μ-Oxido-bis­{chlorido[tris­(2-pyridylmeth­yl)amine]chromium(III)} bis(hexafluoridophosphate)

Sheng Li; Shou-Bin Wang; Fu-Li Zhang; Kun Tang

doi:10.1107/S1600536807061296

This article has been retracted.

Retraction in: Acta Crystallogr Sect E Struct Rep Online. 2012 Jun 13;68(Pt 7):e14 See also: PMC Retraction Policy

. 2007 Dec 6;64(Pt 1):m2. doi: 10.1107/S1600536807061296

μ-Oxido-bis{chlorido[tris(2-pyridylmethyl)amine]chromium(III)} bis(hexafluoridophosphate)

Sheng Li ^a,^*, Shou-Bin Wang ^b, Fu-Li Zhang ^a, Kun Tang ^a

PMCID: PMC2914886 PMID: 21200546

Abstract

The title compound, [Cr₂Cl₂O(C₁₈H₁₈N₄)₂](PF₆)₂, is isostructural with the V^III analogue. Each Cr^III atom is chelated by the tetradentate tris(2-pyridylmethyl)amine ligand via four N atoms, and further coordinated by one Cl atom and one bridging O atom, giving a slightly distorted octahedral coordination geometry. The dinuclear complex is centrosymmetric, with the bridging O atom lying on a centre of inversion.

Related literature

For the isostructural V^III analogue, see: Tajika et al. (2005 ▶). For more general related literature, see: Butler & Carrano (1991 ▶); Crans et al. (1989 ▶); Dey (1974 ▶); Chen & Zubieta (1990 ▶).

Experimental

Crystal data

[Cr₂Cl₂O(C₁₈H₁₈N₄)₂](PF₆)₂
M _r = 1061.57
Triclinic,
a = 8.6107 (17) Å
b = 11.302 (2) Å
c = 12.798 (3) Å
α = 115.50 (3)°
β = 107.45 (3)°
γ = 91.50 (3)°
V = 1054.8 (4) Å³
Z = 1
Mo Kα radiation
μ = 0.81 mm⁻¹
T = 293 (2) K
0.28 × 0.22 × 0.18 mm

Data collection

Bruker APEXII CCD diffractometer
Absorption correction: multi-scan (SADABS; Bruker, 2001 ▶) T _min = 0.804, T _max = 0.867
8686 measured reflections
3877 independent reflections
3594 reflections with I > 2σ(I)
R _int = 0.021

Refinement

R[F ² > 2σ(F ²)] = 0.033
wR(F ²) = 0.089
S = 1.00
3877 reflections
287 parameters
H-atom parameters constrained
Δρ_max = 0.51 e Å⁻³
Δρ_min = −0.33 e Å⁻³

Data collection: APEX2 (Bruker, 2004 ▶); cell refinement: SAINT-Plus (Bruker, 2001 ▶); data reduction: SAINT-Plus; program(s) used to solve structure: SHELXS97 (Sheldrick, 1997 ▶); program(s) used to refine structure: SHELXL97 (Sheldrick, 1997 ▶); molecular graphics: SHELXTL (Bruker, 2001 ▶); software used to prepare material for publication: SHELXTL.

Supplementary Material

Crystal structure: contains datablocks I, global. DOI: 10.1107/S1600536807061296/bi2257sup1.cif

e-64-000m2-sup1.cif^{(19.5KB, cif)}

Structure factors: contains datablocks I. DOI: 10.1107/S1600536807061296/bi2257Isup2.hkl

e-64-000m2-Isup2.hkl^{(190KB, hkl)}

Additional supplementary materials: crystallographic information; 3D view; checkCIF report

Acknowledgments

The authors are grateful for financial support from Henan University (grant No.05YBGG013).

supplementary crystallographic information

Comment

A classical but nevertheless rapidly developing field of application for related metal-Schiff compounds is their use as catalysts in polymerization, oxidation reactions, and model examples for the interaction of metal ions within the active sites of enzymes (Butler & Carrano, 1991; Crans et al., 1989; Dey, 1974; Chen & Zubieta, 1990). In the dinuclear title compound (Fig. 1), each Cr^III atom is chelated by the tetradentate ligand tris(2-pyridylmethyl)amine via four N atoms, and further coordinated by one Cl atom and one bridging O atom to give a slightly distorted octahedral coordination geometry.

