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Proceedings of the National Academy of Sciences of the United States of America logoLink to Proceedings of the National Academy of Sciences of the United States of America
. 1971 Jul;68(7):1467–1468. doi: 10.1073/pnas.68.7.1467

Acyclic Ketones in the Defensive Secretion of a “Daddy Longlegs” (Leiobunum vittatum)

J Meinwald *, A F Kluge *, J E Carrel , T Eisner
PMCID: PMC389219  PMID: 5283937

Abstract

The defensive secretion of the “daddy longlegs” Leiobunum vittatum was analyzed and found to contain the acyclic ketones 4-methylheptan-3-one and E-4,6-dimethyl-6-octen-3-one as its major organic components. Although 4-methylheptan-3-one has been found previously as an alarm substance in certain ant genera, the second component, whose structure is confirmed by synthesis, is new.

Keywords: Arachnida, Opiliones

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Selected References

These references are in PubMed. This may not be the complete list of references from this article.

  1. Eisner T., Meinwald J. Defensive secretions of arthropods. Science. 1966 Sep 16;153(3742):1341–1350. doi: 10.1126/science.153.3742.1341. [DOI] [PubMed] [Google Scholar]

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