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. 2013 Feb 11;8(1):68. doi: 10.1186/1556-276X-8-68

Impact of hydrogen concentrations on the impedance spectroscopic behavior of Pd-sensitized ZnO nanorods

Muhammad Kashif 1,✉, Md Eaqub Ali 2, Syed M Usman Ali 3, Uda Hashim 1, Sharifah Bee Abd Hamid 2
PMCID: PMC3599888  PMID: 23399029

Abstract

ZnO nanorods were synthesized using a low-cost sol-gel spin coating technique. The synthesized nanorods were consisted of hexagonal phase having c-axis orientation. SEM images reflected perpendicular ZnO nanorods forming bridging network in some areas. The impact of different hydrogen concentrations on the Pd-sensitized ZnO nanorods was investigated using an impedance spectroscopy (IS). The grain boundary resistance (Rgb) significantly contributed to the sensing properties of hydrogen gas. The boundary resistance was decreased from 11.95 to 3.765 kΩ when the hydrogen concentration was increased from 40 to 360 ppm. IS gain curve showed a gain of 6.5 for 360 ppm of hydrogen at room temperature. Nyquist plot showed reduction in real part of impedance at low frequencies on exposure to different concentrations of hydrogen. Circuit equivalency was investigated by placing capacitors and resistors to identify the conduction mechanism according to complex impedance Nyquist plot. Variations in nanorod resistance and capacitance in response to the introduction of various concentrations of hydrogen gas were obtained from the alternating current impedance spectra.

Keywords: Sol-gel, Pd-sensitized ZnO nanorods, Impedance behavior, Nyquist plot

Background

While hydrogen gas has been increasingly used as a clean and green fuel in household and transportation appliances, the absence of color, odor, and taste has made it difficult to trace and detect hydrogen under complex matrices [1]. Hydrogen is a light and diffusible gas (diffusion coefficient of 0.61 cm2/s in air) [1] with a wide ranging inflammability (4% to 75%) [2]. Even 4.65% hydrogen in air is sufficient to cause explosion [2]. Thus, the detection and leakage control of this gas is a challenging task, and there is an increasing demand in the development of methodology for the ultrasensitive detection of hydrogen.

Previously, selective H2 sensors were proposed for the detection of hydrogen leakage in solid-state fuel cells [3], proton exchange membrane fuel cells [3], hydrogen engines [4], and hydrogen storage devices [5]. Bamsaoud et al. [6] used nanoparticulate tin oxide (SnO2)-based resistive films for the selective detection of hydrogen against relative humidity and CO2 at 265°C. Wang et al. [7] used mesostructured SnO2 for the selective detection of hydrogen against methane, butane, and CO at 300°C. Tianshu et al. [8] studied the effect of different Cd-doped SnO2-based sensors from 200°C to 450°C and selectively detected 1,000 ppm of hydrogen against 1,000 ppm of CO and 1,000 ppm of isobutane (i-C4H10) in the absence of ethanol vapor at a Cd to Sn ratio of 0.1. Lupan et al. [9] detected 10% H2 in N2 at 112°C using nanosensor based on zinc oxide (ZnO) nanorods. Garcia et al. [10] utilized Pd-decorated ZnO and tungsten oxide (WO3) nanowires for the selective detection of 4,500 ppmv H2/N2 at 100°C. Yamazoe et al. [11] studied the effect of different additives on SnO2 films and found that Ag-SnO2 film showed the highest sensitivity and selectively towards 0.8% hydrogen against 0.5% CH4, 0.2% C3H8, and 0.02% CO. Choi et al. [12] used electrospun Pd-doped SnO2 hollow nanofibers for the detection of hydrogen under ethanol background. Lupan et al. [13] studied the hydrogen selective response at room temperature using tetrapod ZnO sensor. Using an UV source of activation, they detected 100 ppm of hydrogen against 100 ppm of CO, isobutane, CH4, CO2, and SO2. However, in the forthgoing era, there is a requirement of hydrogen sensors having superior stability, sensitivity, and fast response time, along with low operating power and weight.

