{2-[2-(Ethyl­amino)ethyl­imino­meth­yl]-5-methoxy­phenolato}(thio­cyanato-κN)­copper(II)

Abstract

In the title mononuclear copper(II) complex, [Cu(C₁₂H₁₇N₂O₂)(NCS)], the Cu^II atom is four-coordinated by an NNO-donor set of the tridentate Schiff base ligand and the N atom of a terminal thio­cyanate ligand in a slightly distorted square-planar geometry.

Related literature

For Cu^II complexes with Schiff base ligands, see: Dede et al. (2009 ▶); Rai (2010 ▶); Rajasekar et al. (2010 ▶); Roper et al. (1989 ▶). For related structures, see: Adams et al. (2003 ▶); Roy & Manassero (2010 ▶).

Experimental

Crystal data

• [Cu(C₁₂H₁₇N₂O₂)(NCS)]

• M _r = 342.90

• Monoclinic,

• a = 12.296 (6) Å

• b = 10.582 (5) Å

• c = 12.480 (6) Å

• β = 113.810 (7)°

• V = 1485.7 (12) ų

• Z = 4

• Mo Kα radiation

• μ = 1.61 mm⁻¹

• T = 293 K

• 0.30 × 0.27 × 0.27 mm

Data collection

• Bruker SMART CCD area-detector diffractometer

• Absorption correction: multi-scan (SADABS; Sheldrick, 1996 ▶) T _min = 0.643, T _max = 0.670

• 8523 measured reflections

• 3282 independent reflections

• 2123 reflections with I > 2σ(I)

• R _int = 0.039

Refinement

• R[F ² > 2σ(F ²)] = 0.044

• wR(F ²) = 0.129

• S = 1.00

• 3282 reflections

• 183 parameters

• H-atom parameters constrained

• Δρ_max = 0.61 e Å⁻³

• Δρ_min = −0.34 e Å⁻³

Data collection: SMART (Bruker, 1998 ▶); cell refinement: SAINT (Bruker, 1998 ▶); data reduction: SAINT; program(s) used to solve structure: SHELXS97 (Sheldrick, 2008 ▶); program(s) used to refine structure: SHELXL97 (Sheldrick, 2008 ▶); molecular graphics: SHELXTL (Sheldrick, 2008 ▶); software used to prepare material for publication: SHELXTL.

Supplementary Material

Additional supplementary materials: crystallographic information; 3D view; checkCIF report

Table 1. Selected bond lengths (Å).

Cu1—O1	1.817 (3)
Cu1—N1	1.828 (3)
Cu1—N3	1.868 (3)
Cu1—N2	1.912 (4)

supplementary crystallographic information

Comment

Copper(II) complexes with Schiff base ligands have received much attention in coordination chemistry (Rai, 2010; Roy & Manassero, 2010; Rajasekar et al., 2010; Dede et al., 2009). In the present work, we report the the crystal structure of a new copper(II) complex, the title compound, with the Schiff base ligand 2-[(2-ethylaminoethylimino)methyl]-5-methoxyphenolate.

The Cu^II atom in the title complex is four-coordinated by the NNO donor set of the Schiff base ligand, and the N atom of the terminal thiocyanate ligand, in a square-planar geometry. The coordination bond distances (Table 1) are within normal ranges and comparable to those in related complexes (Roper et al., 1989; Adams et al., 2003).

Experimental

Equimolar quantities (1 mmol each) of 2-hydroxy-4-methoxybenzaldehyde, N-ethylethylenediamine, ammonium thiocyanate, and copper nitrate were mixed and stirred in a methanol-acetonitrile (2:1 v/v) solution at room temperature for 3 h. The solution was allowed to evaporate slowly to give needle-shaped single crystals.

Refinement

H atoms were placed in geometrically idealized positions and constrained to ride on their parent atoms, with C–H = 0.93–0.97 Å, N–H = 0.91 Å, and U_iso(H) = 1.2U_eq(C,N) and 1.5U_eq(C_methyl).

Figures

Fig. 1.

The molecular structure of the title compound, showing the atomic numbering. Displacement ellipsoids are drawn at the 50% probability level.

