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Acta Crystallographica Section E: Structure Reports Online logoLink to Acta Crystallographica Section E: Structure Reports Online
. 2008 Nov 8;64(Pt 12):m1509. doi: 10.1107/S1600536808035460

Bis(isopropoxido-κO)bis­(2-methyl­quinolin-8-olato-κ2 N,O)titanium(IV)

Yousef Fazaeli a, Mostafa M Amini a, Seik Weng Ng b,*
PMCID: PMC2960138  PMID: 21581128

Abstract

The two 2-methyl­quinolin-8-olate anions in the title complex, [Ti(C10H8NO)2(C3H7O)2], chelate the TiIV atom, which shows an all-cis distorted octa­hedral N2O4 coordination geometry.

Related literature

For the synthesis, see: Bickley & Nick (1979 ▶); Harrod & Taylor (1975 ▶). For the crystal structure of bis­(isoprop­oxy)bis(quinolin-8-olato)titanium, see: Zeng et al. (2002 ▶).graphic file with name e-64-m1509-scheme1.jpg

Experimental

Crystal data

  • [Ti(C10H8NO)2(C3H7O)2]

  • M r = 482.42

  • Monoclinic, Inline graphic

  • a = 9.5851 (2) Å

  • b = 13.5768 (2) Å

  • c = 18.7779 (3) Å

  • β = 102.559 (1)°

  • V = 2385.19 (7) Å3

  • Z = 4

  • Mo Kα radiation

  • μ = 0.39 mm−1

  • T = 100 (2) K

  • 0.35 × 0.25 × 0.15 mm

Data collection

  • Bruker SMART APEX diffractometer

  • Absorption correction: multi-scan (SADABS; Sheldrick, 1996 ▶) T min = 0.875, T max = 0.943

  • 16391 measured reflections

  • 5467 independent reflections

  • 4651 reflections with I > 2σ(I)

  • R int = 0.025

Refinement

  • R[F 2 > 2σ(F 2)] = 0.032

  • wR(F 2) = 0.088

  • S = 1.03

  • 5467 reflections

  • 304 parameters

  • H-atom parameters constrained

  • Δρmax = 0.39 e Å−3

  • Δρmin = −0.39 e Å−3

Data collection: APEX2 (Bruker, 2007 ▶); cell refinement: APEX2; data reduction: SAINT (Bruker, 2007 ▶); program(s) used to solve structure: SHELXS97 (Sheldrick, 2008 ▶); program(s) used to refine structure: SHELXL97 (Sheldrick, 2008 ▶); molecular graphics: X-SEED (Barbour, 2001 ▶); software used to prepare material for publication: publCIF (Westrip, 2008 ▶).

Supplementary Material

Crystal structure: contains datablocks global, I. DOI: 10.1107/S1600536808035460/tk2320sup1.cif

e-64-m1509-sup1.cif (24.7KB, cif)

Structure factors: contains datablocks I. DOI: 10.1107/S1600536808035460/tk2320Isup2.hkl

e-64-m1509-Isup2.hkl (267.7KB, hkl)

Additional supplementary materials: crystallographic information; 3D view; checkCIF report

Acknowledgments

The authors thank the Vice-President’s Office for Research Affairs of Shahid Beheshti University and the University of Malaya for supporting this work.

supplementary crystallographic information

Experimental

8-Hydroxy-2-methylquinoline (1.59 g, 10 mmol) was added to the titanium isopropoxide (2.84 g, 10 mmol) in toluene (20 ml) at room temperature. The mixture was stirred for a day and than solvent was removed under reduced pressure to furnish an orange solid. The solid was crystallized from dichloromethane and n-hexane (1:1) to give yellow crystals, m.p. 445 K. IR (KBr, cm-1): 1575 (C═C, C═N), 1236 (C—O). 1H NMR (CDCl3, p.p.m.): 0.94 (CH3, doublet), 1.14 (CH3, doublet), 2.83 (CH3, singlet), 4.61 (CH, quartet), 6.9–8.58 (aromatic H atoms).

Refinement

Hydrogen atoms were placed in their calculated positions (C—H 0.95–0.98 Å) and were treated as riding on their parent atoms, with U(H) set to 1.2–1.5 times Ueq(C).

Figures

Fig. 1.

Fig. 1.

