Diaqua­bis(2-bromo­benzoato-κO)bis­(N,N-diethyl­nicotinamide-κN 1)nickel(II)

Tuncer Hökelek; Filiz Yılmaz; Barış Tercan; F Elif Özbek; Hacali Necefoğlu

doi:10.1107/S1600536809021795

. 2009 Jun 13;65(Pt 7):m766–m767. doi: 10.1107/S1600536809021795

Diaquabis(2-bromobenzoato-κO)bis(N,N-diethylnicotinamide-κN ¹)nickel(II)

Tuncer Hökelek ^a,^*, Filiz Yılmaz ^b, Barış Tercan ^c, F Elif Özbek ^d, Hacali Necefoğlu ^d

PMCID: PMC2969431 PMID: 21582698

Abstract

In the monomeric centrosymmetric title Ni^II complex, [Ni(C₇H₄BrO₂)₂(C₁₀H₁₄N₂O)₂(H₂O)₂], the Ni^II ion is located on an inversion center. The asymmetric unit contains one 2-bromobenzoate ligand, one diethylnicotinamide (DENA) ligand and one coordinated water molecule. The four O atoms in the equatorial plane around the Ni^II ion form a slightly distorted square-planar arrangement, while the slightly distorted octahedral coordination is completed by two N atoms of two DENA ligands in the axial positions. The dihedral angle between the benzene ring and the attached carboxylate group is 87.73 (15)°, while the pyridine and benzene rings are oriented at a dihedral angle of 42.48 (7)°. In the crystal structure, O—H⋯O hydrogen bonds link the molecules into a two-dimensional network parallel to (10 Inline graphic ). In addition, C—H⋯O hydrogen bonds are observed.

Related literature

For general backgroud, see: Antolini et al. (1982 ▶); Bigoli et al. (1972 ▶); Nadzhafov et al. (1981 ▶); Shnulin et al. (1981 ▶). For related structures, see: Hökelek et al. (2009a ▶,b ▶,c ▶,d ▶); Özbek et al. (2009 ▶); Sertçelik et al. (2009a ▶,b ▶,c ▶); Tercan et al. (2009 ▶).

Experimental

Crystal data

[Ni(C₇H₄BrO₂)₂(C₁₀H₁₄N₂O)₂(H₂O)₂]
M _r = 851.22
Monoclinic,
a = 12.8506 (3) Å
b = 10.3448 (2) Å
c = 14.9418 (4) Å
β = 114.004 (2)°
V = 1814.53 (8) Å³
Z = 2
Mo Kα radiation
μ = 2.79 mm⁻¹
T = 100 K
0.34 × 0.25 × 0.12 mm

Data collection

Bruker Kappa APEXII CCD area-detector diffractometer
Absorption correction: multi-scan (SADABS; Bruker, 2005 ▶) T _min = 0.442, T _max = 0.710
16814 measured reflections
4528 independent reflections
3603 reflections with I > 2σ(I)
R _int = 0.044

Refinement

R[F ² > 2σ(F ²)] = 0.032
wR(F ²) = 0.078
S = 1.04
4528 reflections
233 parameters
H atoms treated by a mixture of independent and constrained refinement
Δρ_max = 0.78 e Å⁻³
Δρ_min = −0.78 e Å⁻³

Data collection: APEX2 (Bruker, 2007 ▶); cell refinement: SAINT (Bruker, 2007 ▶); data reduction: SAINT; program(s) used to solve structure: SHELXS97 (Sheldrick, 2008 ▶); program(s) used to refine structure: SHELXL97 (Sheldrick, 2008 ▶); molecular graphics: ORTEP-3 for Windows (Farrugia, 1997 ▶); software used to prepare material for publication: WinGX (Farrugia, 1999 ▶).

Supplementary Material

Crystal structure: contains datablocks I, global. DOI: 10.1107/S1600536809021795/ci2824sup1.cif

e-65-0m766-sup1.cif^{(21.3KB, cif)}

Structure factors: contains datablocks I. DOI: 10.1107/S1600536809021795/ci2824Isup2.hkl

e-65-0m766-Isup2.hkl^{(217.4KB, hkl)}

Additional supplementary materials: crystallographic information; 3D view; checkCIF report

Table 1. Selected bond lengths (Å).

Ni1—O1	2.0359 (14)
Ni1—O4	2.0818 (15)
Ni1—N1	2.1207 (17)

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Table 2. Hydrogen-bond geometry (Å, °).

