and torsion angles; correlations between e.s.d.'s in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell e.s.d.'s is used for estimating e.s.d.'s involving l.s. planes.

Refinement. Refinement of F² against ALL reflections. The weighted R-factor wR and goodness of fit S are based on F², conventional R-factors R are based on F, with F set to zero for negative F². The threshold expression of F² > σ(F²) is used only for calculating R-factors(gt) etc. and is not relevant to the choice of reflections for refinement. R-factors based on F² are statistically about twice as large as those based on F, and R- factors based on ALL data will be even larger.

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Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Å²)

	x	y	z	U_iso*/U_eq
Pu1	0.0000	0.0000	0.0000	0.02605 (11)
Cs1	0.34147 (2)	0.0000	0.69601 (6)	0.03801 (11)
Cl1	−0.10351 (7)	−0.24889 (10)	0.21367 (16)	0.0390 (2)
O1	0.1124 (3)	0.0000	0.2222 (6)	0.0395 (8)

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Atomic displacement parameters (Å²)

	U¹¹	U²²	U³³	U¹²	U¹³	U²³
Pu1	0.02849 (15)	0.02078 (14)	0.02946 (15)	0.000	0.00583 (9)	0.000
Cs1	0.03790 (19)	0.03608 (19)	0.0419 (2)	0.000	0.01250 (15)	0.000
Cl1	0.0436 (4)	0.0305 (4)	0.0454 (5)	−0.0015 (3)	0.0162 (4)	0.0058 (3)
O1	0.0381 (19)	0.0424 (19)	0.0371 (19)	0.000	0.0002 (16)	0.000

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Geometric parameters (Å, °)

Pu1—O1ⁱ	1.752 (3)	Cs1—Cl1^xii	3.5201 (8)
Pu1—O1	1.752 (3)	Cs1—Cl1^viii	3.5201 (8)
Pu1—Cl1ⁱⁱ	2.6648 (8)	Cs1—Cl1^xiii	3.5674 (10)
Pu1—Cl1	2.6648 (8)	Cs1—Cl1^xiv	3.5674 (10)
Pu1—Cl1ⁱⁱⁱ	2.6648 (8)	Cs1—O1	3.650 (4)
Pu1—Cl1ⁱ	2.6648 (8)	Cs1—Cl1^xv	3.6710 (9)
Pu1—Cs1^iv	4.5680 (3)	Cs1—Cl1^vi	3.6710 (9)
Pu1—Cs1^v	4.5680 (3)	Cs1—Pu1^xiii	4.5680 (3)
Pu1—Cs1^vi	4.5680 (3)	Cs1—Pu1^xvi	4.5680 (3)
Pu1—Cs1^vii	4.5680 (3)	Cs1—Pu1^xvii	4.6207 (3)
Pu1—Cs1^viii	4.6207 (3)	Cl1—Cs1^xviii	3.5209 (9)
Pu1—Cs1^ix	4.6207 (3)	Cl1—Cs1^viii	3.5201 (8)
Cs1—Cl1^x	3.5209 (9)	Cl1—Cs1^iv	3.5674 (10)
Cs1—Cl1^xi	3.5209 (9)	Cl1—Cs1^vi	3.6710 (9)

