Bis(2-meth­oxy-6-{[2-(methyl­ammonio)eth­yl]imino­meth­yl}phenolato)thio­cyanato­zinc(II) thio­cyanate hemihydrate

Sanjun Peng; Fen Zhang

doi:10.1107/S1600536809022326

. 2009 Jun 20;65(Pt 7):m799. doi: 10.1107/S1600536809022326

Bis(2-methoxy-6-{[2-(methylammonio)ethyl]iminomethyl}phenolato)thiocyanatozinc(II) thiocyanate hemihydrate

Sanjun Peng ^a,^*, Fen Zhang ^b

PMCID: PMC2969465 PMID: 21582724

Abstract

The title mononuclear zinc(II) complex, [Zn(C₁₁H₁₆N₂O₂)₂(NCS)]NCS·0.5H₂O, consists of a complex cation, a thiocyanate anion, and half of a water molecule. The Zn^II atom in the cation is five-coordinated by two imine N and two phenolate O atoms from two bidentate Schiff base ligands, and by one N atom of a thiocyanate ligand, forming a distorted trigonal-bipyramidal geometry. The ammonio H atoms are involved in hydrogen bonding with the ligand O atoms and the solvent water molecules (site occupation factor 0.5), which partially determines the conformation of the ligands.

Related literature

For background to the properties of zinc(II) complexes, see: Lipscomb & Sträter (1996 ▶); Bertini et al. (1994 ▶); Harrison et al. (2006 ▶); Tirosh et al. (2005 ▶); Musie et al. (2004 ▶); Vallee & Auld (1993 ▶). For related structures, see: Li et al. (2008 ▶); Eltayeb et al. (2008 ▶); Zhang & Wang (2007 ▶); Cai (2009 ▶).

Experimental

Crystal data

[Zn(C₁₁H₁₆N₂O₂)₂(NCS)]NCS·0.5H₂O
M _r = 607.06
Triclinic,
a = 9.997 (2) Å
b = 13.017 (3) Å
c = 13.379 (3) Å
α = 73.70 (3)°
β = 77.95 (3)°
γ = 72.25 (3)°
V = 1577.0 (5) Å³
Z = 2
Mo Kα radiation
μ = 0.95 mm⁻¹
T = 298 K
0.30 × 0.28 × 0.27 mm

Data collection

Bruker SMART APEX CCD area-detector diffractometer
Absorption correction: multi-scan (SADABS; Bruker, 2000 ▶) T _min = 0.764, T _max = 0.784
12467 measured reflections
6300 independent reflections
3199 reflections with I > 2σ(I)
R _int = 0.057

Refinement

R[F ² > 2σ(F ²)] = 0.081
wR(F ²) = 0.190
S = 0.99
6300 reflections
346 parameters
18 restraints
H-atom parameters constrained
Δρ_max = 0.51 e Å⁻³
Δρ_min = −0.37 e Å⁻³

Data collection: SMART (Bruker, 2000 ▶); cell refinement: SAINT (Bruker, 2000 ▶); data reduction: SAINT; program(s) used to solve structure: SHELXTL (Sheldrick, 2008 ▶); program(s) used to refine structure: SHELXTL; molecular graphics: SHELXTL; software used to prepare material for publication: SHELXTL.

Supplementary Material

Crystal structure: contains datablocks global, I. DOI: 10.1107/S1600536809022326/su2115sup1.cif

e-65-0m799-sup1.cif^{(22.4KB, cif)}

Structure factors: contains datablocks I. DOI: 10.1107/S1600536809022326/su2115Isup2.hkl

e-65-0m799-Isup2.hkl^{(308.3KB, hkl)}

Additional supplementary materials: crystallographic information; 3D view; checkCIF report

Table 1. Hydrogen-bond geometry (Å, °).