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Thermal ellipsoid plot (Barbour, 2001) of Ti(C10H8NO)2(C3H7O)2 at the 70% probability level showing atom labelling. Hydrogen atoms are drawn as spheres of arbitrary radius.

Crystal data

[Ti(C10H8NO)2(C3H7O)2] F000 = 1016
Mr = 482.42 Dx = 1.343 Mg m−3
Monoclinic, P21/c Mo Kα radiation λ = 0.71073 Å
Hall symbol: -P 2ybc Cell parameters from 6457 reflections
a = 9.5851 (2) Å θ = 2.2–28.3º
b = 13.5768 (2) Å µ = 0.39 mm−1
c = 18.7779 (3) Å T = 100 (2) K
β = 102.559 (1)º Irregular chip, yellow
V = 2385.19 (7) Å3 0.35 × 0.25 × 0.15 mm
Z = 4
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Data collection

Bruker SMART APEX diffractometer 5467 independent reflections
Radiation source: fine-focus sealed tube 4651 reflections with I > 2σ(I)
Monochromator: graphite Rint = 0.025
T = 100(2) K θmax = 27.5º
ω scans θmin = 2.2º
Absorption correction: multi-scan(SADABS; Sheldrick, 1996) h = −12→11
Tmin = 0.875, Tmax = 0.943 k = −17→17
16391 measured reflections l = −24→24
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Refinement

Refinement on F2 Secondary atom site location: difference Fourier map
Least-squares matrix: full Hydrogen site location: inferred from neighbouring sites
R[F2 > 2σ(F2)] = 0.032 H-atom parameters constrained
wR(F2) = 0.088   w = 1/[σ2(Fo2) + (0.0394P)2 + 1.3426P] where P = (Fo2 + 2Fc2)/3
S = 1.03 (Δ/σ)max = 0.001
5467 reflections Δρmax = 0.39 e Å−3
304 parameters Δρmin = −0.39 e Å−3
Primary atom site location: structure-invariant direct methods Extinction correction: none
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Special details

Geometry. All esds (except the esd in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell esds are taken into account individually in the estimation of esds in distances, angles and torsion angles; correlations between esds in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell esds is used for estimating esds involving l.s. planes.
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Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Å2)