O1ⁱ—Pu1—O1	180.0 (3)	Cl1^x—Cs1—Cl1^xiii	158.75 (3)
O1ⁱ—Pu1—Cl1ⁱⁱ	90.98 (8)	Cl1^xi—Cs1—Cl1^xiii	109.41 (2)
O1—Pu1—Cl1ⁱⁱ	89.02 (8)	Cl1^xii—Cs1—Cl1^xiii	104.390 (15)
O1ⁱ—Pu1—Cl1	89.02 (8)	Cl1^viii—Cs1—Cl1^xiii	69.76 (2)
O1—Pu1—Cl1	90.98 (8)	Cl1^x—Cs1—Cl1^xiv	109.41 (2)
Cl1ⁱⁱ—Pu1—Cl1	87.58 (3)	Cl1^xi—Cs1—Cl1^xiv	158.75 (3)
O1ⁱ—Pu1—Cl1ⁱⁱⁱ	89.02 (8)	Cl1^xii—Cs1—Cl1^xiv	69.76 (2)
O1—Pu1—Cl1ⁱⁱⁱ	90.98 (8)	Cl1^viii—Cs1—Cl1^xiv	104.390 (15)
Cl1ⁱⁱ—Pu1—Cl1ⁱⁱⁱ	180.00 (5)	Cl1^xiii—Cs1—Cl1^xiv	65.91 (3)
Cl1—Pu1—Cl1ⁱⁱⁱ	92.42 (3)	Cl1^x—Cs1—O1	66.15 (5)
O1ⁱ—Pu1—Cl1ⁱ	90.98 (8)	Cl1^xi—Cs1—O1	66.15 (5)
O1—Pu1—Cl1ⁱ	89.02 (8)	Cl1^xii—Cs1—O1	63.98 (5)
Cl1ⁱⁱ—Pu1—Cl1ⁱ	92.42 (3)	Cl1^viii—Cs1—O1	63.98 (5)
Cl1—Pu1—Cl1ⁱ	180.00 (4)	Cl1^xiii—Cs1—O1	133.04 (4)
Cl1ⁱⁱⁱ—Pu1—Cl1ⁱ	87.58 (3)	Cl1^xiv—Cs1—O1	133.04 (4)
O1ⁱ—Pu1—Cs1^iv	57.778 (4)	Cl1^x—Cs1—Cl1^xv	99.912 (18)
O1—Pu1—Cs1^iv	122.222 (4)	Cl1^xi—Cs1—Cl1^xv	65.75 (3)
Cl1ⁱⁱ—Pu1—Cs1^iv	53.469 (18)	Cl1^xii—Cs1—Cl1^xv	163.34 (3)
Cl1—Pu1—Cs1^iv	51.24 (2)	Cl1^viii—Cs1—Cl1^xv	112.348 (8)
Cl1ⁱⁱⁱ—Pu1—Cs1^iv	126.531 (18)	Cl1^xiii—Cs1—Cl1^xv	61.25 (2)
Cl1ⁱ—Pu1—Cs1^iv	128.76 (2)	Cl1^xiv—Cs1—Cl1^xv	95.403 (19)
O1ⁱ—Pu1—Cs1^v	122.222 (4)	O1—Cs1—Cl1^xv	131.50 (4)
O1—Pu1—Cs1^v	57.778 (4)	Cl1^x—Cs1—Cl1^vi	65.75 (3)
Cl1ⁱⁱ—Pu1—Cs1^v	126.531 (18)	Cl1^xi—Cs1—Cl1^vi	99.912 (18)
Cl1—Pu1—Cs1^v	128.76 (2)	Cl1^xii—Cs1—Cl1^vi	112.348 (8)
Cl1ⁱⁱⁱ—Pu1—Cs1^v	53.469 (18)	Cl1^viii—Cs1—Cl1^vi	163.34 (3)
Cl1ⁱ—Pu1—Cs1^v	51.24 (2)	Cl1^xiii—Cs1—Cl1^vi	95.403 (19)
Cs1^iv—Pu1—Cs1^v	180.000 (8)	Cl1^xiv—Cs1—Cl1^vi	61.25 (2)
O1ⁱ—Pu1—Cs1^vi	122.222 (4)	O1—Cs1—Cl1^vi	131.50 (4)
O1—Pu1—Cs1^vi	57.778 (4)	Cl1^xv—Cs1—Cl1^vi	63.83 (3)
Cl1ⁱⁱ—Pu1—Cs1^vi	51.24 (2)	Cl1^x—Cs1—Pu1^xiii	131.698 (14)
Cl1—Pu1—Cs1^vi	53.469 (18)	Cl1^xi—Cs1—Pu1^xiii	74.494 (15)
Cl1ⁱⁱⁱ—Pu1—Cs1^vi	128.76 (2)	Cl1^xii—Cs1—Pu1^xiii	135.406 (14)
Cl1ⁱ—Pu1—Cs1^vi	126.531 (18)	Cl1^viii—Cs1—Pu1^xiii	77.734 (14)
Cs1^iv—Pu1—Cs1^vi	64.454 (8)	Cl1^xiii—Cs1—Pu1^xiii	35.626 (12)
Cs1^v—Pu1—Cs1^vi	115.546 (8)	Cl1^xiv—Cs1—Pu1^xiii	96.174 (16)
O1ⁱ—Pu1—Cs1^vii	57.778 (4)	O1—Cs1—Pu1^xiii	122.194 (5)
