Abstract
The asymmetric unit of the title compound, C18H30O2, contains one half-molecule situated on an inversion center. The alkyl chain adopts a fully extended all-trans conformation. The C atoms of the alkyl chain are almost coplanar, with a maximum deviation of 0.042 (6) Å from the mean plane,which is inclined to the central benzene ring by 6.80 (9)°. The crystal packing exhibits no short intermolecular contacts.
Related literature
For the synthesis and applications of the title compound, see: Ramesh & Thomas (2010 ▶); Mayor & Didschies (2003 ▶); Choi et al. (2006 ▶). For the crystal structures of related compounds, see: Li et al. (2008 ▶); Thevenet et al. (2010 ▶).
Experimental
Crystal data
C18H30O2
M r = 278.42
Monoclinic,
a = 18.853 (12) Å
b = 7.512 (5) Å
c = 6.364 (4) Å
β = 95.674 (10)°
V = 896.9 (11) Å3
Z = 2
Mo Kα radiation
μ = 0.07 mm−1
T = 298 K
0.06 × 0.05 × 0.04 mm
Data collection
Bruker APEXII CCD diffractometer
Absorption correction: multi-scan (SADABS; Bruker, 2001 ▶) T min = 0.996, T max = 0.997
6024 measured reflections
1552 independent reflections
760 reflections with I > 2σ(I)
R int = 0.099
Refinement
R[F 2 > 2σ(F 2)] = 0.067
wR(F 2) = 0.238
S = 0.99
1552 reflections
92 parameters
H-atom parameters constrained
Δρmax = 0.17 e Å−3
Δρmin = −0.15 e Å−3
Data collection: APEX2 (Bruker, 2001 ▶); cell refinement: SAINT (Bruker, 2001 ▶); data reduction: SAINT; program(s) used to solve structure: SHELXS97 (Sheldrick, 2008 ▶); program(s) used to refine structure: SHELXL97 (Sheldrick, 2008 ▶); molecular graphics: SHELXTL (Sheldrick, 2008 ▶); software used to prepare material for publication: SHELXTL.
Supplementary Material
Crystal structure: contains datablock(s) I, global. DOI: 10.1107/S1600536813029024/cv5434sup1.cif
Structure factors: contains datablock(s) I. DOI: 10.1107/S1600536813029024/cv5434Isup2.hkl
Supplementary material file. DOI: 10.1107/S1600536813029024/cv5434Isup3.cml
Acknowledgments
The author is grateful to Hubei University of Arts and Science for financial support.
supplementary crystallographic information
1. Comment
The title compound is an important intermediate in the synthesis of conjugated polymers (Mayor & Didschies, 2003; Choi et al., 2006) and supramolecular networks (Ramesh & Thomas, 2010). Herein we report its crystal structure.
In the molecule (Fig. 1), the alkyl chain adopts a fully extended all-trans conformation. The C-atoms of the alkyl chain are almost coplanar with the maximum deviation of 0.042 (6) Å from the mean plane, and this mean plane is inclined to the central benzene ring by 6.80 (9)°. The crystal packing exhibits no short intermolecular contacts.
2. Experimental
The title compound was synthesized according to the known method (Ramesh & Thomas, 2010). Crystals suitable for single-crystal X-ray diffraction were grown by slow evaporation of the solution in hexane-MeOH (5:1).
3. Refinement
All H atoms were positioned geometrically (C—H = 0.93–0.97 Å) and refined as riding, allowing for free rotation of the methyl groups. The constraint Uiso(H) = 1.2 Ueq(C) or 1.5 Ueq(C) (methyl C) was applied.