Recently, semiconductor metal oxides have been increasingly used in humidity, gas, and chemical sensing devices [14]. This is probably because of their simple fabrication, low cost, size reduction, appreciable sensitivity, and fast response time [1]. Catalytic metal-doped semiconductor metal oxides such as SnO2[15], titanium dioxide (TiO2) [16], ZnO [17], and WO3[18] have been used to develop hydrogen sensors. The addition of suitable quantity of appropriate metal catalyst enhances chemical reaction through the lowering of activation energy at the metal oxide thin film and target gas interfaces. The addition of metal as a catalyst also improves target response and selectivity at room temperature [19]. ZnO nanorods and nanowires are particularly promising for these applications because of its large surface area, wide bandgap and exciton energy, fascinating sensitivity, biocompatibility, low weight, and resistance to rust formation [20]. For hydrogen sensing applications, surface modifications of ZnO with metal additives such as Pt, Pd, and/or Au through various techniques have been under intensive investigations [19,21,22]. Several studies have demonstrated that Pd doping on ZnO nanowires and nanorods enhances room temperature hydrogen sensing through the catalytic dissociation of molecular hydrogen to atomic hydrogen at room temperature [21]. The predominant methods documented to synthesize ZnO nanorods for this particular application are chemical vapor deposition (CVD) and molecular beam epitaxy (MBE) [21,22]. However, both CVD and MBE methods involve high temperature growth and expensive instrumentations which are not available and affordable in ordinary laboratories. These techniques also need gold (Au) and/or other expensive metal coatings for the synthesis of ZnO nanorods and nanowires [10,11]. Moreover, Pd doping on the synthesized zinc oxides requires RF sputtering which also demands expensive laboratory setup. Additionally, previous researchers used DC measurements [19,21,22] which cannot elucidate the contributing factors such as the grain, grain boundary, and electrodes that might influence the target response on the Pd-sensitized ZnO nanostructures.

Recently, sol-gel spin coating technique has received enormous attention because of its simplicity, affordable instrumentations, low cost, and controllable growth temperatures [23]. In this paper, c-axis-aligned hexagonal ZnO nanorods with good crystalline properties were synthesized using a low-cost spin coating technique. Pd doping on the synthesized ZnO was performed using very simple instrumentations that require only micropipette and hot plate. However, to the best of our knowledge, such a method is not documented for the synthesis of Pd-sensitized ZnO nanorods for hydrogen detection applications. Room temperature hydrogen sensing was performed in a low-cost homemade gas chamber, and superior sensitivity and stability over the literature-reported Pd-sensitized ZnO nanorods were achieved. Potential contributors to sensor functionalities were elucidated through impedance study which is an AC measurement technique that can define contributions from grain, grain boundary, electrodes, and other associated elements. The simplicity and reproducibility of the method suggested its potential applications in the large-scale synthesis of Pd-sensitized ZnO nanorods for use in hydrogen, chemical, and other gas sensing devices that involved Pd-mediated catalysis.

Methods

ZnO nanorods were synthesized on silicon dioxide substrate as described in our previous research [24]. Briefly, zinc acetate dihydrate (98%; Sigma-Aldrich Corporation, St. Louis, MO, USA) was mixed in 2-methoxyethanol (99.8%; Sigma-Aldrich) where the molarity of Zn was maintained at 0.2 M. After 30 min of stirring at room temperature, the hot plate temperature was ramped up to 60°C. Monoethanolamine (MEA) (99%; Merck & Co., Inc., Whitehouse Station, NJ, USA) was added dropwise as a stabilizer under constant stirring. The molar ratio of MEA/Zn was maintained at 1:1. The stirring was continued until the solution turned into transparent from its initial whitish appearance. The prepared solution was aged for 24 h. The process flow for the device fabrication is depicted in Figure 1.

Figure 1.

Figure 1

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Process flow for the fabrication of ZnO nanorods device.

An oxide layer of approximately 1-μm thickness was grown on a p-type silicon substrate of resistivity 1 to 50 Ω cm through a wet oxidation process. Prior to the oxide growth, the wafer was cleaned with RCA1 and RCA2 solutions followed by draining in dilute HF to remove the native oxide. An interdigitated electrode layer was deposited onto the oxide layer through Cr/Au evaporation using a hard mask and Auto 306 thermal evaporator (Edwards High Vacuum International, Wilmington, MA, USA). ZnO seed layer was deposited on the thermally oxidized silicon substrate using a spin coater rotating at 1,000 rpm for 10 s and then ramped up to 3,000 rpm for 45 s. After coating the seed layer, the film was dried at 250°C for 20 min. The coating and drying processes were repeated five times. After depositing five successive layers, the sample was incubated in a furnace to anneal the thin film at 450°C for 1 h under air atmosphere.