D—H⋯A	D—H	H⋯A	D⋯A	D—H⋯A
N4—H4B⋯O2	0.90	2.38	3.001 (8)	126
N4—H4B⋯O1	0.90	1.84	2.682 (7)	155
N4—H4A⋯O5	0.90	1.99	2.839 (14)	157
N2—H2B⋯N6	0.90	1.93	2.834 (11)	179
N2—H2A⋯O4	0.90	2.35	2.889 (8)	119
N2—H2A⋯O3	0.90	1.86	2.691 (7)	153

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Acknowledgments

We acknowledge Changsha University of Science and Technology for the research grants.

supplementary crystallographic information

Comment

Zinc is the second most abundant transition metal in biology, functions as the active site of hydrolytic enzymes, such as carboxypeptidase and carbonic anhydrase, where it is in a hard donor coordination of nitrogen and oxygen (Lipscomb & Sträter, 1996; Bertini et al., 1994). Zinc atom can readily adopt four-, five- or six-coordination (Harrison et al., 2006; Tirosh et al., 2005; Musie et al., 2004; Vallee & Auld, 1993). As a continuation of work on this area, we report herein the new title zinc(II) complex, with the Schiff base 2-methoxy-6-[(2-methylaminoethylimino)methyl]phenol.

The title compound consists of a complex cation, a thiocyanate anion, and a half water molecule of crystallization (Fig. 1). The Zn^II atom in the cation is five-coordinated by two imine N and two phenolate O atoms, from two Schiff base ligands, and by one N atom of a thiocyanate ligand, so forming a trigonal-bipyramidal geometry. The amine N atom is protonated and does not coordinate to the metal ion. The NH₂⁺ hydrogen atoms are involved in hydrogen bonding with the ligand O-atoms which partially determines the conformation of the ligands. The Zn—O and Zn—N bond lengths [1.977 (4) - 1.979 (4) Å and 2.001 (6) - 2.135 (5) Å, respectively] are comparable to the values in similar complexes (Li et al., 2008; Eltayeb et al., 2008; Zhang & Wang, 2007; Cai, 2009).

Experimental

3-Methoxysalicylaldehyde (0.1 mmol, 15.2 mg) and N-methylethane-1,2-diamine (0.1 mmol, 7.4 mg) were stirred into 30 ml of methanol. After 1 h, ammonium thiocyanate (0.1 mmol, 7.6 mg) in water (1 ml) and zinc acetate (0.1 mmol, 22.0 mg) in methanol (10 ml) was added, and the stirring continued for a further 1 h. The filtrate was kept at rt for about a week, depositing colorless block-like crystals of the title compound.

Figures

Fig. 1. — The molecular structure of the title compound, with displacement ellipsoids drawn at the 30% probability level.

Crystal data

[Zn(C₁₁H₁₆N₂O₂)₂(NCS)]NCS·0.5H₂O	Z = 2
M_r = 607.06	F(000) = 634
Triclinic, P1	D_x = 1.278 Mg m⁻³
Hall symbol: -P 1	Mo Kα radiation, λ = 0.71073 Å
a = 9.997 (2) Å	Cell parameters from 1416 reflections
b = 13.017 (3) Å	θ = 2.4–24.1°
c = 13.379 (3) Å	µ = 0.95 mm⁻¹
α = 73.70 (3)°	T = 298 K
β = 77.95 (3)°	Block, colorless
γ = 72.25 (3)°	0.30 × 0.28 × 0.27 mm
V = 1577.0 (5) Å³

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Data collection

Bruker SMART APEX CCD area-detector diffractometer	6300 independent reflections
Radiation source: fine-focus sealed tube	3199 reflections with I > 2σ(I)
graphite	R_int = 0.057
ω scans	θ_max = 26.5°, θ_min = 2.4°
Absorption correction: multi-scan (SADABS; Bruker, 2000)	h = −12→12
T_min = 0.764, T_max = 0.784	k = −16→16
12467 measured reflections	l = −16→16

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Refinement

Refinement on F²	Primary atom site location: structure-invariant direct methods
Least-squares matrix: full	Secondary atom site location: difference Fourier map
R[F² > 2σ(F²)] = 0.081	Hydrogen site location: inferred from neighbouring sites
wR(F²) = 0.190	H-atom parameters constrained
S = 0.99	w = 1/[σ²(F_o²) + (0.0763P)²] where P = (F_o² + 2F_c²)/3
6300 reflections	(Δ/σ)_max < 0.001
346 parameters	Δρ_max = 0.51 e Å⁻³
18 restraints	Δρ_min = −0.37 e Å⁻³

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Special details

Geometry. All e.s.d.'s (except the e.s.d. in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell e.s.d.'s are taken into account individually in the estimation of e.s.d.'s in distances, angles and torsion angles; correlations between e.s.d.'s in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell e.s.d.'s is used for estimating e.s.d.'s involving l.s. planes.