Experimental

A mixture of chromium(III) trichloride (1 mmol) and tris(2-pyridylmethyl)amine (1 mmol) in 20 ml me thanol was refluxed for two hours. After cooling, the solution was filtered and the filtrate was evaporated naturally at room temperature. Blue blocks of the title compound were obtained after a few days with a yield of 31%. Elemental analysis calculated: C 40.39, H 3.35, N 10.44%; found: C 40.35, H 3.39, N 10.42%.

Figures

Fig. 1. — The molecular structure drawn with 30% probability displacement ellipsoids for the non-H atoms.

Crystal data

[Cr₂Cl₂O(C₁₈H₁₈N₄)₂](PF₆)₂	Z = 1
M_r = 1061.57	F₀₀₀ = 536
Triclinic, P1	D_x = 1.671 Mg m⁻³
Hall symbol: -P 1	Mo Kα radiation λ = 0.71073 Å
a = 8.6107 (17) Å	Cell parameters from 3877 reflections
b = 11.302 (2) Å	θ = 3.0–25.5º
c = 12.798 (3) Å	µ = 0.81 mm⁻¹
α = 115.50 (3)º	T = 293 (2) K
β = 107.45 (3)º	Block, blue
γ = 91.50 (3)º	0.28 × 0.22 × 0.18 mm
V = 1054.8 (4) Å³

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Data collection

Bruker APEX II CCD diffractometer	3877 independent reflections
Radiation source: fine-focus sealed tube	3594 reflections with I > 2σ(I)
Monochromator: graphite	R_int = 0.021
T = 293(2) K	θ_max = 25.5º
φ and ω scans	θ_min = 3.0º
Absorption correction: multi-scan(SADABS; Bruker, 2001)	h = −8→10
T_min = 0.804, T_max = 0.867	k = −13→13
8686 measured reflections	l = −15→15

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Refinement

Refinement on F²	Hydrogen site location: inferred from neighbouring sites
Least-squares matrix: full	H-atom parameters constrained
R[F² > 2σ(F²)] = 0.033	w = 1/[σ²(F_o²) + (0.0565P)² + 0.3428P] where P = (F_o² + 2F_c²)/3
wR(F²) = 0.089	(Δ/σ)_max < 0.001
S = 1.00	Δρ_max = 0.51 e Å⁻³
3877 reflections	Δρ_min = −0.33 e Å⁻³
287 parameters	Extinction correction: SHELXL, Fc^*=kFc[1+0.001xFc²λ³/sin(2θ)]^-1/4
Primary atom site location: structure-invariant direct methods	Extinction coefficient: 0.042 (3)
Secondary atom site location: difference Fourier map

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Special details

Geometry. All e.s.d.'s (except the e.s.d. in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell e.s.d.'s are taken into account individually in the estimation of e.s.d.'s in distances, angles and torsion angles; correlations between e.s.d.'s in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell e.s.d.'s is used for estimating e.s.d.'s involving l.s. planes.

Refinement. Refinement of F² against ALL reflections. The weighted R-factor wR and goodness of fit S are based on F², conventional R-factors R are based on F, with F set to zero for negative F². The threshold expression of F² > σ(F²) is used only for calculating R-factors(gt) etc. and is not relevant to the choice of reflections for refinement. R-factors based on F² are statistically about twice as large as those based on F, and R- factors based on ALL data will be even larger.

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Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Å²)