x y z Uiso*/Ueq
Ti1 0.36712 (3) 0.433571 (18) 0.241664 (14) 0.01288 (8)
O1 0.26537 (11) 0.55637 (7) 0.23824 (6) 0.0166 (2)
O2 0.46090 (11) 0.31617 (7) 0.28355 (5) 0.0153 (2)
O3 0.49414 (11) 0.48288 (8) 0.19514 (6) 0.0187 (2)
O4 0.24248 (11) 0.37144 (8) 0.16802 (5) 0.0171 (2)
N1 0.19366 (13) 0.41035 (9) 0.31601 (6) 0.0142 (2)
N2 0.51257 (13) 0.48222 (9) 0.35581 (6) 0.0145 (2)
C1 0.16171 (16) 0.57482 (11) 0.27306 (8) 0.0169 (3)
C2 0.09311 (17) 0.66473 (12) 0.27024 (9) 0.0219 (3)
H2 0.1206 0.7172 0.2427 0.026*
C3 −0.01715 (18) 0.67913 (12) 0.30789 (9) 0.0261 (4)
H3 −0.0628 0.7415 0.3055 0.031*
C4 −0.05984 (17) 0.60535 (13) 0.34771 (9) 0.0259 (4)
H4 −0.1351 0.6164 0.3724 0.031*
C5 0.00847 (16) 0.51221 (12) 0.35212 (8) 0.0204 (3)
C6 0.12004 (15) 0.49752 (11) 0.31484 (8) 0.0155 (3)
C7 −0.02862 (17) 0.43106 (13) 0.39098 (9) 0.0244 (3)
H7 −0.1022 0.4370 0.4174 0.029*
C8 0.04179 (17) 0.34421 (13) 0.39039 (9) 0.0228 (3)
H8 0.0155 0.2890 0.4157 0.027*
C9 0.15426 (16) 0.33490 (11) 0.35243 (8) 0.0170 (3)
C10 0.22910 (17) 0.23783 (11) 0.35446 (9) 0.0210 (3)
H10A 0.2668 0.2303 0.3102 0.032*
H10B 0.1615 0.1845 0.3570 0.032*
H10C 0.3081 0.2352 0.3975 0.032*
C11 0.54608 (15) 0.31020 (11) 0.34980 (8) 0.0151 (3)
C12 0.60985 (17) 0.22382 (12) 0.37911 (8) 0.0197 (3)
H12 0.5961 0.1647 0.3514 0.024*
C13 0.69565 (17) 0.22374 (12) 0.45060 (9) 0.0226 (3)
H13 0.7381 0.1638 0.4706 0.027*
C14 0.71930 (17) 0.30763 (12) 0.49184 (9) 0.0215 (3)
H14 0.7760 0.3054 0.5401 0.026*
C15 0.65868 (16) 0.39776 (12) 0.46212 (8) 0.0170 (3)
C16 0.57156 (15) 0.39851 (11) 0.39100 (8) 0.0145 (3)
C17 0.68312 (16) 0.49006 (12) 0.49736 (8) 0.0199 (3)
H17 0.7367 0.4940 0.5462 0.024*
C18 0.62969 (17) 0.57309 (11) 0.46108 (8) 0.0197 (3)
H18 0.6493 0.6353 0.4842 0.024*
C19 0.54487 (16) 0.56820 (11) 0.38889 (8) 0.0171 (3)
C20 0.49429 (18) 0.66222 (11) 0.35024 (9) 0.0235 (3)
H20A 0.4595 0.6491 0.2981 0.035*
H20B 0.5736 0.7093 0.3570 0.035*
H20C 0.4166 0.6899 0.3704 0.035*
C21 0.63093 (17) 0.48966 (12) 0.17852 (9) 0.0199 (3)
H21 0.6754 0.5535 0.1980 0.024*
C22 0.6130 (2) 0.48986 (15) 0.09632 (9) 0.0321 (4)
H22A 0.5505 0.5445 0.0754 0.048*
H22B 0.5703 0.4274 0.0764 0.048*
H22C 0.7066 0.4978 0.0840 0.048*
C23 0.72535 (18) 0.40664 (13) 0.21459 (10) 0.0274 (4)
H23A 0.7328 0.4091 0.2674 0.041*
H23B 0.8207 0.4135 0.2042 0.041*
H23C 0.6838 0.3434 0.1956 0.041*
C24 0.17566 (17) 0.41249 (11) 0.09929 (8) 0.0181 (3)
H24 0.2249 0.4755 0.0922 0.022*
C25 0.1915 (2) 0.34129 (13) 0.03960 (9) 0.0308 (4)
H25A 0.2932 0.3306 0.0411 0.046*
H25B 0.1451 0.3687 −0.0079 0.046*
H25C 0.1464 0.2784 0.0470 0.046*
C26 0.02027 (18) 0.43437 (14) 0.09889 (10) 0.0279 (4)
H26A 0.0150 0.4809 0.1381 0.042*
H26B −0.0286 0.3731 0.1065 0.042*
H26C −0.0259 0.4632 0.0518 0.042*
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Atomic displacement parameters (Å2)