Refinement. Refinement of F² against ALL reflections. The weighted R-factor wR and goodness of fit S are based on F², conventional R-factors R are based on F, with F set to zero for negative F². The threshold expression of F² > σ(F²) is used only for calculating R-factors(gt) etc. and is not relevant to the choice of reflections for refinement. R-factors based on F² are statistically about twice as large as those based on F, and R- factors based on ALL data will be even larger.

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Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Å²)

	x	y	z	U_iso*/U_eq	Occ. (<1)
Zn1	0.76677 (7)	0.52215 (5)	0.74443 (5)	0.0565 (3)
S1	0.9762 (3)	0.7599 (2)	0.8261 (2)	0.1405 (10)
S2	0.7074 (3)	0.9701 (2)	0.18236 (19)	0.1322 (9)
O1	0.6935 (4)	0.3968 (3)	0.8352 (3)	0.0743 (12)
O2	0.6337 (7)	0.2068 (5)	0.8807 (4)	0.113 (2)
O3	0.7078 (5)	0.5764 (3)	0.6026 (3)	0.0751 (12)
O4	0.5434 (6)	0.6530 (5)	0.4556 (3)	0.0952 (15)
O5	0.9890 (14)	0.0589 (13)	0.7592 (16)	0.201 (8)	0.50
H5A	0.9333	0.0169	0.7815	0.241*	0.50
H5B	1.0545	0.0478	0.7084	0.241*	0.50
N1	0.5803 (6)	0.6341 (5)	0.8016 (4)	0.0714 (14)
N2	0.5448 (7)	0.7845 (4)	0.5970 (4)	0.0893 (18)
H2A	0.5726	0.7115	0.5985	0.107*
H2B	0.5746	0.8205	0.5321	0.107*
N3	0.9438 (6)	0.4057 (4)	0.6861 (5)	0.0735 (15)
N4	0.9269 (6)	0.2291 (4)	0.8690 (4)	0.0778 (15)
H4A	0.9646	0.1849	0.8236	0.093*
H4B	0.8412	0.2707	0.8519	0.093*
N5	0.8880 (6)	0.5913 (5)	0.7923 (5)	0.0799 (16)
N6	0.6414 (11)	0.8946 (7)	0.3922 (8)	0.150 (3)
C1	0.4525 (8)	0.4901 (9)	0.8824 (5)	0.085 (2)
C2	0.5598 (8)	0.3956 (7)	0.8705 (4)	0.0709 (19)
C3	0.5227 (10)	0.2965 (9)	0.8983 (5)	0.092 (2)
C4	0.3836 (12)	0.2933 (12)	0.9369 (6)	0.125 (4)
H4	0.3624	0.2250	0.9553	0.150*
C5	0.2823 (13)	0.3802 (15)	0.9484 (8)	0.144 (6)
H5	0.1903	0.3741	0.9736	0.172*
C6	0.3115 (9)	0.4821 (11)	0.9230 (6)	0.116 (3)
H6	0.2397	0.5451	0.9323	0.139*
C7	0.6075 (13)	0.1001 (8)	0.9051 (9)	0.162 (5)
H7A	0.5748	0.0793	0.9787	0.242*
H7B	0.6936	0.0466	0.8876	0.242*
H7C	0.5367	0.1025	0.8652	0.242*
C8	0.4715 (8)	0.6024 (8)	0.8540 (5)	0.088 (2)
H8	0.3958	0.6569	0.8765	0.105*
C9	0.5723 (8)	0.7536 (6)	0.7858 (6)	0.091 (2)
H9A	0.6326	0.7613	0.8299	0.109*
H9B	0.4757	0.7932	0.8067	0.109*
C10	0.6180 (9)	0.8039 (6)	0.6729 (6)	0.096 (2)
H10A	0.6007	0.8832	0.6640	0.115*
H10B	0.7193	0.7736	0.6565	0.115*
C11	0.3859 (10)	0.8191 (7)	0.6135 (7)	0.114 (3)
H11A	0.3522	0.7958	0.6867	0.171*
H11B	0.3502	0.7854	0.5731	0.171*
H11C	0.3535	0.8984	0.5914	0.171*
C12	0.8471 (10)	0.4272 (7)	0.5243 (6)	0.085 (2)
C13	0.7338 (8)	0.5214 (6)	0.5289 (5)	0.0712 (19)
C14	0.6466 (9)	0.5591 (7)	0.4474 (5)	0.081 (2)
C15	0.6657 (11)	0.5033 (9)	0.3720 (6)	0.104 (3)
H15	0.6036	0.5282	0.3221	0.125*
C16	0.7754 (14)	0.4109 (11)	0.3687 (8)	0.118 (4)
H16	0.7890	0.3745	0.3152	0.142*
C17	0.8643 (11)	0.3716 (7)	0.4418 (8)	0.105 (3)
H17	0.9377	0.3078	0.4389	0.126*
C18	0.4627 (10)	0.7033 (8)	0.3714 (6)	0.122 (3)
H18A	0.5249	0.7180	0.3070	0.183*
H18B	0.3979	0.7716	0.3832	0.183*
H18C	0.4105	0.6543	0.3666	0.183*
C19	0.9490 (8)	0.3819 (5)	0.5987 (7)	0.085 (2)
H19	1.0291	0.3281	0.5803	0.103*
C20	1.0633 (7)	0.3501 (6)	0.7456 (7)	0.097 (2)
H20A	1.1159	0.4029	0.7418	0.117*
H20B	1.1263	0.2913	0.7137	0.117*
C21	1.0177 (7)	0.3020 (6)	0.8579 (7)	0.085 (2)
H21A	1.1008	0.2603	0.8923	0.102*
H21B	0.9667	0.3617	0.8926	0.102*
C22	0.9086 (9)	0.1580 (7)	0.9783 (6)	0.105 (3)
H22A	0.9993	0.1252	1.0028	0.158*
H22B	0.8676	0.1005	0.9775	0.158*
H22C	0.8473	0.2029	1.0243	0.158*
C23	0.9247 (7)	0.6603 (6)	0.8069 (5)	0.0772 (18)
C24	0.6730 (10)	0.9266 (7)	0.3022 (8)	0.112 (3)