For the growth of ZnO nanorods, the prepared substrate was inserted inside a Teflon sample holder at the cut edges to keep the deposited side downward inside the growth solution. The growth solution was prepared by mixing zinc nitrate hexahydrate (99%; Sigma-Aldrich) and hexamethyltetramine (99%; Merck) in deionized (DI) water, and the final concentration of the solution was maintained at 25 mM. The beaker was placed inside a preheated oven, and the growth process was continued at 90°C for 6 h. The prepared ZnO nanorods were washed in IPA and DI water to remove the excess and contaminated salts. Subsequently, the synthesized ZnO nanorods were annealed at 450°C for 1 h under air environment. For Pd doping, 0.01 M solution of Pd was prepared by mixing the required amount of palladium chloride (PdCl2, 99.999%; Sigma-Aldrich) in ethanol. The solution was stirred overnight to completely dissolve the Pd particles. Five-microliter portion of the above solution was precisely transferred onto the synthesized ZnO nanorods using a micropipette, and the whole mixture was heated at 250°C for 5 min to dry out the residual chloride.

The structural properties of the Pd-sensitized ZnO nanorods were investigated using Bruker X-ray diffractometer (D8 Advance, Bruker AXS GMBH, Karlsruhe, Germany) with Cu Kα radiation at λ = 1.5406 Å. The X-ray diffraction (XRD) pattern was recorded in the range of 20° to 60° operating at a voltage of 40 kV and a current of 40 mA. The X-ray spectra peak analysis was carried out by Diffraction plus 2003 version of Eva 9.0 rev.0 software. The material composition was analyzed using X-ray photoelectron spectroscopy (XPS) (Omicron Dar400, Omicron, Erlangen, Germany). The chamber pressure was maintained at 2.4 e−10 Torr throughout the measurement. CasaXPS software was used for the XPS peak deconvolution. Morphological studies were performed using a scanning electron microscope (JEOL JSM-6460LA, Akishima, Tokyo, Japan). Gas sensing measurements were carried out in a homemade gas chamber of 3-L capacity. The base of the chamber was made up of stainless steel, and the upper area was covered with a high-vacuum glass dome. All the measurements were performed under atmospheric pressure. The chamber inlet was connected with the air pump and 1% H2 in balance N2 gas (Moxlinde, Malaysia). The flow of 1% H2 gas was regulated using a mass flow controller (GFC-17, 0 to 100 ml/min; AALBORG, Orangeburg, NY, USA), whereas the air flow was controlled using a mass flow meter. Impedance spectra were collected at room temperature (RT) in the frequency range of 1 Hz to 10 MHz using Novocontrol alpha high-frequency analyzer (Hundsangen, Germany) under the exposure of variable ppm levels of hydrogen.

Results and discussion

The scanning electron micrograph depicting the morphological feature of ZnO nanorods grown on a thermally oxidized silicon substrate is shown in Figure 2. Uniformly distributed perpendicular and oblique ZnO nanorods of hexagonal shape having 50- to 100-nm diameter and 2- to 3-μm length were observed.

Figure 2.

Figure 2

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SEM image of Pd-sensitized ZnO nanorods.

The XRD spectra demonstrated two noticeable peaks at 34.5° (002) and 38.53° (211) planes (Figure 3a). The sharp peak located at 34.5° (002) plane of the synthesized ZnO nanorods revealed their high-quality crystals and c-axis alignment. The second peak at 38.53° (211) plane confirmed the presence of palladium oxide (PdO). The EDX spectrum of Pd-sensitized ZnO nanorods is presented in Figure 3b. The EDX spectrum demonstrated the presence of zinc, oxygen, and palladium, which indicated the absence of any other impurities in the prepared sample.

Figure 3.

Figure 3

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XRD (a) and EDS (b) spectra of Pd-sensitized ZnO nanorods.

The surface composition of Pd-sensitized ZnO nanorods was further investigated using an XPS spectroscopy (Figure 4a) which reflected the presence of Zn, O, Pd, and carbon. The carbon peaks were due to the unavoidable air exposure during inserting the sample in an XPS chamber [25]. The peaks appearing at 284 and 288 eV were due to C-O and C=O bonds [26]. No other contaminants were detected on the Pd-sensitized ZnO nanorod surfaces. The XPS spectra of ZnO and PdO regions of our samples can be seen in Figure 4b,c. The Pd-sensitized ZnO nanorods showed two peaks at 1,020 and 1,043 eV that correspond to the distribution of Zn 2p3/2 and 2p1/2 core levels [25]. The binding energy peak for Pd 3d3/2 and Pd 3d5/2 core levels were observed at 340.82 and 334.7 eV, reflecting the presence of doped Pd in the form of PdO in the Pd-sensitized ZnO nanorods.

Figure 4.

Figure 4

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XPS spectra of Pd-sensitized ZnO nanorods. (a) Survey spectra, (b) Zn 2p spectra, and (c) the deconvolution spectra in Pd 3d region.

