Table 2.
| |||||||
---|---|---|---|---|---|---|---|
11 |
11/12e | ||||||
entry | cat. | cat. load., mol %b | solvent | time, min | conv, %c | E/Z d | |
1 | 1a | 2.5 | C6H6 | 15 | 25 | 0.97 | 13 |
120 | 32 | 1.4 | 2.9 | ||||
2 | 4 | 2.5 | C6H6 | 45 | 24 | 0.97 | 26 |
120 | 29 | 1.1 | 19 |
All reactions were carried out using 0.005 mmol of catalyst, 0.20 mmol of 8 and 0.10 mmol of tridecane (internal standard for GC analysis) in 1.0 ml of C6H6 at 23°C.
Based on 8.
Conversion of 8 to 11 determined by GC analysis.
Molar ratio of E isomer and Z isomer of 11 determined by GC analysis.
Determined by GC analysis.