Polymeric potassium triformatocobalt(II)

Abstract

In the crystal structure of the title compound, poly[tri-μ-formato-cobalt(II)potassium], [CoK(CHO₂)₃]_n the Co²⁺ cations are coordinated by six O-bonded formate anions in an octa­hedral coordination mode and the K⁺ cations are eightfold coordinated by seven O-bonded formate anions within irregular polyhedra. The Co²⁺ cations are connected by bridging formate anions into a three-dimensional coordination network in which the K⁺ cations are embedded. The asymmetric unit consits of one Co²⁺ cation located on a center of inversion, one K⁺ cation located on a twofold axis and two crystallographically independent formato anions, of which one is located on a twofold axis and the other occupies a general position.

Related literature

For background to this work see: Boeckmann et al. (2010) ▶; Wriedt & Näther (2010 ▶); Wriedt et al. (2009) ▶. For structures of bimetallic compounds based on potassium formate, see: Antsyshkina et al. (1983 ▶); Leontiev et al. (1988 ▶). For a description of the Cambridge Structural Database, see: Allen (2002 ▶).

Experimental

Crystal data

• [CoK(CHO₂)₃]

• M _r = 233.08

• Monoclinic,

• a = 10.7244 (8) Å

• b = 8.9653 (6) Å

• c = 6.8742 (5) Å

• β = 95.539 (6)°

• V = 657.85 (8) ų

• Z = 4

• Mo Kα radiation

• μ = 3.22 mm⁻¹

• T = 293 K

• 0.16 × 0.09 × 0.06 mm

Data collection

• Stoe IPDS-2 diffractometer

• Absorption correction: numerical (X-SHAPE and X-RED32; Stoe & Cie, 2008) ▶ T _min = 0.711, T _max = 0.817

• 6120 measured reflections

• 892 independent reflections

• 853 reflections with I > 2σ(I)

• R _int = 0.031

Refinement

• R[F ² > 2σ(F ²)] = 0.020

• wR(F ²) = 0.046

• S = 1.15

• 892 reflections

• 54 parameters

• H-atom parameters constrained

• Δρ_max = 0.25 e Å⁻³

• Δρ_min = −0.57 e Å⁻³

Data collection: X-AREA (Stoe & Cie, 2008) ▶; cell refinement: X-AREA ▶; data reduction: X-AREA ▶; program(s) used to solve structure: SHELXS97 (Sheldrick, 2008 ▶); program(s) used to refine structure: SHELXL97 (Sheldrick, 2008 ▶); molecular graphics: XP in SHELXTL (Sheldrick, 2008 ▶) and DIAMOND (Brandenburg, 1999 ▶); software used to prepare material for publication: XCIF in SHELXTL.

Supplementary Material

Additional supplementary materials: crystallographic information; 3D view; checkCIF report

Table 1. Selected bond lengths (Å).

K1—O1	2.7371 (10)
K1—O2i	2.8193 (10)
K1—O11i	2.8507 (11)
Co1—O1	2.0943 (10)
Co1—O2ii	2.1015 (10)
Co1—O11iii	2.1026 (9)

Symmetry codes: (i) ; (ii) ; (iii) .

supplementary crystallographic information

Comment

In our current investigation on the synthesis, structures and properties of new coordination polymers based on paramagnetic transition metal, small-sized anions and N-donor ligands, we have shown that thermal decomposition reactions are an elegante route for the discovery and preparation of new ligand-deficient coordination polymers (Boeckmann et al., 2010; Wriedt & Näther, 2010; Wriedt et al., 2009). Within this project we tried to prepare new ligand-rich precursor compounds based on cobalt formate and pyrazine as coligand. However, reaction of cobalt(II) chloride, potassium formate and pyrazine in acteonitrile unexpectedly resulted in single crystals of the title compound.

In the crystal structure of the title compound, each cobalt(II) cation is coordinated by six bridging formato anions with Co—OCHO distances between 2.0943 (10) Å and 2.1026 (9) Å. The CoO₆ octahedron is slightly distorted with angles ranging from 82.66 (4) ° to 97.34 (4) ° and 180° (Fig. 1 and Tab. 1). The K⁺ cations are coordinated by eight oxygen atoms belonging to seven formato anions within irregular polyhedra. The K—O distances ranges from 2.7371 (10) Å to 2.8507 (11) Å and the O—K—O angles are between 59.81 (3) ° and 147.11 (3) °. The cobalt cations are connected via µ-1,3 bridging formato anions into a three dimensional coordination network (Fig. 2). Within this networks cavities are formed in which the K⁺ cations are embedded (Fig 3). The shortest Co···Co distances amount to 5.6487 (3) Å and the shortest K···K distances are 3.9067 (4) Å).

