Hexaaqua­nickel(II) bis­[4-(2-hydroxy­benzyl­ideneamino)benzene­sulfonate]

Abstract

In the title compound, [Ni(H₂O)₆](C_(C13H₁₀NO₄S)₂, the nickel(II) atom, lying on a center of symmetry, is six-coordinated by six aqua O-atom donors. The dihedral angle between the two benzene rings is 33.1 (3)°. The crystal structure is stabilized by aqua–anion O—H⋯O hydrogen bonds. Intra­molecular O—H⋯N and C—H⋯O hydrogen-bonding inter­actions occur in the anion.

Related literature

For related literature, see: Tai & Feng (2008 ▶); Tai et al. (2003 ▶, 2008 ▶); Tai, Yin & Feng (2007 ▶); Tai, Yin & Hao (2007 ▶); Tai, Yin, Feng & Kong (2007 ▶ ▶ ▶); Wang et al. (2007 ▶).

Experimental

Crystal data

• [Ni(H₂O)₆](C₁₃H₁₀NO₄S)₂

• M _r = 719.37

• Monoclinic,

• a = 6.3047 (6) Å

• b = 35.193 (3) Å

• c = 9.3536 (10) Å

• β = 131.822 (2)°

• V = 1546.6 (3) ų

• Z = 2

• Mo Kα radiation

• μ = 0.83 mm⁻¹

• T = 298 (2) K

• 0.43 × 0.38 × 0.25 mm

Data collection

• Bruker SMART CCD area-detector diffractometer

• Absorption correction: multi-scan (SADABS; Bruker, 2000 ▶) T _min = 0.716, T _max = 0.819

• 7465 measured reflections

• 2661 independent reflections

• 2428 reflections with I > 2σ(I)

• R _int = 0.032

Refinement

• R[F ² > 2σ(F ²)] = 0.067

• wR(F ²) = 0.137

• S = 1.28

• 2661 reflections

• 205 parameters

• H-atom parameters constrained

• Δρ_max = 0.32 e Å⁻³

• Δρ_min = −1.00 e Å⁻³

Data collection: SMART (Bruker, 2000 ▶); cell refinement: SAINT (Bruker, 2000 ▶); data reduction: SAINT; program(s) used to solve structure: SHELXS97 (Sheldrick, 2008 ▶); program(s) used to refine structure: SHELXL97 (Sheldrick, 2008 ▶); molecular graphics: SHELXTL (Sheldrick, 2008 ▶); software used to prepare material for publication: SHELXTL.

Supplementary Material

Additional supplementary materials: crystallographic information; 3D view; checkCIF report

Table 1. Hydrogen-bond geometry (Å, °).

D—H⋯A	D—H	H⋯A	D⋯A	D—H⋯A
O4—H4⋯N1	0.82	1.86	2.595 (9)	148
O5—H5A⋯O1i	0.85	1.96	2.737 (6)	151
O5—H5B⋯O2ii	0.85	1.98	2.751 (6)	150
O6—H6A⋯O3i	0.85	1.95	2.764 (7)	161
O6—H6B⋯O1iii	0.85	1.97	2.768 (8)	156
O7—H7A⋯O2	0.85	2.00	2.757 (8)	148
O7—H7B⋯O3ii	0.85	2.00	2.769 (7)	150
C2—H2⋯O3	0.93	2.56	2.917 (7)	104

Symmetry codes: (i) ; (ii) ; (iii) .

supplementary crystallographic information

Comment

As part of our ongoing studies of the coordination chemistry of Schiffbase ligands (Tai et al., 2003; (Tai, Yin & Feng, 2007; Tai, Yin, Feng & Kong, 2007; Tai, Yin & Hao, 2007; Wang et al., 2007; Tai et al., 2008; Tai et al., 2008), we now report the synthesis and structure of the title compound, (I), (Fig. 1).

In the molecule of (I), the nickel (II) center is six-coordinate with six O donor of H₂O. The C7—N1 [1.288 (8) Å] is close to double-bond. Otherwise, the geometrical parameters for (I) are normal. The dihedral angle between the two benzene rings is 33.1°. The packing is stabilized by O_water—H···O_anion hydrogen bonds. The intramolecular O—H···N and C—H···O hydrogen bonding interactions occur in the anion. (Table 1).