Figures
Crystal data
C18H30O2 | F(000) = 308 |
Mr = 278.42 | Dx = 1.031 Mg m−3 |
Monoclinic, P21/c | Mo Kα radiation, λ = 0.71073 Å |
Hall symbol: -P 2ybc | Cell parameters from 885 reflections |
a = 18.853 (12) Å | θ = 2.2–21.8° |
b = 7.512 (5) Å | µ = 0.07 mm−1 |
c = 6.364 (4) Å | T = 298 K |
β = 95.674 (10)° | Block, colourless |
V = 896.9 (11) Å3 | 0.06 × 0.05 × 0.04 mm |
Z = 2 |
Data collection
Bruker APEXII CCD diffractometer | 1552 independent reflections |
Radiation source: fine-focus sealed tube | 760 reflections with I > 2σ(I) |
Graphite monochromator | Rint = 0.099 |
φ and ω scans | θmax = 25.0°, θmin = 2.2° |
Absorption correction: multi-scan (SADABS; Bruker, 2001) | h = −22→21 |
Tmin = 0.996, Tmax = 0.997 | k = −8→8 |
6024 measured reflections | l = −7→7 |
Refinement
Refinement on F2 | Primary atom site location: structure-invariant direct methods |
Least-squares matrix: full | Secondary atom site location: difference Fourier map |
R[F2 > 2σ(F2)] = 0.067 | Hydrogen site location: inferred from neighbouring sites |
wR(F2) = 0.238 | H-atom parameters constrained |
S = 0.99 | w = 1/[σ2(Fo2) + (0.1237P)2] where P = (Fo2 + 2Fc2)/3 |
1552 reflections | (Δ/σ)max < 0.001 |
92 parameters | Δρmax = 0.17 e Å−3 |
0 restraints | Δρmin = −0.15 e Å−3 |
Special details
Geometry. All e.s.d.'s (except the e.s.d. in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell e.s.d.'s are taken into account individually in the estimation of e.s.d.'s in distances, angles and torsion angles; correlations between e.s.d.'s in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell e.s.d.'s is used for estimating e.s.d.'s involving l.s. planes. |
Refinement. Refinement of F2 against ALL reflections. The weighted R-factor wR and goodness of fit S are based on F2, conventional R-factors R are based on F, with F set to zero for negative F2. The threshold expression of F2 > σ(F2) is used only for calculating R-factors(gt) etc. and is not relevant to the choice of reflections for refinement. R-factors based on F2 are statistically about twice as large as those based on F, and R- factors based on ALL data will be even larger. |
Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Å2)
x | y | z | Uiso*/Ueq | ||
C1 | 0.01445 (17) | 0.4133 (3) | 0.8176 (4) | 0.0693 (9) | |
H1 | 0.0241 | 0.3542 | 0.6952 | 0.083* | |
C2 | 0.06718 (16) | 0.5102 (3) | 0.9318 (4) | 0.0664 (8) | |
C3 | 0.05200 (17) | 0.5954 (4) | 1.1147 (4) | 0.0700 (8) | |
H3 | 0.0876 | 0.6597 | 1.1928 | 0.084* | |
C4 | 0.15191 (16) | 0.4640 (4) | 0.6777 (4) | 0.0795 (9) | |
H4A | 0.1171 | 0.5055 | 0.5661 | 0.095* | |
H4B | 0.1514 | 0.3348 | 0.6782 | 0.095* | |
C5 | 0.22423 (18) | 0.5306 (5) | 0.6427 (5) | 0.0905 (10) | |
H5A | 0.2228 | 0.6595 | 0.6360 | 0.109* | |
H5B | 0.2571 | 0.4978 | 0.7634 | 0.109* | |
C6 | 0.25233 (18) | 0.4623 (5) | 0.4483 (5) | 0.0959 (11) | |
H6A | 0.2207 | 0.4996 | 0.3269 | 0.115* | |
H6B | 0.2520 | 0.3332 | 0.4520 | 0.115* | |
C7 | 0.3266 (2) | 0.5246 (5) | 0.4201 (6) | 0.1107 (13) | |
H7A | 0.3262 | 0.6535 | 0.4098 | 0.133* | |
H7B | 0.3576 | 0.4929 | 0.5452 | 0.133* | |
C8 | 0.3570 (3) | 0.4521 (8) | 0.2347 (7) | 0.1542 (19) | |
H8A | 0.3263 | 0.4849 | 0.1095 | 0.185* | |
H8B | 0.3569 | 0.3232 | 0.2443 | 0.185* | |
C9 | 0.4300 (3) | 0.5113 (10) | 0.2076 (9) | 0.202 (3) | |
H9A | 0.4313 | 0.6389 | 0.2018 | 0.303* | |
H9B | 0.4444 | 0.4631 | 0.0787 | 0.303* | |
H9C | 0.4619 | 0.4704 | 0.3245 | 0.303* | |
O1 | 0.13529 (11) | 0.5307 (3) | 0.8769 (3) | 0.0818 (8) |
Atomic displacement parameters (Å2)
U11 | U22 | U33 | U12 | U13 | U23 | |
C1 | 0.106 (2) | 0.0549 (16) | 0.0456 (15) | −0.0004 (15) | 0.0022 (15) | −0.0034 (12) |
