Table 2.
Slope | Y-int. | Slope | Y-int. | R2 | |
---|---|---|---|---|---|
| |||||
cm−1/kcal mol−1 | cm−1 | - | kcal mol−1 | ||
1a | 93.7 | 2548 | 0.268 | 7.29 | 0.99510 |
8a | 63.8 | 5188 | 0.182 | 14.83 | 0.86159 |
| |||||
1b | 75.4 | 4290 | 0.216 | 12.27 | 0.84211 |
8b | 79.5 | 4437 | 0.227 | 12.69 | 0.96922 |
Polarity sensitivity equals the slope of the linearized Stokes shift vs. ET(30) plot. Values for 5-(thiophen-2-yl)-2dU 8a and 5-(fur-2-yl)-2dU 8b in cm−1/kcal mol−1 have been reported.[7, 25] A unitless value for polarity sensitivity is obtained by conversion of the Stokes shift value from cm−1 to kcal mol and replotting it as a function of the sample ET(30) value (in kcal mol−1). The adjusted R2 represents the goodness of the linear fit.