The ohmic behavior was studied to understand the operational stability of the fabricated device. The current to voltage (I-V) characterization curve of the Pd-sensitized ZnO nanorods is depicted in Figure 5. It can be observed that the device exhibited a linear relation between the current and voltage. The I-V curve revealed the enhancement in current from room temperature to 200°C. Further increment in temperature (200°C to 300°C) resulted in the decrement of current flow. The current increment indicated that the electrons gain sufficient energy to overcome the barrier height between the grains with increasing temperature. The decrement in current value above 200°C was due to the formation of chemisorption region at elevated temperatures (200°C ~ 500°C) [27,28] where oxygen molecules adsorbed on the surface of metal oxide trapping electrons. In low temperature range, oxygen molecules were mainly physically adsorbed on the surface. However, at high operating temperature, the absorbed oxygen accepts free electrons from the conduction band of ZnO and be converted into oxygen ions (O2− and O−). These oxygen ions (O2− and O−) increase the surface resistance of the ZnO nanorods. In high temperature range, the adsorbed oxygen molecules turn into chemisorptions (i.e., chemical bond attractions), and the concentration of the adsorbed oxygen molecules on the surface gradually raise. As a result, the absorbed oxygen could trap more free electrons from the conduction band of ZnO to be converted into oxygen ions (O2− and O−), resulting in an increase in surface resistance of the ZnO nanorods. In other words, when the oxygen molecules from the atmosphere are chemisorbed, it attracts the electrons from the conduction band causing a bending in band that creates a surface barrier and electron depletion or space charge layer. These lead to a reduction in conductivity and increase in resistivity in the metal oxide surface. Thus, the band edge bending in the conduction and valence band was related to the change in surface charge distribution.

Figure 5.

Figure 5

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I-V curves of Pd-sensitized ZnO nanorods from RT to 300°C.

Alternating current (AC) impedance spectroscopy was used to investigate the sensing mechanism in which the potential contributors could be defined [29]. Generally, the conduction process (R) and polarization behavior (C) become dominant in sensing mechanism. The device microstructures are composed of grains, grain boundaries, and the metal/ZnO contact. In the Nyquist plot, the major role players in the high, intermediate, and low frequencies are grains (bulk), grain boundaries (Rgb, Cgb) and the metal-semiconductor contact (Rc, Cc) [30]. In order to achieve a single semicircle from the prescribed components, the time constant τ associated with these components must be identical [31]:

τ=RgCg+Rgb+RcCc. (1)

The total impedance ZT of the device structure can be drawn as follows:

ZT=Zg+Zgb+Zc, (2)

where Zg, Zgb, and Zc represent the complex impedance contribution of the grains, grain boundaries, and the electrode contacts, respectively [32]. The grain resistance can be estimated from the interception of the arc at high frequency with the real axis [32]. Every individual semicircles has its own unique relaxation frequency ωmax (the frequency at the top of the arc), which can be represented as ωmaxRC = ωmaxτ = 1, where R and C represent the resistance and capacitance of the equivalent circuit and τ represents the relaxation time that depends only on the intrinsic properties of the material [33]. The effect of hydrogen gas on the impedance behavior of the sensor at different concentrations is shown in Figure 6.

Figure 6.

Figure 6

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Nyquist plot of Pd-sensitized ZnO nanorods as a function of different H2 concentrations at room temperature.

It was observed that when the gas concentration gradually increased from 40 to 360 ppm, the diameter of the arc decreased. The Z′′ maximum values were smaller than the half values of the Z′ maximum, demonstrating the contribution from the constant phase elements (CPEs) in the equivalent circuit [29]. The best-fitted value for capacitance was obtained by replacing C with a CPE, which frequently describe the behavior of polycrystalline materials having inhomogeneous microstructures such as the grain boundary that gives rise to different distributions of respective relaxation time. The impedance of a CPE was clearly described in [34].

ZCPE=1Ajωp, (3)

where A is a constant and p is a dimensionless parameter with value of less than unity. When p = 1, the equation represents the characteristics of a capacitor with A = C. The values noted in Table 1 shows that the resistance Rgb was varied because of the flow of different hydrogen concentrations. When the ZnO nanorods are exposed to air, oxygen molecules can capture free electrons from ZnO nanorods and form a surface depletion layer, which reduces the conducting width of ZnO nanorods and increases the potential barrier of the contacts between the ZnO nanorods. The surface depletion layer controls the density and mobility of electrons in the ZnO nanorods. When the ZnO nanorods are exposed to hydrogen, the adsorbed oxygen releases the previously trapped electrons back to the conduction band. The depletion width decreases as a result of the decrease in surface oxygen. This results in an increase in electron concentration of ZnO nanorods and a decrease in height of the barrier potential at the grain-grain contacts. Thus, the impedance of the ZnO nanorods decreases as the hydrogen concentration increases. Thus, it could be concluded that the hydrogen concentration significantly affects the grain boundary resistance which facilitates its detection.