Experimental

1 mmol of Ni(CH₃COO)₂.4H₂O was added to a solution of salicylaldehyde-4-aminobenzene sulfonic acid (1 mmol) in 10 ml of 95% ethanol. The mixture was stirred for 2 h at refluxing temperature. Evaporating some ethanol, clear blocks of (I) were obtained after one weeks.

Refinement

The H atoms were placed geometrically (C—H = 0.93 Å and O—H = 0.82-0.85Å) and refined as riding with U_iso(H) =1.2 or 1.5U_eq(carrier).

Figures

Fig. 1.

The molecular structure of (I) showing 30% displacement ellipsoids.

Crystal data

[Ni(H2O)6](C13H10NO4S)2	F000 = 748
Mr = 719.37	Dx = 1.545 Mg m−3
Monoclinic, P21/c	Mo Kα radiation λ = 0.71073 Å
Hall symbol: -P 2ybc	Cell parameters from 4537 reflections
a = 6.3047 (6) Å	θ = 2.9–27.7º
b = 35.193 (3) Å	µ = 0.83 mm−1
c = 9.3536 (10) Å	T = 298 (2) K
β = 131.822 (2)º	Block, colourless
V = 1546.6 (3) Å3	0.43 × 0.38 × 0.25 mm
Z = 2

Data collection

Bruker SMART CCD area-detector diffractometer	2661 independent reflections
Radiation source: fine-focus sealed tube	2428 reflections with I > 2σ(I)
Monochromator: graphite	Rint = 0.032
T = 298(2) K	θmax = 25.0º
φ and ω scans	θmin = 2.3º
Absorption correction: multi-scan(SADABS; Bruker, 2000)	h = −7→5
Tmin = 0.716, Tmax = 0.819	k = −41→40
7465 measured reflections	l = −9→11

Refinement

Refinement on F2	Secondary atom site location: difference Fourier map
Least-squares matrix: full	Hydrogen site location: inferred from neighbouring sites
R[F2 > 2σ(F2)] = 0.067	H-atom parameters constrained
wR(F2) = 0.137	w = 1/[σ2(Fo2) + (0.0161P)2 + 4.8144P] where P = (Fo2 + 2Fc2)/3
S = 1.28	(Δ/σ)max < 0.001
2661 reflections	Δρmax = 0.32 e Å−3
205 parameters	Δρmin = −1.00 e Å−3
Primary atom site location: structure-invariant direct methods	Extinction correction: none

Special details

Geometry. All e.s.d.'s (except the e.s.d. in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell e.s.d.'s are taken into account individually in the estimation of e.s.d.'s in distances, angles and torsion angles; correlations between e.s.d.'s in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell e.s.d.'s is used for estimating e.s.d.'s involving l.s. planes.

Refinement. Refinement of F2 against ALL reflections. The weighted R-factor wR and goodness of fit S are based on F2, conventional R-factors R are based on F, with F set to zero for negative F2. The threshold expression of F2 > σ(F2) is used only for calculating R-factors(gt) etc. and is not relevant to the choice of reflections for refinement. R-factors based on F2 are statistically about twice as large as those based on F, and R- factors based on ALL data will be even larger.

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Ų)