Crystal data

[Cu(C12H17N2O2)(NCS)]	F(000) = 708
Mr = 342.90	Dx = 1.533 Mg m−3
Monoclinic, P21/c	Mo Kα radiation, λ = 0.71073 Å
Hall symbol: -P 2ybc	Cell parameters from 2310 reflections
a = 12.296 (6) Å	θ = 2.6–25.0°
b = 10.582 (5) Å	µ = 1.61 mm−1
c = 12.480 (6) Å	T = 293 K
β = 113.810 (7)°	Block cut from needle, blue
V = 1485.7 (12) Å3	0.30 × 0.27 × 0.27 mm
Z = 4

Data collection

Bruker SMART CCD area-detector diffractometer	3282 independent reflections
Radiation source: fine-focus sealed tube	2123 reflections with I > 2σ(I)
graphite	Rint = 0.039
ω scan	θmax = 27.5°, θmin = 1.8°
Absorption correction: multi-scan (SADABS; Sheldrick, 1996)	h = −15→15
Tmin = 0.643, Tmax = 0.670	k = −13→13
8523 measured reflections	l = −16→10

Refinement

Refinement on F2	Primary atom site location: structure-invariant direct methods
Least-squares matrix: full	Secondary atom site location: difference Fourier map
R[F2 > 2σ(F2)] = 0.044	Hydrogen site location: inferred from neighbouring sites
wR(F2) = 0.129	H-atom parameters constrained
S = 1.00	w = 1/[σ2(Fo2) + (0.0551P)2 + 1.5145P] where P = (Fo2 + 2Fc2)/3
3282 reflections	(Δ/σ)max = 0.001
183 parameters	Δρmax = 0.61 e Å−3
0 restraints	Δρmin = −0.34 e Å−3

Special details

Geometry. All esds (except the esd in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell esds are taken into account individually in the estimation of esds in distances, angles and torsion angles; correlations between esds in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell esds is used for estimating esds involving l.s. planes.

Refinement. Refinement of F2 against ALL reflections. The weighted R-factor wR and goodness of fit S are based on F2, conventional R-factors R are based on F, with F set to zero for negative F2. The threshold expression of F2 > σ(F2) is used only for calculating R-factors(gt) etc. and is not relevant to the choice of reflections for refinement. R-factors based on F2 are statistically about twice as large as those based on F, and R- factors based on ALL data will be even larger.

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Ų)

	x	y	z	Uiso*/Ueq
Cu1	0.55890 (4)	0.38272 (4)	0.94272 (4)	0.04744 (18)
N1	0.6492 (3)	0.3114 (3)	1.0844 (3)	0.0465 (8)
N2	0.4301 (3)	0.2831 (3)	0.9449 (3)	0.0596 (9)
H2N	0.3686	0.3382	0.9287	0.072*
N3	0.4579 (3)	0.4525 (3)	0.7995 (3)	0.0488 (8)
O1	0.6770 (2)	0.4836 (3)	0.9392 (2)	0.0543 (7)
O2	1.0326 (3)	0.7210 (3)	1.0840 (3)	0.0718 (9)
S1	0.30391 (13)	0.57348 (14)	0.60132 (10)	0.0790 (4)
C1	0.7807 (3)	0.5063 (4)	1.0246 (3)	0.0460 (9)
C2	0.8513 (4)	0.5995 (4)	1.0075 (3)	0.0516 (10)
H2	0.8249	0.6414	0.9360	0.062*
C3	0.9598 (4)	0.6314 (4)	1.0944 (4)	0.0552 (10)
C4	0.9978 (5)	0.7842 (5)	0.9760 (4)	0.0858 (17)
H4A	0.9877	0.7240	0.9152	0.129*
H4B	1.0578	0.8443	0.9801	0.129*
H4C	0.9240	0.8276	0.9590	0.129*
C5	1.0006 (4)	0.5683 (5)	1.2010 (4)	0.0664 (12)
H5	1.0740	0.5885	1.2598	0.080*
C6	0.9326 (4)	0.4776 (4)	1.2183 (4)	0.0629 (12)
H6	0.9605	0.4365	1.2904	0.075*
C7	0.8217 (4)	0.4421 (4)	1.1327 (3)	0.0480 (9)
C8	0.7542 (4)	0.3458 (4)	1.1546 (3)	0.0510 (10)
H8	0.7884	0.3035	1.2258	0.061*
C9	0.5884 (4)	0.2097 (4)	1.1177 (4)	0.0597 (11)
H9A	0.6175	0.2042	1.2023	0.072*
H9B	0.6024	0.1293	1.0880	0.072*
C10	0.4593 (4)	0.2402 (4)	1.0658 (4)	0.0630 (12)
H10A	0.4129	0.1660	1.0658	0.076*
H10B	0.4421	0.3062	1.1106	0.076*
C11	0.3850 (5)	0.1848 (5)	0.8565 (4)	0.0792 (15)
H11A	0.4379	0.1126	0.8819	0.095*
H11B	0.3879	0.2159	0.7845	0.095*
C12	0.2620 (5)	0.1410 (5)	0.8301 (4)	0.0816 (16)
H12A	0.2569	0.1124	0.9009	0.122*
H12B	0.2422	0.0727	0.7748	0.122*
H12C	0.2074	0.2095	0.7976	0.122*
C13	0.3932 (4)	0.5018 (4)	0.7173 (3)	0.0459 (9)