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Atomic displacement parameters (Å²)

	U¹¹	U²²	U³³	U¹²	U¹³	U²³
Zn1	0.0650 (5)	0.0525 (4)	0.0489 (4)	−0.0206 (3)	0.0020 (3)	−0.0083 (3)
S1	0.183 (2)	0.131 (2)	0.153 (2)	−0.0873 (19)	−0.0027 (18)	−0.0688 (17)
S2	0.178 (2)	0.1057 (17)	0.0884 (16)	−0.0077 (16)	−0.0165 (15)	−0.0174 (13)
O1	0.072 (3)	0.074 (3)	0.070 (3)	−0.034 (2)	−0.010 (2)	0.010 (2)
O2	0.139 (5)	0.099 (4)	0.120 (4)	−0.080 (4)	−0.067 (4)	0.036 (3)
O3	0.107 (3)	0.068 (3)	0.047 (2)	−0.025 (2)	0.001 (2)	−0.014 (2)
O4	0.133 (4)	0.111 (4)	0.050 (3)	−0.053 (4)	−0.013 (3)	−0.007 (3)
O5	0.117 (10)	0.167 (14)	0.36 (3)	−0.047 (10)	−0.001 (12)	−0.148 (16)
N1	0.074 (4)	0.090 (4)	0.044 (3)	−0.008 (3)	−0.009 (3)	−0.022 (3)
N2	0.131 (6)	0.059 (3)	0.068 (4)	−0.018 (4)	−0.021 (4)	−0.001 (3)
N3	0.073 (4)	0.063 (3)	0.081 (4)	−0.028 (3)	0.019 (3)	−0.021 (3)
N4	0.096 (4)	0.053 (3)	0.089 (4)	−0.024 (3)	−0.028 (3)	−0.007 (3)
N5	0.076 (4)	0.084 (4)	0.095 (4)	−0.036 (3)	0.004 (3)	−0.038 (3)
N6	0.199 (7)	0.121 (6)	0.124 (6)	−0.057 (5)	0.000 (5)	−0.018 (5)
C1	0.080 (6)	0.151 (8)	0.034 (3)	−0.047 (6)	−0.003 (3)	−0.021 (4)
C2	0.073 (5)	0.111 (6)	0.030 (3)	−0.046 (5)	−0.010 (3)	0.007 (3)
C3	0.114 (7)	0.130 (7)	0.047 (4)	−0.075 (6)	−0.033 (4)	0.021 (4)
C4	0.120 (8)	0.226 (13)	0.056 (5)	−0.121 (9)	−0.014 (6)	0.007 (6)
C5	0.105 (8)	0.31 (2)	0.069 (6)	−0.127 (11)	0.016 (6)	−0.059 (9)
C6	0.074 (5)	0.236 (12)	0.060 (5)	−0.057 (7)	0.012 (4)	−0.067 (6)
C7	0.233 (12)	0.125 (8)	0.174 (10)	−0.131 (8)	−0.104 (9)	0.040 (7)
C8	0.063 (4)	0.146 (8)	0.041 (4)	0.000 (5)	−0.004 (3)	−0.032 (4)
C9	0.113 (6)	0.079 (5)	0.076 (5)	0.007 (4)	−0.023 (4)	−0.039 (4)
C10	0.134 (7)	0.066 (4)	0.093 (6)	−0.021 (4)	−0.032 (5)	−0.021 (4)
C11	0.120 (7)	0.102 (6)	0.115 (7)	−0.005 (5)	−0.038 (5)	−0.029 (5)
C12	0.111 (6)	0.084 (5)	0.064 (4)	−0.053 (5)	0.032 (4)	−0.024 (4)
C13	0.095 (5)	0.070 (4)	0.052 (4)	−0.049 (4)	0.032 (4)	−0.019 (3)
C14	0.119 (6)	0.092 (5)	0.044 (4)	−0.062 (5)	0.012 (4)	−0.015 (4)
C15	0.143 (8)	0.137 (8)	0.058 (5)	−0.086 (7)	0.022 (5)	−0.037 (5)
C16	0.162 (10)	0.148 (9)	0.082 (6)	−0.103 (8)	0.051 (6)	−0.064 (7)
C17	0.134 (7)	0.093 (6)	0.088 (6)	−0.054 (5)	0.047 (6)	−0.043 (5)
C18	0.151 (7)	0.166 (9)	0.066 (5)	−0.080 (7)	−0.028 (5)	−0.003 (5)
C19	0.087 (5)	0.051 (4)	0.103 (6)	−0.031 (4)	0.042 (5)	−0.020 (4)
C20	0.056 (4)	0.068 (5)	0.156 (8)	−0.017 (4)	0.000 (5)	−0.018 (5)
C21	0.072 (4)	0.062 (4)	0.131 (7)	−0.022 (4)	−0.026 (4)	−0.022 (4)
C22	0.139 (7)	0.089 (5)	0.085 (5)	−0.028 (5)	−0.047 (5)	0.004 (4)
C23	0.077 (5)	0.085 (5)	0.072 (4)	−0.022 (4)	−0.002 (3)	−0.029 (4)
C24	0.166 (8)	0.074 (5)	0.092 (6)	−0.041 (5)	−0.002 (6)	−0.015 (5)

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Geometric parameters (Å, °)