Table 1.

Modeled RC parameters for Pd-sensitized ZnO nanorods under different H2 concentrations at room temperature

H2 (ppm) Rgb (Ω) CPE (nF) p value
0
 22,938
 4.99
 0.89
40
 11,950
 3.53
 0.9
100
 9,950
 3.5
 0.9
200
 6,550
 2.938
 0.91
300
 4,780
 2.88
 0.91
360 3,765 2.83 0.91
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However, the variation in the capacitance values was not significant. This reflected that the hydrogen gas mainly affects the surface charge region of the grain boundaries of Pd-sensitized ZnO nanorods.

The peak frequencies related to the relaxation frequencies of the impedance were also estimated by plotting the −Z′′ versus the logarithmic frequency curve (Figure 7). It was observed that the imaginary part of impedance decreased as the gas concentration increased [2]. The decrement in the impedance imaginary part was related to the carrier concentrations. As the hydrogen concentration increases, the barrier height decreases causing more carriers to flow. This results in a decrease in impedance. It was also observed that the peak frequency shifted toward higher frequencies with increasing hydrogen concentration. The shifting of the peak towards high frequencies is related to an ease in the flow of charge carriers to the AC electric field [35]. The broadening of peak with an increase in hydrogen concentration was due to the different distribution of relaxation time [33,36]. The relaxation process may be due to the presence of electrons and/or immobile species [33].

Figure 7.

Figure 7

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Imaginary parts of impedance for Pd-sensitized ZnO nanorods under different H2 concentrations at room temperature.

The sensitivity of the fabricated ZnO nanorod sensor was evaluated as a function of frequency and hydrogen concentration using the equation given below:

S=ZaZg, (4)

where Za represents the impedance of air and Zg represents the real part of impedance under hydrogen flow. Figure 8 displayed the effect of frequency at different parts per million (ppm) values of hydrogen on Pd-sensitized ZnO nanorods at room temperature. The sensitivity of our device at room temperature was better than the reported literature values at 400°C [2]. The noticeable change in the sensitivity was observed in the frequency range of 1 Hz to 100 kHz.

Figure 8.

Figure 8

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Gain curve for Pd-sensitized ZnO nanorods as a function of different H2 concentrations at room temperature.

In 1 Hz- to 100-kHz range, the space charge region rules the conductivity process. There is a sharp decrement in the sensitivity with the increment of frequency and little variation in the gain values at frequency higher than 100 kHz, where the conductivity is mainly dependent on the surface charge of the grains. This revealed that a suitable selection of frequency could achieve maximum gain in sensitivity.

The sensing mechanism can be described from the following aspects: The oxygen molecules from the ambient atmosphere were initially adsorbed onto the ZnO surface. The electrons were extracted from the conduction band of the ZnO material and were converted to a single or a double oxygen ion and became ionosorbed on the surface [2]. This led to a decrease in electron concentration and consequently an increase in resistance. This mechanism can be described as follows [2,37]:

O2g+e−→O2−ads. (5)

The reaction of the hydrogen or any reduction gases with the ionosorbed Oads−O results in the release of the captured electrons back to the conduction band. This results in an increase in electron concentration, decreasing the resistance which could be explained by the following reaction [2]:

H2Oads−→H2Og+e−. (6)

When the hydrogen is introduced, PdO is reduced to metallic palladium, returning electrons to ZnO. Hydrogen molecules adsorbed on palladium simultaneously spill over the surface of ZnO, activating the reaction between hydrogen and the adsorbed oxygen:

PdO+H2→Pd+H2O. (7)

At elevated temperature, Pd is oxidized by the chemisorbed oxygen:

2Pd+2Oabs→2PdO. (8)

The weak bonding of Pd atoms with the oxygen gas results in the dissociation of the complex at relatively low temperature releasing atomic oxygen. The oxygen atoms migrate along the surface of the grains. This migration is induced by the Pd catalyst and is known as spillover of the gaseous ions [38]. Thus, the oxygen atoms capture electrons from the surface layer forming an acceptor surface at the grain boundary. The presence of catalyst atoms activates the reaction between reducing gases and the adsorbed oxygen [39-41]. Thus, the Pd sensitization on the ZnO nanorod surface enabled the hydrogen sensing at relatively low operating temperature.