	x	y	z	Uiso*/Ueq
Ni1	0.5000	1.0000	1.0000	0.0310 (2)
N1	0.4029 (11)	0.76969 (14)	0.4874 (8)	0.0565 (13)
O1	0.3354 (7)	0.95021 (11)	0.3248 (5)	0.0486 (10)
O2	0.6843 (8)	0.94957 (11)	0.6726 (5)	0.0462 (9)
O3	0.8302 (7)	0.93929 (10)	0.4933 (5)	0.0392 (8)
O4	0.0669 (10)	0.71618 (13)	0.4256 (8)	0.0767 (14)
H4	0.1257	0.7379	0.4400	0.115*
O5	0.2072 (7)	0.97532 (11)	0.9978 (5)	0.0474 (9)
H5A	0.2819	0.9621	1.0975	0.071*
H5B	0.0852	0.9623	0.8972	0.071*
O6	0.7945 (8)	0.96016 (12)	1.1929 (6)	0.0549 (11)
H6A	0.8124	0.9592	1.2913	0.082*
H6B	0.9559	0.9642	1.2273	0.082*
O7	0.3791 (8)	0.96590 (13)	0.7796 (6)	0.0600 (12)
H7A	0.4709	0.9703	0.7444	0.090*
H7B	0.2009	0.9665	0.6838	0.090*
S1	0.6046 (2)	0.93471 (4)	0.49681 (17)	0.0319 (3)
C1	0.5566 (9)	0.88532 (14)	0.4986 (7)	0.0313 (10)
C2	0.6556 (12)	0.86005 (16)	0.4406 (8)	0.0451 (13)
H2	0.7524	0.8689	0.4039	0.054*
C3	0.6082 (14)	0.82145 (16)	0.4382 (9)	0.0529 (15)
H3	0.6758	0.8042	0.4012	0.063*
C4	0.4623 (12)	0.80853 (16)	0.4899 (9)	0.0483 (14)
C5	0.3614 (13)	0.83417 (16)	0.5454 (9)	0.0509 (15)
H5	0.2614	0.8253	0.5795	0.061*
C6	0.4079 (12)	0.87246 (15)	0.5503 (8)	0.0438 (13)
H6	0.3404	0.8896	0.5878	0.053*
C7	0.5721 (13)	0.74368 (17)	0.5168 (9)	0.0525 (15)
H7	0.7384	0.7507	0.5446	0.063*
C8	0.5084 (15)	0.70327 (16)	0.5074 (9)	0.0527 (14)
C9	0.2544 (14)	0.69149 (18)	0.4569 (9)	0.0589 (17)
C10	0.1982 (16)	0.65268 (18)	0.4407 (9)	0.0643 (18)
H10	0.0295	0.6445	0.4068	0.077*
C11	0.3845 (17)	0.6265 (2)	0.4733 (9)	0.068 (2)
H11	0.3396	0.6008	0.4588	0.082*
C12	0.6424 (19)	0.6376 (2)	0.5281 (11)	0.077 (2)
H12	0.7726	0.6196	0.5549	0.092*
C13	0.7008 (15)	0.67614 (18)	0.5417 (9)	0.0610 (17)
H13	0.8689	0.6840	0.5739	0.073*

Atomic displacement parameters (Ų)

	U11	U22	U33	U12	U13	U23
Ni1	0.0214 (4)	0.0436 (5)	0.0287 (4)	−0.0007 (4)	0.0170 (4)	−0.0012 (4)
N1	0.060 (3)	0.044 (3)	0.061 (3)	−0.010 (2)	0.038 (3)	−0.004 (2)
O1	0.0284 (19)	0.064 (2)	0.048 (2)	0.0099 (18)	0.0234 (19)	0.0211 (19)
O2	0.042 (2)	0.056 (2)	0.051 (2)	−0.0096 (18)	0.035 (2)	−0.0105 (18)
O3	0.0269 (17)	0.055 (2)	0.041 (2)	−0.0029 (16)	0.0250 (16)	0.0003 (17)
O4	0.056 (3)	0.059 (3)	0.094 (4)	−0.008 (2)	0.042 (3)	0.002 (3)
O5	0.0309 (19)	0.074 (3)	0.035 (2)	−0.0104 (19)	0.0206 (17)	−0.0005 (19)
O6	0.038 (2)	0.082 (3)	0.055 (3)	0.018 (2)	0.035 (2)	0.025 (2)
O7	0.036 (2)	0.100 (3)	0.053 (3)	−0.023 (2)	0.033 (2)	−0.033 (2)
S1	0.0229 (6)	0.0420 (7)	0.0311 (6)	−0.0014 (5)	0.0181 (5)	0.0003 (5)
C1	0.021 (2)	0.041 (3)	0.027 (2)	−0.004 (2)	0.014 (2)	−0.002 (2)
C2	0.053 (3)	0.049 (3)	0.047 (3)	−0.003 (3)	0.039 (3)	−0.004 (3)
C3	0.066 (4)	0.046 (3)	0.054 (4)	−0.006 (3)	0.043 (3)	−0.012 (3)
C4	0.041 (3)	0.046 (3)	0.049 (3)	−0.007 (3)	0.026 (3)	0.001 (3)
C5	0.054 (4)	0.046 (3)	0.068 (4)	−0.004 (3)	0.047 (4)	0.001 (3)
C6	0.053 (3)	0.044 (3)	0.053 (3)	−0.004 (3)	0.043 (3)	0.001 (3)
C7	0.050 (4)	0.056 (4)	0.048 (4)	−0.014 (3)	0.031 (3)	−0.009 (3)
C8	0.059 (4)	0.045 (3)	0.047 (3)	−0.008 (3)	0.032 (3)	−0.008 (3)
C9	0.050 (4)	0.049 (4)	0.048 (4)	−0.003 (3)	0.021 (3)	0.002 (3)
C10	0.065 (4)	0.049 (4)	0.055 (4)	−0.014 (3)	0.030 (4)	−0.002 (3)
C11	0.082 (5)	0.050 (4)	0.051 (4)	−0.013 (4)	0.035 (4)	0.000 (3)
C12	0.098 (6)	0.049 (4)	0.079 (5)	0.000 (4)	0.057 (5)	0.002 (4)
C13	0.068 (4)	0.052 (4)	0.063 (4)	−0.007 (3)	0.044 (4)	−0.007 (3)