	x	y	z	U_iso*/U_eq
Cr1	1.03745 (3)	0.34679 (3)	0.39271 (2)	0.0408 (4)
C1	0.9871 (3)	0.1897 (2)	0.53070 (18)	0.0447 (4)
H1	1.1018	0.1984	0.5573	0.054*
C2	0.8992 (3)	0.1306 (2)	0.5741 (2)	0.0534 (5)
H2	0.9533	0.0998	0.6296	0.064*
C3	0.7284 (3)	0.1173 (3)	0.5340 (2)	0.0605 (6)
H3	0.6662	0.0779	0.5626	0.073*
C4	0.6514 (3)	0.1630 (2)	0.4513 (2)	0.0552 (5)
H4	0.5367	0.1537	0.4226	0.066*
C5	0.7464 (2)	0.22306 (19)	0.41135 (18)	0.0425 (4)
C6	0.6721 (2)	0.2874 (2)	0.3310 (2)	0.0490 (5)
H6A	0.5643	0.2353	0.2730	0.059*
H6B	0.6563	0.3757	0.3822	0.059*
C7	0.7467 (3)	0.1753 (2)	0.1450 (2)	0.0573 (6)
H7A	0.7443	0.2004	0.0811	0.069*
H7B	0.6381	0.1253	0.1216	0.069*
C8	0.8712 (2)	0.08565 (19)	0.14924 (17)	0.0414 (4)
C9	0.8351 (3)	−0.0448 (2)	0.0588 (2)	0.0528 (5)
H9	0.7315	−0.0793	−0.0028	0.063*
C10	0.9546 (3)	−0.1237 (2)	0.0606 (2)	0.0617 (6)
H10	0.9327	−0.2119	0.0003	0.074*
C11	1.1069 (3)	−0.0697 (2)	0.1532 (2)	0.0607 (6)
H11	1.1894	−0.1208	0.1564	0.073*
C12	1.1346 (3)	0.0605 (2)	0.2404 (2)	0.0526 (5)
H12	1.2374	0.0964	0.3028	0.063*
C13	0.7605 (3)	0.4147 (2)	0.23723 (19)	0.0475 (5)
H13A	0.7430	0.4881	0.3059	0.057*
H13B	0.6651	0.3917	0.1639	0.057*
C14	0.9146 (3)	0.4574 (2)	0.21891 (17)	0.0471 (5)
C15	0.9138 (4)	0.5296 (2)	0.1547 (2)	0.0606 (6)
H15	0.8154	0.5482	0.1149	0.073*
C16	1.0629 (4)	0.5734 (3)	0.1512 (2)	0.0728 (8)
H16	1.0650	0.6237	0.1100	0.087*
C17	1.2075 (4)	0.5435 (3)	0.2077 (3)	0.0715 (7)
H17	1.3076	0.5721	0.2047	0.086*
C18	1.2007 (3)	0.4704 (3)	0.2686 (2)	0.0610 (6)
H18	1.2978	0.4490	0.3069	0.073*
Cl1	1.31398 (6)	0.35078 (6)	0.48445 (5)	0.05507 (17)
F1	0.5115 (2)	0.90789 (16)	0.13882 (17)	0.0825 (5)
F2	0.4878 (2)	0.8490 (2)	0.27945 (15)	0.0893 (5)
F3	0.5830 (3)	0.6607 (2)	0.1912 (2)	0.1078 (7)
F4	0.7325 (2)	0.8610 (2)	0.24906 (17)	0.0999 (6)
F5	0.6040 (2)	0.72005 (19)	0.04870 (17)	0.0929 (6)
F6	0.36012 (19)	0.71102 (16)	0.08031 (14)	0.0726 (4)
N1	1.0192 (2)	0.13917 (16)	0.23969 (15)	0.0436 (4)
N2	1.0566 (2)	0.42848 (18)	0.27454 (16)	0.0482 (4)
N3	0.91312 (19)	0.23567 (15)	0.45104 (15)	0.0406 (3)
N4	0.7776 (2)	0.29834 (16)	0.26214 (15)	0.0424 (4)
O1	1.0000	0.5000	0.5000	0.0420 (4)
P1	0.54870 (7)	0.78424 (6)	0.16549 (5)	0.05276 (17)

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Atomic displacement parameters (Å²)