U11 U22 U33 U12 U13 U23
Ti1 0.01437 (14) 0.01316 (13) 0.01128 (13) 0.00042 (10) 0.00319 (9) 0.00035 (9)
O1 0.0175 (5) 0.0147 (5) 0.0178 (5) 0.0012 (4) 0.0042 (4) 0.0013 (4)
O2 0.0170 (5) 0.0156 (5) 0.0125 (5) 0.0015 (4) 0.0016 (4) −0.0008 (4)
O3 0.0177 (5) 0.0219 (5) 0.0178 (5) 0.0005 (4) 0.0068 (4) 0.0032 (4)
O4 0.0201 (5) 0.0170 (5) 0.0130 (5) −0.0005 (4) 0.0013 (4) 0.0005 (4)
N1 0.0133 (6) 0.0169 (6) 0.0119 (6) −0.0007 (5) 0.0017 (5) −0.0018 (4)
N2 0.0132 (6) 0.0164 (6) 0.0144 (6) −0.0013 (5) 0.0041 (5) 0.0001 (5)
C1 0.0155 (7) 0.0176 (7) 0.0158 (7) −0.0004 (6) −0.0006 (5) −0.0037 (5)
C2 0.0216 (8) 0.0172 (7) 0.0240 (8) 0.0025 (6) −0.0016 (6) −0.0030 (6)
C3 0.0224 (8) 0.0231 (8) 0.0296 (9) 0.0087 (7) −0.0013 (7) −0.0095 (7)
C4 0.0170 (8) 0.0343 (9) 0.0262 (8) 0.0060 (7) 0.0039 (6) −0.0099 (7)
C5 0.0136 (7) 0.0289 (8) 0.0177 (7) 0.0009 (6) 0.0011 (6) −0.0054 (6)
C6 0.0131 (7) 0.0185 (7) 0.0133 (7) 0.0000 (6) −0.0005 (5) −0.0034 (5)
C7 0.0162 (8) 0.0388 (10) 0.0197 (8) −0.0011 (7) 0.0071 (6) −0.0023 (7)
C8 0.0192 (8) 0.0305 (9) 0.0189 (8) −0.0048 (7) 0.0049 (6) 0.0035 (6)
C9 0.0154 (7) 0.0214 (7) 0.0129 (7) −0.0034 (6) 0.0003 (5) 0.0001 (5)
C10 0.0216 (8) 0.0205 (8) 0.0214 (8) −0.0019 (6) 0.0056 (6) 0.0045 (6)
C11 0.0128 (7) 0.0189 (7) 0.0139 (7) 0.0002 (5) 0.0034 (5) 0.0007 (5)
C12 0.0196 (8) 0.0188 (7) 0.0205 (8) 0.0022 (6) 0.0042 (6) 0.0016 (6)
C13 0.0208 (8) 0.0237 (8) 0.0223 (8) 0.0055 (6) 0.0025 (6) 0.0077 (6)
C14 0.0173 (8) 0.0296 (8) 0.0164 (7) 0.0009 (6) 0.0010 (6) 0.0047 (6)
C15 0.0136 (7) 0.0240 (8) 0.0140 (7) −0.0016 (6) 0.0042 (6) 0.0013 (6)
C16 0.0122 (7) 0.0182 (7) 0.0141 (7) −0.0002 (5) 0.0049 (5) 0.0014 (5)
C17 0.0152 (7) 0.0301 (8) 0.0142 (7) −0.0047 (6) 0.0030 (6) −0.0032 (6)
C18 0.0183 (8) 0.0221 (8) 0.0191 (7) −0.0062 (6) 0.0052 (6) −0.0061 (6)
C19 0.0151 (7) 0.0188 (7) 0.0182 (7) −0.0037 (6) 0.0057 (6) −0.0018 (6)
C20 0.0278 (9) 0.0167 (7) 0.0238 (8) −0.0025 (6) 0.0009 (7) −0.0008 (6)
C21 0.0189 (8) 0.0216 (8) 0.0210 (8) −0.0041 (6) 0.0081 (6) −0.0003 (6)
C22 0.0325 (10) 0.0447 (11) 0.0233 (9) 0.0086 (8) 0.0156 (7) 0.0071 (8)
C23 0.0180 (8) 0.0340 (9) 0.0305 (9) 0.0017 (7) 0.0059 (7) 0.0053 (7)
C24 0.0218 (8) 0.0189 (7) 0.0130 (7) 0.0004 (6) 0.0024 (6) 0.0019 (5)
C25 0.0447 (11) 0.0302 (9) 0.0160 (8) 0.0091 (8) 0.0031 (7) −0.0011 (7)
C26 0.0225 (9) 0.0362 (10) 0.0245 (8) 0.0057 (7) 0.0037 (7) 0.0071 (7)
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Geometric parameters (Å, °)