Conclusions

A hydrogen sensor was successfully developed using Pd-sensitized ZnO nanorods synthesized on oxidized silicon substrate using a sol-gel spin coating technique. The sensor detected ppm level hydrogen at room temperature with more sensitivity over the literature-reported values for the ZnO-based sensors. The variation in the resistance value of the grain boundary which was the basis of analyte detection mechanism was due to the sole variation in hydrogen concentration. Nyquist plot strongly supported the impedance findings.

Competing interests

The authors declare that they have no competing interests.

Authors’ contributions

The work presented here was performed in collaboration of all authors. MK carried out the fabrication and electrical characterization of Pd-sensitized ZnO nanorods and drafted the manuscript. MEA and SMUA proofread the manuscript and corrected the language. UH supervised the work. SBAH provides the lab facilities for the XRD measurements. All authors read and approved the final manuscript.

Contributor Information

Muhammad Kashif, Email: kashif_bme@yahoo.com.

Md Eaqub Ali, Email: eaqubali@gmail.com.

Syed M Usman Ali, Email: uashah68@neduet.edu.pk.

Uda Hashim, Email: uda@unimap.edu.my.

Sharifah Bee Abd Hamid, Email: sharifahbee@um.edu.my.

Acknowledgments

MK acknowledges the financial support of the Malaysian Ministry of Higher Education (MOHE) through FRGS grant number 9003-00276 to Professor UH. The authors are thankful to the technical staff of the Institute of Nano Electronic Engineering and School of Microelectronic Engineering in Universiti Malaysia Perlis for their kind support in performing this research.