Zn1—O3	1.977 (4)	C5—H5	0.9300
Zn1—O1	1.979 (4)	C6—H6	0.9300
Zn1—N5	2.001 (6)	C7—H7A	0.9600
Zn1—N3	2.119 (5)	C7—H7B	0.9600
Zn1—N1	2.135 (5)	C7—H7C	0.9600
S1—C23	1.632 (8)	C8—H8	0.9300
S2—C24	1.545 (10)	C9—C10	1.503 (10)
O1—C2	1.325 (7)	C9—H9A	0.9700
O2—C3	1.381 (10)	C9—H9B	0.9700
O2—C7	1.426 (9)	C10—H10A	0.9700
O3—C13	1.314 (7)	C10—H10B	0.9700
O4—C14	1.353 (9)	C11—H11A	0.9600
O4—C18	1.412 (9)	C11—H11B	0.9600
O5—H5A	0.8500	C11—H11C	0.9600
O5—H5B	0.8500	C12—C13	1.399 (10)
N1—C8	1.280 (9)	C12—C17	1.437 (11)
N1—C9	1.489 (9)	C12—C19	1.450 (11)
N2—C10	1.483 (9)	C13—C14	1.423 (10)
N2—C11	1.499 (10)	C14—C15	1.351 (10)
N2—H2A	0.9000	C15—C16	1.363 (13)
N2—H2B	0.9000	C15—H15	0.9300
N3—C19	1.278 (9)	C16—C17	1.347 (13)
N3—C20	1.460 (9)	C16—H16	0.9300
N4—C21	1.462 (8)	C17—H17	0.9300
N4—C22	1.503 (9)	C18—H18A	0.9600
N4—H4A	0.9000	C18—H18B	0.9600
N4—H4B	0.9000	C18—H18C	0.9600
N5—C23	1.144 (8)	C19—H19	0.9300
N6—C24	1.168 (10)	C20—C21	1.489 (10)
C1—C2	1.387 (10)	C20—H20A	0.9700
C1—C6	1.425 (11)	C20—H20B	0.9700
C1—C8	1.465 (11)	C21—H21A	0.9700
C2—C3	1.380 (10)	C21—H21B	0.9700
C3—C4	1.388 (12)	C22—H22A	0.9600
C4—C5	1.290 (16)	C22—H22B	0.9600
C4—H4	0.9300	C22—H22C	0.9600
C5—C6	1.380 (15)