Ti1—O3 1.7766 (11) C12—C13 1.414 (2)
Ti1—O4 1.8255 (10) C12—H12 0.9500
Ti1—O2 1.9130 (10) C13—C14 1.368 (2)
Ti1—O1 1.9255 (10) C13—H13 0.9500
Ti1—N2 2.3822 (12) C14—C15 1.416 (2)
Ti1—N1 2.4130 (12) C14—H14 0.9500
O1—C1 1.3266 (18) C15—C16 1.413 (2)
O2—C11 1.3338 (17) C15—C17 1.413 (2)
O3—C21 1.4153 (18) C17—C18 1.359 (2)
O4—C24 1.4239 (17) C17—H17 0.9500
N1—C9 1.3311 (19) C18—C19 1.422 (2)
N1—C6 1.3756 (19) C18—H18 0.9500
N2—C19 1.3270 (19) C19—C20 1.496 (2)
N2—C16 1.3731 (19) C20—H20A 0.9800
C1—C2 1.382 (2) C20—H20B 0.9800
C1—C6 1.419 (2) C20—H20C 0.9800
C2—C3 1.407 (2) C21—C23 1.511 (2)
C2—H2 0.9500 C21—C22 1.515 (2)
C3—C4 1.365 (3) C21—H21 1.0000
C3—H3 0.9500 C22—H22A 0.9800
C4—C5 1.418 (2) C22—H22B 0.9800
C4—H4 0.9500 C22—H22C 0.9800
C5—C7 1.409 (2) C23—H23A 0.9800
C5—C6 1.414 (2) C23—H23B 0.9800
C7—C8 1.360 (2) C23—H23C 0.9800
C7—H7 0.9500 C24—C25 1.512 (2)
C8—C9 1.421 (2) C24—C26 1.517 (2)
C8—H8 0.9500 C24—H24 1.0000
C9—C10 1.497 (2) C25—H25A 0.9800
C10—H10A 0.9800 C25—H25B 0.9800
C10—H10B 0.9800 C25—H25C 0.9800
C10—H10C 0.9800 C26—H26A 0.9800
C11—C12 1.380 (2) C26—H26B 0.9800
C11—C16 1.419 (2) C26—H26C 0.9800
O3—Ti1—O4 101.96 (5) C14—C13—C12 121.83 (15)
O3—Ti1—O2 101.84 (5) C14—C13—H13 119.1
O4—Ti1—O2 95.62 (4) C12—C13—H13 119.1
O3—Ti1—O1 93.07 (5) C13—C14—C15 119.54 (14)
O4—Ti1—O1 97.56 (5) C13—C14—H14 120.2
O2—Ti1—O1 157.58 (4) C15—C14—H14 120.2
O3—Ti1—N2 90.48 (5) C16—C15—C17 116.11 (14)
O4—Ti1—N2 165.52 (4) C16—C15—C14 119.09 (14)
O2—Ti1—N2 74.36 (4) C17—C15—C14 124.74 (14)
O1—Ti1—N2 89.03 (4) N2—C16—C15 123.90 (14)
O3—Ti1—N1 164.98 (5) N2—C16—C11 115.65 (13)
O4—Ti1—N1 87.60 (4) C15—C16—C11 120.37 (14)
O2—Ti1—N1 88.54 (4) C18—C17—C15 119.67 (14)
O1—Ti1—N1 74.02 (4) C18—C17—H17 120.2
N2—Ti1—N1 81.82 (4) C15—C17—H17 120.2
C1—O1—Ti1 125.12 (9) C17—C18—C19 120.95 (14)
C11—O2—Ti1 124.87 (9) C17—C18—H18 119.5
C21—O3—Ti1 154.13 (10) C19—C18—H18 119.5
C24—O4—Ti1 126.66 (9) N2—C19—C18 120.93 (14)
C9—N1—C6 117.94 (13) N2—C19—C20 120.36 (14)
C9—N1—Ti1 134.90 (10) C18—C19—C20 118.70 (13)
C6—N1—Ti1 107.09 (9) C19—C20—H20A 109.5
C19—N2—C16 118.24 (13) C19—C20—H20B 109.5
C19—N2—Ti1 134.14 (10) H20A—C20—H20B 109.5
C16—N2—Ti1 107.62 (9) C19—C20—H20C 109.5
O1—C1—C2 123.29 (14) H20A—C20—H20C 109.5
O1—C1—C6 117.65 (13) H20B—C20—H20C 109.5
C2—C1—C6 119.06 (14) O3—C21—C23 110.24 (12)
C1—C2—C3 120.43 (15) O3—C21—C22 108.63 (13)
C1—C2—H2 119.8 C23—C21—C22 112.47 (14)
C3—C2—H2 119.8 O3—C21—H21 108.5
C4—C3—C2 121.38 (15) C23—C21—H21 108.5
C4—C3—H3 119.3 C22—C21—H21 108.5
C2—C3—H3 119.3 C21—C22—H22A 109.5
C3—C4—C5 119.79 (15) C21—C22—H22B 109.5
C3—C4—H4 120.1 H22A—C22—H22B 109.5
C5—C4—H4 120.1 C21—C22—H22C 109.5
C7—C5—C6 116.69 (14) H22A—C22—H22C 109.5
C7—C5—C4 124.21 (15) H22B—C22—H22C 109.5
C6—C5—C4 119.09 (15) C21—C23—H23A 109.5
N1—C6—C5 123.64 (14) C21—C23—H23B 109.5
N1—C6—C1 116.11 (13) H23A—C23—H23B 109.5
C5—C6—C1 120.24 (14) C21—C23—H23C 109.5
C8—C7—C5 119.49 (15) H23A—C23—H23C 109.5
C8—C7—H7 120.3 H23B—C23—H23C 109.5
C5—C7—H7 120.3 O4—C24—C25 108.89 (12)
C7—C8—C9 120.86 (15) O4—C24—C26 109.19 (12)
C7—C8—H8 119.6 C25—C24—C26 112.20 (14)
C9—C8—H8 119.6 O4—C24—H24 108.8