C2 | 0.089 (2) | 0.0570 (17) | 0.0516 (15) | −0.0033 (13) | −0.0020 (13) | 0.0104 (13) |
C3 | 0.103 (2) | 0.0531 (16) | 0.0516 (15) | −0.0086 (14) | −0.0060 (13) | 0.0021 (12) |
C4 | 0.099 (2) | 0.0787 (19) | 0.0600 (18) | 0.0063 (16) | 0.0020 (14) | −0.0041 (15) |
C5 | 0.105 (2) | 0.085 (2) | 0.081 (2) | 0.0025 (18) | 0.0044 (16) | −0.0080 (17) |
C6 | 0.100 (3) | 0.102 (3) | 0.086 (2) | 0.0084 (19) | 0.0097 (17) | −0.0030 (19) |
C7 | 0.108 (3) | 0.116 (3) | 0.108 (3) | 0.002 (2) | 0.013 (2) | −0.002 (2) |
C8 | 0.140 (4) | 0.200 (5) | 0.127 (4) | 0.002 (4) | 0.041 (3) | −0.017 (4) |
C9 | 0.140 (4) | 0.272 (9) | 0.205 (6) | −0.003 (4) | 0.070 (4) | −0.004 (5) |
O1 | 0.0997 (16) | 0.0855 (15) | 0.0591 (12) | −0.0089 (11) | 0.0017 (10) | −0.0092 (10) |
Geometric parameters (Å, º)
C1—C3i | 1.366 (4) | C5—H5B | 0.9700 |
C1—C2 | 1.380 (4) | C6—C7 | 1.505 (5) |
C1—H1 | 0.9300 | C6—H6A | 0.9700 |
C2—O1 | 1.372 (3) | C6—H6B | 0.9700 |
C2—C3 | 1.383 (4) | C7—C8 | 1.467 (5) |
C3—C1i | 1.366 (4) | C7—H7A | 0.9700 |
C3—H3 | 0.9300 | C7—H7B | 0.9700 |
C4—O1 | 1.427 (3) | C8—C9 | 1.472 (6) |
C4—C5 | 1.490 (4) | C8—H8A | 0.9700 |
C4—H4A | 0.9700 | C8—H8B | 0.9700 |
C4—H4B | 0.9700 | C9—H9A | 0.9600 |
C5—C6 | 1.484 (4) | C9—H9B | 0.9600 |
C5—H5A | 0.9700 | C9—H9C | 0.9600 |
C3i—C1—C2 | 119.7 (3) | C7—C6—H6A | 108.8 |
C3i—C1—H1 | 120.2 | C5—C6—H6B | 108.8 |
C2—C1—H1 | 120.2 | C7—C6—H6B | 108.8 |
O1—C2—C1 | 124.7 (3) | H6A—C6—H6B | 107.7 |
O1—C2—C3 | 116.0 (2) | C8—C7—C6 | 115.0 (4) |
C1—C2—C3 | 119.3 (3) | C8—C7—H7A | 108.5 |
C1i—C3—C2 | 121.1 (2) | C6—C7—H7A | 108.5 |
C1i—C3—H3 | 119.5 | C8—C7—H7B | 108.5 |
C2—C3—H3 | 119.5 | C6—C7—H7B | 108.5 |
O1—C4—C5 | 107.4 (3) | H7A—C7—H7B | 107.5 |
O1—C4—H4A | 110.2 | C7—C8—C9 | 115.2 (5) |
C5—C4—H4A | 110.2 | C7—C8—H8A | 108.5 |
O1—C4—H4B | 110.2 | C9—C8—H8A | 108.5 |
C5—C4—H4B | 110.2 | C7—C8—H8B | 108.5 |
H4A—C4—H4B | 108.5 | C9—C8—H8B | 108.5 |
C6—C5—C4 | 114.6 (3) | H8A—C8—H8B | 107.5 |
C6—C5—H5A | 108.6 | C8—C9—H9A | 109.5 |
C4—C5—H5A | 108.6 | C8—C9—H9B | 109.5 |
C6—C5—H5B | 108.6 | H9A—C9—H9B | 109.5 |
C4—C5—H5B | 108.6 | C8—C9—H9C | 109.5 |
H5A—C5—H5B | 107.6 | H9A—C9—H9C | 109.5 |
C5—C6—C7 | 113.9 (3) | H9B—C9—H9C | 109.5 |
C5—C6—H6A | 108.8 | C2—O1—C4 | 118.7 (2) |
C3i—C1—C2—O1 | −178.8 (2) | C5—C6—C7—C8 | 177.1 (4) |
C3i—C1—C2—C3 | 0.7 (4) | C6—C7—C8—C9 | −179.4 (4) |
O1—C2—C3—C1i | 178.9 (2) | C1—C2—O1—C4 | 6.9 (4) |
C1—C2—C3—C1i | −0.7 (4) | C3—C2—O1—C4 | −172.7 (2) |
O1—C4—C5—C6 | 175.7 (2) | C5—C4—O1—C2 | 170.4 (2) |
C4—C5—C6—C7 | −177.6 (3) |
Symmetry code: (i) −x, −y+1, −z+2.
Footnotes
Supplementary data and figures for this paper are available from the IUCr electronic archives (Reference: CV5434).
References
- Bruker (2001). APEX2, SAINT and SADABS Bruker AXS Inc., Madison, Wisconsin, USA.
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- Li, Y.-F., Xu, C., Cen, F.-F., Wang, Z.-Q. & Zhang, Y.-Q. (2008). Acta Cryst. E64, o1930. [DOI] [PMC free article] [PubMed]
- Mayor, M. & Didschies, C. (2003). Angew. Chem. Int. Ed. 42, 3176–3179. [DOI] [PubMed]
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- Sheldrick, G. M. (2008). Acta Cryst. A64, 112–122. [DOI] [PubMed]
- Thevenet, D., Neier, R., Sereda, O., Neels, A. & Stoeckli-Evans, H. (2010). Acta Cryst. E66, o837–o838. [DOI] [PMC free article] [PubMed]
Associated Data
This section collects any data citations, data availability statements, or supplementary materials included in this article.
Supplementary Materials
Crystal structure: contains datablock(s) I, global. DOI: 10.1107/S1600536813029024/cv5434sup1.cif
Structure factors: contains datablock(s) I. DOI: 10.1107/S1600536813029024/cv5434Isup2.hkl
Supplementary material file. DOI: 10.1107/S1600536813029024/cv5434Isup3.cml