Table 3.
Hydrogen Bonds in Diclofenac Co-Crystals.
| Bond length, D-H (Å) | Bond length, H⋯A (Å) | Bond length, D⋯A (Å) | Bond angle, D-H⋯A (°) | |
|---|---|---|---|---|
| (DC)·(AP) | ||||
| O(11) H(11) N(31) | 0.940(18) | 1.682(18) | 2.6130(14) | 170.2(17) |
| N(12) H(12) O(11) | 0.873(17) | 2.305(17) | 3.0510(13) | 143.5(14) |
| N(32) H(32A) O(12) | 0.931(18) | 2.000(19) | 2.9191(15) | 168.7(16) |
| N(32) H(32B) N(33) | 0.876(18) | 2.153(19) | 3.0286(15) | 176.9(17) |
| (DC)·(AMP) | ||||
| O(11) H(11) N(31) | 0.98(4) | 1.68(4) | 2.642(3) | 169(4) |
| N(12) H(12) O(12) | 1.00(4) | 2.11(4) | 2.957(3) | 142(3) |
| N(32) H(32A) O(12) | 0.94(4) | 2.13(4) | 3.071(4) | 172(3) |
| N(32) H(32B) N(33) | 0.86(4) | 2.27(4) | 3.111(4) | 166(3) |
| (DC)·(ACMP) | ||||
| O(11) H(11) N(31A) | 0.866(17) | 1.830(18) | 2.688(5) | 170.7(17) |
| N(12) H(12) O(12) | 0.812(16) | 2.275(17) | 2.9793(16) | 145.4(16) |
| N(32A) H(32A) O(12) | 0.85(2) | 2.22(2) | 3.045(7) | 163.4(18) |
| N(32A) H(32B) N(33A) | 0.76(2) | 2.44(2) | 3.193(8) | 172(2) |
| N(32B) H(32C) O(12) | 0.88 | 2.29 | 3.15(3) | 167.0 |
| N(32B) H(32D) N(33A) | 0.88 | 2.26 | 3.13(2) | 170.8 |