	U¹¹	U²²	U³³	U¹²	U¹³	U²³
Cr1	0.0378 (11)	0.0424 (10)	0.0424 (10)	0.0088 (8)	0.0112 (8)	0.0212 (8)
C1	0.0415 (10)	0.0468 (10)	0.0459 (10)	0.0095 (8)	0.0121 (8)	0.0233 (8)
C2	0.0597 (14)	0.0546 (12)	0.0513 (12)	0.0109 (10)	0.0179 (10)	0.0300 (10)
C3	0.0606 (14)	0.0666 (14)	0.0669 (14)	0.0057 (11)	0.0281 (11)	0.0381 (12)
C4	0.0395 (11)	0.0606 (13)	0.0695 (14)	0.0063 (9)	0.0206 (10)	0.0324 (11)
C5	0.0351 (9)	0.0412 (9)	0.0456 (10)	0.0057 (7)	0.0117 (8)	0.0166 (8)
C6	0.0302 (9)	0.0572 (12)	0.0614 (12)	0.0093 (8)	0.0107 (8)	0.0322 (10)
C7	0.0517 (13)	0.0499 (12)	0.0462 (11)	0.0099 (9)	−0.0011 (9)	0.0127 (9)
C8	0.0424 (10)	0.0438 (10)	0.0403 (9)	0.0052 (8)	0.0153 (8)	0.0207 (8)
C9	0.0562 (13)	0.0484 (11)	0.0497 (11)	0.0027 (9)	0.0185 (10)	0.0189 (9)
C10	0.0769 (17)	0.0441 (11)	0.0634 (14)	0.0138 (11)	0.0334 (13)	0.0178 (10)
C11	0.0653 (15)	0.0551 (13)	0.0714 (15)	0.0256 (11)	0.0342 (12)	0.0297 (11)
C12	0.0460 (12)	0.0572 (12)	0.0570 (12)	0.0167 (9)	0.0199 (10)	0.0265 (10)
C13	0.0504 (11)	0.0490 (11)	0.0410 (10)	0.0162 (9)	0.0097 (8)	0.0224 (9)
C14	0.0599 (13)	0.0426 (10)	0.0358 (9)	0.0112 (9)	0.0152 (9)	0.0162 (8)
C15	0.0864 (18)	0.0503 (12)	0.0451 (12)	0.0140 (11)	0.0197 (11)	0.0237 (10)
C16	0.114 (2)	0.0544 (13)	0.0572 (14)	0.0012 (14)	0.0362 (15)	0.0288 (12)
C17	0.084 (2)	0.0710 (16)	0.0683 (16)	−0.0005 (14)	0.0357 (14)	0.0343 (13)
C18	0.0612 (14)	0.0666 (14)	0.0615 (14)	0.0042 (11)	0.0280 (11)	0.0307 (12)
Cl1	0.0334 (3)	0.0609 (3)	0.0596 (3)	0.0131 (2)	0.0101 (2)	0.0215 (2)
F1	0.0810 (11)	0.0724 (10)	0.0988 (12)	0.0060 (8)	0.0208 (9)	0.0507 (9)
F2	0.0836 (12)	0.1141 (14)	0.0632 (9)	0.0059 (10)	0.0336 (8)	0.0300 (9)
F3	0.1008 (15)	0.1236 (16)	0.163 (2)	0.0524 (12)	0.0641 (14)	0.1074 (16)
F4	0.0483 (9)	0.1549 (19)	0.0854 (12)	−0.0063 (10)	0.0024 (8)	0.0605 (12)
F5	0.0973 (13)	0.0965 (12)	0.0873 (12)	0.0083 (10)	0.0563 (10)	0.0288 (10)
F6	0.0571 (9)	0.0710 (9)	0.0731 (9)	−0.0042 (7)	0.0144 (7)	0.0248 (7)
N1	0.0425 (9)	0.0456 (9)	0.0444 (9)	0.0116 (7)	0.0164 (7)	0.0210 (7)
N2	0.0526 (10)	0.0497 (9)	0.0451 (9)	0.0087 (8)	0.0187 (8)	0.0231 (8)
N3	0.0348 (8)	0.0421 (8)	0.0447 (8)	0.0082 (6)	0.0125 (7)	0.0205 (7)
N4	0.0376 (8)	0.0442 (8)	0.0411 (8)	0.0101 (7)	0.0077 (6)	0.0195 (7)
O1	0.0384 (10)	0.0430 (10)	0.0424 (10)	0.0081 (8)	0.0119 (8)	0.0190 (8)
P1	0.0429 (3)	0.0665 (4)	0.0529 (3)	0.0075 (3)	0.0151 (2)	0.0321 (3)

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Geometric parameters (Å, °)

Cr1—O1	1.7986 (7)	C9—H9	0.930
Cr1—N3	2.1206 (18)	C10—C11	1.378 (4)
Cr1—N2	2.1238 (18)	C10—H10	0.930
Cr1—N4	2.2370 (19)	C11—C12	1.370 (3)
Cr1—N1	2.2814 (19)	C11—H11	0.930
Cr1—Cl1	2.3070 (9)	C12—N1	1.351 (3)
O1—Cr1ⁱ	1.7986 (7)	C12—H12	0.930
C1—N3	1.341 (3)	C13—N4	1.482 (3)
C1—C2	1.369 (3)	C13—C14	1.516 (3)
C1—H1	0.930	C13—H13A	0.970
C2—C3	1.386 (4)	C13—H13B	0.970
C2—H2	0.930	C14—N2	1.345 (3)
C3—C4	1.376 (4)	C14—C15	1.383 (3)
C3—H3	0.930	C15—C16	1.384 (4)
C4—C5	1.382 (3)	C15—H15	0.930
C4—H4	0.930	C16—C17	1.371 (4)
C5—N3	1.352 (3)	C16—H16	0.930
C5—C6	1.506 (3)	C17—C18	1.369 (4)
C6—N4	1.479 (3)	C17—H17	0.930
C6—H6A	0.970	C18—N2	1.351 (3)
C6—H6B	0.970	C18—H18	0.930
C7—N4	1.483 (3)	F1—P1	1.5939 (17)
C7—C8	1.499 (3)	F2—P1	1.5803 (18)
C7—H7A	0.970	F3—P1	1.582 (2)
C7—H7B	0.970	F4—P1	1.5859 (18)
C8—N1	1.342 (3)	F5—P1	1.5804 (18)
C8—C9	1.379 (3)	F6—P1	1.6129 (17)
C9—C10	1.380 (4)