O1—Pu1—Cs1^vii	122.222 (4)	Cl1^xv—Cs1—Pu1^xiii	35.683 (12)
Cl1ⁱⁱ—Pu1—Cs1^vii	128.76 (2)	Cl1^vi—Cs1—Pu1^xiii	94.713 (15)
Cl1—Pu1—Cs1^vii	126.531 (18)	Cl1^x—Cs1—Pu1^xvi	74.494 (15)
Cl1ⁱⁱⁱ—Pu1—Cs1^vii	51.24 (2)	Cl1^xi—Cs1—Pu1^xvi	131.698 (14)
Cl1ⁱ—Pu1—Cs1^vii	53.469 (18)	Cl1^xii—Cs1—Pu1^xvi	77.734 (14)
Cs1^iv—Pu1—Cs1^vii	115.546 (8)	Cl1^viii—Cs1—Pu1^xvi	135.406 (14)
Cs1^v—Pu1—Cs1^vii	64.454 (8)	Cl1^xiii—Cs1—Pu1^xvi	96.174 (16)
Cs1^vi—Pu1—Cs1^vii	180.000 (7)	Cl1^xiv—Cs1—Pu1^xvi	35.626 (12)
O1ⁱ—Pu1—Cs1^viii	69.04 (11)	O1—Cs1—Pu1^xvi	122.194 (5)
O1—Pu1—Cs1^viii	110.96 (11)	Cl1^xv—Cs1—Pu1^xvi	94.713 (15)
Cl1ⁱⁱ—Pu1—Cs1^viii	130.706 (17)	Cl1^vi—Cs1—Pu1^xvi	35.683 (12)
Cl1—Pu1—Cs1^viii	49.294 (17)	Pu1^xiii—Cs1—Pu1^xvi	115.546 (8)
Cl1ⁱⁱⁱ—Pu1—Cs1^viii	49.294 (17)	Cl1^x—Cs1—Pu1^xvii	123.572 (15)
Cl1ⁱ—Pu1—Cs1^viii	130.706 (17)	Cl1^xi—Cs1—Pu1^xvii	123.572 (15)
Cs1^iv—Pu1—Cs1^viii	78.510 (5)	Cl1^xii—Cs1—Pu1^xvii	35.021 (13)
Cs1^v—Pu1—Cs1^viii	101.490 (5)	Cl1^viii—Cs1—Pu1^xvii	35.021 (13)
Cs1^vi—Pu1—Cs1^viii	101.490 (5)	Cl1^xiii—Cs1—Pu1^xvii	76.579 (13)
Cs1^vii—Pu1—Cs1^viii	78.510 (5)	Cl1^xiv—Cs1—Pu1^xvii	76.579 (13)
O1ⁱ—Pu1—Cs1^ix	110.96 (11)	O1—Cs1—Pu1^xvii	70.49 (5)
O1—Pu1—Cs1^ix	69.04 (11)	Cl1^xv—Cs1—Pu1^xvii	136.161 (13)
Cl1ⁱⁱ—Pu1—Cs1^ix	49.294 (17)	Cl1^vi—Cs1—Pu1^xvii	136.161 (13)
Cl1—Pu1—Cs1^ix	130.706 (17)	Pu1^xiii—Cs1—Pu1^xvii	101.490 (5)
Cl1ⁱⁱⁱ—Pu1—Cs1^ix	130.706 (17)	Pu1^xvi—Cs1—Pu1^xvii	101.490 (5)
Cl1ⁱ—Pu1—Cs1^ix	49.294 (17)	Pu1—Cl1—Cs1^xviii	154.58 (3)
Cs1^iv—Pu1—Cs1^ix	101.490 (5)	Pu1—Cl1—Cs1^viii	95.68 (2)
Cs1^v—Pu1—Cs1^ix	78.510 (5)	Cs1^xviii—Cl1—Cs1^viii	87.583 (18)
Cs1^vi—Pu1—Cs1^ix	78.510 (5)	Pu1—Cl1—Cs1^iv	93.13 (2)
Cs1^vii—Pu1—Cs1^ix	101.490 (5)	Cs1^xviii—Cl1—Cs1^iv	109.41 (2)
Cs1^viii—Pu1—Cs1^ix	180.000 (3)	Cs1^viii—Cl1—Cs1^iv	110.24 (2)
Cl1^x—Cs1—Cl1^xi	66.90 (3)	Pu1—Cl1—Cs1^vi	90.85 (2)
Cl1^x—Cs1—Cl1^xii	92.417 (18)	Cs1^xviii—Cl1—Cs1^vi	80.088 (18)
Cl1^xi—Cs1—Cl1^xii	130.133 (13)	Cs1^viii—Cl1—Cs1^vi	163.34 (3)
Cl1^x—Cs1—Cl1^viii	130.133 (13)	Cs1^iv—Cl1—Cs1^vi	84.597 (19)
Cl1^xi—Cs1—Cl1^viii	92.417 (18)	Pu1—O1—Cs1	178.55 (16)
Cl1^xii—Cs1—Cl1^viii	66.25 (3)