Atomic displacement parameters (Ų)

	U11	U22	U33	U12	U13	U23
Cu1	0.0569 (3)	0.0430 (3)	0.0396 (3)	−0.0019 (2)	0.0166 (2)	0.00224 (19)
N1	0.063 (2)	0.0397 (17)	0.0379 (16)	0.0056 (15)	0.0213 (15)	0.0010 (13)
N2	0.077 (3)	0.0499 (19)	0.0485 (19)	−0.0137 (18)	0.0216 (18)	0.0024 (15)
N3	0.055 (2)	0.0471 (18)	0.0396 (17)	−0.0061 (16)	0.0142 (15)	0.0017 (14)
O1	0.0489 (16)	0.0666 (18)	0.0378 (14)	−0.0067 (14)	0.0073 (12)	0.0121 (12)
O2	0.0598 (19)	0.089 (2)	0.0557 (19)	−0.0252 (18)	0.0123 (15)	−0.0104 (16)
S1	0.0831 (9)	0.1010 (10)	0.0463 (6)	0.0400 (8)	0.0192 (6)	0.0180 (6)
C1	0.046 (2)	0.050 (2)	0.0409 (19)	0.0040 (18)	0.0167 (17)	−0.0023 (17)
C2	0.048 (2)	0.063 (3)	0.040 (2)	−0.002 (2)	0.0142 (17)	−0.0014 (18)
C3	0.052 (2)	0.060 (3)	0.051 (2)	−0.004 (2)	0.0181 (19)	−0.0141 (19)
C4	0.078 (4)	0.106 (4)	0.069 (3)	−0.044 (3)	0.024 (3)	−0.008 (3)
C5	0.051 (3)	0.078 (3)	0.054 (3)	0.002 (2)	0.004 (2)	−0.007 (2)
C6	0.063 (3)	0.068 (3)	0.045 (2)	0.010 (2)	0.008 (2)	0.003 (2)
C7	0.047 (2)	0.050 (2)	0.043 (2)	0.0092 (19)	0.0146 (17)	0.0009 (17)
C8	0.064 (3)	0.048 (2)	0.038 (2)	0.018 (2)	0.0180 (19)	0.0068 (17)
C9	0.087 (3)	0.044 (2)	0.047 (2)	0.001 (2)	0.025 (2)	0.0102 (18)
C10	0.086 (4)	0.052 (2)	0.052 (2)	−0.018 (2)	0.029 (2)	0.002 (2)
C11	0.103 (4)	0.073 (3)	0.065 (3)	−0.030 (3)	0.037 (3)	−0.011 (3)
C12	0.078 (3)	0.093 (4)	0.057 (3)	−0.029 (3)	0.009 (2)	−0.002 (3)
C13	0.054 (2)	0.046 (2)	0.038 (2)	−0.0007 (19)	0.0193 (18)	−0.0025 (17)