References

  1. Fardindoost S, Iraji zad A, Rahimi F, Ghasempour R. Pd doped WO3 films prepared by sol–gel process for hydrogen sensing. Int J Hydrogen Energ. 2010;35:854–860. doi: 10.1016/j.ijhydene.2009.11.033. [DOI] [Google Scholar]
  2. Al-Hardan NH, Abdullah MJ, Aziz AA. Sensing mechanism of hydrogen gas sensor based on RF-sputtered ZnO thin films. Int J Hydrogen Energ. 2010;35:4428–4434. doi: 10.1016/j.ijhydene.2010.02.006. [DOI] [Google Scholar]
  3. Ingimundarson A, Stefanopoulou AG, McKay DA. Model-based detection of hydrogen leaks in a fuel cell stack. Control Systems Technology, IEEE Transactions. 2008;16:1004–1012. [Google Scholar]
  4. Verhelst S, Sierens R. Hydrogen engine-specific properties. Int J Hydrogen Energ. 2001;26:987–990. doi: 10.1016/S0360-3199(01)00026-X. [DOI] [Google Scholar]
  5. Pundt A, Kirchheim R. Hydrogen in metals: microstructural aspects. Annu Rev Mater Res. 2006;36:555–608. doi: 10.1146/annurev.matsci.36.090804.094451. [DOI] [Google Scholar]
  6. Bamsaoud SF, Rane SB, Karekar RN, Aiyer RC. Nano particulate SnO2 based resistive films as a hydrogen and acetone vapour sensor. Sensor Actuat B: Chem. 2011;153:382–391. doi: 10.1016/j.snb.2010.11.003. [DOI] [Google Scholar]
  7. Wang Y-D, Ma C-L, Wu X-H, Sun X-D, Li H-D. Electrical and gas-sensing properties of mesostructured tin oxide-based H2 sensor. Sensor Actuat B: Chem. 2002;85:270–276. doi: 10.1016/S0925-4005(02)00131-4. [DOI] [Google Scholar]
  8. Tianshu Z, Hing P, Li Y, Jiancheng Z. Selective detection of ethanol vapor and hydrogen using Cd-doped SnO2-based sensors. Sensor Actuat B: Chem. 1999;60:208–215. doi: 10.1016/S0925-4005(99)00272-5. [DOI] [Google Scholar]
  9. Lupan O, Chai G, Chow L. Fabrication of ZnO nanorod-based hydrogen gas nanosensor. Microelectron J. 2007;38:1211–1216. doi: 10.1016/j.mejo.2007.09.004. [DOI] [Google Scholar]
  10. Garcia-Serrano O, Goiz O, Chavez F, Romero-Paredes G, Pena-Sierra R. Sensors, 2011. IEEE:Oct 28-31 2011; Limerick, Ireland. Piscataway: IEEE; 2011. Pd-decorated ZnO and WO3 nanowires for sensing applications; pp. 998–1001. [Google Scholar]
  11. Yamazoe N, Kurokawa Y, Seiyama T. Effects of additives on semiconductor gas sensors. Sensors and Actuator. 1983;4:283–289. [Google Scholar]
  12. Choi J-K, Hwang I-S, Kim S-J, Park J-S, Park S-S, Jeong U, Kang YC, Lee J-H. Design of selective gas sensors using electrospun Pd-doped SnO2 hollow nanofibers. Sensor Actuat B: Chem. 2010;150:191–199. doi: 10.1016/j.snb.2010.07.013. [DOI] [Google Scholar]
  13. Lupan O, Chow L, Chai G. A single ZnO tetrapod-based sensor. Sensor Actuat B: Chem. 2009;141:511–517. doi: 10.1016/j.snb.2009.07.011. [DOI] [Google Scholar]
  14. Han N, Tian Y, Wu X, Chen Y. Improving humidity selectivity in formaldehyde gas sensing by a two-sensor array made of Ga-doped ZnO. Sensor Actuat B: Chem. 2009;138:228–235. doi: 10.1016/j.snb.2009.01.054. [DOI] [Google Scholar]
  15. Lee JM, Park J-e, Kim S, Kim S, Lee E, Kim S-J, Lee W. Ultra-sensitive hydrogen gas sensors based on Pd-decorated tin dioxide nanostructures: room temperature operating sensors. Int J Hydrogen Energ. 2010;35:12568–12573. doi: 10.1016/j.ijhydene.2010.08.026. [DOI] [Google Scholar]
  16. Chen K, Xie K, Feng X, Wang S, Hu R, Gu H, Li Y. An excellent room-temperature hydrogen sensor based on titania nanotube-arrays. Int J Hydrogen Energ. 2012;37:13602–13609. doi: 10.1016/j.ijhydene.2012.06.067. [DOI] [Google Scholar]
  17. Kanungo J, Saha H, Basu S. Pd sensitized porous silicon hydrogen sensor—influence of ZnO thin film. Sensor Actuat B: Chem. 2010;147:128–136. doi: 10.1016/j.snb.2010.03.044. [DOI] [Google Scholar]
  18. Zhang C, Boudiba A, Navio C, Bittencourt C, Olivier M-G, Snyders R, Debliquy M. Highly sensitive hydrogen sensors based on co-sputtered platinum-activated tungsten oxide films. Int J Hydrogen Energ. 2011;36:1107–1114. doi: 10.1016/j.ijhydene.2010.10.011. [DOI] [Google Scholar]
  19. Ren S, Fan G, Qu S, Wang Q. Enhanced H2 sensitivity at room temperature of ZnO nanowires functionalized by Pd nanoparticles. J Appl Phys. 2011;110:084312–084316. doi: 10.1063/1.3647310. [DOI] [Google Scholar]
  20. Usman Ali SM, Alvi NH, Ibupoto Z, Nur O, Willander M, Danielsson B. Selective potentiometric determination of uric acid with uricase immobilized on ZnO nanowires. Sensor Actuat B: Chem. 2011;152:241–247. doi: 10.1016/j.snb.2010.12.015. [DOI] [Google Scholar]
  21. Wang HT, Kang BS, Ren F, Tien LC, Sadik PW, Norton DP, Pearton SJ, Lin J. Detection of hydrogen at room temperature with catalyst-coated multiple ZnO nanorods. Appl Phys A. 2005;81:1117–1119. doi: 10.1007/s00339-005-3310-5. [DOI] [Google Scholar]