O3—Zn1—O1	114.77 (18)	C10—C9—H9A	109.4
O3—Zn1—N5	122.2 (2)	N1—C9—H9B	109.4
O1—Zn1—N5	123.0 (2)	C10—C9—H9B	109.4
O3—Zn1—N3	89.1 (2)	H9A—C9—H9B	108.0
O1—Zn1—N3	88.67 (19)	N2—C10—C9	114.0 (7)
N5—Zn1—N3	93.1 (2)	N2—C10—H10A	108.8
O3—Zn1—N1	89.57 (18)	C9—C10—H10A	108.8
O1—Zn1—N1	89.0 (2)	N2—C10—H10B	108.8
N5—Zn1—N1	90.4 (2)	C9—C10—H10B	108.8
N3—Zn1—N1	176.5 (2)	H10A—C10—H10B	107.7
C2—O1—Zn1	128.0 (4)	N2—C11—H11A	109.5
C3—O2—C7	118.9 (8)	N2—C11—H11B	109.5
C13—O3—Zn1	128.1 (4)	H11A—C11—H11B	109.5
C14—O4—C18	116.7 (7)	N2—C11—H11C	109.5
H5A—O5—H5B	120.0	H11A—C11—H11C	109.5
C8—N1—C9	116.2 (6)	H11B—C11—H11C	109.5
C8—N1—Zn1	122.4 (5)	C13—C12—C17	118.7 (9)
C9—N1—Zn1	121.3 (5)	C13—C12—C19	123.6 (7)
C10—N2—C11	116.9 (6)	C17—C12—C19	117.7 (9)
C10—N2—H2A	108.1	O3—C13—C12	123.0 (7)
C11—N2—H2A	108.1	O3—C13—C14	119.9 (7)
C10—N2—H2B	108.1	C12—C13—C14	117.1 (7)
C11—N2—H2B	108.1	C15—C14—O4	124.8 (8)
H2A—N2—H2B	107.3	C15—C14—C13	122.1 (9)
C19—N3—C20	118.3 (7)	O4—C14—C13	113.0 (6)
C19—N3—Zn1	121.3 (5)	C14—C15—C16	120.4 (10)
C20—N3—Zn1	120.4 (5)	C14—C15—H15	119.8
C21—N4—C22	113.0 (6)	C16—C15—H15	119.8
C21—N4—H4A	109.0	C17—C16—C15	120.8 (9)
C22—N4—H4A	109.0	C17—C16—H16	119.6
C21—N4—H4B	109.0	C15—C16—H16	119.6
C22—N4—H4B	109.0	C16—C17—C12	120.8 (9)
H4A—N4—H4B	107.8	C16—C17—H17	119.6
C23—N5—Zn1	157.9 (6)	C12—C17—H17	119.6
C2—C1—C6	120.1 (9)	O4—C18—H18A	109.5
C2—C1—C8	124.6 (6)	O4—C18—H18B	109.5
C6—C1—C8	115.3 (9)	H18A—C18—H18B	109.5
O1—C2—C3	119.7 (8)	O4—C18—H18C	109.5
O1—C2—C1	123.2 (7)	H18A—C18—H18C	109.5
C3—C2—C1	117.1 (8)	H18B—C18—H18C	109.5
C2—C3—O2	113.9 (7)	N3—C19—C12	128.9 (7)
C2—C3—C4	120.6 (11)	N3—C19—H19	115.5
O2—C3—C4	125.5 (9)	C12—C19—H19	115.5
C5—C4—C3	123.3 (12)	N3—C20—C21	112.5 (6)
C5—C4—H4	118.4	N3—C20—H20A	109.1
C3—C4—H4	118.4	C21—C20—H20A	109.1
C4—C5—C6	119.4 (11)	N3—C20—H20B	109.1
C4—C5—H5	120.3	C21—C20—H20B	109.1
C6—C5—H5	120.3	H20A—C20—H20B	107.8
C5—C6—C1	119.5 (11)	N4—C21—C20	111.9 (6)
C5—C6—H6	120.2	N4—C21—H21A	109.2
C1—C6—H6	120.2	C20—C21—H21A	109.2
