Table 4. A Guide to Chiral Dirhodium-(II) Catalyzed Cyclopropanation.
| |||
---|---|---|---|
Ar | catalyst | yield (%) | ee(%) |
Rh2(R-DOSP)4 | 66-93 | 82-92 | |
Rh2(S-PTAD)4 | 80-87 | 80-97 | |
Rh2(R-BNP)4 | 63-93 | 88-97 |
| |||
---|---|---|---|
Ar | catalyst | yield (%) | ee(%) |
Rh2(R-DOSP)4 | 66-93 | 82-92 | |
Rh2(S-PTAD)4 | 80-87 | 80-97 | |
Rh2(R-BNP)4 | 63-93 | 88-97 |