N1—C9—C8 121.34 (14) C25—C24—H24 108.8
N1—C9—C10 120.18 (13) C26—C24—H24 108.8
C8—C9—C10 118.48 (13) C24—C25—H25A 109.5
C9—C10—H10A 109.5 C24—C25—H25B 109.5
C9—C10—H10B 109.5 H25A—C25—H25B 109.5
H10A—C10—H10B 109.5 C24—C25—H25C 109.5
C9—C10—H10C 109.5 H25A—C25—H25C 109.5
H10A—C10—H10C 109.5 H25B—C25—H25C 109.5
H10B—C10—H10C 109.5 C24—C26—H26A 109.5
O2—C11—C12 123.48 (13) C24—C26—H26B 109.5
O2—C11—C16 117.07 (13) H26A—C26—H26B 109.5
C12—C11—C16 119.45 (13) C24—C26—H26C 109.5
C11—C12—C13 119.68 (15) H26A—C26—H26C 109.5
C11—C12—H12 120.2 H26B—C26—H26C 109.5
C13—C12—H12 120.2
O3—Ti1—O1—C1 −171.18 (11) Ti1—N1—C6—C1 −0.15 (14)
O4—Ti1—O1—C1 86.32 (11) C7—C5—C6—N1 −1.2 (2)
O2—Ti1—O1—C1 −39.19 (19) C4—C5—C6—N1 179.55 (14)
N2—Ti1—O1—C1 −80.75 (11) C7—C5—C6—C1 178.57 (14)
N1—Ti1—O1—C1 1.02 (11) C4—C5—C6—C1 −0.6 (2)
O3—Ti1—O2—C11 91.30 (11) O1—C1—C6—N1 0.93 (19)
O4—Ti1—O2—C11 −165.20 (11) C2—C1—C6—N1 −179.29 (13)
O1—Ti1—O2—C11 −39.37 (18) O1—C1—C6—C5 −178.89 (13)
N2—Ti1—O2—C11 4.16 (10) C2—C1—C6—C5 0.9 (2)
N1—Ti1—O2—C11 −77.75 (11) C6—C5—C7—C8 −0.6 (2)
O4—Ti1—O3—C21 −112.2 (2) C4—C5—C7—C8 178.58 (15)
O2—Ti1—O3—C21 −13.8 (2) C5—C7—C8—C9 1.4 (2)
O1—Ti1—O3—C21 149.4 (2) C6—N1—C9—C8 −1.4 (2)
N2—Ti1—O3—C21 60.3 (2) Ti1—N1—C9—C8 −177.92 (10)
N1—Ti1—O3—C21 119.1 (2) C6—N1—C9—C10 178.99 (13)
O3—Ti1—O4—C24 −50.83 (12) Ti1—N1—C9—C10 2.4 (2)
O2—Ti1—O4—C24 −154.22 (11) C7—C8—C9—N1 −0.4 (2)
O1—Ti1—O4—C24 43.96 (12) C7—C8—C9—C10 179.26 (15)
N2—Ti1—O4—C24 160.41 (16) Ti1—O2—C11—C12 178.57 (11)
N1—Ti1—O4—C24 117.49 (11) Ti1—O2—C11—C16 −1.88 (18)
O3—Ti1—N1—C9 −152.04 (17) O2—C11—C12—C13 −178.34 (14)
O4—Ti1—N1—C9 77.85 (14) C16—C11—C12—C13 2.1 (2)
O2—Ti1—N1—C9 −17.84 (14) C11—C12—C13—C14 −0.8 (2)
O1—Ti1—N1—C9 176.41 (14) C12—C13—C14—C15 −1.1 (2)
N2—Ti1—N1—C9 −92.25 (14) C13—C14—C15—C16 1.7 (2)
O3—Ti1—N1—C6 31.1 (2) C13—C14—C15—C17 −175.58 (15)
O4—Ti1—N1—C6 −98.96 (9) C19—N2—C16—C15 3.5 (2)
O2—Ti1—N1—C6 165.34 (9) Ti1—N2—C16—C15 −176.65 (11)
O1—Ti1—N1—C6 −0.40 (9) C19—N2—C16—C11 −173.27 (13)
N2—Ti1—N1—C6 90.94 (9) Ti1—N2—C16—C11 6.53 (14)
O3—Ti1—N2—C19 71.95 (14) C17—C15—C16—N2 0.4 (2)
O4—Ti1—N2—C19 −138.53 (18) C14—C15—C16—N2 −177.12 (13)
O2—Ti1—N2—C19 174.12 (14) C17—C15—C16—C11 177.10 (13)
O1—Ti1—N2—C19 −21.11 (14) C14—C15—C16—C11 −0.4 (2)
N1—Ti1—N2—C19 −95.11 (14) O2—C11—C16—N2 −4.13 (19)
O3—Ti1—N2—C16 −107.81 (9) C12—C11—C16—N2 175.45 (13)
O4—Ti1—N2—C16 41.7 (2) O2—C11—C16—C15 178.93 (12)
O2—Ti1—N2—C16 −5.64 (9) C12—C11—C16—C15 −1.5 (2)
O1—Ti1—N2—C16 159.13 (9) C16—C15—C17—C18 −3.3 (2)
N1—Ti1—N2—C16 85.13 (9) C14—C15—C17—C18 174.09 (15)
Ti1—O1—C1—C2 178.74 (11) C15—C17—C18—C19 2.3 (2)
Ti1—O1—C1—C6 −1.49 (18) C16—N2—C19—C18 −4.6 (2)
O1—C1—C2—C3 179.34 (14) Ti1—N2—C19—C18 175.66 (10)
C6—C1—C2—C3 −0.4 (2) C16—N2—C19—C20 174.44 (13)
C1—C2—C3—C4 −0.3 (2) Ti1—N2—C19—C20 −5.3 (2)
C2—C3—C4—C5 0.6 (2) C17—C18—C19—N2 1.8 (2)
C3—C4—C5—C7 −179.23 (16) C17—C18—C19—C20 −177.27 (14)
C3—C4—C5—C6 −0.1 (2) Ti1—O3—C21—C23 8.2 (3)
C9—N1—C6—C5 2.2 (2) Ti1—O3—C21—C22 131.9 (2)
Ti1—N1—C6—C5 179.66 (12) Ti1—O4—C24—C25 132.10 (12)
C9—N1—C6—C1 −177.60 (13) Ti1—O4—C24—C26 −105.08 (14)
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Footnotes