D—H⋯A	D—H	H⋯A	D⋯A	D—H⋯A
O4—H41⋯O3ⁱ	0.80 (3)	1.97 (3)	2.770 (2)	176 (4)
O4—H42⋯O2ⁱⁱ	0.78 (4)	1.88 (4)	2.623 (3)	161 (3)
C4—H4⋯O2ⁱⁱⁱ	0.93	2.54	3.172 (3)	126
C8—H8⋯O3ⁱ	0.93	2.31	3.241 (3)	177
C10—H10⋯O1^iv	0.93	2.47	3.392 (3)	172
C14—H14A⋯O2^v	0.97	2.50	3.448 (3)	166
C14—H14B⋯O3^vi	0.97	2.55	3.483 (3)	161

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Symmetry codes: (i) Inline graphic ; (ii) ; (iii) ; (iv) ; (v) ; (vi) .

Acknowledgments

The authors are indebted to Anadolu University and the Medicinal Plants and Medicine Research Centre of Anadolu University, Eskişehir, Turkey, for the use of X-ray diffractometer.

supplementary crystallographic information

Comment

Transition metal complexes with biochemically active ligands frequently show interesting physical and/or chemical properties, as a result they may find applications in biological systems (Antolini et al., 1982). The structural functions and coordination relationships of the arylcarboxylate ion in transition metal complexes of benzoic acid derivatives change depending on the nature and position of the substituent groups on the benzene ring, the nature of the additional ligand molecule or solvent, and the medium of the synthesis (Nadzhafov et al., 1981; Shnulin et al., 1981). The nicotinic acid derivative N,N-diethylnicotinamide (DENA) is an important respiratory stimulant (Bigoli et al., 1972).

The structure determination of the title compound, (I), a nickel complex with two 2-bromobenzoate (BB), two diethylnicotinamide (DENA) ligands and two water molecules, was undertaken in order to determine the properties of the ligands and also to compare the results obtained with those reported previously.

Compound (I) is a monomeric complex, with the Ni^II ion on a centre of symmetry (Fig. 1). All ligands are monodentate. The four O atoms (O1, O4, and the symmetry-related atoms, O1', O4') in the equatorial plane around the Ni atom form a slightly distorted square-planar arrangement, while the slightly distorted octahedral coordination is completed by two N atoms of two DENA ligands (N1, N1') in axial positions (Table 1 and Fig. 1).

The near equality of C1—O1 [1.267 (3) Å] and C1—O2 [1.240 (3) Å] bonds in the carboxylate group indicates a delocalized bonding arrangement, rather than localized single and double bonds, and may be compared with the corresponding distances: 1.262 (3) and 1.249 (3) Å in [Mn(DENA)₂(C₈H₅O₃)₂(H₂O)₂], (II) (Sertçelik et al., 2009a), 1.263 (4) and 1.249 (4) Å in [Ni(DENA)₂(C₈H₅O₃)₂(H₂O)₂], (III) (Sertçelik et al., 2009b), 1.262 (5) and 1.257 (5) Å in [Co(DENA)₂(C₈H₅O₃)₂(H₂O)₂], (IV) (Sertçelik et al., 2009c), 1.244 (4) and 1.270 (4) Å in [Co(NA)₂(H₂O)₄](C₇H₄FO₂)₂, (V) (Özbek et al., 2009), 1.284 (2), 1.248 (2) and 1.278 (2), 1.241 (2) Å in [Zn(NA)₂(C₈H₈NO₂)₂], (VI) (Tercan et al., 2009), 1.267 (3) and 1.258 (3) Å in [Ni(NA)₂(C₇H₄ClO₂)₂(H₂O)₂], (VII) (Hökelek et al., 2009a), 1.263 (2) and 1.240 (2) Å in [Zn(DENA)₂(C₇H₄BrO₂)₂(H₂O)₂], (VIII) (Hökelek et al., 2009b), 1.2611 (17) and 1.2396 (19) Å in [Mn(DENA)₂(C₇H₄BrO₂)₂(H₂O)₂], (IX) (Hökelek et al., 2009c) and 1.2616 (17) and 1.2435 (18) Å in [Ni(DENA)₂(C₇H₄ClO₂)₂(H₂O)₂], (X) (Hökelek et al., 2009d). In (I), the average Ni—O bond length is 2.0589 (15) Å and the Ni1 atom is displaced out of the least-squares plane of the carboxylate group (O1/C1/O2) by 0.291 (1) Å. The dihedral angle between the planar carboxylate group and the benzene ring A (C2-C7) is 87.73 (15)°, while that between rings A and B (N1/C8-C12) is 42.48 (7)°.

In the crystal structure, intermolecular O—H···O hydrogen bonds (Table 2) link the molecules into a two-dimensional network parallel to the (1 0 1). In addition, C—H···O hydrogen bonds are observed.

Experimental

The title compound was prepared by the reaction of NiSO₄.6H₂O (1.31 g, 5 mmol) in H₂O (20 ml) and i>N,N-diethylnicotinamide (1.78 g, 10 mmol) in H₂O (20 ml) with sodium 2-bromobenzoate (2.23 g, 10 mmol) in H₂O (50 ml). The mixture was filtered and set aside to crystallize at ambient temperature for 2 d, giving blue single crystals.