  22. Wang HT, Kang BS, Ren F, Tien LC, Sadik PW, Norton DP, Pearton SJ, Lin J. Hydrogen-selective sensing at room temperature with ZnO nanorods. Appl Phys Lett. 2005;86:243503–243505. doi: 10.1063/1.1949707. [DOI] [Google Scholar]
  23. Kashif M, Usman Ali SM, Ali ME, Abdulgafour HI, Hashim U, Willander M, Hassan Z. Morphological, optical, and Raman characteristics of ZnO nanoflakes prepared via a sol–gel method. Phys Status Solidi (A) 2012;209:143–147. doi: 10.1002/pssa.201127357. [DOI] [Google Scholar]
  24. Kashif M, Hashim U, Ali ME, Usman Ali SM, Rusop M, Ibupoto ZH, Willander M. Effect of different seed solutions on the morphology and electrooptical properties of ZnO nanorods. J Nanomater. [DOI]
  25. Lupan O, Emelchenko GA, Ursaki VV, Chai G, Redkin AN, Gruzintsev AN, Tiginyanu IM, Chow L, Ono LK, Roldan Cuenya B, Heinrich H, Yakimov EE. Synthesis and characterization of ZnO nanowires for nanosensor applications. Mater Res Bull. 2010;45:1026–1032. doi: 10.1016/j.materresbull.2010.03.027. [DOI] [Google Scholar]
  26. Machado G, Guerra DN, Leinen D, Ramos-Barrado JR, Marotti RE, Dalchiele EA. Indium doped zinc oxide thin films obtained by electrodeposition. Thin Solid Films. 2005;490:124–131. doi: 10.1016/j.tsf.2005.04.042. [DOI] [Google Scholar]
  27. Barsan N, Weimar U. Conduction model of metal oxide gas sensors. J Electroceram. 2001;7:143–167. doi: 10.1023/A:1014405811371. [DOI] [Google Scholar]
  28. Barsan N, Weimar U. Understanding the fundamental principles of metal oxide based gas sensors; the example of CO sensing with SnO2 sensors in the presence of humidity. J Phys: Condensed Matter. 2003;15:R813–R839. doi: 10.1088/0953-8984/15/20/201. [DOI] [Google Scholar]
  29. Lee Y-M, Huang C-M, Chen H-W, Yang H-W. Low temperature solution-processed ZnO nanorod arrays with application to liquid ethanol sensors. Sensor Actuat A: Phys. 2013;189:307–312. [Google Scholar]
  30. Sen S, Muthe KP, Joshi N, Gadkari SC, Gupta SK, Jagannath, Roy M, Deshpande SK, Yakhmi JV. Room temperature operating ammonia sensor based on tellurium thin films. Sensor Actuat B: Chem. 2004;98:154–159. doi: 10.1016/j.snb.2003.10.004. [DOI] [Google Scholar]
  31. Ponce MA, Bueno PR, Varela J, Castro MS, Aldao CM. Impedance spectroscopy analysis of SnO2 thick-films gas sensors. J Mater Sci: Mater El. 2008;19:1169–1175. doi: 10.1007/s10854-007-9517-9. [DOI] [Google Scholar]
  32. Aguir K, Labidi A, Lambert-Mauriata C. Sensors, 2006. 5th IEEE Conference: Oct 22-25 2006; Daegu, Korea. Piscataway: IEEE; 2006. Impedance spectroscopy to identify the conduction mechanisms in WO3 sensors; pp. 267–270. [Google Scholar]
  33. Barik SK, Choudhary RNP, Mahapatra PK. Impedance spectroscopy study of Na1/2Sm1/2TiO3 ceramic. Appl Phys A. 2007;88:217–222. doi: 10.1007/s00339-007-3990-0. [DOI] [Google Scholar]
  34. Saif AA, Poopalan P. Correlation between the chemical composition and the conduction mechanism of barium strontium titanate thin films. J Alloy Compd. 2011;509:7210–7215. doi: 10.1016/j.jallcom.2011.04.068. [DOI] [Google Scholar]
  35. Idrees M, Nadeem M, Mehmood M, Atif M, Keun Hwa Chae HK, Hassan MM. Impedance spectroscopic investigation of delocalization effects of disorder induced by Ni doping in LaFeO3. J Phys D Appl Phys. 2011;44:105401–105412. doi: 10.1088/0022-3727/44/10/105401. [DOI] [Google Scholar]
  36. Seitz M, Hampton F, Richmond W. In: Advances in Ceramics, 7. Yan MF, Heuer AH, editor. Columbus: The American Ceramic Society Inc; 1983. Influence of chemisorbed oxygen on the ac electrical behavior of polycrystalline ZnO; pp. 60–70. [Google Scholar]
  37. Lupan O, Chai G, Chow L. Novel hydrogen gas sensor based on single ZnO nanorod. Microelectron Eng. 2008;85:2220–2225. doi: 10.1016/j.mee.2008.06.021. [DOI] [Google Scholar]
  38. Mitra P, Chatterjee AP, Maiti HS. ZnO thin film sensor. Mater Lett. 1998;35:33–38. doi: 10.1016/S0167-577X(97)00215-2. [DOI] [Google Scholar]
  39. Yamazoe N, Fuchigami J, Kishikawa M, Seiyama T. Interactions of tin oxide surface with O2, H2O AND H2. Surf Sci. 1979;86:335–344. [Google Scholar]
  40. Egashira M, Shimizu Y, Takao Y, Sako S. Variations in I–V characteristics of oxide semiconductors induced by oxidizing gases. Sensor Actuat B: Chem. 1996;35:62–67. doi: 10.1016/S0925-4005(96)02015-1. [DOI] [Google Scholar]
  41. Shimizu Y, Kuwano N, Hyodo T, Egashira M. High H2 sensing performance of anodically oxidized TiO2 film contacted with Pd. Sensor Actuat B: Chem. 2002;83:195–201. doi: 10.1016/S0925-4005(01)01040-1. [DOI] [Google Scholar]

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