O1—Cr1—N3	91.01 (5)	N1—C12—H12	118.5
O1—Cr1—N2	92.46 (5)	C11—C12—H12	118.5
N3—Cr1—N2	154.67 (7)	N4—C13—C14	110.48 (16)
O1—Cr1—N4	91.36 (6)	N4—C13—H13A	109.6
N3—Cr1—N4	78.03 (7)	C14—C13—H13A	109.6
N2—Cr1—N4	76.81 (7)	N4—C13—H13B	109.6
O1—Cr1—N1	166.58 (5)	C14—C13—H13B	109.6
N3—Cr1—N1	81.87 (7)	H13A—C13—H13B	108.1
N2—Cr1—N1	89.30 (7)	N2—C14—C15	120.7 (2)
N4—Cr1—N1	76.09 (7)	N2—C14—C13	116.67 (18)
O1—Cr1—Cl1	103.29 (5)	C15—C14—C13	122.5 (2)
N3—Cr1—Cl1	104.03 (5)	C14—C15—C16	118.4 (3)
N2—Cr1—Cl1	99.56 (6)	C14—C15—H15	120.8
N4—Cr1—Cl1	165.11 (5)	C16—C15—H15	120.8
N1—Cr1—Cl1	89.52 (6)	C17—C16—C15	120.8 (2)
N3—C1—C2	122.1 (2)	C17—C16—H16	119.6
N3—C1—H1	118.9	C15—C16—H16	119.6
C2—C1—H1	119.0	C16—C17—C18	118.2 (3)
C3—C2—C1	118.8 (2)	C16—C17—H17	120.9
C3—C2—H2	120.6	C18—C17—H17	120.9
C1—C2—H2	120.6	N2—C18—C17	121.8 (3)
C2—C3—C4	119.4 (2)	N2—C18—H18	119.1
C2—C3—H3	120.3	C17—C18—H18	119.1
C4—C3—H3	120.3	C12—N1—C8	117.79 (18)
C3—C4—C5	119.3 (2)	C12—N1—Cr1	126.02 (15)
C3—C4—H4	120.4	C8—N1—Cr1	115.61 (13)
C5—C4—H4	120.4	C14—N2—C18	120.1 (2)
N3—C5—C4	120.95 (19)	C14—N2—Cr1	114.45 (14)
N3—C5—C6	116.79 (18)	C18—N2—Cr1	124.62 (17)
C4—C5—C6	122.07 (19)	C1—N3—C5	119.42 (18)
N4—C6—C5	112.19 (16)	C1—N3—Cr1	125.22 (14)
N4—C6—H6A	109.2	C5—N3—Cr1	115.07 (13)
C5—C6—H6A	109.2	C6—N4—C7	112.30 (18)
N4—C6—H6B	109.2	C6—N4—C13	112.63 (16)
C5—C6—H6B	109.2	C7—N4—C13	109.74 (17)
H6A—C6—H6B	107.9	C6—N4—Cr1	105.11 (12)
N4—C7—C8	114.97 (17)	C7—N4—Cr1	112.78 (13)
N4—C7—H7A	108.5	C13—N4—Cr1	103.96 (12)
C8—C7—H7A	108.5	Cr1—O1—Cr1ⁱ	180.0
N4—C7—H7B	108.5	F5—P1—F3	90.59 (12)
C8—C7—H7B	108.5	F5—P1—F2	178.06 (11)
H7A—C7—H7B	107.5	F3—P1—F2	90.59 (13)
N1—C8—C9	122.2 (2)	F5—P1—F4	90.15 (11)
N1—C8—C7	117.57 (17)	F3—P1—F4	91.62 (13)
C9—C8—C7	120.13 (19)	F2—P1—F4	91.35 (11)
C10—C9—C8	119.3 (2)	F5—P1—F1	89.58 (11)
C10—C9—H9	120.4	F3—P1—F1	179.22 (11)
C8—C9—H9	120.4	F2—P1—F1	89.22 (11)
C11—C10—C9	118.9 (2)	F4—P1—F1	89.14 (11)
C11—C10—H10	120.5	F5—P1—F6	90.19 (10)
C9—C10—H10	120.5	F3—P1—F6	90.39 (12)
C10—C11—C12	118.9 (2)	F2—P1—F6	88.26 (10)
C10—C11—H11	120.6	F4—P1—F6	177.95 (11)
C12—C11—H11	120.6	F1—P1—F6	88.85 (10)
N1—C12—C11	122.9 (2)