O2—C7—H7A	109.5	N4—C21—H21B	109.2
O2—C7—H7B	109.5	C20—C21—H21B	109.2
H7A—C7—H7B	109.5	H21A—C21—H21B	107.9
O2—C7—H7C	109.5	N4—C22—H22A	109.5
H7A—C7—H7C	109.5	N4—C22—H22B	109.5
H7B—C7—H7C	109.5	H22A—C22—H22B	109.5
N1—C8—C1	127.5 (7)	N4—C22—H22C	109.5
N1—C8—H8	116.3	H22A—C22—H22C	109.5
C1—C8—H8	116.3	H22B—C22—H22C	109.5
N1—C9—C10	111.2 (5)	N5—C23—S1	179.2 (7)
N1—C9—H9A	109.4	N6—C24—S2	177.3 (10)

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Hydrogen-bond geometry (Å, °)

D—H···A	D—H	H···A	D···A	D—H···A
N4—H4B···O2	0.90	2.38	3.001 (8)	126
N4—H4B···O1	0.90	1.84	2.682 (7)	155
N4—H4A···O5	0.90	1.99	2.839 (14)	157
N2—H2B···N6	0.90	1.93	2.834 (11)	179
N2—H2A···O4	0.90	2.35	2.889 (8)	119
N2—H2A···O3	0.90	1.86	2.691 (7)	153

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Footnotes

Supplementary data and figures for this paper are available from the IUCr electronic archives (Reference: SU2115).

References

Bertini, I., Gray, H. B., Lippard, S. J. & Valentine, J. S. (1994). In Bioinorganic Chemistry Mills Valley, CA, USA: University Science Books.
Bruker (2000). SMART, SAINT and SADABS Bruker AXS Inc., Madison, Wisconsin, USA.
Cai, B.-H. (2009). Acta Cryst. E65, m142. [DOI] [PMC free article] [PubMed]
Eltayeb, N. E., Teoh, S. G., Chantrapromma, S., Fun, H.-K. & Adnan, R. (2008). Acta Cryst. E64, m738–m739. [DOI] [PMC free article] [PubMed]
Harrison, W. T. A., Ramadevi, P. & Kumaresan, S. (2006). Acta Cryst. E62, m513–m515.
Li, H.-Q., Xian, H.-D., Liu, J.-F. & Zhao, G.-L. (2008). Acta Cryst. E64, m1495. [DOI] [PMC free article] [PubMed]
Lipscomb, W. N. & Sträter, N. (1996). Chem. Rev.96, 2375–2434. [DOI] [PubMed]
Musie, G. T., Li, X. & Powell, D. R. (2004). Acta Cryst. E60, m471–m472.
Sheldrick, G. M. (2008). Acta Cryst. A64, 112–122. [DOI] [PubMed]
Tirosh, E., Maman, R. & Goldberg, I. (2005). Acta Cryst. E61, m751–m754.
Vallee, B. L. & Auld, D. S. (1993). Acc. Chem. Res.26, 543–551.
Zhang, Q.-W. & Wang, G.-X. (2007). Acta Cryst. E63, m652–m653.