According to a search in the CCDC database (ConQuest Ver.1.12.2010) (Allen, 2002) mixed cobalt and potassium formates are unkown but bimetallic compounds based on potassium formate are known with different metals (Antsyshkina et al., 1983 and Leontiev et al., 1988.

Experimental

Potassium formate (KCHOO) and pyrazine were obtained from Alfa Aesar and cobalt(II) chloride was obtained from Acros Organics. All chemicals were used without further purification. 0.25 mmol (32.5 mg) CoCl₂, 0.5 mmol (42.1 mg) KCHOO and 0.5 mmol (40 mg) pyrazine were reacted with 1 ml acetonitrile in a closed test-tube at 120°C for three days. On cooling block-shaped single crystals of the title compound were obtained in a mixture with an unknown phase. It must be noted, that the reaction under similar conditions without pyrazine does not lead to the formation of the title compound.

Refinement

The H atoms were positioned with idealized geometry and were refined isotropic with U_iso(H) = 1.2U_eq(C) and C—H distances of 0.93 Å using a riding model.

Figures

Fig. 1.

: Crystal structure of the title compound with labelling and displacement ellipsoids drawn at the 50 % probability level. Symmetry codes: i = -x+1/2, y-1/2, -z+1/2; ii = -x+1/2, -y+1/2, -z; iii = +x, -y+1, +z-1/2; iv = -x+1, +y, -z+1/2; v = +x-1/2, -y+1/2, +z-1/2.

Fig. 2.

Crystal structure of the title compound with view along the crystallographic b axis. The K+ cations are omitted for clarity.

Fig. 3.

Crystal structure of the title compound with view along the crystallographic c axis.

Crystal data

[CoK(CHO2)3]	F(000) = 460
Mr = 233.08	Dx = 2.353 Mg m−3
Monoclinic, C2/c	Mo Kα radiation, λ = 0.71073 Å
Hall symbol: -C 2yc	Cell parameters from 6120 reflections
a = 10.7244 (8) Å	θ = 3.0–29.2°
b = 8.9653 (6) Å	µ = 3.22 mm−1
c = 6.8742 (5) Å	T = 293 K
β = 95.539 (6)°	Block, light blue
V = 657.85 (8) Å3	0.16 × 0.09 × 0.06 mm
Z = 4

Data collection

Stoe IPDS-2 diffractometer	892 independent reflections
Radiation source: fine-focus sealed tube	853 reflections with I > 2σ(I)
graphite	Rint = 0.031
ω scans	θmax = 29.2°, θmin = 3.0°
Absorption correction: numerical (X-SHAPE and X-RED32; Stoe & Cie, 2008)	h = −14→14
Tmin = 0.711, Tmax = 0.817	k = −12→12
6120 measured reflections	l = −9→9

Refinement

Refinement on F2	Secondary atom site location: difference Fourier map
Least-squares matrix: full	Hydrogen site location: inferred from neighbouring sites
R[F2 > 2σ(F2)] = 0.020	H-atom parameters constrained
wR(F2) = 0.046	w = 1/[σ2(Fo2) + (0.0276P)2 + 0.1263P] where P = (Fo2 + 2Fc2)/3
S = 1.15	(Δ/σ)max < 0.001
892 reflections	Δρmax = 0.25 e Å−3
54 parameters	Δρmin = −0.57 e Å−3
0 restraints	Extinction correction: SHELXL97 (Sheldrick, 2008), Fc*=kFc[1+0.001xFc2λ3/sin(2θ)]-1/4
Primary atom site location: structure-invariant direct methods	Extinction coefficient: 0.0126 (12)

Special details

Geometry. All esds (except the esd in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell esds are taken into account individually in the estimation of esds in distances, angles and torsion angles; correlations between esds in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell esds is used for estimating esds involving l.s. planes.

Refinement. Refinement of F2 against ALL reflections. The weighted R-factor wR and goodness of fit S are based on F2, conventional R-factors R are based on F, with F set to zero for negative F2. The threshold expression of F2 > 2sigma(F2) is used only for calculating R-factors(gt) etc. and is not relevant to the choice of reflections for refinement. R-factors based on F2 are statistically about twice as large as those based on F, and R- factors based on ALL data will be even larger.