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Symmetry codes: (i) −x+2, −y+1, −z+1.

Footnotes

Supplementary data and figures for this paper are available from the IUCr electronic archives (Reference: BI2257).

References

Bruker (2001). SADABS, SAINT-Plus and SHELXTL Bruker AXS Inc., Madison, Wisconsin, USA.
Bruker (2004). APEX2 Bruker AXS Inc., Madison, Wisconsin, USA.
Butler, A. & Carrano, C. J. (1991). Chem. Rev.109, 61–105.
Chen, Q. & Zubieta, I. (1990). Inorg. Chem.29, 1456–1458.
Crans, D., Bunch, R. L. & Theisen, L. A. (1989). J. Am. Chem. Soc.111, 7597–7601.
Dey, K. J. (1974). Sci. Ind. Res.33, 76–97.
Sheldrick, G. M. (1997). SHELXS97 and SHELXL97 University of Göttingen, Germany.
Tajika, Y., Tsuge, K. & Sasaki, Y. (2005). Dalton Trans. pp. 1438–1447. [DOI] [PubMed]

Associated Data

This section collects any data citations, data availability statements, or supplementary materials included in this article.

Supplementary Materials

Crystal structure: contains datablocks I, global. DOI: 10.1107/S1600536807061296/bi2257sup1.cif

e-64-000m2-sup1.cif^{(19.5KB, cif)}

Structure factors: contains datablocks I. DOI: 10.1107/S1600536807061296/bi2257Isup2.hkl

e-64-000m2-Isup2.hkl^{(190KB, hkl)}

Additional supplementary materials: crystallographic information; 3D view; checkCIF report

[bb1] Bruker (2001). SADABS, SAINT-Plus and SHELXTL Bruker AXS Inc., Madison, Wisconsin, USA.

[bb2] Bruker (2004). APEX2 Bruker AXS Inc., Madison, Wisconsin, USA.

[bb3] Butler, A. & Carrano, C. J. (1991). Chem. Rev.109, 61–105.

[bb4] Chen, Q. & Zubieta, I. (1990). Inorg. Chem.29, 1456–1458.

[bb5] Crans, D., Bunch, R. L. & Theisen, L. A. (1989). J. Am. Chem. Soc.111, 7597–7601.

[bb6] Dey, K. J. (1974). Sci. Ind. Res.33, 76–97.

[bb7] Sheldrick, G. M. (1997). SHELXS97 and SHELXL97 University of Göttingen, Germany.

[bb8] Tajika, Y., Tsuge, K. & Sasaki, Y. (2005). Dalton Trans. pp. 1438–1447. [DOI] [PubMed]

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μ-Oxido-bis{chlorido[tris(2-pyridylmethyl)amine]chromium(III)} bis(hexafluoridophosphate)

Sheng Li

Shou-Bin Wang

Fu-Li Zhang

Kun Tang

Abstract

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Refinement

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Acknowledgments

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μ-Oxido-bis­{chlorido[tris­(2-pyridylmeth­yl)amine]chromium(III)} bis(hexafluoridophosphate)

Sheng Li

Shou-Bin Wang

Fu-Li Zhang

Kun Tang

Abstract

Related literature

Experimental

Crystal data

Data collection

Refinement

Supplementary Material

Acknowledgments

supplementary crystallographic information

Comment

Experimental

Refinement

Figures

Fig. 1.

Crystal data

Data collection

Refinement

Special details

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Å2)

Atomic displacement parameters (Å2)

Geometric parameters (Å, °)

Footnotes

References

Associated Data

Supplementary Materials

ACTIONS

PERMALINK

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μ-Oxido-bis{chlorido[tris(2-pyridylmethyl)amine]chromium(III)} bis(hexafluoridophosphate)

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Å²)

Atomic displacement parameters (Å²)