Associated Data

This section collects any data citations, data availability statements, or supplementary materials included in this article.

Supplementary Materials

Crystal structure: contains datablocks global, I. DOI: 10.1107/S1600536809022326/su2115sup1.cif

e-65-0m799-sup1.cif^{(22.4KB, cif)}

Structure factors: contains datablocks I. DOI: 10.1107/S1600536809022326/su2115Isup2.hkl

e-65-0m799-Isup2.hkl^{(308.3KB, hkl)}

Additional supplementary materials: crystallographic information; 3D view; checkCIF report

[bb1] Bertini, I., Gray, H. B., Lippard, S. J. & Valentine, J. S. (1994). In Bioinorganic Chemistry Mills Valley, CA, USA: University Science Books.

[bb2] Bruker (2000). SMART, SAINT and SADABS Bruker AXS Inc., Madison, Wisconsin, USA.

[bb3] Cai, B.-H. (2009). Acta Cryst. E65, m142. [DOI] [PMC free article] [PubMed]

[bb4] Eltayeb, N. E., Teoh, S. G., Chantrapromma, S., Fun, H.-K. & Adnan, R. (2008). Acta Cryst. E64, m738–m739. [DOI] [PMC free article] [PubMed]

[bb5] Harrison, W. T. A., Ramadevi, P. & Kumaresan, S. (2006). Acta Cryst. E62, m513–m515.

[bb6] Li, H.-Q., Xian, H.-D., Liu, J.-F. & Zhao, G.-L. (2008). Acta Cryst. E64, m1495. [DOI] [PMC free article] [PubMed]

[bb7] Lipscomb, W. N. & Sträter, N. (1996). Chem. Rev.96, 2375–2434. [DOI] [PubMed]

[bb8] Musie, G. T., Li, X. & Powell, D. R. (2004). Acta Cryst. E60, m471–m472.

[bb9] Sheldrick, G. M. (2008). Acta Cryst. A64, 112–122. [DOI] [PubMed]

[bb10] Tirosh, E., Maman, R. & Goldberg, I. (2005). Acta Cryst. E61, m751–m754.

[bb11] Vallee, B. L. & Auld, D. S. (1993). Acc. Chem. Res.26, 543–551.

[bb12] Zhang, Q.-W. & Wang, G.-X. (2007). Acta Cryst. E63, m652–m653.

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Abstract

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Experimental

Crystal data

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Refinement

Supplementary Material

Table 1. Hydrogen-bond geometry (Å, °).

Acknowledgments

supplementary crystallographic information

Comment

Experimental

Refinement

Figures

Fig. 1.

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Data collection

Refinement

Special details

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Å²)

Atomic displacement parameters (Å²)

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Hydrogen-bond geometry (Å, °)

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Abstract

Related literature

Experimental

Crystal data

Data collection

Refinement

Supplementary Material

Table 1. Hydrogen-bond geometry (Å, °).

Acknowledgments

supplementary crystallographic information

Comment

Experimental

Refinement

Figures

Fig. 1.

Crystal data

Data collection

Refinement

Special details

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Å2)

Atomic displacement parameters (Å2)

Geometric parameters (Å, °)

Hydrogen-bond geometry (Å, °)

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References

Associated Data

Supplementary Materials

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Bis(2-methoxy-6-{[2-(methylammonio)ethyl]iminomethyl}phenolato)thiocyanatozinc(II) thiocyanate hemihydrate

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Å²)

Atomic displacement parameters (Å²)