Geometric parameters (Å, °)

Ni1—O5i	2.028 (3)	C1—C2	1.388 (7)
Ni1—O5	2.028 (3)	C2—C3	1.388 (8)
Ni1—O7i	2.043 (4)	C2—H2	0.9300
Ni1—O7	2.043 (4)	C3—C4	1.371 (8)
Ni1—O6	2.049 (4)	C3—H3	0.9300
Ni1—O6i	2.049 (4)	C4—C5	1.389 (8)
N1—C7	1.288 (8)	C5—C6	1.373 (8)
N1—C4	1.414 (7)	C5—H5	0.9300
O1—S1	1.458 (4)	C6—H6	0.9300
O2—S1	1.459 (4)	C7—C8	1.465 (8)
O3—S1	1.454 (3)	C7—H7	0.9300
O4—C9	1.333 (8)	C8—C9	1.397 (9)
O4—H4	0.8209	C8—C13	1.402 (9)
O5—H5A	0.8494	C9—C10	1.394 (8)
O5—H5B	0.8492	C10—C11	1.357 (10)
O6—H6A	0.8500	C10—H10	0.9300
O6—H6B	0.8498	C11—C12	1.396 (10)
O7—H7A	0.8497	C11—H11	0.9300
O7—H7B	0.8504	C12—C13	1.387 (9)
S1—C1	1.767 (5)	C12—H12	0.9300
C1—C6	1.387 (7)	C13—H13	0.9300
O5i—Ni1—O5	180.0 (2)	C3—C2—H2	120.5
O5i—Ni1—O7i	90.78 (15)	C1—C2—H2	120.5
O5—Ni1—O7i	89.22 (15)	C4—C3—C2	120.4 (5)
O5i—Ni1—O7	89.22 (15)	C4—C3—H3	119.8
O5—Ni1—O7	90.78 (15)	C2—C3—H3	119.8
O7i—Ni1—O7	180.000 (2)	C3—C4—C5	119.9 (5)
O5i—Ni1—O6	89.99 (15)	C3—C4—N1	123.2 (6)
O5—Ni1—O6	90.01 (15)	C5—C4—N1	116.9 (5)
O7i—Ni1—O6	90.23 (18)	C6—C5—C4	120.6 (5)
O7—Ni1—O6	89.77 (18)	C6—C5—H5	119.7
O5i—Ni1—O6i	90.01 (15)	C4—C5—H5	119.7
O5—Ni1—O6i	89.99 (15)	C5—C6—C1	119.1 (5)
O7i—Ni1—O6i	89.77 (18)	C5—C6—H6	120.4
O7—Ni1—O6i	90.23 (18)	C1—C6—H6	120.4
O6—Ni1—O6i	180.000 (3)	N1—C7—C8	121.5 (6)
C7—N1—C4	120.7 (5)	N1—C7—H7	119.3
C9—O4—H4	109.5	C8—C7—H7	119.3
Ni1—O5—H5A	112.9	C9—C8—C13	119.8 (6)
Ni1—O5—H5B	112.8	C9—C8—C7	121.0 (6)
H5A—O5—H5B	110.6	C13—C8—C7	119.1 (6)
Ni1—O6—H6A	111.7	O4—C9—C8	122.0 (6)
Ni1—O6—H6B	111.9	O4—C9—C10	119.4 (6)
H6A—O6—H6B	109.6	C8—C9—C10	118.6 (7)
Ni1—O7—H7A	113.0	C11—C10—C9	121.4 (7)