Geometric parameters (Å, °)

Cu1—O1	1.817 (3)	C4—H4B	0.96
Cu1—N1	1.828 (3)	C4—H4C	0.96
Cu1—N3	1.868 (3)	C5—C6	1.346 (6)
Cu1—N2	1.912 (4)	C5—H5	0.93
N1—C8	1.286 (5)	C6—C7	1.402 (6)
N1—C9	1.463 (5)	C6—H6	0.93
N2—C11	1.453 (6)	C7—C8	1.410 (6)
N2—C10	1.474 (5)	C8—H8	0.93
N2—H2N	0.91	C9—C10	1.488 (6)
N3—C13	1.139 (5)	C9—H9A	0.97
O1—C1	1.313 (4)	C9—H9B	0.97
O2—C3	1.346 (5)	C10—H10A	0.97
O2—C4	1.409 (6)	C10—H10B	0.97
S1—C13	1.610 (4)	C11—C12	1.487 (7)
C1—C2	1.386 (6)	C11—H11A	0.97
C1—C7	1.409 (5)	C11—H11B	0.97
C2—C3	1.379 (6)	C12—H12A	0.96
C2—H2	0.93	C12—H12B	0.96
C3—C5	1.389 (6)	C12—H12C	0.96
C4—H4A	0.96
O1—Cu1—N1	94.97 (13)	C3—C5—H5	120.4
O1—Cu1—N3	88.49 (13)	C5—C6—C7	122.9 (4)
N1—Cu1—N3	176.29 (15)	C5—C6—H6	118.5
O1—Cu1—N2	177.40 (14)	C7—C6—H6	118.5
N1—Cu1—N2	86.67 (15)	C6—C7—C1	117.6 (4)
N3—Cu1—N2	89.82 (15)	C6—C7—C8	120.9 (4)
C8—N1—C9	120.1 (3)	C1—C7—C8	121.6 (4)
C8—N1—Cu1	126.4 (3)	N1—C8—C7	125.5 (3)
C9—N1—Cu1	113.4 (3)	N1—C8—H8	117.3
C11—N2—C10	114.7 (3)	C7—C8—H8	117.3
C11—N2—Cu1	116.6 (3)	N1—C9—C10	107.1 (3)
C10—N2—Cu1	108.9 (3)	N1—C9—H9A	110.3
C11—N2—H2N	105.2	C10—C9—H9A	110.3
C10—N2—H2N	105.2	N1—C9—H9B	110.3
Cu1—N2—H2N	105.2	C10—C9—H9B	110.3
C13—N3—Cu1	174.4 (3)	H9A—C9—H9B	108.5
C1—O1—Cu1	127.7 (2)	N2—C10—C9	106.8 (4)
C3—O2—C4	118.0 (3)	N2—C10—H10A	110.4
O1—C1—C2	118.0 (3)	C9—C10—H10A	110.4
O1—C1—C7	122.9 (4)	N2—C10—H10B	110.4
C2—C1—C7	119.1 (4)	C9—C10—H10B	110.4
C3—C2—C1	121.3 (4)	H10A—C10—H10B	108.6
C3—C2—H2	119.3	N2—C11—C12	115.7 (4)
C1—C2—H2	119.3	N2—C11—H11A	108.4
O2—C3—C2	124.5 (4)	C12—C11—H11A	108.4
O2—C3—C5	115.7 (4)	N2—C11—H11B	108.4
C2—C3—C5	119.8 (4)	C12—C11—H11B	108.4
O2—C4—H4A	109.5	H11A—C11—H11B	107.4
O2—C4—H4B	109.5	C11—C12—H12A	109.5
H4A—C4—H4B	109.5	C11—C12—H12B	109.5
O2—C4—H4C	109.5	H12A—C12—H12B	109.5
H4A—C4—H4C	109.5	C11—C12—H12C	109.5
H4B—C4—H4C	109.5	H12A—C12—H12C	109.5
C6—C5—C3	119.3 (4)	H12B—C12—H12C	109.5
C6—C5—H5	120.4	N3—C13—S1	178.8 (4)