Abstract
The solvolyses of phosphorocreatine (creatine phosphate) and models for phosphorocreatine have been investigated and the results are applied to the mechanism of action of creatine kinase (EC 2.7.3.2). A metaphosphate intermediate appears to be involved.
Keywords: solvolyses, creatinine, dimethylphosphoroguanidinate, methylbenzylphosphoroguanidinate, reaction kinetics
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