Ni1—O7—H7B	112.9	C11—C10—H10	119.3
H7A—O7—H7B	110.5	C9—C10—H10	119.3
O3—S1—O1	111.7 (2)	C10—C11—C12	120.9 (7)
O3—S1—O2	112.3 (2)	C10—C11—H11	119.5
O1—S1—O2	112.5 (2)	C12—C11—H11	119.5
O3—S1—C1	106.6 (2)	C13—C12—C11	118.7 (8)
O1—S1—C1	107.3 (2)	C13—C12—H12	120.6
O2—S1—C1	105.9 (2)	C11—C12—H12	120.6
C6—C1—C2	120.8 (5)	C12—C13—C8	120.5 (7)
C6—C1—S1	119.0 (4)	C12—C13—H13	119.7
C2—C1—S1	120.2 (4)	C8—C13—H13	119.7
C3—C2—C1	119.0 (5)
O3—S1—C1—C6	163.8 (4)	C2—C1—C6—C5	0.6 (8)
O1—S1—C1—C6	−76.3 (5)	S1—C1—C6—C5	177.7 (4)
O2—S1—C1—C6	44.1 (5)	C4—N1—C7—C8	−177.6 (5)
O3—S1—C1—C2	−19.0 (5)	N1—C7—C8—C9	3.2 (10)
O1—S1—C1—C2	100.8 (4)	N1—C7—C8—C13	−179.6 (6)
O2—S1—C1—C2	−138.8 (4)	C13—C8—C9—O4	179.1 (6)
C6—C1—C2—C3	−1.1 (8)	C7—C8—C9—O4	−3.8 (10)
S1—C1—C2—C3	−178.2 (4)	C13—C8—C9—C10	−0.4 (10)
C1—C2—C3—C4	0.8 (9)	C7—C8—C9—C10	176.8 (6)
C2—C3—C4—C5	−0.1 (10)	O4—C9—C10—C11	−179.3 (6)
C2—C3—C4—N1	178.9 (6)	C8—C9—C10—C11	0.2 (10)
C7—N1—C4—C3	29.9 (9)	C9—C10—C11—C12	1.3 (11)
C7—N1—C4—C5	−151.1 (6)	C10—C11—C12—C13	−2.4 (11)
C3—C4—C5—C6	−0.4 (10)	C11—C12—C13—C8	2.2 (10)
N1—C4—C5—C6	−179.5 (6)	C9—C8—C13—C12	−0.8 (10)
C4—C5—C6—C1	0.2 (9)	C7—C8—C13—C12	−178.0 (6)

Symmetry codes: (i) −x+1, −y+2, −z+2.

Hydrogen-bond geometry (Å, °)

D—H···A	D—H	H···A	D···A	D—H···A
O4—H4···N1	0.82	1.86	2.595 (9)	148
O5—H5A···O1ii	0.85	1.96	2.737 (6)	151
O5—H5B···O2iii	0.85	1.98	2.751 (6)	150
O6—H6A···O3ii	0.85	1.95	2.764 (7)	161
O6—H6B···O1iv	0.85	1.97	2.768 (8)	156
O7—H7A···O2	0.85	2.00	2.757 (8)	148
O7—H7B···O3iii	0.85	2.00	2.769 (7)	150
C2—H2···O3	0.93	2.56	2.917 (7)	104

Symmetry codes: (ii) x, y, z+1; (iii) x−1, y, z; (iv) x+1, y, z+1.