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Symmetry codes: (i) −x, −y, −z; (ii) −x, y, −z; (iii) x, −y, z; (iv) x−1/2, y−1/2, z−1; (v) −x+1/2, −y+1/2, −z+1; (vi) −x+1/2, −y−1/2, −z+1; (vii) x−1/2, y+1/2, z−1; (viii) −x, −y, −z+1; (ix) x, y, z−1; (x) x+1/2, −y−1/2, z; (xi) x+1/2, y+1/2, z; (xii) −x, y, −z+1; (xiii) x+1/2, y+1/2, z+1; (xiv) x+1/2, −y−1/2, z+1; (xv) −x+1/2, y+1/2, −z+1; (xvi) x+1/2, y−1/2, z+1; (xvii) x, y, z+1; (xviii) x−1/2, y−1/2, z.

Footnotes

Supplementary data and figures for this paper are available from the IUCr electronic archives (Reference: FI2048).

References

Bean, A. C., Abney, K., Scott, B. L. & Runde, W. (2005). Inorg. Chem.44, 5209–5211. [DOI] [PubMed]
Bean, A. C., Albrecht-Schmitt, T. E. & Runde, W. (2004). J. Solid State Chem.177, 1346–1351.
Bruker (2000). SHELXTL Version 6.10. Bruker AXS Inc., Madison, Wisconsin, USA.
Bruker (2001). SAINT-Plus Version 7.06. Bruker AXS Inc., Madison, Wisconsin, USA.
Bruker (2003). APEX2. Version 1.08. Bruker AXS Inc., Madison, Wisconsin, USA.
Grenthe, I., Drozdzynski, J., Fujino, T., Buck, E. C., Albrecht-Schmitt, T. E. & Wolf, S. F. (2006). The Chemistry of the Actinide and Transactinide Elements, Vol. 1, ch. 5, edited by L. R. Morrs, N. M. Edelstein, J. Fuger & J. J. Katz, 3rd ed., p. 578. Dordrecht: Springer.
Grigoriev, M. S., Antipin, M. Yu., Krot, N. N. & Bessonov, A. A. (2004). Radiochim. Acta, 92, 405–409.
Hall, D., Rae, A. D. & Waters, T. N. (1966). Acta Cryst.20, 160–162.
Runde, W., Bean, A. C., Albrecht-Schmitt, T. E. & Scott, B. L. (2003). Chem. Commun. pp. 478–479. [DOI] [PubMed]
Sessler, J. L., Gorden, A. E. V., Seidel, D., Hannah, S., Lynch, V., Gordon, P. L., Donohoe, R. J., Tait, C. D. & Keogh, D. W. (2002). Inorg. Chim. Acta, 341, 54–70.
Sheldrick, G. M. (1997). SHELXS97 and SHELXL97 University of Göttingen, Germany.
Sheldrick, G. M. (2001). SADABS University of Göttingen, Germany.
Watkin, D. J., Denning, R. G. & Prout, K. (1991). Acta Cryst. C47, 2517–2519.
Wilkerson, M. P., Arrington, C. A., Berg, J. M. & Scott, B. L. (2007). J. Alloys Compd.444–445, 634–639.
Wilkerson, M. P., Dewey, H. J., Gordon, P. L. & Scott, B. L. (2004). J. Chem. Crystallogr.34, 807–811.