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Ų)

	x	y	z	Uiso*/Ueq
K1	0.0000	0.10357 (5)	0.2500	0.02582 (12)
Co1	0.2500	0.2500	0.0000	0.01561 (10)
O1	0.16793 (10)	0.33291 (11)	0.24238 (15)	0.0274 (2)
O2	0.25445 (9)	0.54804 (11)	0.34563 (15)	0.0271 (2)
C1	0.18397 (13)	0.44031 (15)	0.3568 (2)	0.0244 (3)
H1	0.1371	0.4392	0.4638	0.029*
O11	0.43048 (9)	0.31029 (12)	0.12114 (14)	0.0260 (2)
C11	0.5000	0.2478 (2)	0.2500	0.0271 (4)
H11	0.5000	0.1441	0.2500	0.033*

Atomic displacement parameters (Ų)

	U11	U22	U33	U12	U13	U23
K1	0.0278 (2)	0.01932 (19)	0.0318 (2)	0.000	0.01004 (16)	0.000
Co1	0.01611 (14)	0.01374 (14)	0.01648 (14)	−0.00041 (8)	−0.00102 (8)	0.00122 (8)
O1	0.0332 (5)	0.0223 (5)	0.0277 (5)	−0.0087 (4)	0.0091 (4)	−0.0093 (4)
O2	0.0300 (5)	0.0204 (4)	0.0318 (5)	−0.0063 (4)	0.0076 (4)	−0.0089 (4)
C1	0.0312 (6)	0.0213 (6)	0.0215 (6)	−0.0042 (5)	0.0069 (5)	−0.0037 (5)
O11	0.0215 (4)	0.0303 (5)	0.0245 (5)	−0.0036 (4)	−0.0063 (4)	0.0033 (4)
C11	0.0270 (9)	0.0217 (9)	0.0310 (10)	0.000	−0.0057 (8)	0.000

Geometric parameters (Å, °)

K1—O1	2.7371 (10)	Co1—O11iv	2.1026 (9)
K1—O2i	2.8193 (10)	O1—C1	1.2448 (17)
K1—O11ii	2.8335 (10)	O2—C1	1.2335 (17)
K1—O11i	2.8507 (11)	C1—H1	0.9300
K1—C11i	3.189 (2)	O11—C11	1.2356 (13)
Co1—O1	2.0943 (10)	C11—H11	0.9300
Co1—O2iii	2.1015 (10)
O1—K1—O1v	82.62 (5)	O1—Co1—O11iv	87.99 (4)
O1—K1—O2i	140.19 (3)	O1iv—Co1—O11iv	92.01 (4)
O1v—K1—O2i	59.81 (3)	O2iii—Co1—O11iv	94.96 (4)
O2i—K1—O2vi	159.66 (4)	O2vi—Co1—O11iv	85.04 (4)
O1—K1—O11ii	92.48 (3)	O11iv—Co1—O11	180.00 (6)
O1v—K1—O11ii	63.08 (3)	C1—O1—Co1	137.25 (9)
O2i—K1—O11ii	60.35 (3)	C1—O1—K1	128.31 (9)
O2vi—K1—O11ii	126.22 (3)	Co1—O1—K1	94.38 (3)
O11ii—K1—O11iv	148.37 (5)	C1—O2—Co1vii	126.81 (9)
O1—K1—O11i	147.11 (3)	C1—O2—K1viii	138.13 (9)
O1v—K1—O11i	123.09 (3)	Co1vii—O2—K1viii	91.88 (3)
O2i—K1—O11i	71.79 (3)	O2—C1—O1	127.90 (13)
O2vi—K1—O11i	89.25 (3)	O2—C1—H1	116.0
O11ii—K1—O11i	116.58 (3)	O1—C1—H1	116.0
O11iv—K1—O11i	93.17 (3)	C11—O11—Co1	129.50 (9)
O11i—K1—O11vi	45.45 (4)	C11—O11—K1iv	125.17 (6)
O1—K1—C11i	138.69 (2)	Co1—O11—K1iv	91.47 (3)
O2i—K1—C11i	79.83 (2)	C11—O11—K1viii	94.23 (9)
O11ii—K1—C11i	105.81 (2)	Co1—O11—K1viii	124.29 (4)
O11i—K1—C11i	22.727 (19)	K1iv—O11—K1viii	86.83 (3)
O1—Co1—O1iv	180.0	O11ix—C11—O11	126.09 (18)
O1—Co1—O2iii	97.34 (4)	O11ix—C11—K1viii	63.04 (9)
O1iv—Co1—O2iii	82.66 (4)	O11—C11—H11	117.0
O2iii—Co1—O2vi	180.00 (3)	K1viii—C11—H11	180.0

Symmetry codes: (i) x−1/2, y−1/2, z; (ii) x−1/2, −y+1/2, z+1/2; (iii) x, −y+1, z−1/2; (iv) −x+1/2, −y+1/2, −z; (v) −x, y, −z+1/2; (vi) −x+1/2, y−1/2, −z+1/2; (vii) −x+1/2, y+1/2, −z+1/2; (viii) x+1/2, y+1/2, z; (ix) −x+1, y, −z+1/2.