Supplementary data and figures for this paper are available from the IUCr electronic archives (Reference: TK2320).

References

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  2. Bickley, D. G. & Nick, S. (1979). Inorg. Chem.18, 2200–2204.
  3. Bruker (2007). APEX2 and SAINT Bruker AXS Inc., Madison, Wisconsin, USA.
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  5. Sheldrick, G. M. (1996). SADABS University of Göttingen, Germany.
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  7. Westrip, S. P. (2008). publCIF In preparation.
  8. Zeng, W. F., Chen, Y. S., Chiang, M. Y., Chern, S. S. & Cheng, C. P. (2002). Polyhedron, 21, 1081–1087.

Associated Data

This section collects any data citations, data availability statements, or supplementary materials included in this article.

Supplementary Materials

Crystal structure: contains datablocks global, I. DOI: 10.1107/S1600536808035460/tk2320sup1.cif

e-64-m1509-sup1.cif (24.7KB, cif)

Structure factors: contains datablocks I. DOI: 10.1107/S1600536808035460/tk2320Isup2.hkl

e-64-m1509-Isup2.hkl (267.7KB, hkl)

Additional supplementary materials: crystallographic information; 3D view; checkCIF report

Articles from Acta Crystallographica Section E: Structure Reports Online are provided here courtesy of International Union of Crystallography

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