Associated Data

This section collects any data citations, data availability statements, or supplementary materials included in this article.

Supplementary Materials

Crystal structure: contains datablocks global, I. DOI: 10.1107/S1600536807066354/fi2048sup1.cif

e-64-000i5-sup1.cif^{(15.7KB, cif)}

Structure factors: contains datablocks I. DOI: 10.1107/S1600536807066354/fi2048Isup2.hkl

e-64-000i5-Isup2.hkl^{(35.5KB, hkl)}

Additional supplementary materials: crystallographic information; 3D view; checkCIF report

[bb1] Bean, A. C., Abney, K., Scott, B. L. & Runde, W. (2005). Inorg. Chem.44, 5209–5211. [DOI] [PubMed]

[bb2] Bean, A. C., Albrecht-Schmitt, T. E. & Runde, W. (2004). J. Solid State Chem.177, 1346–1351.

[bb3] Bruker (2000). SHELXTL Version 6.10. Bruker AXS Inc., Madison, Wisconsin, USA.

[bb4] Bruker (2001). SAINT-Plus Version 7.06. Bruker AXS Inc., Madison, Wisconsin, USA.

[bb5] Bruker (2003). APEX2. Version 1.08. Bruker AXS Inc., Madison, Wisconsin, USA.

[bb6] Grenthe, I., Drozdzynski, J., Fujino, T., Buck, E. C., Albrecht-Schmitt, T. E. & Wolf, S. F. (2006). The Chemistry of the Actinide and Transactinide Elements, Vol. 1, ch. 5, edited by L. R. Morrs, N. M. Edelstein, J. Fuger & J. J. Katz, 3rd ed., p. 578. Dordrecht: Springer.

[bb7] Grigoriev, M. S., Antipin, M. Yu., Krot, N. N. & Bessonov, A. A. (2004). Radiochim. Acta, 92, 405–409.

[bb8] Hall, D., Rae, A. D. & Waters, T. N. (1966). Acta Cryst.20, 160–162.

[bb9] Runde, W., Bean, A. C., Albrecht-Schmitt, T. E. & Scott, B. L. (2003). Chem. Commun. pp. 478–479. [DOI] [PubMed]

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Dicaesium tetrachloridodioxidoplutonate(VI)

Marianne P Wilkerson

Brian L Scott

Abstract

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Data collection

Refinement

Supplementary Material

Acknowledgments

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Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Å²)

Atomic displacement parameters (Å²)

Geometric parameters (Å, °)

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Dicaesium tetra­chlorido­dioxido­plutonate(VI)

Marianne P Wilkerson

Brian L Scott

Abstract

Related literature

Experimental

Crystal data

Data collection

Refinement

Supplementary Material

Acknowledgments

supplementary crystallographic information

Comment

Experimental

Figures

Fig. 1.

Crystal data

Data collection

Refinement

Special details

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Å2)

Atomic displacement parameters (Å2)

Geometric parameters (Å, °)

Footnotes

References

Associated Data

Supplementary Materials

ACTIONS

PERMALINK

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Dicaesium tetrachloridodioxidoplutonate(VI)

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Å²)

Atomic displacement parameters (Å²)